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By Robert H. Peters

This U.S. Bureau of Mines report identifies the types of serious accidents that occur most frequently at small underground coal mines and describes the strategies that could help prevent these accidents. A wide variety of methods for improving safety are suggested, including improvements in the design of equipment, work procedures, work schedules, safety programs, and emergency response plans, as well as techniques for diagnosing the potential hazards associated with new technologies and work procedures. Some of the papers in this volume focus on preventing specific types of mining accidents-ones associated with materials handling (primarily back injuries), equipment maintenance, improper machine guarding, and ground failure during retreat mining. Although the recommendations in this volume are heavily influenced by research performed at underground coal mines in the Appalachian coalfields, most of the papers contain advice that is equally pertinent to almost any type of mine.

Jan 1, 1994

During development mining, ventilation capacity may decrease and the ventilation requirements may depart from initially planned values depending on the mining rate, increases in the methane emission rate, and changes in ventilation airway leakages. Insufficient ventilation air quantities and the occurrences of high methane liberation rates can overwhelm the existing quantity of ventilation air and result in elevated levels of methane gas during development mining. This condition can both limit the development of that section and increase the risk for an ignition that may lead to an explosion. Thus, the prediction of ventilation air requirements prior to mining can enhance worker safety by reducing the likelihood that explosive methane-air mixtures form. This study presents an approach for prediction of methane inflow rates using coalbed methane reservoir modeling. For this purpose, a two-phase coalbed reservoir model of a three-entry type roadway is developed. In the model, grids are dynamically controlled to simulate development of entries. Examples are given for methane inflow and ventilation air requirements as a function of mining rate, development section length, mining height, and the existence of degasification boreholes. This technology can be used to limit the methane concentrations occurring as a result of the influences of various coalbed and operational parameters.

Jan 1, 2008

By L. H. Reiss, J. Groult, L. Montadert

Many fields, where the reservoir is composed of sandy layers, show great complexity because of the lack of continuity which results from a particular type of seditnentation. This complexity may be a factor of prime importance in studying reservoir drainage, especially in the displacement of oil by water or gas. This paper describes work done to study this heterogeneity and its influence in the exploitation of the fields of the lower Devonian sandy shale in the Fort Polignac Basin in Algeria. Two lines of research were followed. 1. On the border of the hasin, a detailed sedimentological study established rules for the distribution of the sandy zones, which furnished hypotheses necessary for devising a geologic model of the reservoir. A certain number of sandy zones were recognized and characterized by their sedimentation. 2. In the interior of the basin, production logs deterrnined the productivity profile. Study of these point data led to a description of the distribution of oil and gas phases in the reservoir so that the continuity of different zones between the wells could be deduced. These techniques were applied to the study of the lower Devonian sandy shale reservoir of Zarzaitine. The sedimentological study guiding the correlation work, with the aid of the conventional static data (logs and cores), led to the establishment of a useful geologic model of the reservoir. Production logs, thanks to the contribution of dynamic elements, permitted corrobora-tion of the model. In particular, the logs confirmed separation, as proposed by the sedimenfological study, of two comparable sandy groups by revealing the continuity of a thin impermeable layer, invisible on conventional logs. INTRODUCTION The heterogeneity of sandstone reservoirs considerably influences the distribution of fluids, as well as their displacement in the reservoir. Rational development of a field and maximum recovery of hydrocarbons are closely tied to an exact and precise knowledge of the intern architecture. We will try to show how it is possible I refine the knowledge of the reservoir by seeking qui different and varied sources of information. Productic geology, the group of techniques which leads to idei concerning reservoir architecture and its geometric descris tion, furnishes the framework of this undertaking. Of these techniques. those used so far are qui varied. Descriptive as well as quantitative, the technique partake as much of classical geology as of reservo science. They include (1) geologic studies of the enti basin, especially a stratigraphic and sedimentologic study of the reservoir member at its outcrop, detail1 observations of cores taken from wells and, finall oriented cores; (2) interpretation of geophysical dat (3) interpretation of electric logs, nuclear and sonic lo and dipmeters: (4) petrophysical study of the reserve on samples taken from wells; (5) reservoir dynamics (stu of the production history and, in particular, interpretati of production logs); and (6) analysis of the fluids a thermodynamic studies. This incomplete list could also include (1) study the migration of the fluids, (2) geochemistry (chemi characterization of the oils), (3) regional hydrodynamii and (4) injection and detection of tracers. If most of these techniques are classic, attention i nevertheless be called to applying two of the techniql in conjunction: the study of the reservoir member its outcrop and the study of dynamic distribution fluid phases in the reservoir through use of product logs, used in the study of the sandy shale reservoirs the lower Devonian of the Fort Polignac Basin, Alge in particular, their application to the study of the 2 zaitine field where they have led to a new and satisfact model of the reservoir will be described. THE ZARZAITlNE FIELD Situated in the interior of the Fort Polignac 8 about 150 kilometers (km) north of the lower Devol outcrop, the Zarzaitine Devonian oil field was discovc On Ian. 28, 19'' (Figs. 1 and l8). It is in the fern a monocline truncated by two perpendicular fault: great throw, with a downthrown section to the north\: Erosion at the top of the structure has caused one of it to disappear. It is a reservoir with a gas cap an m coefficient on the order of 1:5, open to the aql On the northeast, with the oil zone covering an Of 106 sq km and with initial oil reserves of 222 mi

