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By J. Henry Harden

I DESIRE to call the attention of the Institute to a new form of drawing-board trestle. With the ordinary four-legged trestle, commonly used, one has not the means of adjusting the height of the board to the draughtsman. To obviate this inconvenience, and at the same time to enable one to incline the board, I have devised an arrangement of curved and straight slots and thumb-screws, by means of which the board can be raised three or more inches, and placed at any desired angle of inclination on either side. Figures 2, 3 (Plate I) show side and end elevations of the trestle for a single board, and Figure 4 for two boards. The latter form is adapted for use in schools, or where it is desired to economize space.

Jan 1, 1874

By Cristiane Vilma Rocha Galiazzi

As matérias primas para Alto Forno devem ter qualidade física adequada para melhor controle do processo e estabilidade operacional. A distribuição granulométrica e consequentemente sua estabilidade são importantes, pois interferem na porosidade e permeabilidade no interior do Alto-Forno, criando assim uma condição adequada e específica de marcha com reflexo na estabilidade da produção de gusa. A Sinterização da ThyssenKrupp Companhia Siderúrgica do Atlântico (TKCSA) foi projetada sem britagem secundária, devido à fase de ajustes no processo operacional e baixa produtividade havia dificuldade para controlar a fração grossa do sinter (> 50 mm), impactando na distribuição granulométrica do sinter. Visando reduzir os desvios da qualidade física, estudou-se a melhor relação da altura de camada x velocidade da esteira encontrando um ponto de equilíbrio entre os níveis de produção e qualidade especificada que, juntamente com o início da operação do britador secundário, resultou na garantia da qualidade física do sinter para os Altos Fornos. Este trabalho tem como objetivo apresentar o desenvolvimento e resultados deste estudo.

Aug 1, 2018

By J. A. Jr. Church

I. EARLY FURNACES. COPPER blast-furnace construction in America has long recognized a general standard in the rectangular mater jacketed shaft with separate forehearth. The details, however, and especially those relating to shaft dimensions, have had to meet a great variety of conditions, and show no uniformity whatever. Selecting a few of the present day Western plants, we find furnace lengths varying from 12.5 to 87 ft., widths at tuyere level from 42 to 84 in., and heights above tuyeres from 5 ft. 4 in. to 22 ft. 4 in. ; and comparing present designs with those of the past, we meet contrasts no less striking. Unlike its transverse section, the length of a furnace has come to depend rather on the size of unit desired than on the requirements of smelting ; and if the question of length be ignored, several of the various existing designs can be grouped together on the basis of a common transverse section. This section, having a width at tuyere level of 56 in. and a height above tuyeres of 18 ft., was developed at Great Falls, and the story of its development contains some interesting features. Ground was broken for the Great Falls works in the spring of 1891. About a year later, the concentrator was able to begin operation, followed within the next few mouths by the Brueckner, reverberatory, and converter departments, and in April, 1893, by the first blast fur-

Jan 7, 1913

By J. A. Jr. Church

I. EARLY FURNACES. . COPPER blast-furnace construction in America has long recognized a general standard in the rectangular water-jacketed shaft with separate forehearth. The details, however, and especially those relating to shaft dimensions, have had to meet a great variety of conditions, and show no uniformity whatever. Selecting a few of the present day Western plants, we find furnace lengths varying from 12.5 to 87 ft., widths at tuyere level from 42 to 84 in., and heights above tuyeres from 5 ft. 4 in. to 22 ft. 4 in. ; and comparing present designs with those of the past, we meet contrasts no less striking. Unlike its transverse section, the length of a furnace has come to depend rather on the size of unit desired than on the requirements of smelting ; and if the question of length be ignored, several of the various existing designs can be grouped together on the basis of a common transverse section. This section, having a width at tuyere level of 56 in. and a height above tuyeres of 18, ft., was developed at Great Falls, and the story of its development contains some interesting features. Ground was broken for the Great Falls works in the spring of 1891. About a year later, the concentrator was able to begin operation, followed within the next few months by the Brueckner, reverberatory, and converter departments, and in April, 1893, by the first blast fur-

