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By E. J. Duggan

In the course of the grinding experiments conducted at Climax over the past twenty years one interesting phenomenon was discovered. This was that balls made of certain types of steel grind more ore than some others. The most significant variation was found in the results secured with a hard alloyed forged bail compared with the forged carbon ball supplied by most ball manufacturers These findings were confirmed in many repeated controlled tests. The value of these tests depends on the methods used, the facilities available and the care with which the investigations were conducted. These are described in the following. This testing has largely been done in eight 91 x 81 low discharge ball mills in closed circuit with 7811 duplex screw classifiers. The mills run at 20 RPM on a feed approximately minus 3/8 inch. The ore is ground through 28 - 35 mesh in one stage. Each mill and auxiliary classifier is in a separate, parallel grinding and flotation section The, ore to each: section is the same in every particular and is fed to each mill bin from a common conveyor tripper. The ore from the bin to the ball mill is weighed on a conveyor scale. The power input to each mill motor is determined with a watt hour meter which measures the power to the mill motor only. Both the scales and meters are checked periodically by standard methods and have been found to give consistent readings. Automatic samplers are employed on each section to obtain accurate measurement of the size reduction. A size analysis of the classifier overflow is made each shift and a composite size analysis is obtained from a weighted average of the various shift analyses. The mills are driven by 450 horsepower synchronous motors so that there is no speed variation and shell liner age is kept as nearly the same as possible in mills under test. The same set of operators is assigned to a mill under test as to the control mill. In all other particulars such as ball load, mill density, liner design, etc., the mills are operated in precisely the same manner. This is an ideal arrangement for plant testing. From observations of ball mill performance over the past twenty years, it is the opinion of the operating staff that variations of as little as one to two percent in mill capacities may be determined if sufficient operating hours are devoted, to a test. Relations between mill capacities, fineness of grinds and power consumptions have been established with a high degree of accuracy. In Table I are given the figures for one test. These show that while the grind with the hard ball was slightly coarser, the tons ground per hour was 5.4 percent greater with the soft ball, and 6.1 percent greater on the basis of minus 100 mesh produced. The power consumed per ton with the hard ball was 4.4 percent greater on a tons per hour basis. The soft ball was inferior in wearing qualities and steel consumption per ton of ore was 24 percent greater with it. In this test the mills were charged with the two different balls for a period of three months to allow the ball loads to come to equilibrium. In Table II are given the specifications of the two balls. The difference in grinding rates may be accounted for by the nature of the ball surfaces. The surfaces of the soft balls after being worn a while are rougher to the touch. Enlarged photographs of the worn-in surfaces of hard and soft balls are shown in Figure I. These show the presence of scratches or skid marks on the hard ball surface which indicates less nipping effect. The Climax ore pulp has a pH of 6.0 and is in a dispersed state. The viscosity is low compared with most ores especially those that are conditioned with lime. This would lower the tendency of the pulp to adhere to the balls with a lower grinding efficiency as a result. It was also thought that the relative rates of wear from surface to center might affect the make-up of an equilibrium ball charge. This probably has little effect on capacity as shown by the size analyses of the two ball charges in Table III. This hypothesis was subsequently investigated by the use of rationed charges. The rationed charge did not overcome the advantage in

Jan 1, 1958

All the TECHNICAL PUBLICATIONS and CONTRIBUTIONS published in 1935 are available at Institute headquarters, unless otherwise noted. They are also on file in many public, university and technical libraries and, when so indicated in the list, may be found in the TRANSACTIONS. Copies of the TECHNICAL PUBLICATIONS have been mailed to members of the Institute that are registered in the different classes: A-Metal Mining; B-Milling and Concentration; C-Iron and Steel Division; D-Nonferrous Metallurgy; E-Institute of Metals Division; F-Coal Division; G-Petroleum Division; H-Industrial Minerals Division (Nonmetallics); I-Mining Geology; J-Mineral Industry Education Division; K-Mining Administration; I-Geophysical Prospecting. Other members may obtain copies by writing to the Secretary. Copies of CONTRIBUTIONS may also be obtained from the Secretary's office. Additional copies are sold at the rate of 1 cent per page; minimum charge, 25 cents. Nonmembers may purchase the papers at the prices mentioned. [ ]