Jan 1, 1967

By Chuan-fu Zhang

In present work, the physical properties of molten FenO-MgO-CaO-SiO2 slags were measured .It is shown by the results that when the slag composition is as follow: MgO 8%~12%, CaO 2%~8%, Fe/SiO2 1.2~1.6, the viscosity of the slags decreases with the increase of temperature. When the Fe/SiO2ratio and the MgO content are fixed, the electrical conductivity increases and the viscosity decreases as CaO content increasing, while the content of CaO exceeds 6% its influence weakens. When the MgO content is 11% and the CaO is 6%, the viscosity of the slag decreases markedly as the increase of Fe/SiO2 ratio. Its influence to viscosity is inconspicuous when the Fe/SiO2 ratio exceeds 1.5. When the CaO content is 6% and Fe/SiO2 is 1.2, the electrical conductivity decreases with the increase of MgO content as temperature is below 1290, but increases when temperature is above 1290. When the MgO content is 11% and the Fe/SiO2 ratio is 1.2, the electrical conductivity increases with the increase of CaO content. When the CaO content is 6% and MgO content is 11%, the electrical conductivity increases as the increase of Fe/SiO2 ratio, while its influence weakens as the temperature increases continuously. The electrical conductivity rises when temperature increases at any slag content. The melting temperatures of FenO-MgO-CaO-SiO2 semi- synthesis slags from this work were below 1290.

Jan 1, 2006

By Michael R. Brown

A facilities success or failure of doing well during a regulatory inspection is typically measured by the number and type of citations that result, and financial liability resulting from those citations. The success of a facility during an inspection depends on several factors including, the preparation prior to an inspection, behavior and activities during and inspection, and finally, action taken following the inspection. This paper contains suggestions for improving inspection results and establishing an attitude of compliance at manufacturing and mining facilities.

May 1, 2002

By A. M. Dale, J. Standeven, B. Evanoff

We encountered several areas of methodologic uncertainty during development of a data collection method for use with vibrating hand tools in metal assembly. A local manufacturer sought our assistance designing a data collection method for evaluating and predicting risks of upper extremity disorders associated with use of vibrating hand tools. Current methods of vibration measurement are described in ISO 5349 [2]. However, the complexity of measuring vibration along with other exposures such as force and posture has limited the number of workplace-based studies of upper extremity disorders that have included direct measurements of vibration. Data from this preliminary study was used to look at two issues: a comparison of vibration values between production and non-production workers when performing the same task, and a comparison of worker ratings of vibration comfort to direct measurement of tool vibration. Methods Eight experienced production workers used each of six metal fastening tools to install fasteners. Vibration was collected by 3 tri-axial accelerometers, one attached to the tool handle following ISO 5349 recommended locations, one attached to the hand dorsum on the 3rd knuckle and one to the thumb side of the wrist. Data sampling rate was 10,000 samples/second. Hand grip and feed forces were obtained using a Novel pressure sensing mat on the palm. Each trial consisted of installing 10 fasteners per tool for each of the 6 tools. The test set-up placed the wrist in the position typically used by the operator during production. Each worker documented subjective comfort and effort ratings on a seven point scale following each series of fastener installations. One series of testing was completed by three non-production workers inexperienced in fastener installation to simulate use of alternative employees for data gathering. Vibration data for each trial were acquired, digitized, and stored using Lab View. The X, Y, & Z axes were used to calculate the vector sum response for each tri-axial accelerometer. The tool data were digitally filtered following ISO recommendations. Calculated data consisted of the mean RMS over the tool’s on- time, the starting and breaking peak impulses, and the peak of the frequency response. Results Production workers (n=8) were right hand dominant males with a mean age of 55 years and normal hand strength (mean right grip = 106 lbs). Non-production workers (n=3) had similar characteristics. We found large and statistically meaningful differences in hand force during tool use between production and non-production workers (mean production workers = 9.77 lbs, mean non-production workers = 43.30 lbs, p = 0.0001). Vibration values obtained from the hand also showed a statistically meaningful difference (mean in production workers = 0.67 Gs, mean in non-production workers = 1.48Gs, p = 0.0014, figure 1). Experienced worker ratings of comfort during tool use demonstrated a moderate correlation with measured vibration (r=0.63). Worker ratings trended with direct recordings from the tool handle as shown in figure 2.