Jan 7, 1913

By H. M. Dess, S. R. Bolin

A modifiedl Czochralski technique has been utilized to grow single crystals of YVO, pure or doped with europium or neodymium, from 1 to 2 in. long and 4 to 1/2 in. in dianz. An oxyhydrog-en gas-fired furftace zuas used in this ulork, and melts were contained in iridium crucibles. Successful application of the Czochralski ~vzethod was found to depend upon atmosphere control to prevent crusting and to limit melt decomposition, the establishment of symmetrical thermal gradients in the melt to obtain stable growth, and the selection of high-quality single-crystal seeds to prevent propagation of misorientations during growth and subsequent catastrophic cracking. The suitability of YVO4 as a host for laser-active trivalent rare earth ions has long been recognized. However, the problems associated with the growth of sufficiently large, good-quality single crystals have, until quite recently, seriously hindered satisfactory evaluation of the laser potentialities of this material. Both flux growth and Czochralski growth techniques were investigated at an early stage of interest in YVO,. The former method proved incapable of yielding crystals large enough for practical use,ly2 and the latter was beset with difficulties which took some considerable time to understand and overcome. Recently, however, the Czochralski growth process for YVO, has been improved along separate but similar lines of development by groups working independently in the Crystal Products Department of Union Carbide's Electronics Division and Bell Telephone Laboratories3 so that now good-quality single crystals of satisfactory size can be produced on a routine basis. Stimulated emission from a neodymium-doped YVO4 crystal grown by the Crystal Products Department of Union Carbide was obtained by O'connor4 of MIT, Lincoln Labs. An oxyhydrogen gas-fired furnace was used in this work, Fig. 1, and melts were contained in iridium crucibles. The starting material was 99.9 to 99.99 pct pure YVO4 powder purchased from the Chemical and Metallurgical Division of the Sylvania Electric Products Co. Typical impurity levels, determined by spectrographic analyses, were as follows: Si, 50 to 500 ppm Al, Fe, Mg, 5 to 50 ppm Ni, Pb, Mo, Mn, Ce, Cs, 1 to 10 ppm Initially, YV04 powders predoped with neodymium or europium were obtained from Sylvania. Later, however, because of a desire to grow a series of crystals containing relatively broad concentration ranges of these dopants, it proved more convenient to start with pure YV04 and mechanically admix Nd2O3 or Eu@~ powders plus equimolar amounts of V2O5. The empty crucibles were preheated to 1900" to 1950oC, a temperature range where melting occurred readily. The powdered YVO4 feedstock was then added incrementally. However, a marked tendency toward