Jan 1, 1936

By K. I. Savage, S. C. Sun

This paper describes a process developed to recover coal, clays and pyrite from coal wastes. The process consists of fine grinding followed by coal and pyrite flotation which leaves the clays in the flotation pulp. A bituminous coal refuse containing 10% sulfur and 30% carbonaceous material was treated by this method to yield a coal product containing 4% sulfur, 10% ash; a pyrite product containing 45% sulfur (84% FeS2), 1% carbonaceous material; and a clay product containing 2% sulfur (3.5% FeS2). The coal yield was about 89%. The pyrite yield was about 77%. The process steps may be entirely flotation, or gravity separation (hydrocycloning) may be used to increase the pyrite : coal ratio in the flotation feed. Cost estimates for the process show a profit of $2.28 per ton of low pyrite grade refuse, but these do not include labor, maintenance, overhead and plant depreciation. The development of this process consisted of three parts: (1) exploratory tests, (2) op-timazation tests and (3) confirmatory tests. The objectionable qualities that sulfur imparts to coal have been commented upon from early times, and they have become more objectionable as the uses of coal have grown. In whatever form coal takes — raw, carbonized or gasified —the sulfur content remains objectionable, and therefore its compounds are removed as completely as possible. It has long been known that sulfur occurs in coal in different forms. In 1861, sulfur was said to exist in the state of sulfuric acid in combination with a base; in combination with iron as iron pyrites; as bisulfides of iron; and in combination with the organic elements of coal.' Pyritic sulfur is a term loosely used to cover the sulfur associated with iron in its various forms. The mineralogically recognized forms are pyrite (FeS2), pyrrhotite (Fe 1-x S) and marcasite (FeS2). The particle sizes of pyrites vary widely. Isolated grains of marcasite smaller than 15 microns have been found disseminated through coal.2 Hair-like "veins" of pyrite filling cracks in vitrain have been found. At the other extreme, lumps or nodules of pyrites large enough for removal by hand picking have been encountered. Organic sulfur, unlike pyritic sulfur, does not exist as discrete particles, but is instead intimately associated with the coal structure and thus it is impossible to remove it or reduce its concentration by physical or mechanical means.2 In the preparation of coal for its various markets, the pyrite minerals (pyrites) are separated from the raw coal feed. This separation process concentrates the pyrites in the tailings or other waste products. It would be desirable to recover these pyrites for three reasons: (1) Pyrites are potential sources of sulfur and iron. In 1967, for the fifth consecutive year, Free World consumption of sulfur exceeded production.3 Propelled by the shortage, the domestic price of sulfur has risen from $24 to $38 per long ton (bright). (2) The refuse, when placed in piles, becomes ignited. The pyrites (FeS2) bum, giving off SO,. Thus, the pyrites are a cause of air pollution. (3) Also, the pyrites undergo chemical reaction when exposed to air. The refuse is leached by waters which result in stream pollution due to the water-soluble iron and acidic reaction products. Coal refuse also contains coal minerals and clay minerals. Therefore, any process for recovering the pyrites must successfully separate them from the coal and clay minerals. In the study discussed here, ten different bituminous coal refuse samples were successfully upgraded in pyrite content. These samples represented a wide variety of coal waste materials from Pennsylvania and other states. The variabilities of the sulfur and coal contents are shown in Table I. The extremes are Sample J, a high sulfur-low coal, and Sample B, a low sulfur-high coal. Definitions of some of the symbols or terms used in this report are given below: Mesh size—Tyler standard mesh screen sieves with an opening based on the square root of two. Fe —Indicates iron, as determined by a stannous reduction-dichromatic oxidation method. S—Indicates sulfur, as determined by the ASTM "Eschka" method for sulfur in coal.