Jan 6, 2006

By John E. Hockett

The need for basic information about the relationship between resistance to dejormatim (flow stress), temperature, strain, and strain rate, for the solution of metal-fovming problems, is pointed out. Some early attempts to satisfy the need are mentioned. A brief description of a machine called a Cam Plastome-ter is given, including the processing of results of testing in the machine. Next, a program of testing aluminum in compression over a wide range of constant true-strain rates (0.1 to > 200 sec-1) and a modevately broad range of temperatures (223° to 673°K) is described. The results of this program are presented in the form of true-stress us true-strain cuvves. The data in these curves are presented in the form of relationships between true stress and true-strain rate in sermilogarithmic and log-log form, as functions of temperatures—for several true strains. Finally, true stress, for a given true strain, is displayed as a function of log true-strain rate and absolute temperature, i.e., a surface. SINCE the publication of Hill's book1 on plasticity theory, increasingly rapid advances have been made in analytical solutions to forming problems. Methods in common use are the slab method, the uniform deformation energy method, the limit analysis method, the slipline field method, and the semiexperimental method called "visioplasticity". These approaches, and examples of their use, are covered in detail by Johnson and Melloor2 and by Thornsen, Yang, and Kobayashi.3 unfortunately, practically all of the above work has had to rely upon a number of basic assumptions, e.g., homogeneous deformation and Coulomb (sliding) friction; and virtually no dependence of the mechanical behavior of the deforming metal, upon temperature, strain, and strain rate, has been included. It is with this dependency that this paper is concerned. Loizou and sims4 looked at the above relationship for lead using both a constant compression-speed Cam Plastometer and a constant true-strain-rate Cam Plastometer designed by Orowan.5 Alder and Phillips8 investigated the relationships for aluminum, copper, and steel in the same constant true-strain-rate Plastometer. cook7 tested twelve steels at temperatures ranging from 1170° to 1473°K in the same Plastometer over a range of true-strain rates of 1.5 to 100 sec-'. The writer tested commercially pure aluminum at room temperature and depleted uranium at temperatures from 573" to 873°K at strain rates from 10-3 to 1.0 sec-1 in a Cam Plastometer designed and built at Los Alamos Scientific Laboratory.8 During the past few years the Cam Plastometer at Los Alamos has been used for a number of relatively minor experiments on brass, mild steel, duralumin, Armco iron, and depleted uranium. In this time the machine has been continually modified and improved. It was decided to utilize fully the wide range of strain rates now available with the machine by testing a material about which some information was already in the literature. Prior work on commercially pure aluminum6 appeared to deserve confirmation and expansion. So it was decided to explore the resistance to compression of this material over the currently available range of constant true-strain rates and a convenient range of temperatures. This paper is a report of that exploration. I) EQUIPMENT AND PROCEDURE The principal item of equipment is, of course, the Cam Plastometer, the working part of which is shown in Fig. 1. In this figure, an aluminum specimen may be seen between two tungsten carbide platens, in position for a room-temperature test. Above the upper carbide platen is a load cell. Output from the load cell is amplified and applied to a galvanometer in a recording oscillograph. Auxiliary equipment includes the oscillograph, the control console, a counter, and a time-mark generator. The counter is first used in adjusting the time base. Then it registers the count, of sixty pips per revolution generated by the rotating cam, in each second. These pips and the time base are also applied to galvanometers in the oscillograph. Thus, load, time, and cam position are recorded simultaneously. Heating of a specimen prior to compression is done

Jan 1, 1968

By Espi J

The Nena high sulphidation deposit, located in the Sandaun Province, PNG, contains a measured and indicated resource of 51 Mt of copper ore grading 0.5% Cu and 0.6 g/t Au at a 0.5% Cu cut-off. The copper orebody is overlain by an 18Mt oxide gold resource grading 0.1 % Cu and 1.4 g/t Au at a 0.6 g/t Au cut-off. The deposit is hosted in advanced argillic altered pyroclastics interstratified with lavas, volcanoclastics, epiclastics and sediments of the Debom Volcanics within the Frieda River Intrusive Complex. Foraminiferal sediments indicate the Debom Volcanics to be Early-Middle Miocene in age. Alteration is elongated along, and concentric about a northwest trending structure (Nena Structural Corridor) which is about 7km in length. The inner two alteration types, residual and massive silica-alunite are strongly brecciated and host the bulk of later hypogene Cu-Au mineralisation. Weakly mineralised weak silica- alunite and barren peripherally zoned clay alteration surround the inner mineralised alterations. The hypogene sulphide deposition was polyphasal, episodic and is zoned from north to south from covellite-enargite ¦ chalcocite (5600N to 5200N) to a mixed enargite-luzonite (5200N to 4700N) to luzonite-stibioluzonite (4700N to 4400N) in the south within a 1200m long by 300m diameter sub horizontal pipe like body. Paragenesis studies indicate that pyrite ¦ marcasite were introduced early with barite and black native sulphur before deposition of banded pyrite (melnicovite) with barite during a period of brecciation. Continued brecciation allowed bladed covellite ¦ chalcocite followed by enargite-luzonite-stibioluzonite ¦ pyrite (brassy) and minor acicular covellite deposition. Yellow native sulphur and trace amounts of galena were deposited in remaining pores. Pre-acid alteration intrusives domed the mainly volcanic stratigraphy in the southwest and post-mineralisation porphyries in the northeast truncate mineralisation. Supergene processes and erosion have modified the top of the deposit, creating a 45m thick goethitic-scoroditic-haematitic gold cap above a 40m thick (on average) chalcocite rich supergene blanket. Lesser amounts of digenite, covellite native copper and rarely seen malachite occur in the supergene copper zone.