Jan 1, 1968

By Willard C. Lacy

Rather than attempting to present a summary of the many and highly varied papers that have been presented at this symposium on sampling and grade control, I will attempt to extract the general philosophy of analysis and approach, and attempt to identify the trend of future developments. First, the term "sampling" is used with its broadest connotations. A sample consists of a representative portion of a larger mass, and must represent the mass not only in the grade of contained metals or minerals, but also in all other respects in terms of mineralogy and mineral quality (1, 5), deleterious materials, recoverability of economic components, physical behavior, geophysical response (I), and even archaeological and environmental aspects (7, 11). The sample must be taken from a locality and in such a manner and quantity that it is representative of the larger rock mass. This calls for complete and accurate geological control and an understanding of the nature and distribution of the contained chemical and physical elements and a record of the effectiveness of the different sampling methods. Second, value of a given mass of ore material is based upon its profitability - the difference between recoverable value and costs to achieve recovery, beneficiation and sale. There is a strong movement in mining geology control toward more complete analysis in determining cutoff grades and in grade control, as illustrated by the kriging of metallurgical recovery factors as well as grade at the Mercur Mine (8). To achieve a "profit- ability factor" as a guide for economic mining practice requires further integration of: 1) the value of contained metal or mineral, 2) percentage recovery of values, 3) dilution of ore with waste rock, 4) addition to, or loss of value as a consequence of by-product materials or deleterious components, 5) cost of producing a saleable product plus mini- mum profit to justify the effort (cutoff), and 6) cost of land restoration (7, 11). All these parameters vary with the rock type, rock structure, mineralogy, depth, geometry, mining and metallurgical methods, but they must be sampled and analyzed if sampling and grade control are to reflect profitability. A wide variety of deposits has been presented at this symposium; each deposit with its own problems and special solutions. Deposits containing high unit-value components, e.g. precious metals and diamonds, present special problems in the obtaining of accurate samples and generally require statistical analysis control methods or may disregard or modify occasional high or occasional low values, based upon experience (12 ) Grade control may be accurate for the long term but may vary for the short term. Bulk sampling is always essential. Deposits containing metals or minerals with low unit value are very sensitive to transport costs, and they are often very sensitive to small amounts of deleterious components or differences in physical or chemical behavior. Problems of sampling and grade control change with the genetic type of deposit, with the stage of deposit development and with the size of the information base. Precious metal epithermal deposits (2, 6, 8), because of rapid vertical zonation and erratic lateral distribution of values, have always been difficult to evaluate and maintain grade control and ore reserves. On the other hand, evaluation and grade control are relatively easy in bulk-low- grade deposits (4, 13). However, these deposits generally have a low margin of profit and are sensitive to mining and beneficiaton costs, price fluctuations and political costs. Industrial mineral deposits (5) often must be evaluated on the basis of their behavior, rather than by chemical analysis. Environmental impact generally increases with the scale of the operation, but certain elements or minerals have especially high impact effects (7, 11). In the exploration phase there is no production control of sampling procedures and careful geological observations are particularly essential. The greatest number of problems is related to the oxidized outcrop where the chemical environment of the ore body has changed and the contained values may have been enriched, depleted or values left unchanged (2, 6). Present evidence suggests that gold values may be very mobile under certain conditions (2, 6) and stable under others. Everything must be sampled in detail. Principal values and by-product or deleterious elements may vary dependent upon their position within the soil profile. Such factors as geomorphic position, erosion rate, vegetation, climate, etc., may affect the interpretation (1, 3). During the development phase it is equally easy to overtest, to have "paralysis by analysis," as to undertest (3, 6). Bulk samplng and testing are

Jan 1, 1985

By Otaviano Donizeti Valadão de Freitas

Ruídos elétricos afetam os circuitos lógicos e conseqüentemente podem comprometer a confiabilidade nos controles de processos, e para minimizar as influências desses ruídos, algumas medidas básicas foram tomadas, com instalações adequadas de todo o sistema, como padronização do aterramento, encaminhamento de cabos, etc. Depois que as medidas foram implementadas, o resultado foi um sistema mais confiável. Se apenas um fio for encaminhado de forma incorreta ou se o aterramento estiver inadequado, pode ser suficiente para causar problemas. A experiência mostra que é muito difícil que todas as medidas sejam aplicadas integralmente, mas se não forem tomadas pelo menos as medidas básicas, o sistema ficará suscetível.

Sep 25, 2017

By D. Prince, G. Nollet

"Since 1994, Aur Ressources has operated Louvicourt mine, a zinc and copper mine close to Val d’Or, at a rate of 4300 t/d. Ever since the start-up of the plant, management has encouraged innovative approaches in reliability. The first of three papers will discuss the vibration monitoring program in place. The program will be described and two examples will be given: detection of a rolling bearing defect on a pinion driving the ball mill and identification of wear on the bearings of the flotation cells. Figures on the return on investment and the costs of a monitoring program will also be given.The second article will discuss the lubrication aspect. Since the establishment of a good monitoring and oil analyses, Louvicourt mine decreased its oil consumption by more than 38 000 L/yr. In addition, the company set up an oil regeneration system that restores the original properties of oil.The third article will cover the management aspect. Work organization as well as the management philosophy enabling the employes to push predictive technology to higher levels will be examined in detail. The key elements which made it possible for Louvicourt mine to position itself among world-class companies in the organization of maintenance will be discussed."

