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By Frederick M. Becket

SHORTLY after the Armistice there appeared a few references to numerous attempts that had been made to produce steel without the aid of manganese, or at least with manganese in abnormally low percentage. Some years later, during two consecutive days of train travel, I had excellent opportunity to read Sir Robert Hadfield's book, entitled "Metallurgy-Its Influence on Modern Progress," and also his paper, "The Metal Manganese and Its Properties : Also the Production of Ferro-Manganese and Its History," presented at the spring meeting of the Iron and Steel Institute, 1927. Both the book and the paper are most interesting historically to makers of alloy steels and

Jan 1, 1931

By H. V. Kinsey

"IntroductionTITANIUM is probably the most widely publicized metal today. Much has been written, both in the lay press and the technical press, about its properties and potentialities. In view of the fact that Canada possesses large quantities of titanium-bearing ore, and could conceivably become a major producer of metallic titanium, it was felt that a paper dealing mainly with the physical metallurgy of titanium would be of interest to this Institute. This paper is concerned chiefly with the useful properties of titanium and its alloys and the fundamentals governing the modification of its properties by alloying.Physical Properties of TitaniumTitanium belongs to a family of metals that have been termed 'gas sensitive' (I), because their mechanical properties are altered by certain gases which they readily absorb and retain. Other metals of this group are zirconium, hafnium, vanadium, columbium, tantalum, and chromium. Titanium has a strong affinity for oxygen and nitrogen and once it has absorbed these gases they cannot be removed either by melting in vacuum or by any degassing agent. These gases, when present in excess of about half a per cent oxygen plus nitrogen, render the metal brittle and useless as a structural material.Some of the typical physical properties of titanium are listed in Table I along with those of common structural metals for comparison."

Jan 1, 1953

By K. D. Luxbacher, J. T. Davis

"A wind tunnel was designed to examine air flow, heat transfer and layering near an active fire at a working face. This tunnel simulates an active entry in an underground coal mine including an attached cross-cut of similar dimensions. A steel rectangular duct 1 ft. (0.305 m) tall, 3 ft. (0.914 m) wide and 10 ft. (3.05 m) long composes the main body of the tunnel and represents a mine entry. Air flow is generated by an exhausting centrifugal fan attached to one end of the crosscut. This fan was sized to supply air velocities based on Froude scaling. A 6 in. (15.25 cm) propane burner is used to simulate fires of various heat release rates at the working face. Thermocouples are used to map heat layering in the tunnel. Ports are installed for the introduction of tracer gases into and from sampling the system. Barometric, differential pressure, and temperature sensors are also included to monitor environmental conditions. Details about the design and testing of the system are presented including an overview of how the tunnel was scaled to accurately represent fire and flow phenomena. Finally, the proposed use of the tunnel for better understanding of mine fire phenomena and prevention is given. INTRODUCTION Fires in underground mines have been a concern since the dawn of mining. While technological advancements, regulations and best practices have improved both fire detection and firefighting techniques, mine fires continue to represent high risk events. From 2006 through 2015, fires accounted for 1.06% of fatalities in underground coal mines and 0.85 percent of fatalities in all underground mines in the United States (U.S. Department of Labor, 2006 to 2015). In addition to the risk of loss of life, mine fires can cause millions of dollars in equipment damages and lost production revenue. Extensive research has been conducted on how fires occur and spread in underground mines. In addition to testing conducted by government agencies such as the Mine Safety and Health Administration (MSHA) and the National Institute for Safety and Health (NIOSH) (e.g.(Liming, 2006), researchers like Verakis and Dalzell (Verakis, 1988) and Lowndes, et. al. (Lowndes, 2004) have furthered this field by studying ignitions and propagation of conveyor belt fires. While the studies of belt fires in mines are extensive, studies focused on fires at the working face are few in number. The particularly confined space and limited access to a working face, coupled with less robust, temporary ventilation controls create a unique environment that warrants special attention. Separate from studies on mine fires, the use of tracer gases to characterize flow patterns in normal mining ventilation is well established. In 1982, Timko and Thimons (Timko, 1982) outlined current and future applications of sulfur hexafluoride (SF6). However, little experimentation has been conducted to study specifically how tracer gases might be used to evaluate active mine fires and the fires’ effect on the surrounding mine environment (e.g.(Lindsay, 2014). In order to better understand the dynamics of smoke layering from a fire in an enclosed space, a small-scale apparatus was designed to map smoke layering and to examine other aspects of fire behavior at a working face. In addition to studying smoke flow around an active fire, experiments will be conducted using tracer gases in order to determine how they might be used to evaluate an underground fire."