Jan 1, 1997

By V. V. Musaev, A. M. Klyushnikov, R. R. Galimov

"A study was made of chemical and material compositions of the oxidized gold-bearing ore of the Kochkovskoe deposit. It was demonstrated that examined ore consisted mainly of quartz, carbonate and feldspar with a gold content of 2.2 g/t and a silver content of 6.1 g/t. By means of agitation leaching tests it was founded that about 79-80 % of gold can be extracted from ore using cyanide leaching solutions. The achieved high-speed dissolution rate of gold was due to its presence in a finely dispersed state (less than 2.73 µm), which was confirmed by the research of Uralmekhanobr. It was proposed that the ore can be processed by heap leaching process using cyanide leach solutions. Technological studies on the modeling of the heap leaching process were initially carried out in percolators with a capacity of 5 kg on agglomerated ore. It was preliminary established that agglomeration should be carried out at a cement consumption of 12-16 kg/t, with the moisture content in pellets reaching up to 10-12 %. The best percolation leaching results can be obtained with ore crushed to the size of -20 mm. The maximum extraction of gold to the solution was 79-80 % while the L:S ratio reached 1.2-1.4:1.In cooperation with the research center of OJSC ""Berezovsky mine"" a semi-industrial heap leaching test was accomplished. The result of a test performed was an extraction of 78.5 % of Au and 21 % of Ag from ore to a pregnant solution. This extraction degree was achieved at a L:S ratio 0.9: 1. On the ground of results obtained, a technical regulation was developed for design of the heap leaching plant with the capacity of 500 thousand tons of ore per year.INTRODUCTION The ore of the Kochkovskoe deposit represents an important reserve of gold in the Zabaikal region. Of the upmost interest are oxidized ores, the processing of which can be carried out by heap leaching (HL) with cyanide solutions. The purpose of this work was to study the composition and to develop a technology for heap leaching of oxidized ore."

Jan 1, 2018

By Ming-Kao Yen

A considerable amount of work has been reported in the literature in regard to the texture and earing behavior of copper strip. The rolling texture of copper has been confirmed as (110) [112] and (112) [111], which yields ears of a drawn cup at the position 45" from the rolling direction.1-3 The recrystallization texture has been established as the cubic or (100) [001] texture, where the earing positions are at 0" and 90" to the rolling direction.4-8 It has also been reported that in the development of cubically aligned grains of copper strips, the percentage of this cubic texture increased with an increase of final reduction and final annealing temperature.8,9 A comprehensive study on H.C. copper (British commercial copper of high-conductivity quality = Cu 99.95 pct, O2 0.03 pct, Ag 0.003 pct, Fe 0.005 pct and Pb < 0.001 pct) was made by Cook and Richards.6 They concluded that the recrystallization textures could be described as one or more of the following textures: (1) a single texture (100) 10011, (2) a twin texture (110) [112] and (3) a random orientation, depending upon the previous history of the specimen concerned. The effect of various alloying additions in copper was reported by Dahl and Pawlek.10 They found that certain alloying additions, such as 5 pct Zn, 1 pct Sn, 4 pct Al, 0.5 pct Be, 0.5 pct Cd, or 0.05 pct P suppressed the formation of cubic texture. Brick, Martin and Angierll reported that the cold rolled textures due to various additions fitted a rather simple pattern. However, the recrystallization textures were subject to very considerable variations. In the discussion of this paper, Baldwin stated that deoxidized copper containing 0.02 pct P gave a complicated recrystallization texture at lower temperature. When this copper was annealed at high temperature, a single texture appeared which was described as (110) [ill] but. according to a pri- vate communication from Baldwin, this orientation reported was in error and should have been reported as (110)[112]. He also reported that the earing positions of drawn cups were at 60" to the rolling direction.12 Recently, Howald, in his discussion on the paper by Hibbard and Yen,13 reported that the rolling texture of phosphorus deoxidized copper, containing from 0.006 to 0.020 pct phosphorus, was of the pure copper type. When these coppers were annealed at lower temperatures, they exhibited a random orientation, and when they were annealed at higher temperatures they had a mixed (111)[110] and (100)[001] texture, depending on the severity of the final reduction and annealing temperature. However, the specific influence of phosphorus and other impurities on the recrystallization textures and the deep drawing properties of copper strip has not been thoroughly reported. Therefore, an attempt has been made in the present work to determine the rolling and recrystallization textures and also the earing behavior of five types of commercial copper and thereby to evaluate the effect of phosphorus and some other significant impurities on the development of texture for cold reductions of about 87 to 89 pct. Materials Used The five types of copper employed in the present investigation were two phosphorus deoxidized coppers of different phosphorus content (0.007 and 0.013 pct P), an oxygen-free copper (OFHC), an electrolytic tough-pitch copper, and a fire-refined tough-pitch copper. These materials were subjected to a thorough spectroscopic and chemical analysis. The designations and the chemical compositions were as shown in Table 1. The coppers, FA1, FA2 and FA3. were hot-forged from 3-in. billets into a ½ X 6-in. plate and cold rolled to the ready-to-finish gauge indicated below. FA4 and FA5 were hot rolled and scalped to ready-to-finish gauge. The grain size of all the materials in the ready-to-finish condition was about 0.030 to 0.045 mm. Table 2 shows the last stage of the production schedule for each copper strip used. Experimental Procedure ANNEALING, GRAIN SIZE AND HARDNESS DETERMINATIONS Specimens of each type of copper were finally annealed in air for periods of one hour at temperatures ranging from 300 to 1600°F and were subsequently cooled in air. The average grain diameter of the annealed specimen was estimated by comparing with a standard grain size chart. Hardness was determined on the Rockwell 15 T scale. CUPPING TESTS Cups were made in a blanking and drawing set, in which blanks of 2-in. diam were drawn to a cup of 1.25-in. diam with an average depth of about 0.75 in. The clearance between the punch and die was about 0.032 in. The ears of the cup were measured with a special fixture which read the height of ears to one-thousandth of an inch on every ten-degree interval along the circumference of the cup. POLE FIGURES The usual transmission diffraction method with unfiltered copper radiation was employed to determine the pole-figures of the specimens cold-rolled or annealed at 900°F. All the pole-figures were derived from the positions of intensity maxima on 111 diffraction rings of the X ray photo-grams taken at 10 rotation of a