Jan 1, 2002

By R. H. Seraphim

"The Phoenix Camp, in the Boundary Creek district of southern British Columbia, produced before 1920 about 15 million tons of ore averaging more than l ·5 per cent copper, about 0.03 ounces per ton in gold, and 0·5 ounces per ton in silver. Attwood Copper Mines Ltd. conducted an exploration program in the Phoenix area from 1951to1953.Publications on the camp are listed in the bibliography. Brock's work was not sufficiently detailed to unravel the structural and stratigraphic pro bl.ems. The work of LeRoy and McNaughton is referred to later.The stratigraphic column is as follows:Tertiary.Midway Formation: Volcanics and hypabyssals; dacitic to basaltic flows, with associated dykes and sills of syenite (pulaskite in part) and augite porphyry.Jura-Cretaceous.Intrusives of quartz diorite and diorite (nearest outcrop two miles from Phoenix).Late Palaeozoic or Triassic (Attwood Series).Brooklyn Formation: Sharps tone conglomerate, limestone, grey-wacke and/ or andesitic tuff, with minor shale and basalt. Rawhide Formation: shale with minor conglomerate.Early Palaeozoic.Knob Hill Formation: Chert and andesite, with minor limestone, shale, and serpentine.This column differs from that of LeRoy in two important respects: (I) Attwood's work indicates that the Rawhide shale is basal to, rather than stratigraphically above, the Brooklyn formation. The shale contains conglomerate lenses, which become more abundant and thicker toward the top, and grades upward into Brooklyn conglomerate. Ripple marks indicate that the shale is right side up."

Jan 1, 1949

By B. S. Pierce

The National Coal Resource Assessment – 2000 project was a multi-year effort by the U.S. Geological Survey to identify, characterize, and assess the coal resources that will supply a major part of the Nation’s energy needs during the 21st century. The purpose of the USGS National Coal Resource Assessment (NCRA) was to (1) digitally assess selected coal beds and zones that will be the most important in the next few decades, (2) create publically available stratigraphic, geochemical, and geographic information system (GIS) databases to answer a variety of questions of importance to government, industry and public decision makers, and (3) provide interpretive geologic and geochemical information for the primary coal resources of the Nation. Five priority regions were assessed: the Appalachian Basin, Illinois Basin, Gulf Coast, Illinois Basin, and Northern Rocky Mountains and Great Plains. The NCRA was a cooperative effort between the USGS and a number of State geological surveys in these coal-bearing regions. A study of coal resources on Federal lands was also conducted. Adequate energy supplies and the efficient use of those supplies are critical to the economic well being of a country. Affordable and reliable coal supplies are essential to the interests of our national and local policymakers. Policy makers require a range of information on the energy supply, as well as the economic and environmental issues associated with that energy source and its use. Formulation of an effective national energy policy and development of energy resources requires that we understand the geology, distribution, quality, and size of the national energy endowment.

Jan 1, 2001

By D. B. Spears

The sillimanite group includes the aluminosilicate minerals sillimanite, kyanite and and alusite, all of which have the same chemical composition (Al2SiO5). This discussion also includes the closely related mineral, mullite(about Al6Si3O15), which, although rare in nature, is produced artificially for industrial use. All of the minerals in this group have a low coefficient of thermal expansion and high corrosion resistance. This makes them desirable for refractory applications, especially in the steel and foundry industries. Other uses include electrical insulators, abrasives and household ceramic products. The minerals in the sillimanite group decompose with an irreversible expansion at temperatures between 1,300° C and 1,600° C (2,372° F and 2,912° F). Sillimanite and and alusite have relatively small expansion on decomposition (4 percent to 6 percent) and, therefore, can be used as aggregates in refractory products. Kyanite’s expansion on decomposition is large (18 percent). So it is sometimes used to balance shrinkage of other materials such as clays in refractory mixtures. For applications requiring high-temperature volume stability, mullite is more desirable. As an additive, mullite improves resistance to creep and corrosion, and imparts thermal and electrical insulating properties.