Jan 1, 1969

By Robert Glass Cleland

[Incorporated under the laws of the State of New York OFFICE, 41) WALL STREET, NEW YORK 5, N. Y. Authorized4,000,000 shares $150,000,000.00 Outstanding-5,071,260 shares 126,781,500.00]

Jan 1, 1952

By Seung-Kyu Son

This study was investigated about physico-chemical parameter such as water temperature, salinity, inorganic nutrients and total organic carbon (TOC). CTD (Model: Sea-Bird 911 Plus) castings were carried out on two transects in the northeast equatorial Pacific Ocean. As a part of the Korea Deep-sea Environment Study (KODES), inorganic nutrients and TOC were determined at 41 stations located from 131° to 136°W along 10.5°N and from 17° to 5°N along 131.5°W (Fig. 1). We particularly chose KODES Long-term Monitoring Station (St. KOMO) to observe for the annually environmental baseline study in the contract area. [ ]

Jan 1, 2005

By D. W. White

The kinetics of isothermal transformation of ß-to-u uranium have been studied over a broad temperature range in alloys containing from 0.3 to 4.0 atomic pct Cr. Two modes of transformation are indicated by the existence of two C-curves in the TTT diagram. The upper temperature mode is regarded as a nucleation and growth mechanism, whose rate is controlled by diffusion of chromium in the ß phase matrix. The lower temperature mode is martensitic in nature. The M, temperature increases with decreasing chromium content, suggesting that the two transformation processes become synonymous in unalloyed uranium. URANIUM metal undergoes two allotropic transformations in the solid state. The a phase, orthorhombic in crystal structure,' is stable from room temperature up to about 665°C. The ß phase, characterized by a complex tetragonal structure,' prevails from 665" to about 770°C. The y phase is body-centered-cubic3 and is the stable modification from 770°C up to the melting point (about 1130"). In uranium of reasonable purity, neither of the two high temperature phases can be retained by quenching. However, the addition of certain alloying elements to uranium makes it possible to retain either the y-uranium phase or the ß-uranium phase at room temperature. Chromium alloyed in small amounts with uranium will permit retention of the ß-uranium phase in a metastable state at room temperature upon quenching from a ß-phase temperature.' From available information' on the equilibrium phase diagram for the U-Cr alloy system (Fig. I), it is to be expected that, however sluggish in its rate, the ß phase in such alloys should decompose eutectoidally to a phase and elemental chromium. It was the aim of this investigation to measure the rate and study the nature of this decomposition as a function of temperature and of chromium content. The investigation was reported in classified literature about five years ago and has recently been declassified for publication. In the meantime, there have appeared the papers of Holden,5 Mott and Haines,".' and Butcher and Rowe8 ealing with the metallography and the crystallography of the ß-to-a transformation in U-Cr alloys. These investigators have confirmed several of the phenomenological observations that will be described in the present paper and have examined in considerable detail certain aspects of the transformation and its mechanism. Although all of these investigations have concerned themselves experimentally with U-Cr alloys for the most part, an important consequence has been a clearer understanding of the nature of the ß-to-a transformation in uranium metal itself. Experimental Procedure This investigation dealt with a series of uranium alloys varying in chromium content from 0.3 to 4.0 atomic pct (0.066 to 0.90 weight pct). On five of the alloys, rates of isothermal transformation from the ß to the a phase were measured over a wide temperature range, leading to the development of TTT (time-temperature-transformation) diagrams. Transformation rates were measured over certain narrow temperature ranges on additional alloys. The alloys were prepared by vacuum melting and casting, using zircon or magnesia crucibles and graphite molds. Electrolytic chromium was used as the alloying addition, and the uranium was Mallin-ckrodt biscuit metal that had been vacuum remelted and cropped to remove many of the nonmetallic impurities that had floated to the top of the ingot. The ingots, 3/4 or 1 in. diam, were reduced in size by swaging. Alloys containing less than about 2 atomic pct Cr were swaged at 250° to 275°C, with initial and intermediate anneals at 550°C after every 75 pct reduction in area. Alloys with higher amounts of chromium were swaged at 550" to 600°C, although at the smaller sizes some of them were reduced by the procedure used on the more dilute alloys. Before use as test specimens, the swaged rods were annealed at 700" to 720°C for several hours, followed by slow furnace-cooling. The purpose of the anneal was to achieve the maximum amount of solution of the available chromium into the ß phase, as well as to remove extensive preferred orientation. The isothermal transformation rates were measured dilatometrically, using a quenching dilatometer and an experimental technique similar to those employed by Davenport and Bain in their original work on the transformation kinetics of austenite in