Jan 1, 2017

By D. B. Dreisinger, M. Rasouli

"Developing technology to address the environmental hazards associated with selenium in mine-impacted waters has been a serious challenge. Ion exchange (IX) has been identified as a potential treatment technology. This paper begins with a review on selenium adsorption with commercially-available basic anionic exchangers (BAS). It then looks at the use of resins for selenium removal via modification with the addition of -O, -N, or -S-containing chelating ligands and chelating polymeric ion exchangers pre-loaded with immobilized metal cations. The synthesis of chelating exchangers requires a final product with a highly stable metal in the ligand-metal complex. The nature, oxidation state, size, and affinity of the metal for the target oxyanions and the size, degree of protonation and space configuration of the oxyanion are among critical factors affecting the oxyanion uptake. There is a limited number of studies on the critical parameters affecting the selenium affinity for chelating exchangers. Such a study could fill in the gaps of our understanding of selenium-metal-chelating ligand interactions and assist in developing a new ion exchanger. In addition to commercial IX resins, layered double hydroxide materials (LDH) have received attention for oxyanion removal from waste water. The adsorption capacity of the LDHs are affected by the crystallinity of LDH, the nature of metal components, the ratio of metals, charge and type of anion, and the space between the layers. In particular, the Friedel phase (FP), a member of the LDH family, showed high adsorption capacity for selenate removal from synthetic solution. A study is currently underway at the University of British Columbia to investigate the effect of different synthesis methods and aging on the suitability of FP for selenium removal from mine waste water."

Jan 1, 2017

By Lowell S. Thomas

I have been asked to speak to you on the subject of "Scrap Metals from the Army." With your kind permission I'd like to change this subject to "Scrap Metals from Ordnance," as the Property and Salvage Section, which I head, is a part of the Office, Chief of Ordnance, and only handles Scrap, Cuttings and By-products produced by Ordnance establishments. Scrap, Cuttings and By-prod-

Jan 1, 1943

By J. F. Barkley

To reduce fuel consumption in industrial and commercial fuel-burning plants throughout the Nation, cooperative efforts of thousands of individuals are required. These individuals are scattered over the country and hold various positions in thousands of independent establishments. To accomplish as much as possible on this problem during the Second World War, it was decided that personal contact with fuel users was absolutely necessary; publicity, although an important factor, could not by itself give satisfactory and needed results. It was planned to have qualified engineers visit commercial establishments to go over with them the problem of reducing their fuel consumption. The specific plan, toward which all efforts aimed and around which the rest of the program revolved, consisted in brief of 1. Conference of visiting engineer with management to obtain cooperation. 2. Appointment by management of a plant employee as fuel "waste chaser." 3. Work of engineer with "waste chaser" and, if appropriate, with plant operators on most efficient operation of equipment.

Jan 1, 1948

By Jr. Sayre

Results of studies of reservoir and wax-precipitation temperatures relating to wax deposition in the reservoir of the Bradford oil field are presented in this report. During 1949 and 1950 Bureau of Mines engineers made temperature measurements in 42 wells, which indicate that the Bradford Third-sand temperatures range from 59.7° F., at 1,150 feet, to 71.9° F., at 2,040 feet. Reservoir temperatures measured at the same depths in newly drilled wells and oil-producing wells differed as much as 4.5u F. Injection-well temperatures measured during water injection showed that the temperature of the water entering the sand was 11.5° F. lower than reservoir temperatures before injection. The cooling in the formation resulting froth the injection of low-temperature water was 11.5° F. in the vicinity of the injection-well bore, and a maximum of 2.1° F. 200 feet from the injection well. Sand temperature, after 5 months of water injection, was reduced 1.5° F. 90 feet from water-injection wells. The temperature at which wax begins to precipitate from solution in crude oil was determined at atmospheric pressure for 26 samples and ranged from 51° to 67° F. Oil samples from wells producing no water had wax-precipitation temperatures ranging from 51° to 58° F. and wax contents from 2.20 to 2.97 weight percent, whereas the samples from wells producing water and oil had wax precipitation temperatures ranging from 580 to 67° F. and wax contents from 2.57 to 3.42 weight percent .

