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By Luana De Lucca de Costa

A microestrutura resultante do processo de forjamento é influenciada por variáveis como temperatura, deformação, tamanho de grão austenítico inicial e taxa de resfriamento. A proposta deste trabalho é estudar o comportamento termomecânico do aço ABNT 4140 mantido nas temperaturas de 900, 1000, 1100 e 1200ºC por 22, 66 e 200 minutos e, posteriormente, forjado e analisar a influência da temperatura sobre os grãos austeníticos que caracterizam os fenômenos metalúrgicos ocorridos.

Aug 16, 2017

By Philip R. Whitney

Precipitation of hydrous manganese/iron oxides in streams can be readily observed in much of the northeastern United States, and is apparently a common phenomenon in other glaciated areas (1,2,3,4). Deposition occurs when Mn-enriched ground or surface water enters the stream environment and encounters conditions of higher Eh and pH. The preferred location for deposition is in shallow, fast-flowing segments of stream; the oxides usually form as coatings on detrital material. The experimental studies of Hem(5) and a considerable amount of work on marine and lacustrine manganese nodules(6,7,8) suggest that given an appropriate substrate, deposition of manganese oxides may occur even when the water is undersaturated in Mn with respect to the oxides, due to catalysis by organisms or by silicate, carbonate, or ferric hydroxide surfaces. Once begun, manganese oxide deposition is autocatalytic (9). Studies of the distribution of oxides in various size fractions of stream sediments indicate that the thickness and prevalence of the coatings commonly increases with increasing particle size in the coarse sand and gravel size ranges. Figures 1 and 2 show a fairly typical distribution of leachable metals over nine size fractions from 62 microns up to 8-16 mm. The leaching solution used was neutral ammonium citrate with hydroxylamine hydrochloride, which effectively removes the oxide coatings without significantly attacking most silicates, carbonates or sulfides. Figure 1 shows metal content as ppm of the total sample; figure 2 shows' the same data as micrograms of metal per square millimeter of surface area.

Jan 1, 1975

By M. R. Geer

The cleaning of fine coal, particularly for metallurgical use, is receiving greater attention. An increase in the proportion of fine coal in the run-of-mine product has been created by changes in mining practice, and a concur-rent deterioration in the quality of the fines has occurred because of more widespread full-seam mining. These two factors, augmented by the depletion of premium beds of metallurgical coal in some areas and the resulting shift to "dirtier" beds, are providing the impetus for adoption of improved cleaning techniques. For example, froth flotation, which has been used for years in a few preparation plants, now is gaining more rapidly in acceptance. Similarly, the dense-medium cyclone, which is used widely in Europe for making difficult separations, recently has been introduced to the United States. Regardless of the cleaning process employed, the finer sizes of coal can be treated with maximum effectiveness only when they are removed from the run-of-mine product and treated separately. No present process can treat the full range of sizes together with complete effectiveness. Flotation is applicable only to the coal finer than a top size ranging between 14-and 48-mesh, and cyclones require removal of all material finer than 0.5 to 0.3 mm. from the feed. Thus, the trend toward more-effective cleaning of the fine coal imposes the attendant problem of fine screening. Whereas in the past there was little need to screen finer than about l/4-in., present developments indicate that fine screening will become increasingly prevalent.

Jan 1, 1960

By Mark Alan Marlkos

Blebs of solid bitumen from the Magmont West orebody of the Viburnum Trend were examined and analyzed in an attempt to relate hydrocarbon distribution and origin to ore genesis. The bitumen was calculated to be approximately 48 to 63 percent aliphatic and is considered to be a polymerized normal crude oil. Polymerization, which was probably caused by water-washing, hardened the bleb surfaces and appears to have "frozen" the blebs during primary migration from local source beds. Comparison of the bitumen to kerogen in local shaly partings strongly Indicates that the oil was derived locally. The polymerized oil blebs are considered to have been derived from a type II (marine) kerogen. Textural analyses indicate that oil migration occurred after lead-zinc mineralization and at temperatures that exceed normal ancient or present geothermal gradients. The following sequence of events is postulated for the Magmont West orebody: 1 Generation of hydrogen sulfide during diagenesis of a normal organic-rich carbonate sequence. 2 Introduction of pulses of hot, metal-rich fluids that resulted in: a Lead-zinc mineralization by the following reaction: Me++ + H2S ? MeS + 2H+ b Solution of carbonates by excess acid produced during the above reaction. c Brecciation of host rock in some cases. 3 Passages of the pulse resulted in: a Carbonate buffering of fluid system to more alkaline conditions. b Precipitation of dolomite c Slight temperature drop. 4 Eventually the high temperatures Introduced by heated brine caused oil generation and initiated primary migration. 5 Water-washing and mild biodegradation altered the hydrocarbon blebs to their present composition.