Jan 1, 1956

By C. P. Broadbent

The process metallurgy of many nickel laterite smelting operations is controlled largely by the physical chemistry of the slag system. Consequently, accurate phase diagram information and physicochemical property data are essential to interpret and predict the behaviour and optimisation of the overall process. The system (SiO2 - MgO - FeO) first described by Bowen et al. between 1914 and 1935 and the system (SiO2 - MgO - FeO - Fe2O3) determined by Muan and Osborne in 1956 are of particular relevance to the study of nickel laterite smelting slags as these systems form a reasonable approximation of many industrial slags. This paper will review the literature for these (and other relevant) phase systems. In addition data available from the ternary and (quasi)ternary phase diagrams will be compared with data obtained from industrial slags. The physico-chemical properties under consideration will include; melting and crystallisation behaviour (solidus and liquidus temperatures), viscosity - temperature relationships, heat flux considerations, electrical conductivity, surface and interfacial tension.

Jan 1, 1993

By R. C. Urquhart, D. D. Howat, R. I. L. Guthrie

Heat losses from ladles during teeming by R. C. URQUHART, M.Eng. (McGiII), Ph.D. (Visitor). R. I. L. GUTHRIE, B.Sc. (Eng.) (London), A.R.S.M., Ph.D., D.I.C. (Visitor), and D. D. HOWAT, B.Sc. (Glas.), Ph.D. (Fellow) In an investigation of the loss of temperature by liquid steel during a teeming operation, a numerical technique was used to calculate the heat flows and the rate of temperature drop over the entire teeming operation. The calculations show that, before teeming, approximately 50 per cent of the heat loss is into the ladle wall at the level of the metal. As teeming progresses, the amount of heat lost by radiation to the wall above the metalline increases. The effect of variables, such as initial metal temperature, the preheat of the ladle and ladle cover, and delays, on the rate of temperature loss by the metal were determined.

Jan 11, 1973

By Horst Kappes

Tradicionalmente, a escória é descartada em poços secos ou granulada com água, gerando um produto de maior valor agregado devido à vitrificação e consequente aproveitamento na indústria de cimento. Com larga experiência em granulação e mais de 260 referências do sistema INBA®, a Paul Wurth agora apresenta a solução mais robusta do mercado para granulação a seco. Promovendo a granulação através da injeção de esferas de aço, comprovou-se, através de uma série de testes, características iguais ou superiores à da escória granulada com água. Uma apresentação desta tecnologia bem como uma narrativa de sua trajetória e os resultados parciais obtidos é descrito neste trabalho.

Aug 2, 2018

By C. García

Several modifications to Zaldivar's original design have been made in order to reach the design cathode production. This paper describes the modifications to the crushing, leaching, solvent extraction and electrowinning operations, which in turn have increased the production by 14.8% over the design capacity in 1999. The principal modifications were to (1) incorporate a dry pre- screening plant between the secondary and tertiary crushers to increase the percentage of fines to the piles, (2) increase the retention time of the solutions inside of the piles, and (3) increase the efficiency of the tertiary crushers to reduce the particle size of the product material. The leaching ratio was increased from 2.8 to 5.6 m3/ton. The temperature of the pregnant leach solution (PLS) was increased, the amount of acid used was reduced, and a strain of native bacteria was adapted in highly contaminated solutions. The copper concentration in the PLS was increased by more than 50% and was stabilized at this level by commissioning a process of two-stage leaching. The current density in the tankhouse was increased from an average of 2 16 to 3 17 A/m