Jan 1, 1952

One Hundred Sixteenth Meeting of the Institute, Monday, Feb. 18, to Thursday, Feb. 21, inclusive, 1918 A preliminary program, for the New York Meeting was printed in the January Bulletin, and a more detailed program was mailed to all members early in January. The following schedule is the outcome, of sundry committee meetings up to the middle of January. Committee on Arrangements J.` E. JOHNSON, JR., Chairman BRADLEY STOUGHTON, Vice-Chairman RALPH W. DEACON MRS. S. J. JENNINGS E. M. SHIPP J. V. N. DOER A. R. LEDOUX G. D. VAN ARSDALE L. `V. FRANCIS . . F. T. RUBIDGE ARTHUR L. WALKER Summarized Program MONDAY, FEBRUARY 18 9 a. m. to 5. p. m. Registration at Institute Headquarters. 10 a. m. Sessions on Coal and Non-Ferrous Metallurgy. 12.30 p. m. Luncheon at Engineering Societies'. Building. 2 p. m. Visit to Subway Workings.

Jan 2, 1918

By J. Moyes

The Intec Process is a generic process for the production of pure base metals and precious metals from sulphides concentrates derived from copper, nickel, zinc and lead ores. The development program for the Intec Process initially focussed on the treatment of copper concentrates, (the ?Intec Copper Process?), and more recently of zinc concentrates, (?the Intec Zinc Process?). Developed and proven in Sydney, Australia at a cost of US$15m over the last ten years, the Intec Copper Process is now ready for commercial application. The knowledge gained during the development of the Intec Copper Process has been applied to the Intec Zinc Process, which utilises the same basic chemistry to produce high purity zinc ingot from metallurgically complex zinc sulphide concentrates containing lead, copper, iron, silver and gold. The demonstrated ability of the Intec Zinc Process to treat low grade mixed zinc/lead/copper concentrates, including those with high iron and manganese levels, holds out the real prospect of overcoming major metallurgical hurdles that have long affected the zinc industry. The Intec Zinc Process consists of the three consecutive circuits of leaching, purification and electrowinning. The leach circuit is of single stage configuration with a series of reactors to which concentrate and lixiviant are fed. Purification consists of cementation and precipitation by pH adjustment. Electrowinning employs an electrolytic cell very similar in design to that of the Intec Copper Process, but differs in that a conventional plate cathode is produced. During electrowinning, the same mixed halide species (BrCl2 -, HalexTM) that is integral to the Intec Copper Process is generated in solution at the anode and exhibits powerful leaching characteristics capable of directly leaching the sulphide concentrate feed. The need to roast the concentrate prior to leaching, as is practised in the conventional Roast/Leach/Electrowin (RLE) process, is thus eliminated whilst a range of by-products (notably lead, copper and precious metals) can be extracted in the simple, single-stage leach. This paper describes the Intec Zinc Process; the technology, predicted economics and its environmental aspects.

May 1, 2002

By J. A. Innes

"""The oxygen, next uniting with the carbon, sent up an ever-increasing stream of sparks and a voluminous white flame. Then followed a succession of mild explosions, throwing molten slags and splashes of metal high up into the air, the apparatus becoming a veritable volcano in a state of active eruption.""IntroductionHenry Bessemer F.R.S(An autobiography, 1905)Thank you Mr Chairman for the opportunity to speak: at this, the opening session of your International Symposium on the subject of ""Injection in Pyrometallurgy"". Judging from the list of papers to be presented over the next three days, the Symposium promises to provide a most valuable addition to our existing knowledge base in what is now an extremely active area of R&D investigations. Whilst we have obviously come a long way since Sir Henry Bessemer's pioneering experiments of the mid-19th century, there is still much for us to learn.Most importantly, the Symposium offers a further opportunity to acknowledge the many significant technical contributions made in this field by the Organising Committee's special guest, Professor Howard Worner - one of this country's most respected research leaders.When first approached to give this talk I had two areas of concern. Firstly, I was not entirely clear just what injection metallurgy was meant to cover. How should the overall scope of this particular subject be defined?My second concern related to Howard Worner himself - a man for whom I have the highest personal regard and who, in fact, played a most influential role in respect of shaping my own career. Having already spoken about Howard's achievements on earlier occasions, I wondered what I could sensibly add.Notwithstanding these personal reservations, I am delighted to be here with you this morning. If my thoughts on the meaning and scope of injection metallurgy appear to be slightly off-course, and if Howard should perhaps recognise some repetition in my remarks, then I hope I can be forgiven."