Jan 1, 2013

By D. Brabec

One of the analytical problems in exploration geochemistry is the choice of a method of sample attack which would be rapid, simple and reliable in terms of precision and discrimination between different concentration levels of elements sought. The wet sample attacks currently used in analysis of silicate rocks vary from total decomposition to leaching by weak extractants. The total decomposition of such materials is usually achieved either by alkaline fusion or hydrofluoric acid attack. The first method requires the use of platinum vessels which is both expensive and slow for batch operation. The second type of attack is more widely applied in rock geochemistry1, but it is still relatively slow for exploration purposes and requires extra care (especially when hydrofluoric acid is used in mixture with perchloric acid). Considerable improvement in speed can be achieved by using the sample attacks which release only part of the metal present in a rock.2,4 One of such attacks is the leaching of pulverized rocks by hot aqua regia.3 Another technique widely used in geochemical prospecting involves fusion of the samples with potassium pyrosulfate (or bisulfate) followed by an acid leach of the malt .5 One of the advantages of these techniques is the use of glassware in decomposition stage which considerably increases the analytical productivity. It should be noted that partial chemical attacks tend to extract from a rock mainly the non-silicate metal which may give results more significant for exploration purposes than the analysis for total metal.

Jan 1, 1970

By Angelus S. C. Owili-Eger

The investigation into the hydrologic and hydrogeochemical influence of longwall coal mining in the Appalachian coal basin was under- taken in response to the need to technically address problems of damaged or impaired well yields, and quality deterioration. Prior to this study, issues regarding reduced aquifer yields and degraded water quality had to be handled in a very qualitative manner. Such an approach would, in the long run, claim a heavy toll on the mining industry. The primary objective of this undertaking, therefore, was to provide sufficient and reliable information base for the determination of the local and possibly the regional effects of longwall mining on well yields, and the hydraulic and hydrogeochemical parameters of the immediate surface and subsurface water systems. Specifically, the program was designed to supply definitive data to answer the following series of questions: 1. Does longwall mining affect the quantity and quality of water in local wells above and adjacent to longwall panels and barrier pillars? 2. If the water quality is affected as soon as mining takes place, does it heal? or if it is not affected immediately, does it change over a longer period of time? 3. How do the aquifer water transmitting characteristics respond to induced physical ad hydrologic variations? 4. What is the extent of the various changes in quantity and quality of the water resources? 5. Should and can standard hydrologic evaluation techniques be used to determine the hydraulic properties of highly fractured zones located within a larger and less permeable aquifer?

Jan 1, 1983

By I. Cerny, M. Vanek, J. Hubácek

"SWOT analyses and the closely related TOWS matrix are frequent starting points for an organization to develop its strategy. The paper deals with the evaluation of the TOWS matrix and presents three novel approaches to evaluate the different factors of the TOWS matrix, namely (1) approach to evaluate the factors with identical weights; (2) approach to evaluate factors with their weights determined within the different quadrants of the TOWS matrix; and (3) approach to evaluate factors with weights determined within the whole TOWS matrix. The third approach has two variants. The proposed approaches to evaluate the TOWS matrix were tested on a SWOT analysis of a significant mining company in the Czech Republic. The results imply that the strategy W-T (weaknesses-threats) is recommended in three cases, while the strategy S-T (strengths-threats) is recommended once. The paper may be valuable for managers responsible for strategic planning.IntroductionThe process of human needs gratification has been closely connected with raw material resources of the planet. In the contemporary socio-economic conditions, the task of the mining company managers, apart from extracting mineral resources, is to meet the owners' intents.The managerial work itself becomes very complex. In mining companies in particular, the complexity is augmented by the characteristics of the business. Undoubtedly, the key factor is that mineral resources cannot be renewed or relocated. Stojanovi (2013) characterizes mining projects as involving great investments in finance and time, as well as consecutive decisions and a 'complex mosaic of numerous unknown factors that affect the value of the project'. He adds that mining projects are typified by a 'number of geological, technological, technical, economic, environmental, social, and financial risks' (Stojanovi , 2013).Inter alia, the managerial work may also be intese due to the dynamic internal and external conditions for the existence of any company (Vane? k, 2014). This tallies with Peter Drucker’s prediction in 1969; that the times at the turn of the millennium could be expected to be turbulent (Drucker, 1969)."