Jan 1, 1999

By Leslie S. Halasz

This paper describes the techniques implemented at Randfontein Estates to develop twin-haulages at 'high speed'. An operation which culminated in the world record advance for twin-end multiblast cyclic development in hard abrasive quartzites. A major expansion project was planned for the mine, with the sinking of a third twin-shaft system (to be known as Cooke No. 3), to raise the level of ore production from 3 500 000 to 5 000 000 tonnes per alumm. Subsequent redesign of the proposed shaft system as a single 9 m brattice wall shaft took place, reducing the planned shaft sinking period by 12 months and saving an estimated R 250 000 (U.S. $ 330 000) in sinking costs. The advancement of the Cooke No. 3 Shaft sinking and development programme necessitated a rapid excavation schedule for two interconnecting twin-haulages from the existing Cooke No. 2 twin shaft complex to provide a second means of egress. An early holing between the two shafts would provide significant financial and technical benefits. Pre-development and equipping of shaft pillar excavations would enable a rapid shaft production build up and blocking out of at least one year's ore-reserves.

Jan 1, 1983

There is growing acknowledgement that successful organisations, including mining companies, achieve their competitive advantage by better managing their employees, customers and other stakeholders. The fact that I have been asked to address this conference is perhaps evidence of the recognition of the importance of ensuring the improved management capabilities of the personnel within Australian mining companies. As many of you will be aware, prior to my appointment to the role of President of Minera Alumbrera Limited (MAA), the operator of the Bajo de la Alumbrera project, my career had been more generally focussed on industrial relations and human resources management. My appointment was met by surprise in some quarters, as it is unusual for a person without the technical background of a mining discipline to manage a world-class mining operation. However, it was recognised early in the life of the Alumbrera project that the operation did not lack technical expertise or a committed workforce; rather what was required was innovative management of the project and its operational resources, particularly given that we were operating with totally ægreenÆ workforce in a country without a large-scale mining culture. It is my experience that a particular shortcoming of mining companies is that they have tended to ægrowÆ managers based on their technical expertise rather than people management skills. Historically, many companies have assumed, or at least hoped, that their better technical people would develop the requisite skills to take on the challenges of management. Such philosophy has not always met with success. Whilst the topic for my presentation was originally published as People in the Mining Industry, within the context of the overall theme for this plenary session, People: Education for the Future, it is a subject with an extraordinary breadth of possibilities for discussion. Therefore, I have chosen to redefine my presentation to People Management Issues in Offshore Mining Projects,an issue which I consider to be an important area within the overall topic and one which has particular currency given the increased tendency by Australian miners towards offshore exploration. It is also relevant from the perspective of continued rationalisation of our industry, the recognition that there will be more large-scale, global corporate mining entities and that significantly more mining professionals will become æcitizens of the worldÆ. We therefore need to prepare our future leaders for these challenges. The topic also allows me to highlight the importance of an holistic management approach as the establishment of a new project in a foreign environment puts into stark relief the need for the application of the full range of competencies, rather than the narrow ætechnicalÆ approach to doing business. I hasten to add, however, that the mining industry is not alone in this regard and I was interested to read an article in the Weekend Australian of 22/23 January 2000, which reported on the first key speech of former Westpac CEO, Bob Joss, as Dean of the Stanford University Graduate School of Business. He said: à We know that when our students go out into the world, if they have to struggle, it will not be because theyÆre not smart enough, or they donÆt have enough good ideas. It will be because they struggle over managing themselves and their relationships to other people. The article then went on to say that Bob Joss foreshadowed an initiative to build alliances between the Business School and other Humanities departments within Stanford University to draw on their learning. Other business schools have also recognised this need, albeit somewhat late in the day, as have the most enlightened of modern corporations; in summary, successful businesses have recognised that in an age where competitive advantage through, for example, technological breakthroughs is very short-lived, it is the quality of management that will provide the leading edge. By using the Alumbrera project as a case study, I will identify certain of the challenges with which companies and individuals may be confronted in the establishment of a greenfields project outside Australia. However, many of the issues raised will have direct application in the context of the development of an Australian operation. My objective is to provide an indication of areas which should be considered at the formative stages of a projectÆs development, with particular focus on the issues of people management. I would expect that such a study would be of benefit to companies, education institutions and individuals in preparing themselves for similar experiences.