Jan 1, 1996

By L. Luini, E. Lee

An exploratory survey of the heat treatment response of commercial titanium alloys (Ti-150A, RC-130B, and MST 3AI-5Cr al-loys) shows a wide range of possible hardness and microstructural characteristics. The hardening is primarily dependent on the solid state transformation of the phase. An age hardening reaction which apparently is associated with ß decomposition and precipitation has been shown. Brittleness and notch sensitivity appear to be characteristic of age hardening to high hardness. Ductility, tensile strengths, and elongations are given. A NUMBER of commercially produced titanium-base alloys have been made available by the titanium metals industry. These alloys were developed to combine the light weight of titanium with increased strength through alloy additions. Usually the properties of these alloys are reported for material in the hot rolled and annealed condition. Since the production of commercial titanium has preceded the investigation of titanium-base alloy systems, the potential of these alloys is not well known. Although heat treatability has been indicated for these alloys, data on the response to heat treatment are quite limited. The heat treatability of titanium is based on the allotropic transformation of the high temperature, body-centered cubic ß structure to the low temperature, hexagonal close-packed a structure at approximately 1625 °F. This transformation in the pure metal is of little practical significance in heat treatment since the high temperature phase is not amenable to controlled transformation. Alloy additions serve to alter the transformation kinetics and permit control of the transformation by heat treatment variables. The effects of different alloys on the allotropic transformation in titanium classify them in two general categories,1 a stabilizing and ß stabilizing elements. The a stabilizers, represented by aluminum and oxygen, raise the temperature limits of the low temperature phase and introduce a two-phase a + ß temperature range. The ß stabilizers, represented by molybdenum and columbium, lower the equilibrium temperature of ß and give rise to an extended temperature range where both a and ß phases are stable. Another type of ß stabilizer, represented by iron, chromium, and manganese, introduces a eutectoid reaction. Some commercial titanium alloys belong to complex multiple element systems. Based upon the phase diagrams of the binary systems, the general effect of commercial compositions is to vary the stability of the high temperature phase and significantly alter its transformation characteristics. Therefore it is expected that the characteristics of alloyed titanium can be altered by heat treatment. The present investigation was undertaken to survey the variations in hardness, microstructure, and mechanical properties as affected by heat treatment variables. Commercial Alloys lnvestigated The commercially available titanium-base alloys selected for this investigation and obtained as 3/4 in. diameter hot rolled and annealed bars are listed in Table I. The producer did not determine the chemical composition of the Ti-150A heats X1052 and L685. The early heats of Ti-150A, prefixed with the letter X, were melted with tungsten-tipped electrodes and cast in approximately 500 lb ingots 12 in. in diameter. The heats prefixed with the letter L were melted under a revised melting practice yielding approximately 1300 lb ingots 16 in. in diameter. The final annealing treatment was at 1200" to 1250°F for 1 hr. The MST-3A1-5Cr alloy was melted in an induction furnace and cast in 7 in. diameter ingots. This practice produces high carbon material and some variation in the amount of carbides was found in different sections of the same bar. The RC-130B alloy was melted with a carbon arc. This alloy showed approximately 2 pct carbides. No large segregation effects were observed.