Dec 1, 2018

By W. C. Ellis

IN an ingot of germanium solidified progressively from the bottom by a method' devised by J. H. Scaff and H. C. Theuerer, examination discloses ex- IH. C. Torrey and C. A. Whitmer, Crystal Rectifiers. p. 364. 1948. New York. McGraw-Hill Pub. Co. tensive twin relationships. A slice taken about midway in a cylindrical ingot approximately 3/4 in. in diameter and 1 1/2 in. in length, after etching and polishing to delineate different orientations, is shown in fig. la. The orientations of the regions designated with letters were determined by Laue X-ray back-reflection methods and plotted on stereograms. The orientation relationships of the designated components were determined by comparing the values for the nine angles between the three respective cube poles of each orientation with the values calculated in a formal treatment of octahedral multiple twinning in cubic crystals. Germanium, diamond cubic in structure, has the octahedral twinning habit. I am indebted to K. H. Storks for the calculation of the angular relationships of cube poles in octahedral twinning to four orders. The set of values for the nine angles is distinctive of the order of twinning. Confirmation for a multiple twin relationship is obtained from the determined indices of the mirror planes. These exist for all orders of twinning through the third and for some of the fourth." If the orientations are not those for twinning, then the nine angles for the cube poles do not correspond in value and distribution to those formally calculated. Since all nine angles must correspond in values and distribution of values to the calculated ones, the Laue method with a precision of one or two degrees is adequate to establish or deny with confidence the existence of multiple twins. Regions of the same orientation can also frequently be identified by the optical reflections. For example, the narrow twin bands in A at 2: 00 o'clock have orientation B1. The interesting twin relationships shown schematically in fig. lb were found for the section in fig. la. Most of this slice was made up of orientation, A, appearing in widely separated regions. Of the four possible first order twins of A, three were present in this slice and are designated by B with subscripts. Four second order twins of A are designated by C with subscripts. It is worth emphasizing that two of these, C, and C,, are second orders of A through the first order missing in this section. Two regions, designated by D with subscripts are third order twins of A. D2 is a sixth order twin of D,. All orientations found were ascribable to multiple twinning, as if the orientations in this section originated earlier in solidification from a single nucleus. The presence of extensive multiple twinning to- gether with the absence of other orientations appears to be a characteristic result in many instances of solidification of germanium. Fertile conditions for twinning probably exist in the array of atoms in the diamond cubic structure. The high order twins in the section shown, it is reasonable to presume, are the result of progressive octahedral twinning through several generations in the material freezing earlier. Some of these generations do not appear in this section, it is suggested, because their orientations with respect to the growth direction were unfavorable for survival. The extensive twinning is probably promoted during solidification by constraint imposed by volume increase, and to an irregular growth front. Twinning may also be due, in part, to the attempt of the solidifying region to attain the orientation most favorable to the growth direction (maximum thermal gradient). The nucleus for a twinned orientation could have its origin in a "stacking fault" on the close-packed octahedral plane. Further work is being done in which the course of twinning throughout an ingot is being studied. The results appear to be important in the general theory of solidification.

Jan 1, 1951

By P. Favreau

"This paper describes the progress accomplished at the Noranda Technology Centre in the field of three-dimensional computer-aided underground blast design. Traditional methods of laying out underground blasts are reviewed, and the new computer-aided approach is described. Time savings achieved through the use of BLASTCAD can be advantageously used to better engineer blasts, using models and blast vibration analysis. Future work involving the attachment of blast models directly to the system is also addressed.IntroductionThe Noranda Technology Centre's (NTC) Environment and Mining Laboratory, in cooperation with the mining operations of the Noranda Group, is committed to the development and implementation of new technologies in the field of mineral extraction . Within the frame of its research program, the Blasting Technology Program is developing computer "" tools"" designed to assist the blasting engineer or technician. These computer "" tools"" are regrouped under a global software system called BLASTCAD.The BLASTCAD project started in 1990 at NTC. At that time computer programs designed to calculate and model various blasting parameters had been accumulated. These programs cam e from different sources and were mutually incompatible. Furthermore, they were developed as research programs with tittle effort spent on user interface. These programs are very useful, but are highly specialized, need large input files and can be quite tedious to use as ""standalone"" packages .Therefore, the situation being faced was one where all these programs were available at the Noranda Technology Centre, but not a t the operations. The two following options were then considered: 1. continue to run all the models and programs at the Noranda Technology Centre, and present results through reports to the mines, or2. regroup all the different programs under a single one that would make them share the same data base and be transported to the user. This second option is the one that was adopted; the result is BLASTCAD."