Jan 1, 2000

Contribution by W.D. Ortlepp In the Journal of May 1994, the authors first presented the concept and analysis that formed the basis for a design approach for deep tunnels, now expressed more explicitly in the present paper (March/April 1996). In a contribution in the Journal of March/April 1995, I expressed a certain disquiet about the validity of their original approach. The authors responded to these criticisms in the same issue. It is apparent to me now that both the contribution and its rebuttals were written, probably for different reasons, in such an obscure and pedantic way as to further confuse the reader rather than provide enlightenment. My concern still persists. But in order to avoid further confusion I will attempt to pose my uncertainties and difficulties in a much more direct way. On page 98 (top of 2nd column) in the earlier paper, an important statement concluded as follows: '. . . the horizontal ellipse requires 140 per cent less force for equivalent stability'.

Jan 1, 1996

By Song-yu Liu, Chao Yan, Yong-feng Deng

"In order to investigate the stability of embankment on soft subgrade improved by T-shaped deep mixed column composite foundation, the internal forces and failure modes of columns were analyzed on the shape of critical slip surface and the displacement fields of composite foundation through strength reduction method of three dimensional numerical simulation. Then comparison between T-shaped and conventional deep mixed column composite foundation were conducted. The simulation results indicate that the stability analysis was overestimated by limit equilibrium methods. Piles within the slope shoulder provide great resistance slide effect through the vertical bearing capacity, while the piles nearby slope shoulder and outside slope shoulder providing great moment to resistant slip. The embankment stability of T-shaped deep mixed column composite foundation is higher than that of conventional deep mixed column composite foundation while cost less cement and construction time.INTRODUCTIONThe soft soil has many unfavorable project properties such as high compressibility, low strength, and high water component. Embankment built on the soft soil will face subsidence, horizontal displacement and stability problems. Cement-soil deep mixed column composite foundation is more commonly used as a method for construction of embankment on soft ground [1-2]. For the existing problems of China's current cement-soil pile (wet jet mixing pile), including strength uneven, effective treatment with shallow depth and high cost, a new technique, T-shaped bidirectional deep mixed column, is introduced [3]. An automatic expanding mixing blade was developed by Liu et al. shown in Figure. 1, to install TDM columns [4].T-shaped deep mixed (TDM) column combines bi-directional deep mixing technique and T-shaped deep mixing technique: ?Using concentric biaxial drill pipe, opposite rotational direction of the blade on the inner drill pipe and the outer drill pipe. By squeezing action of the blade on the outer drill pipe, forward and reverse rotation of the blades bidirectional mixing at the same time, blocking the way to take the grout, the uniformity of cement mixing is improved. ?Scalable stirring blades, which can be stretched for two different radius at any depth below ground, expand cross-section of the upper pile (enlarged head), forming expanding cross-section within the upper part of a certain depth which is similar to the shape of nail. As a new composite foundation, T-shaped mixing pile composite foundation is widely applied. However, studies on the stability of T-shaped column treated soft subgrade are rare in the research. So the stability study on T-shaped column composite foundation under embankment for guiding the design and construction has important significance."

Jan 1, 2015

By Robert Ammon

The milling practice at Mascot, at present, consists of dry crushing to % in., jigging, fine grinding, and flotation. The ore arrives at the mill from two mines, No. 1 mine shaft being located in the mill proper, and No. 2 mine shaft being situated about 2000 ft. east of the mill. No. 2 mine is served by a coarse-crushing plant and aerial tramway to the mill bins. In jigging the No. 2 mine ore, 50 per cent. of the mill feed is rejected by the jigs as a jig tailing ranging from 5/8 in. to 10 mesh; the balance of this ore, after removing a jig concentrate, is ground to flotation feed. In jigging No. 1 mine ore, approximately 80 per cent. of the mill feed is rejected as a coarse jig tailing, and the balance is ground to flotation feed without the removal of a jig concentrate. The difference in the treatment is due to the fact that No. 2 mine ore carries a higher content of zinc than that from No. 1 mine. Of the total concentrates produced, 30 per cent. is made on jigs and 70 per cent. by flotation. At present, 1350 tons of No. 2 ore and 800 tons of No. 1 ore are treated each 24 hours. The recoveries for a typical week are as follows: Heads.......................... 3.55 Jig concentrates................ 61.30 Jig tails......................... 0.80 Flotation concentrates........... 60.60 Flotation tails................... 0.09 Extraction..................... 86.50 The associated minerals are a straw-colored sphalerite, dolomite, calcite, pyrite, quartz, and a small amount of greenockite, which occurs as a stain and sometimes small crystals along with sphalerite, but is comparatively rare. Pyrite is present in small quantities, usually less than 0.5 per cent.; quartz occurs in bands a few inches thick. A complete analysis of the ore is as follows: PEr Cent. Per Cent. Calcium carbonate.............. 48.11 Zinc sulfide.................... 5.43 Magnesium carbonate........... 35.36 Cadmium sulfide............... Nil Silica.......................... 8.73 Lead sulfide................... Nil Alumina....................... 1.04 Iron oxide...................... 1.33 Total....................... 100.00