Jan 1, 1955

By R. V. Ramani, A. S. C. Owili-eger

? THIS PROGRAM SIMULATES METHANE FLOWRATES THROUGH THE GOAL ? SEAM BY THE GAUSS-SEIDEL ITERATIVE TECHNIQUE. THE MODEL IS A TWO ? DIMENSIONAL SYSTEM. THE ITERATIVE FORM OF THE GAUSS-SEIDEL IS ? OBTAINED FROM A PARTIAL DIFFERENTIAL EQUATION OF FLOW BY CENTRAL ? FINITE-DIFFERENCING APPROXIMATION SCHEME ? NPRESS IS THE NUMBER OF SPECIFIED PRESSURES EXCLUDING ? RESERVOIR AND FACE PRESSURES ? NQUAN IS THE NUMBER OF SPECIFIED FLOW QUANTITY.... EXCEPT FLOW ? OUT OF THE FACE. THIS- QUANTITY CAN BE POSITIVE(INJECTION) OR ? NEGATIVE ( PRODUCTION) ? XPERM(I,J) I S THE DIRECTIONAL PERMEABILITY IN THE X-DIRECTION AT THE POINT (I,J) ? YPERM(I,J) IS THE DIRECTIONAL PERMEABILITY IN THE Y-DIRECTION ? AT THE POINT (I,J) ? RESEP' IS THE RESERVOIR PRESSURE ? FACEP IS THE FACE PRESSURE. THIS PRESSURE IS ASSUMED TO BE ? APPROXIMATELY ATMOSPHERIC ? LENGTH, WIDTH, AND THICK ARE THE ZONE OR MEDIUM DIMENSIONS * PUHL I S A DUMMY NAME FOR VISCOSITY ? DMAXI IS VARIABLE NAME FOR INITIAL MAXIMUM ERROR OF ITERATION ? DMAXF IS A VARIABLE NAME FOR FINAL MAXIMUM ERROR OF ITERATION ? NITER IS A VARIABLE NAME FOR STORAGE OF NUMBER OF ITERATIONS ? RAD IS A VARIABLE NAME FOR THE SPECTRAL RADIUS OF THE GAUSS¬ ? SEIDEL MATRI-X. THIS PARAMETER ALSO MEASURES THE RATE OF ? CONVERGENCE OF THE ITERATION ? KOUNT IS AN ITERATION COUNTER ? MAXIT IS THE MAXIMUM NUMBER OF ITERATION SPECIFIED BY THE USER # EPS IS THE MAXIMUM RESIDUAL ALLOWABLE ERROR-FOR CONVERGENCE

Jan 1, 1974

By G. C. Stone

At the conclusion of my paper on the same subject read at the Boston meeting of the Institute, I offered to send some of sample No. 2 to any chemist who wished to analyze it. Eight chemists wrote to me for samples; so far I have received results from five. I give these results in a table (on the following page), together with the results previously obtained: As to the chemists and their methods : K is an iron-works chemist whom I only know by correspondence; lie writes: "No. 27(13.64) was obtained by the method I generally use, as follows : Dissolve 0.8 grams spiegel in hydrochloric acid and a little potassium chlorate, in a half-liter flask. Boil off most of the acid, add ammonia in slight excess, redissolve in acetic acid, using rather more than is really necessary, and then add 8 or 10 grams of sodium acetate and make up to the mark with warm water. Boil hard for fifteen minutes, then allow to settle (cool?), until the liquid reaches the mark, and withdraw 300 C.C. of the nearly clear liquid. Add to this an excess of hydrochloric acid, evaporate to dryness, take up with hydrochloric acid and water, and separate the iron by two precipitations with ammonia (I have often tested the ferric hydrate for manganese, but have never found any, if the separation by ammonia was properly made). Finally, precipitate the manganese as phosphate." Nos. 28, 29 (13.35, 13.07) were by Ford's method." No. 30 (13.50) was by Troilus's method He writes, " I may add the results are quite as good as I expected, although for any element except manganese, they are not close enough for anything like accurate work." L is a firm of commercial chemists of large experience who have made a specialty of iron work. Their method is as follows : Dissolve

Jan 1, 1884

By Julian W. Feiss

Before undertaking to present to you a current analysis of copper, I would like to preface my remarks with a few observations that in themselves have a bearing upon commodity reviews in general. Having sat through a large number of such reviews since first joining the A. I. M. E. nearly forty years ago, I have no illusions about the hazards of the undertaking. If a speaker presents a statistical summary of commodity economics for the last year, most of his audience, having already read at least four commodity summaries on the identical subject, either get up and walk out or fall asleep. Should the latter happen, and were the listener to tumble from his chair and break his neck, obviously the speaker is liable. The subject matter seldom lends itself to histrionics on the part of the speaker so dangers of heart attack in the audience are not too great. Therefore the speaker, in order to retain listener interest, resorts to prophecy. Such venture was undertaken long ago by weather soothsayers, the "harouspex" of Ancient Rome, who generally cut up a sacrificial sheep and after staring at the entrails made their predictions which I understand had a batting average somewhat better than those undertaken on Wall Street based upon Dow Jones averages. Not being a licensed harouspex I cannot undertake predictions. I shall, however, fall back upon the experts.