Jan 1, 1993

By E. V. Bratygin, S. P. Elnikova

"In the article carrying out technique of experiments for estimation of power efficiency of process of crushing in cone crushers «in a layer». The conformity of the granulometric characteristics of the crushed products obtained as a result of the tests, the theoretical equations for the size characteristics, and the choice of the optimal equation for the prediction of the granulometric characteristics of the final products obtained by crushing ""in a layer"". Optimization of granulometric composition of power of crushers working ""in a layer"" is carried out with the purpose of reduction of the electric power consumption at reception of a product of required quality. As a result of the experiments, dependencies are obtained, the relevance and applicability of the crushing process ""in the layer"" for obtaining crushed stone of improved quality is proved. INTRODUCTION A number of equations have been proposed for calculating the breakage energy. These include equations by Kirpichev and Kick, Rittinger and Bond (Bogdanov, Olevsky, 1982). Another equation for calculating the specific breakage work in breakage by impact and in stratum was proposed by Devyatkin (Boiko, 2003). In these equations, the breakage energy is proportional to the particle size raised to some power. In the equation proposed by Devyatkin, the ore piece thickness or the feed average diameter is used. The relationship between energy and breakage can be expressed as an equation (Lynch, 1981; Tikhonov, no. 3, 2008) where k is a coefficient characterizing the energy parameter depending on the strength of the feed, l is size in microns. The Rittinger formula is obtained for n = 2, the Kirpichev-Kick formula for n = 1, the Bond formula for n = 1.5. For n = 3 or higher, the equation describes fine and ultrafine grinding. R. Hookey proposed a formula (Lynch, 1981, Tikhonov, no. 3, 2008), where the size exponent n is substituted by a size function In all of the above equations, a single value of the feed and product size is used; for example, in the Bond equation, size is defined as the particle size of the 20% oversize (P80 and F80). However, a single size value can represent multiple distributions, making that the Bond method inappropriate for determining the size (Lynch, 1981). Describing an equation for estimating the grinding energy will allow to design the electric drive and ore preparation circuit for the given breakage method."

Jan 1, 2018

By Jorge Alberto Soares Tenório, Denise Crocce Romano Espinosa, Amilton Barbosa Botelho Junior

A new step in the Bayer process has been used to recover NaOH and to reduce its content in red mud. After digestion, the residue is separated from the Bayer liquor and goes through press filters, which enables the recovery of NaOH and decreases the moisture content. It is well known that red mud is one of the most important sources of scandium. For this reason, the goal of this work was to characterize a Brazilian red mud (BRM) for scandium recovery. The sample was collected after the press filter system process. Analysis of energy-dispersive X-ray fluorescence (EDXRF), scanning electron microscopy/energy-dispersive X-ray spectroscopy (SEM/EDS), and X-ray diffraction (XRD) was performed. Microwave digestion using an acid mixture was carried out to determine the concentration of the main elements. Fe2O3 represented 40% of the BRM, and the Sc concentration was 43 mg/kg. The SiO2 content was 24%, which is the highest value found in the literature, whereas the sodium concentration was the lowest. A literature review was carried out to compare results with BRM, as well as the current studies for recovery of scandium by the leaching/ion-exchange process. Scandium recovery using a leaching/ion exchange process may be possible with efficiency higher than 90%. The greatest challenge is the occurrence of silica gel formation during leaching.