Jan 1, 1925

By R. Padilla

In most of the Chilean copper and gold concentrates, arsenic is present mainly as enargite, Cu3AsS4, which at the conventional roasting or smelting temperatures decomposes liberating arsenic as gaseous compounds. The objective of this investigation was to study the decomposition reaction of enargite in an inert atmosphere in the range of 500 °C - 750°C. The results obtained indicated that the decomposition begins at about 525 °C. Two distinct regions in the temperature dependence of the decomposition rate were observed: a low temperature region between 525 °C to 650°C and a high temperature region between 650 °C to 725 °C. The X-ray diffraction analysis suggests that the decomposition of enargite occurs through the formation of intermediate tenantite, according to the following sequential reactions: 4Cu3AsS4(s) ? Cu12 As4S13(s)+ 3/2S2(g) Cu12 AS4S13(s) ? 6Cu2S(s) + 2As2S3(g) + 1/2S2(g) The decomposition kinetics was analyzed by using the model for a topochemical reaction of spherical particles: 1-(1-X) 1/3 = kt, which represented well the data. Apparent activation energies of 113 kJ/mol and 60.5 kJ/mol were found for the low and high temperature regions, respectively.

Jan 1, 1999

By V. G. Leak, R. A. Swalin

The dilhsion of silver and trace concentrations of tin in liquid silver has been rrzeasured in the temperature range from about 975° to 1350°C. The difBsion dala. fil lhe following equations: fov self-diffusion of silver The ratio of DSn to DAg is found to be about 1.34. The higher diffusivity of tin is interpreted in terms of the coullombic repulsion which results from the fact that tin dissolved in silver has a valence of +3 relative to silver. THE phenomenon of diffusion has been well-described theoretically for hard-sphere gases and solids and found to be in good agreement with experimental data for certain gases and solids. Liquid-diffusion phenomena have not been well described theoretically and there is generally a lack of good experimental data. In this investigation self-diffusion and solute diffusion in liquid silver were studied. Silver was chosen as a solvent for two main reasons. First, silver is a noble metal and the atoms are considered to have a spherically symmetric charge field; hence the liquid may be considered to be a random array of approximate hard spheres. Mercury, gallium, and other lower-melting metals were eliminated from consideration since it appears possible that in their liquid states there is some residual long-range order and directional bonding. Second, silver behaves as a monovalent solvent and, while cadmium, indium, tin, and antimony all have nearly the same atomic size, they have chemical valences relative to that of silver of +1, +2, + 3, and +4, respectively. Slifkin, Lazarus, and coworkers1-5 investigated the diffusion of these solutes in solid silver and found that their diffusion rates increased with an increase of the excess valence of the solute. In the solid state the diffusion-rate increase was calculated to be due to a change in local modulus of the solvent caused by the excess valence of the solute.1"3 For the present investigation it was planned to determine the effect of valence upon solute diffusion in liquid silver. It was deduced that a coulombic repulsion between solute and solvent might be responsible for larger volume fluctuations in the vicinity of the solute thereby enhancing the diffusion of the solute atoms. Tin was the first solute investigated and was chosen for experimental convenience. If an excess-valence diffusion effect exists in the liquid state, the solute tin with its excess valence of + 3 might show a large enough effect to distinguish it from the self-diffusion of silver in silver. The silver self-diffusion data were obviously required as a base line for comparison. In addition silver self-diffusion was investigated with a view toward examining the data in connection with the Sutherland- Einstein: Coheen-Turnbull,7 and swalin8 theories of diffusion in liquids. I) EXPERIMENTAL TECHNIQUES The diffusion coefficients for tin and silver in liquid silver were determined in separate experiments using the capillary-reservoir method of Anderson and saddingtono but following closely the experimental techniques outlined by Ma and Swa1in. The radioactive alloy bath was prepared by plating either tin-113 or silver-110 m isotope* onto 99.999 *Isotopes obtained from Oak Ridge National Laboratory. pct Ag rods.* The silver and isotope were melted *Silver obtained from Cominco Co. and mixed in a graphite crucible under a purified argon atmosphere, then outgassed for capillary filling. Some of the fused-silica capillaries were filled individually as reported by Ma and Swalin, but most were filled in a different manner. A long piece of capillary tubing was sealed off on one end and held in the system so that the open end was just above the surface of the molten alloy. The system was evacuated, the open end submerged into the alloy, and argon was admitted into the system up to atmospheric pressure. The molten alloy was forced up the capillary several inches where it solidified and was subsequently cut into segments of the proper length for diffusion annealing. The apparatus for diffusion annealing was the same as that used for capillary filling except that a Pt—Pt, 10 pct Rh therinocouple was placed in the solvent bath in order to accurately measure the temperature during the run. A diagram of the dif-