Jan 1, 2005

By John Ralston, Jonas Addai-Mensah, Patience Mpofu

The flocculation and dewatering behaviour of kaolinite (non swelling) and smectite (swelling) clay dispersions has been investigated using hydrolysable metal ions Mn(II) and Ca(II) and anionic polyacrylamide-acrylate copolymer (PAM) at pH 7.5 and 10.5. A pH-dependent, specific metal ion adsorption behaviour, accompanied by a marked reduction in particle zeta potential and slurry shear yield stress, was observed to have a profound influence on the colloid stability of both types of clays. Due to the differences in the cation exchange capacity, the smectite clay dispersion required a higher amount of metal ions than kaolinite dispersion to produce similar effects. The adsorption density of the anionic PAM at the negatively charged clay particle surfaces correlated well with metal ion hydrolysis and adsorption behaviour, all of which had a strong effect on slurry settling rate and extent of consolidation. At pH 7.5 where Mn(II) ions hydrolyse, metal ion and flocculant adsorption densities were both greater in the presence of Mn(II) than Ca(II) ions. At pH 10.5, however, where Ca(II) ions begins to hydrolyse, higher adsorption densities were observed for Ca(II) ions in comparison with Mn(II) ions, as the latter hydrolysed completely and precipitated. The metal ion mediated flocculant adsorption led to improved hydrogen bond driven particle bridging and facilitated charge neutralisation flocculation mechanisms which significantly enhanced the dewaterability of both clay dispersions.

Jan 1, 2003

By James C. Bradbury

Tripoli is a naturally occurring, finely divided form of silica found chiefly in midwestern and southeastern states and used commercially in fillers and abrasives. The name comes from the location of a silica deposit in North Africa and was applied in the latter part of the 19th century to similar material near Seneca, Missouri. Subsequently, the North African material was found to be diatomite, composed of siliceous skeletons of microscopic marine plants called diatoms, and the material's name was changed to tripolite. The name, tripoli, remained with the Missouri silica, which is inorganic in origin, and tripoli is now used to designate all naturally occurring silica that is similar in characteristics and origin to the Missouri material. Just to confuse things further, in commercial trade tripoli usually designates silica from the Missouri-Oklahoma field, whereas silica from southern Illinois, the other major producing area, is called amorphous silica. Each term, however, may be used commercially for any material, regardless of place of origin that has the characteristics or uses ascribed to material from either major producing area. For example, Engineering and Mining Journal routinely lists under "tripoli," prices "f.o.b. Elco, I11." and "f.o.b. Seneca, Mo. and Rogers, Ark.", and under "silica, amorphous," prices "f.o.b. I11 and "f.o.b. Dierks, Ark." "Soft silica" is another term that has been applied to tripoli from Illinois, west central Arkansas, and Tennessee, presumably to distinguish it from the more compact Missouri material. It has also been used in the ceramic trade to distinguish tripoli from "hard" silica, or silica flour, which is produced by pulverizing silica sand. Tripoli is produced mainly in extreme southwestern Illinois, in the Missouri-Oklahoma district in Newton County, Missouri, and Ottawa County, Oklahoma; and in the novaculite belt of west central Arkansas. Some tripoli is produced for local and specialized uses near Austin, Texas.