Oct 19, 2020

By H. Dong, J. J. Valencia, L. Nastac

"A comprehensive computer model was developed to understand and optimize the centrifugal casting process for manufacturing TiC/Al-bronze friction drums. Performance of these components requires proper distribution of TiC particles, which is shown by dimensional analysis to be dominated by centrifugal buoyancy effects and solidification kinetics.The model addresses the following: (1) a rheology-viscosity model of the interference between moving particles, (2) engulfment (entrapment) or pushing of particles in the mushy region by the advancing solid/liquid interface, (3) nucleation and growth of equiaxed and eutectic phases, (4) effects of particle size, particle concentration, and cooling rate on the final grain size, and (5) the impingement effect of particles on the nucleation and growth kinetics of solidifying microstructure.Parametric studies were conducted using the computer model to investigate the effects of various process and material parameters on the distribution of TiC particles. The effects of the volume fraction, size, and morphology of the particles (including clusters and agglomerates) on the particle distribution were evaluated in detail. The complex interaction between the solidifying structure and insoluble ceramic particles in centrifugally-cast metal-matrix-composites was also investigated.The model predictions of particle distribution and microstructure were validated with experimental data for centrifugally-cast A356/SiC and TiC/Al-bronze alloys.This work was conducted by the National Center for Excellence in Metalworking Technology, operated by Concurrent Technologies Corporation under contract No. N00140-92- C-BC49 to the U.S. Navy as part of the U.S. Navy Manufacturing Technology Program."

Jan 1, 2000

By B. L. Averbach, E. E. Underwood

The vapor pressure of zinc in equilibrium with solid ß AgZn alloys has been measured by the dew-point method. The thermodynamic activities of silver, and the molar heats of formation have been calculated. Similar measurements have been made for the ternary alloys formed by adding gold to AgZn. An apparent particle size effect has been observed for AgZn filings. The vapor pressure of zinc over filings is 15 to 20 pct higher than over the solid alloys. STATISTICAL methods have been used to inter pret the thermodynamic activities of the components of a solid solution in terms of average equilibrium atomic configurations. In some cases, the atomic arrangements can be measured by X-ray methods, and the results are usually expressed in terms of short range order parameters. Only in the cases of Cu³Au and AgAu have there been sufficient X-ray and thermodynamic data to verify the assumed correlation between the X-ray and the thermodynamic measurements. In Cu³Au the agreement is good; negative deviations from Raoult's law are observed and the number of Cu-Au nearest neighbor pairs predicted on the basis of the thermodynamic treatments agrees quite well with the number of such pairs observed by the X-ray methods. The ß brass alloys present a different set of conditions. The ordering is so rapid in these alloys that the disordered state cannot be retained on quenching. In contrast, the disordered state in CuAu is easily retained on quenching. On heating, the ordered ß brass loses its long range order continuously as the critical temperature is approached; in Cuau the order decreases slightly on heating and then drops discontinuously to zero at the critical temperature. These differences indicate that the short range order configurations in ß brass systems may be of a different character than in Cudu systems. However, X-ray measurements of local order cannot be made in the Cu-Zn alloys because of the similarity in scattering factors. The alloy AgZn is isomorphous with CuZn, however, and recent experiments have indicated that there is a good possibility of observing short range order in this system. Another complication arises in the case of ß AgZn. The disordered body-centered cubic structure exists above 280°C. On quenching from above this temperature an ordered structure of the cesium-chloride type is formed. On slow cooling, however, a complex hexagonal structure, the 3 phase, is produced; and if an ordered quenched alloy is reheated the phase begins to form above 80°C. It is thus difficult to study local order by X-ray methods in single crystals of AgZn since the C phase formed on heating does not necessarily return to a single crystal of the original orientation. This problem has been met, however, by adding a few percent of gold to the AgZn. The gold suppresses the formation of the c

Jan 1, 1952

By MARIUS R. CIMPBELL, Edward W. Parker

DESCRIPTION. ACCORDING to the estimates prepared by the U. S. Geological Survey, the area underlain by workable coal-beds in the United States is 496,776 sq. miles. Of this total area, 480 sq. miles contain the entire anthracite coal-fields of Pennsylvania. The bituminous coal-fields are estimated to be contained in areas aggregating 250,051 sq. miles. The grade of coal between bituminous and lignite, and which is designated by the Geological Survey as " sub-bituminous," is estimated to be contained within areas aggregating 97,636 sq. miles, while the areas containing lignite aggregate 148,609 sq. miles. The coal-fields are divided, for the sake of convenience in classification, into six main provinces, as follows: 1. The Eastern. Province, containing the anthracite coal-fields of Pennsylvania and the bituminous coal-fields of the Appalachian region-namely, those of western Pennsylvania, Ohio, Virginia, West Virginia, Kentucky, Tennessee, Georgia, Alabama, and small outlying areas in North Carolina. 2. The Interior .Province, containing the bituminous coal-producing regions of Michigan, Illinois, Indiana, western Kentucky, Iowa, Kansas, Missouri, Oklahoma, Arkansas, and Texas. 3. The Gulf Province, containing the lignite-areas of Alabama, Mississippi, Louisiana, Arkansas, and Texas. 4. The Northern or Great Plains Province, containing the lignite and sub-bituminous areas of North and South Dakota, eastern Montana, and northeastern Wyoming. 5. The Rocky Mountain Province, containing the bituminous and sub-bituminous areas of western Montana and western Wyoming, Colorado, Utah, and New Mexico. 6. The Pacific Coast Province, containing-the areas of Washington, Oregon, and California.