Jan 1, 1964

By G. C. Laurence

"This paper discusses the hazards and extensive precautions taken in Canadian uranium mines, concentrating plants and processing plants. It also outlines Canadian policy regarding the control of the sale and distribution of uranium and other nuclear materials.OVER THIRTY YEARS AGO, I spoke to The Canadian Institute of Mining and Metallurgy here in Montreal about radioactivity and its dangers. I must have made quite an impression thirty odd years ago, because now you have asked me to do it again. Of course, the picture has changed. Then they were mining uranium ore, recovering the radium from it and throwing away the uranium. Now they are still mining uranium ore, but are throwing the radium out on the tailings dumps. Thirty years ago, most people did not know what ""radioactivity"" meant. Nowadays, they have beard that it is dangerous, and some of them, recently, be-came worried about the radium in the tailings dumps and what becomes of it."

Jan 1, 1969

By H. M. Lima, L. A. Gomiero, C. A. de Morais

ABSTRACT The Caetité-Brazil uranium facility produces approximately 400 tonnes U3O8 per year from an ore averaging 0.29% U3O8. The process steps are ore crushing, heap leaching with sulphuric acid, uranium separation and purification by solvent extraction (SX) with a tertiary amine, followed by stripping with a sodium chloride solution, precipitation as ammonium diuranate (ADU), and product drying. A change in the milling process is being evaluated to increase production and uranium recovery. Heap leaching will be replaced by conventional agitated tank leaching of the –590 µm ground ore slurry in a sulphuric acid medium. Replacement of the stripping reagent is also being considered.

Jan 1, 2012

By I. Tsolas

This paper presents the use of the Jaggi-Freedman model for deriving composite environmental sustainability indicators at the mine level (i.e. indicators which focus on both the environmental and economic dimension of the sustainable development) using environmental, economic and/or integrated indicators (i.e. indicators which inter-relate two dimensions of sustainability). The derivation of composite environmental sustainability indicators by means of the Jaggi-Freedman model concerns the South-Field lignite mine of Public Power Corporation (PPC) in Western Macedonia. In the light of the results of the present paper it is evident that the performance of South-Field mine, during 1986-1990, was the exclusive domain of large production yearly activities. The considerably low indicators? scores during the 1986-1987 period are attributed to the increased environmental impacts and electrical energy consumed. The merit of this framework is that it can be used both internally, for benchmarking purposes and externally, for sustainability reporting.

Jan 1, 2006