Jan 1, 1980

By Ulin Herlina, Fajar Nurjaman, Yepi Triapriani, Pulung Karo Karo, Slamet Sumardi, Achmad Shofi, Riska N. Tirmayani, Fathan Bahfie, Diah Susanti

The process of selectively reducing limonite ore involves adding 10 wt% sodium sulfide and using anthracite as a reducing agent in varying amounts (5, 10, 15, and 20 wt%). The research aims to optimize the extraction process by studying how factors like reduction temperature, holding time, and reducing agent dosage affect on iron and nickel content and recovery. The ideal conditions identified are a temperature of 1150 °C, a 10 wt% additive, and a corresponding 10 wt% reducing agent amount, with a crucial 60-min reduction process. X-ray diffraction (XRD) results show dominant phases like ironnickel (FeNi), iron sulfide (FeS), fayalite (Fe2SiO4), and wustite (FeO) under these conditions, indicating complex chemical interactions. Impressive X-ray fluorescence (XRF) test results precisely measure a nickel component with a 3.03 wt% and a recovery rate of 89.32%, highlighting the process’s effectiveness in extracting potential from limonitic nickel ore. The resulting ferronickel alloy has a controlled particle size of 29.23 µm. The study emphasizes the influence of sodium sulfide and anthracite dosage on the selective reduction of limonite ore.

Apr 2, 2024

By Michael S. Moats, Scott C. Campin, J. Brent Hiskey

"Electrochemical techniques are a valuable means of analyzing the passivation of commercial copper anodes. Electrochemical impedance spectroscopy (EIS) provides information concerning transport and reaction phenomena occurring at an electrode surface. Commercial. copper anodes of varying compositions have been examined using EIS. Experiments were conducted in a flat cell with an electrolyte of 40 gil Cu2 + and 160 gil H2S04 maintained at 65 DC. Impedance spectra were obtained at the potentials characteristic of the open circuit voltage and passive region for each anode. The spectra of the passivating films exhibited a flattened resistive/capacitive loop at middle to high frequencies and an inductive loop at low frequencies. An equivalent· circuit utilizing an inductor-resistor series in parallel with the double layer capacitance and charge transfer resistance was adequate in modeling the impedance data. The influence of anodes impurities on the components of the equivalent circuit is discussed and correlated with a hi-layer passivation model.IntroductionPassivation of copper anodes during industrial electrorefining has received considerable attention in the past few decades. Great strides have been made in understanding the roles of anode impurities [1-25], electrolysis parameters [20,26], and electrolyte chemistries [20,26]. Even so, passivation still occurs even in the most modem of refineries. The exact cause of passivation is not fully understood. It is known that the anode surface becomes covered by a passivating film. This film has been proposed to be CuS04'&5H20, Cu20, or mixed oxides. The localized concentrations of Ft, Cu+, and Cu2+ ions determines which phase is more favorable. The presence of these ions is controlled by the reaction kinetics and diffusion of species through the slimes layer.Reaction kinetics between Cu, Cu +, and Cu2+ are based on the dissolution mechanism of copper. There exists four different models to describe the dissolution of pure copper. The classical model of Mattsson and Bockris [27] involves two single electron transfers with the cuprous-cupric reaction being the rate detennining step. More recently, Wong, Collier, and MacFarlane [28] used ac impedance to elucidate a more complex mechanism involving the affect of pH and anions. Their findings indicate that the formation of cuprous ions in solution, Cu(I)so~ is favored over Cu(1I) ions adsorbed to the electrode surface in the presence of sulfate and as pH increases from pH 1 to pH 5."

Jan 1, 1997

By J. Henry Harden

I desire to call the attention of the Institute to a new form of drawing-board trestle. With the ordinary four-legged trestle, commonly used, one has not the means of adjusting the height of the board to the draughtsman. To obviate this inconvenience, and at the same time to enable one to incline the board, I have devised an arrangement of curved and straight slots and thumb-screws, by means of which the hoard can be raised three or more inches, and placed at any desired angle of inclination on either side. Figures 2, 3 (Plate I) show side and end elevations of the trestle for a single board, and Figure 4 for two boards. The latter form is adapted for use in schools, or where it is desired to economize space.