Apr 1, 1909

By H. W. Davis, Richard J. Lund

"In presenting the results of this survey on consumption of ferrous scrap and pig iron for the year 1935 the Bureau of Mines, responding to requests from industry, seeks to fill a major gap that has long existed in the field of metalliferous raw-material statistics. This type of information is designed to meet the needs of: (1) Consumers of ferrous scrap. including operators of blast furnaces, steel mills, ferrous foundries, and rolling mills; (2) marketers of scrap iron and steel, including large brokers who sell, and dealers who collect, prepare, and sell the material; (3) large scrap producers; (4) producers of iron ore, with which scrap competes indirectly; and (5) other individuals and agencies interested in more general economic analysis, since the scrap market has repeatedly been cited as one of the most sensitive of all industrial barometers, If the survey prover as useful as now seems probable, it will be continued annually with possibly an enlarged scope of treatment.The Bureau appreciates that its first efforts in this field may not meet all expectations: but it hopes to develop gradually, through suggestions, advice, and criticism from the industrial groups most interested, a type of analysis that will accord closely with technical processes and best meet the needs of all groups vitally interested in supplies and use of ferrous scrap. Constructive criticism and suggestions from industry regarding improvements to be desired in the conduct of future surveys on this subject will therefore be warmly received by the Bureau."

Nov 1, 1936

By J. W. Cooksley

Seismic methods provide an efficient and comprehensive approach to overburden studies pertinent to mining exploration and development, and to other mining and civil engineering problems such as rock mechanics, slope stability, and foundation engineering. For the purpose of defining geologic units and structural features, these methods are generally regarded as the most accurate, but most expensive, of the commonly-used geophysical exploration methods. Although the accuracy and cost of seismic work are generally affected adversely by rugged topography and complicated geologic conditions, it is in rough terrain and complex geology that seismic methods offer important advantages in overburden investigations. For example, to find the surface of rock underlying unconsolidated overburden at depths of approximately 200 feet, a 50-foot spacing of drill holes along the profile line would be required to yield a degree of resolution and accuracy similar to that obtained from a 50-foot spacing between seismic detectors along the same line. See Figure 1. In cases similar to that shown in Figure 1, a twelve-channel recording seismic system would be used. The main components of such a system would be: 1. detectors (commonly referred to as geophones) which convert the ground movement resulting from seismic waves into an electrical signal. 2. a multi-conductor cable which connects the seismic detectors to the amplifiers. 3. ampliiiers, amplify and filter the electrical signals . 4. oscillograph, records the amplified signal. 5. the blaster and firing line. A typical layout of the seismic spread and the components of the system Is shown in Figure 2.

Jan 1, 1968

By F. Charette

Instrumentation has been developed that can monitor the strain applied to a D-Bolt up to 7.5% elongation. The technology far exceeds the limit for foil resistance strain gauges. In the laboratory the instrumentation has provided insight into the fundamental behaviour of the D-Bolt following yield. Currently the instrumentation is undergoing field trials at a number of Canadian Mines. Discussion on field results is provided with regards to significance, reliability and temperature effects.