Jan 1, 1950

By H. M. Giegerich

"INTRODUCTIONThe Red Dog Project in Alaska is being developed by Cominco Alaska, a subsidiary of Corninco Ltd. of Canada, and the Nana Regional Corporation, one of the 12 native corporations created by the Alaska Native Claims Settlement Act of1971.The State of Alaska is also a very key part of the project through its financing of the transportation system for Red Dog. Red Dog will be the third, and largest, of Cominco&apos;s Arctic mining developments in the past thirteen years, after the Black Angel Mine in Greenland, which started up in 1973, and the Polaris Mine in the Canadian Arctic, which began production six years ago in 1982.Red Dog is one of the world&apos;s great mineral deposits, with a unique combination of large size, high-grade, and a waste-to- ore ratio less than I: I, which will make it the world&apos;s largest, and one of the lowest cost zinc producers, when at full production. The present mineral reserve is estimated to be 85 million tons , at a grade of 17.1010 zinc, 5% lead, and 2.4 ounces per ton of silver. Based on the current production forecast, this will give a mine life of almost 50 years, and the deposit is still open in two directions, although the structure is becoming thinner at depth. As well, there is a satellite zone about one mile south of the main deposit which could contain up to another 8 million tons of mineral at Red Dog grades or better. This is not presently included in the reserve due to potential processing difficulties.In relation to other zinc deposits, Red Dog is the second largest ever discovered, smaller than the original Broken Hill deposit in Australia, but larger than Cominco&apos;s own Sullivan Mine in British Columbia, which is number three. It is quite possible that, when the area is adequately explored, Red Dog will be number one."

Jan 1, 1989

By J. M. Sands

Describes important developments in, four counties, all of which brought in 40° oil. Indications are favorable for the future, although the daily production of the agate decreased 19,000 bbl. during the year 1923. THE state of Kansas had a daily average crude-oil production of about 87,000 bbl. at the beginning of the year. This showed a steady but consistent decline during the 12 months, so that the daily average production at the end of the year was slightly over 68,000 barrels. GREENWOOD COUNTY THE most active development in Kansas during the year was in Green-. wood County, in a line from near Sallyards in T 25-R 9 to east of Madison in T 22-R, 11. The main part of. this development has been in a succession of pools beginning at the south with the Polhamus pool in 34-24-9 and 3 and 4-25-9; Thrall pool in 28, 29, 32 and 33-23-10; Burkett pool in. 13, 23, 24 and 26-23-10; Seeley and Wick pool in 22, 27, 28, 32 and 33-22-11 and 5, 6, 7, and 8-23-11; Frohm pool in 11, 14 and 15-22-11; Madison pool in 31 and 32-21-12 and 6, 22, 12 and 1-22-11. Some of these pools, have two or more sands, locally called Bartlesville and Burgess Sands. They range in. depth from 1850 ft. near Madison to 2450 ft. near Sallyards, the general dip being to the west. The thickness of these sands runs from 20 to 100 ft., the initial production of the wells being 50 to 1000 bbl. of 40-gravity oil or better.