Jan 1, 1965

By George W. Maynard

For an account of the discovery and the determination of chromite on Port au Port Bay I am indebted to Mr. Obalski, Government mining engineer for the Province of Quebec. He writes: " In June, 1894, with the authorization of our Government, I went to Newfoundland to examine some asbestos property. Passing through Halifax, I had interviews with some gentlemen who told me that besides the asbestos there was in the same district a big deposit of iron-ore. They handed me some specimens, and, after ascertaining that they were not magnetic, and learning that they were found in serpentine, I said they were chromic iron. I visited the place on June 27, 1894, and confirmed my opinion, pointing out at the same time the importance of the deposit, as appears in my report of July 9, 1894. I do not claim any credit for the discovery of chrome-ore in Newfoundland; but, as a matter of fact. when I came in contact with the Halifax gentlemen they did not appear to know the nature or the value of the mineral until I mentioned to them that it was chromite. "' Mr. Obalski's report was mainly devoted to the asbestos-deposits. That portion relating to the chromite was as follows: " On the right side of the creek there is a show of chromic iron of good quality, which appears scattered through the serpentine in several places on the face of the cliff for 40 to 50 feet. A few boulders are found farther up at a distance of 100 feet, and also in the ckeek itself. From this point the deposit exists on a relatively large area, the widest exposures being from 6 to 7 feet. Chromic iron deposits in serpentine rock have no regularity, and are merely pockets. In the case of the property in question this rule is not changed, but the pockets look to be of large extent, and could be easily worked." My own preliminary investigation of the property was made

Jan 1, 1898

By Perry JH, King RL

The Bureau of Mines in cooperation with Kaiser Steel Corporation conducted two methane drainage studies in an advancing section of the Sunnyside No. I Mine where production was being severely hampered by methane emissions. A total of six horizontal aoreholes were completed during the studies to an average length of 291 meters. Total gas production from the boreholes as of December 1981 has exceeded 6,088,800 m3. Methane emissions into the section were reduced by 40 pct as a result of the first drainage system. The second drainage system is currently producing 11,328 m3/day from four Doreholes. Mining of the section and cementing of the horizontal horeholes is expected to begin within 2 Years.