Aug 1, 2013

By Beatrice Pierre, Juan Carrasco

Altonorte began as a concentrate roasting operation in 1988 under the name of Refimet. In 1993, a copper smelter was built with a design capacity of 203,000 tonnes per annum of concentrate. Since 2001, many technological advances have been made in Altonorte, where the biggest Noranda Reactor in the world is installed being the first Noranda Reactor reaching above one million tonnes of copper concentrates processed per annum. In 2013, Altonorte was acquired by Glencore. Recently due to various new environmental regulations in Chile, Altonorte has evolved to new standards of operation in order to reach the vision of becoming a World Class Smelter. This paper describes the path followed to improve safety, environmental performance, process capacity, reliability, and productivity. The foundation for the growth and success in Altonorte is our People. Employee engagement and branding of our cultural journey is what allows Altonorte to face the future with the certainty of becoming a World Class Smelter. INTRODUCTION Altonorte is located in Antofagasta, the mining capital in the north of Chile and is the last smelter built in Chile practically completed with second hand equipment. The biggest technological change in Altonorte occurred during the phase 3 expansion in 2003, where the old Reverberatory furnace was shut down and replaced by the biggest Noranda Reactor installed in the world. The vessel measures 5.3 m × 26m. ºAdditionally, this project contemplated a new rotary dryer, three (3) new Peirce Smith converters, new anode furnaces and a new Acid plant. The nominal capacity was to treat 816.000 tons of new concentrate per year. In 2008, a new expansion phase was implemented where a new double absorption acid plant replaced the oldest acid plant. Bottlenecks such as blowing capacity and oxygen availability were solved installing a new air blower and a new contract was negotiated with our oxygen supplier to increase oxygen availability up to 683 tpd. This improvement defined the current nominal capacity of 1.100.000 ton of new concentrate per year. Current process description All concentrates are received by trucks directly from domestic mines or from the Antofagasta international port in cases of imported concentrates; the concentrate warehouse has a capacity of 25 kt where the blend is prepared to feed the smelter.

Jan 1, 2019

By J J. Pretorius, G M. Hoffmann

Utilisation of lower-grade (<60 per cent Fe) resources, not utilised in the current products, is crucial to ensure optimal resource utilisation and maintaining/improving future profit margins by reclassifying low-grade material to ore. The purpose of the Sishen Expansion Project (?SEP?) is therefore to investigate the technical and financial viability of producing up to an additional 10 Mtpa of new products at Sishen from material currently classified as low-grade materials. Jigging technology has progressed to a point where Sishen?s 50 to 60 per cent Fe run of mine (?ROM?) material, once considered as waste, can be beneficiated to produce a saleable 64 per cent Fe product. This has been confirmed through appropriate beneficiation testwork. Consequently, Sishen can now produce saleable product from material not currently included in the resource definition, increasing the resource base of the mine significantly and ensuring higher resource utilisation. Mine Planning utilised the geological models to produce detail planning schedules, reflecting the current and SEP plants separately, optimised to comply with product specifications of both the current and SEP plants and to confirm the viability of the low-grade resources identified as SEP feed material. The SEP products specifications have been derived by optimally matching iron ore market requirements with the revised resource base. A 64.0 per cent Fe lump product and a 63.5 per cent Fe fine product are the optimal SEP products. The SEP plant will be able to produce 10Mtpa at an average yield of 60 per cent and a lump to fine ratio of 62 to 38. The plant consists of five major sections namely crushing, material preparation, beneficiation, final product handling and quality control services. Maximum integration with the current Sishen plant was considered. Kumba currently has an agreement with Transnet to rail up to 23.5 Mtpa through the Sishen Saldanha Iron Ore Export Channel (?IOEC?). Transnet and Sishen Iron Ore Company have signed a Definitive Agreement that deals with the expansion of IOEC?s capacity, which increases Kumba?s entitlement from 23.5Mtpa to 35.0Mtpa. The detailed enviro-legal impact assessments for the SEP indicated that the project has low enviro-legal risk as a result of it being a brownfields project incorporated into the current Sishen operations.

Jan 1, 2006

By Hyung Sup Choi

The preparation of high-purity zirconyl compounds was studied in order to develop an economical process for obtaining pure zirconium via the caustic fritting of zircon sand. The direct dissolution of caustic frits with concentrated hydrochloric or nitric acid at 80c. followed by the addition of a small amount of acidified gelatin, gave high-purity zirconyl chloride or nitrate. The addition of a small amount of gelatin caused a mutual flocculation between colloidal silica and gelatin. The precipitation of this silica floc markedly lowered the content of silica in the product. The silica content of the compounds (or solution) so produced, generally less than 100 ppm., was sufficiently low for tributyl phosphate extraction for nitrate solutions. It was found that the degree of purification de-pends not only on the procedures employed but also on the nature of the frit itself. Silica was more effectively eliminated from the fritted product produced at higher temperatures, and less silica was present in the com-pound prepared from the frit produced in a shorter heating time. In order to ascertain the nature of the

Jan 1, 1965