Jan 3, 1924

By N Akizawa, A Tamura, S Arai

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Reaction products between high-temperature hydrothermal solution/uppermost mantle peridotite or lowermost crustal gabbro have been reported along Wadi Fizh of the northern Oman ophiolite; they are named as ‘mantle diopsidite’ and ‘crustal diopsidite’ respectively (Figure 1).The mantle diopsidite contains Cr-rich minerals like chromite, Cr-rich diopside (&lt;2.5 wt per cent Cr2O3) and Cr-bearing grossular (&lt;7.0 wt per cent Cr2O3). The chromites are varied in shape in the mantle diopsidite, euhedral to anhedral chromite grains contain globular inclusions of grossular and chlorite, and film-like chromite veinlets branch off from partially dissolved coarse chromite grains. In the crustal diopsidite, fine chromite grains are included in oscillatory-zoned skeletal uvarovite, especially in its high-Cr zones. The uvarovites are rich in rare earth elements (REEs). Direct laser ablation – inductively coupled plasma – mass spectrometer (LA-ICP-MS) analysis of the primary fluid inclusions detected Na, but not K.Our detailed studies of Wadi Fizh diopsidites clarify that the high-temperature hydrothermal solution dissolves chromite grains at the uppermost mantle section and precipitates hydrothermal chromite at the lowermost crust section. In addition, REEs were mobilised in the hydrothermal solution together with Cr. The hydrothermal solution involved in the diopsidite formation is assumed to have been rich in NaCl, and could mobilise appreciable amounts of Cr and REE.CITATION:Akizawa, N, Arai, S and Tamura, A, 2015. Chromium and rare earth elements mobility by sodium-bearing high-temperature hydrothermal solution – an example from mantle diopsidite and crustal diopsidite, in Proceedings PACRIM 2015 Congress, pp 291–296 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By C. R. Van Hise

[Concluding Contribution of Prof. Van Hise to the Discussion of his Paper, and Others on the Same General Subject, presented at the Washington Meeting, February, 1900 (see Trans., xxx., 27, 177, 323, 424, 5 S); also of the contributions of Vogt, De Launay, Beck, Lindgren, hemp, Rickard, Bain, Keyes, Collins and Adams, presented at the Richmond Meeting, February, 1901, and printed in the present volume.] IN June, 1900, shortly after my paper was published in the Transactions, I made a briefer statement* before the Western Society of Engineers covering the same `round, which, in certain respects, is somewhat of an improvement. For instance, instead of using the terms descending and ascending with reference to the waters resulting in the two concentrations, my modified statement is as follows " The first concentration of many ore-deposits is the work of a relatively deep water-circulation, while the reconcentration is the result of reactions upon an earlier concentration through the agency of a relatively shallow water-circulation. Commonly the deep water circulation is lacking in free oxygen, and contains reducing agents, and the shallow water contains free oxygen. The deep water is therefore a reducing, and the shallow water an oxidizing agent."† Of the papers upon ore-deposits which, in vol. xxx. of the Transactions, follow my own, or which were presented at the Richmond meeting, a considerable number are wholly confirmatory of the conclusions which I have presented. Among these are the Washington paper of Emmons upon the Secondary Enrichment of Ore-Deposits‡ and his discussion at Richmond of other papers,§ that of Weed upon the Enrichment of Gold and Silver Veins,[ ]the discussion of Emmons&apos;, and at Richmond of Weed&apos;s paper by Collinst and Prof. De Launay,† the paper of Lindgren on Metasomatic Processes in Fissure Veins,¶ that of-Rickard upon the Formation of Bonanzas in the Upper Portions of Gold Veins,** and the remarks of Bain upon the Mississippi Valley lead- and zinc-deposits.†† It is therefore un-

Jan 1, 1902

By D. S. Cronan

Studies on polymetallic manganese nodules and Co-rich crusts in the EEZ&apos;s of the Cook, Line, Ellice and Phoenix Islands between 0-20°S show that Ni and Cu reach their greatest combined abundances of over 2% between 2-8°S on the southern margin of the equatorial zone of high biological productivity, as a result of biological fluxing of Ni and Cu to the nodules at and just below the CCD. By contrast, Co reaches it greatest abundance of 0.6% south of 8°S in nodules on non-biogenic clays well below the CCD where little biological Co supply is likely. Nodule abundances are greatest (up to 30kg/m2) in the Co-rich area in part due to AABW flow, giving highest overall metal quantities per sq meter in the nodules there, particularly of Co. There are approximately 110 x 106 tonnnes of combined Ni plus Cu plus Co expressed as Ni equivalent in Cook Islands EEZ nodules, approximately 12 x 106t. in Phoenix Islands ones, and approximately 1.4 x 106 t. in Ellice Islands ones, in areas of greater than 5kg/m2 nodule abundance. In the Co-rich crusts, Co averages about 0.7% and crust thickness about 1.6cm, both related to metal fluxes in and adjacent to the 02 minimum zone in association with which both maximum thicknesses and Co grades occur. Within the Cook Islands permissive area there are about 930 x 103 t. of Co and 630 x 103 t. of Ni in crusts, in Phoenix Islands crusts there are about 69 x 103 t. of Co and 55 x 103 t. of Ni, and in Ellice Islands crusts there are about