Jan 1, 1982

By P. Douglas, G. M. Leak, B. Mills

The sinusoidal surface relaxation technique has been used to measure the surface self-diffusion coefficient of spectroscopically pure nickel over a wide temperature range under a hydrogen atmosphere. A kink in the Arrhenius plot has been observed. In the temperature range T/T 0.98 to 0.80 (T in O K and T, is the melting temperature) the average self diffusion coefficient is given by Below the temperature T/T,- 0.80a decrease in the slope of the log Ds us 1/T plot is observed. This is associated with a diffusion process characterized by a lower activation energy (-20,000 cal mole'') and smaller preexponential term (-10- sq cm sec"). A series of experiments were carried out at T/Tm = 0.61 under a hydrogen atmosphere of higher oxygen partial pressure than for the rest of the experiments. It was found that Ds was significantly depressed due to oxygen adsorption. This evidence supports the opinion that the low temperature process (activation energy -20,000 cal mole-') is unlikely to be due to oxygen adsorption. An interesting feature of the present data is that the transition temperature (T/Tm - 0.80) is a function of orientation. For a small number of crystals of measured orientation the transition temperature was observed to be higher towards the low index (100) pole. Theories of surface diffusion are briefly reviewed and it is concluded that the present reszuts are best explained by invoking a surface roughening process. GJOSTEIN has recently analyzed available surface diffusion data for a wide range of metals. He suggested that two mechanisms were operative for fcc metals, an adatom process at high temperatures and a vacancy process at low temperatures. Results for nickel can be summarized as follows. At low temperatures (T/T, - 0.3 to 0.44) under ultra high vacuum conditions, Melmed2 measured an activation energy Q of 21 kcal mole-' using field electron emission microscopy. At higher temperatures (T/T - 0.7 to 0.9) under a vacuum of 10- ' torr, Maiya and lakel measured y as 39 kcal mole-' using the multiple scratch smoothing technique. The present work was undertaken to try to find out if two distinct processes could be observed. High temperature results give Q about 47 kcal mole-': there is evidence also for a low temperature value of about 20 kcal mole-'. These measurements were all made under a hydrogen atmosphere, in the temperature range 860" to 1412°C. Concurrent with the present study Bonze1 and jostein> have also observed a break in the Arrhenius plot for the (110) surface of nickel. These measure- ments under ultrahigh vacuum conditions using the laser diffraction technique are in excellent agreement with the work reported here under hydrogen annealing conditions. THEORY The available surface relaxation techniques include single and multiple scratch smoothing and grain boundary grooving. The processes have been compared in detail by Gjostein for conditions where surface diffusion dominates6 and Mills et al? where volume diffusion dominates. In summary the relevant points are as follows. Grain boundary grooving gives an average Ds for the two surfaces adjacent to the boundary and this can, to some extent, be simplified by using symmetrical bicrystals. This technique has been used to study the effect of environment on Ds for silver and copper.'-'' Scratch techniques yield Ds values for the small orientation range exposed by the scratches (-2 deg). The multiple scratch process is preferable because the profile rapidly becomes sinusoidal and can then be interpreted theoretically in a relatively simple way. Also corrections for mass transport processes other than surface diffusion can be introduced easily. Mullins" considered a sinusoidal profile described the wavelength of the profile. After time t the profile can be described by the equation The terms A, A', C, and B which account, respectively, for contributions due to evaporation-condensation, diffusion through the gas phase, volume diffusion through the lattice, and surface diffusion are defined as: where Ds = the surface self diffusion coefficient ys = the surface energy per unit area p = the equilibrium vapor pressure over a flat surface pa = the equilibrium vapor density over a flat surface DG= the diffusion coefficient of vapor molecules in the inert gas DM = the mass transfer diffusion coefficient which for a pure cubic metal is Dv/f where Dv is the radiotracer diffusion coefficient and f is the correlation factor H = the molecular volume V = the surface density of atoms, il2'3 M = mass of an evaporating molecule

Jan 1, 1970

By Victor R. Eyzaguirre

Cerro Verde is one of several large porphyry-type copper deposits in Southern Peru. The copper occurs as primary sulphides, with a significant oxide capping. The exploitation of the deposit has been correspondingly divided into two stages, the first consisting of copper production from oxides, and the second from sulphides. Minero Peru successfully started the Stage I plant in June of 1977 with the first production of electrowon copper cathodes. This paper is essentially devoted to a description of the Stage I process, which can be summarized as follows: Ore is trucked to the primary crusher, where it is crushed to 225 mm and conveyed to a coarse ore stockpile. Ore withdrawn from the stockpile is secondary crushed to 65 mm, conveyed to a truck loadout bin, loaded into trucks and driven to the leaching pads. Ore is placed on the pads in lifts and sprayed with sulphuric acid solution to dissolve the copper. Copper-bearing solution forms a pond behind a dam at the lower end of each pad and is pumped from there to the solvent extraction plant. Copper is extracted from the leach solution into an organic phase and is then stripped from the organic phase to form a purified concentrated copper solution suitable for feed to electrowinning. In electrowinning, the copper is finally recovered as cathodes suitable for sale as refined copper.

Jan 1, 1978

By J. B. Cheatham

Applications of the mathematical theory of plasticity promises to lead to the solution of many drilling and rock mechanics problems. ,Because of mathematical considerations, the inelastic behavior of rock has frequently been represented by a perfectly plastic model in conjunction with a yield criteria of the Coulomb or Mohr type. The totality of all stress states for which a solid ceases to behave elastically can be represented as a limit surface in stress space. ,Probing of such limit surfaces indicates details of strain hardening which are not provided by the standard triaxial testing procedure. Probing tests of the limit surfaces have been performed on Cardova Cream limestone to provide data for extending plasticity theory to cover situations in which consolidation and strain hardening are present. Test results indicate that this highly porous limestone undergoes a permanent volume decrease when it is subjected to hydrostatic pressures in excess of 3,500 psi. A virgin sample tested under a confining pressure of 1,500 psi has a yield strength of 1,700 psi; however, if the sample is subjected to a consolidation pressure of 5,000 psi, before testing at 1,500 psi, the yield strength is raised to 2,300 psi. Thus, both consolidation and strain hardening are important considerations in describing the mechanical behavior of this limestone. Tests conducted with the axis of the core having different orientations indicate that this rock is also anisotropic. Portions of the initial and subsequent limit surfaces are determined for samples loaded either perpendicular or parallel to the bedding planes. INTRODUCTION Previous experimental work in rock mechanics indicates that no mathematically tractable constitutive theory is inclusive enough to describe the mechanical behavior exhibited by all types of rocks under all conditions of stress and temperature. Indeed, the type of deformation encountered in a single type of rock is known to depend upon the stress and temperature conditions in the rock during deformation.l-5 Certain rocks and minerals, notably those minerals composed of ionic salts, have been shown to exhibit plastic deformation when tested under conditions of high confining pressure.2 Since the mathematical theory of plasticity provides simplifications over the theory of elasticity in certain types of problems, such as those in which limit analysis can be applied, it is of interest to know under what conditions plasticity theory may be applied to rock mechanics problems. The following factors determine the nature of the deformation a particular specimen will undergo: (1) the microscopic structure of the rock, i.e., the structure visible under an optical microscope, including number of phases, porosity, distribution of phases, (2) the mineralogical structure of the solid phases, (3) the conditions of stress and the rate of change of stress and (4) the temperature. Extensive experiments on Yule marble, Carthage marble, Solenhofen limestone and other calcerous rocks indicate that these relatively nonporous rocks deform plastically under certain conditions of loading, and creep under other conditions of loading.l-3 This study is concerned with the behavior of Cordova Cream limestone (Austin chalk) which is also composed almost entirely of calcite and thus has the same mineralogical composition but, because of a rather large porosity, it possesses a different microscopic structure. This investigation was undertaken to learn if Cordova Cream limestone deforms plastically despite the embrittling effect of the pore spaces, and to provide data which can be used to determine whether the mathematical theory of plasticity can describe the mechanical behavior of Cordova Cream limestone. A brief discussion is given of some of the underlying principles of plasticity theory concerning stress space and limit surfaces. Strain hardening is defined and a discussion is given of how the mechanical behavior of a material can depend on the previous history of the loading. This is followed by a description of the experimental procedures

Titanium tetrachloride may be reduced to trichloride with hydrogen on a hot tungsten filament and other hot: surfaces. The effect of temperature, time and size of t.he filament on the rate of reaction has been studied. A laboratory unit for preparing a few pounds of trichloride at a time is described. The yield of trichloride is 2·2 - 2·4 gm/sq. cm. of hot surface/hour at 1,000°C. and the energy requirement 3'5-4 kWh/pound of trichloride produced.'INTRODUCTIONThe lower chlorides of titanium (titanium tri- and dichlorides) are amenable to electrolysis, being electrovalent in nature. Furthermore, relative to other oxygen-free titanium salts, they are easy to prepare in a pure state and their use has been investigated to prepare titanium. The experimentaJ work described in this paper deals with the preparation of titanium trichloride by reduction of titanium tetrachloride with hydrogen on hot surfaces.REDUCING AGENTS FOR TITANIUM TETRACHLORIDEThe free energy diagram (Fig. 1) for the formation of chlorides suggests that titanium' tetrachloride may be reduced to trichloride by various reducing agents such as aluminium, zinc, arsenic, antimony, tin, mercury, silver, hydrogen, sodium, potassium and magnesium. Ruff and Neumann (1923), Thorpe (1885) , Billy and Brasseur (1935) and Seurbert and Schmidt (1892) used various metals to reduce tetrachloride to trichloride and found that the yields were invariably low and the products difficult to separate.Besides the metallic reducing agents, hydrogen may also be used to reduce titanium tetrachloride to trichloride.Goerges and Stahler (1909) obtained a deposit of violet...

Jan 1, 1956