Jan 1, 1989

By A. S. Paschoa, A. W. Nóbrega

INTRODUCTION There are now over twenty years since the radiological characteristics of the brazilian regions of Araxá, Tapira and Barreiros, three locations adjacent to each other, in the state of Minas Gerais, Brazil, started being surveyed by investigators from the Instituto de Biofísica da Universidade Federal do Rio de Janeiro (IB/UFRJ), Pontifícia Universidade Católica do Rio de Janeiro (PUC/RJ), and New York University (NYU) (Roser and Cullen, 1958; Cullen et al, 1980). The importance of the Araxá apatite – Ca5,(P04)3(OH, F, Cl) - and pyrochlore - NaCaNB206F - for the production of large quantities of fertilizers and niobium was early recognized (Roser and Cullen, 1958). Interesting data have been gathered and published throughout the years on the contents of naturally occurring radionuclides in geologic materials, soils, grass, foods and waters of the Araxá region (Eisenbud, et al., 1964; Penna Franca, et al., 1965a, b; Roser et al., 1966; Penna Franca et al., 1970; Cullen, 1977; Penna Franca, 1977; Cullen and Paschoa, 1978; and Cullen et al., 1980). The radioactivity of the Araxá region is associated with mineral deposits of niobium rich pyrochlore and phosphate rich apatite. There are in this region mineral ores with 3 to 5% pyrochlore with 2 to 2.5% Th as Th02 and 50 to 150 ppm U308 in the matrix, while the apatite deposits contain up to 150 ppm U308 and a thorium concentration similar to that of the pyrochlore deposits (Paschoa and Palacios, 1981). As an indication of the high thorium content of the Araxá soils the 228Ra and 224Ra activity concentrations were reported to range from 10.6±0.2 to 62.4±0.7 pCi228Ra/g soil in 7 samples and 2.1±0.1 to 104±1 pCi224Ra/g soil in 19 samples (Cullen, et al., 1966). The uptake of radium isotopes by edible roots vegatables and fruits growing in the soils of the Araxá region can be illustrated by the data listed in Table I. The biological availability of natural radium isotopes in some segments of the Araxá soil allows a large variation in the 228Ra, 224Ra and 226Ra concentrations in vegetables and edible roots, as can be seen in Table I. This fact makes quite difficult a quantitative local assessment of the radiological implications of mining the Araxá mineral deposits of pyrochlore and apatite for production of niobium and phosphate fertilizers, respectively; since one cannot easily separate the naturally occurring from the technogically enhanced radionuclide contents of foods. The position of the city of Araxá inside the contour of the state of Minas Gerais appears in the upper part of Figure 1, which shows the outlined map of Brazil with the positions of the cities Brasilia and Rio de Janeiro also indicated. The lower part of Figure 1 is a representation of the Araxá region in an expanded scale, which indicates the locations of the pyrochlore and apatite deposits in relation to the city of Araxá, as well as the nearby hydrographic basins. The distance between the city of Araxá and the pyrochlore deposit is about 8 km, and between the pyrochlore and apatite deposits is 4 km. This paper deals tentatively with the radiological implications of the industrial operations taking place in the Araxá region for the exploration of the pyrochlore and apatite deposits. However, one must bear in mind, firstly, that the radiological implications of these industrial activities are by far too complex to be covered adequately by the limited amount of data to be presented in this paper, and secondly, that such implications cannot be considered of local character only. INDUSTRIAL OPERATIONS The commercial exploration of the Araxá deposits of pyrochlore and apatite started only few years ago, motivated by the increasing demand of niobium and phosphate fertilizers in Brazil and the world. As a consequence of the industrial operations in Araxá, a redistribution of the uranium, thorium, and radium originally present in the local deposits of pyrochlore and apatite started occurring in the seventies, with possible radiological implications for the Araxá region and its immediate surroundings, not to mention the destinations of the end products of such industrial operations. A literature review on the radioactivity associated with the extration industries of selected minerals was made by the USEPA (Bliss, 1978). The low level radioactive wastes of the industries for copper ore mining and rare metals processing have been object of particular attention (Fitzgerald, Jr., 1976; Eng, et al., 1979), but the short and long term implications of the radioactivity associated with the niobium industry were also subjects of concern (Knight and Makepeace, 1978). Recently, high 232Th and 226Ra concentrations in samples from the tin mining industry in West Malaysia were reported (Hu et al., 1981). A great deal of attention has been dedicated to the implications of the redistribution of radionuclides originally present in the mineral ores used by the phosphate fertilizer industry (Moore, 1967; Menzel, 1968; Spalding and Sackett, 1972; Eisenbud, 1973; Guimond and Windham, 1975; Guimond, 1976; Roessler,

Jan 1, 1981

By P. A. Larssen, P. R. Gage, R. W. Bartlett

The kinetics of formation of intermediate sili-cide compounds from MoSi2/Mo and WSi2/W couples were studied using a cylindrical sample configuration. Concentration profiles of the constituent metals were deter mined from electron-microprobe analysis of cross-sectioned samples after isotlzernzal diffusion annealing. These data also yielded hand widths of phases. Growth of intermediate phases depends on diffusionin them and obeys a parabolic rate law. The rates of formation of the intermediate phases decrease in the order Mo5Si3 > W5Si3 > Mo3Si. Crowth rates. for the isomorphous phases Mo5Si3 and W5Si3 had the same activation energy. 43 kcal per mole. SILICIDE coatings employed to protect refractory metals from high-temperature oxidation are usually formed by a diffusion process requiring concurrent transfer of silicon to the refractory metal surface. For a simple binary system and a coating thickness of one or two mils, the coatings on molybdenum and tungsten are primarily the disilicides WSi2 and MoSi2, respectively. During use of the coated re- fractory-metal system at high temperatures, in the absence of the silicon source, further diffusion causes growth of lower silicide compounds and depletion of the disilicides. Recent investigations have shown that the lower silicides are less effective than the disilicides in forming a glassy oxide film which impedes oxidation.&apos; Consequently, failure of coatings at high temperatures may coincide with complete conversion of the disilicide phase. The purpose of this part of the study is to investigate the growth kinetics of the intermediate compounds in the W-Si and Mo-Si systems. There are three intermetallic compounds in the Mo-Si system: MoSi2 with a tetragonal structure

Jan 1, 1964

By Omar A. Muhtadi

6.1 INTRODUCTION The three most critical factors in successful heap leaching operations are: • The methods employed to pretreat ore (i.e, crushing and agglomeration); • Placement of ore on the leach pad (heap building techniques); and • Wetting of the ore with cyanide (solution application techniques). Improper execution of any of these initial steps may result in a substantial sacrifice of total metal extraction or, in the worst case, in project failure. Ore preparation in terms of crushing and agglomeration was discussed in Chapter 5; this chapter therefore focuses on commonly employed techniques for heap construction and solution application. The main objective of heap construction is to obtain the most homogeneous heap possible. "Channeling" of leachate in heaps with preferential seepage paths leads to preferential leachate distribution and uneven/incomplete extraction. The two main contributing causes of channeling are inadequate attention to heap construction and uneven solution application. These pitfall s can best be avoided through a knowledge of the various techniques available and the applicability and success of these techniques with various ore types and site conditions. The remainder of this chapter provides a discussion on these two subjects. 6.2 HEAP BUILDING TECHNIQUES Successful heap building techniques vary with the type of ore and, since no two orebodies are exactly alike, some slight modifications are usually necessary for each specific project. However, it is possible to generalize in terms of the appropriate techniques to be used with ores having similar characteristics. This section discusses the three most commonly used methods of heap construction and provides some guidelines with regard to ore types, construction constraints, and lift height parameters for each of the three. 6.2.1 Run-of-Mine Dumping and Dozing The run-of-mine method of heap building can only be used with ore of a highly silicious nature (i.e., ore which will not generate a large amount of

Jan 1, 1988

By H. H. Murray

Significant changes in ownership and production of industrial clays have occurred since 2000. Clays covered in this presentation are kaolins, ball clays, smectites, (bentonite), and palygorskite (attapulgite)-sepiolite. IMERYS discontinued production of paper coating kaolins at their Cornwall operations and have expanded their kaolin production in Brazil. J. M. Huber sold their kaolin operation in Georgia to KaMin whose headquarters are in Ft. Worth, Texas. BASF purchased Engelhard?s kaolin and attapulgite operations in Georgia. ActiveMinerals purchased Southeastern Kaolin in South Carolina, Wilkinson County Kaolin in Gordon, Georgia, and Zemex Attapulgite in Quincy, Florida. Chemical Lime purchased Spinks Ball Clay Company in Paris, Tennessee. Most of the ball clays used in Italy and Eastern Europe comes from expanded operations in the Ukraine. Bentonite operations have expanded production in Wyoming and Montana because of strong demand for drilling mud, foundries, cat litter, and iron ore pelletizing. The production and exports of palygorskite in China continues to increase. Nanoclays utilizing sodium montmorillonite, palygorskite, and halloysite are actively being developed.

Jan 1, 2009

By Richard Bosustow, Van Dyne Howbert

The Presidio mine of The American Metal Co. is situated in the "Big Bend" region, some 45 miles over state highway south of Marfa, a station on the Southern Pacific R.R. It lies 20 miles by road north of the Mexican border, in semidesert surroundings typical of this general section of the United States and the adjoining part of Mexico. All supplies are hauled in by truck from Marfa under contract. The concentrates and precipitates produced by the mill are carried by the same trucks to Marfa, from whence they are shipped, respectively, to the El Paso and Selby plants. History The mine was discovered about the year 1880 and was soon thereafter taken over for development by some army officers stationed at Fort Davis, Texas. It was later operated by the Presidio Mining Co., which treated the ore in a small pan-amalgamation mill from 1883 until 1913, when a cyanide plant was erected which has been in continuous operation ever since. When the present company, a subsidiary of The American Metal Co., Ltd., took over the mine in April, 1926, the ore-bearing zone had been worked for about 2200 ft. to the east of I the outcrops down the dip of the formation, at which point it is at a I vertical depth of 500 ft. below the surface. Up to that time the mine had produced some 1,150,000 tons of ore averaging about 17 oz. silver. After a development campaign the company started milling again in February, 1927. Since then the production has been approximately 4700 tons per month of ore; of which the yearly average grade has varied from 19.7 to 23.2 oz. silver, $0.20 to $0.50 gold, and 2.0 to 2.5 per cent. lead. No other property in this district has ever produced tonnage of any importance.

Jan 1, 1931