By Mauro Andrés Cerra Flórez

O presente estudo visa avaliar a resistência à corrosão de dois aços alto manganês com relação ao aço 9% Níquel em solução eletrólito 0,001M de H2SO4. Para esta pesquisa foram utilizados dois aços com teores de manganês de 22% e 26%, e a liga de aço 9% Níquel que é amplamente utilizada na indústria petroquímica. Os ensaios realizados para comparação da resistência à corrosão foram o monitoramento do potencial de circuito aberto (OCP) e polarização linear anódica. Foi escolhida a solução de H2SO4 pela presença do enxofre, oriundo dos campos de produção como impureza no gás natural. Foram utilizadas as técnicas de Microscopia Eletrônica de Varredura (MEV) e Espectroscopia de Energia Dispersiva de Raios-X (EDS) para a caracterização dos produtos de corrosão. Os resultados obtidos mostraram que os aços alto Manganês apresentaram valores similares de resistência à corrosão, mas ainda inferiores em relação ao aço 9% Níquel.

Oct 30, 2017

By Marcos Natan da Silva Lima

O presente estudo tem como objetivo avaliar a resistência à corrosão de dois aços alto teor de Manganês com relação à liga 9% Níquel em solução eletrólito 0,001M de NaCl. Para esta pesquisa foram utilizados dois aços com teores de Manganês de 22%, 27% e uma liga 9% Níquel que é amplamente utilizada na indústria petroquímica. Os ensaios realizados para comparação da resistência à corrosão foram o monitoramento do potencial de circuito aberto (OCP) e polarização linear anódica. Foi escolhida a solução de NaCl pela presença da maioria dos tanques de armazenamento e transporte de gás natural se localizarem próximos à região marítima portuária. Foram utilizadas as técnicas de Microscopia Eletrônica de Varredura (MEV), Microscopia óptica e Espectroscopia de Energia Dispersiva de Raios-X (EDS) para a caracterização dos produtos de corrosão. Os resultados obtidos mostraram que os aços alto Manganês apresentaram valores similares de resistência à corrosão, mas ainda inferiores em relação ao aço 9% Níquel.

Oct 30, 2017

By Ashok Kumar, Rajendra Singh, Petr Waclawik

High-grade coal is locked in the shaft protective pillars at 900 m below surface in the Czech part of Upper Silesian Coal Basin. To optimise recovery of coal from the larger size shaft protective pillar, room and pillar (called bord and pillar in India) is trialled to further develop these on smaller pillars. This development followed a constant gallery width of 5.2 m and 3.5 m height. The monitored pillar size in the first developed panel varied from 860 m2 to 1225 m2 of area. The stability of these pillars (i.e., natural supports) at this depth of cover is observed to be a vital issue to control ground movement and safety of the surface structures. A simple calculation of safety factor revealed that application of an empirical method for estimating size and shape of the pillar is inappropriate due to complex geo-mining conditions of the site. Accordingly, geo-technical instruments are installed in the panel for monitoring the stability of the diamond shaped pillar at different stages of the development. Extensive monitoring of the pillar behaviour by these instruments provided an important set of data for such optimum recovery. An established process of simulation-based pillar strength estimation is often used by the mining industry, but calibration is generally done with the help of empirical formulation. However, for the deep-seated pillar, the strength suggested by the existing empirical formulations (except the CMRI formula) is found to be much different from the instrument observations. Using a study conducted at Czech hard coal mines, an attempt is made to develop a strain-softening-based numerical modelling approach to assess pillar performance at deeper cover. The recorded value and nature of the pillar spalling in the field along with the CMRI formula are used to calibrate the developed simulation approach. An assessment of the stability of the developed pillars using simulated models did not indicate any collapse of the natural supports. This paper briefly presents difficulties in pillar design at great depth of cover and field and simulation results of pillar strength estimation in Czech hard coal mines.

Jan 1, 2018

By Robert Maes, Robert de Strycker

The Cu-Sn-As systeM was studied in the region near the Cu-42 and (214-As binary diagrams, where reactions in the solid state appear, resulting from the decomposition of the y(Cu-Sn) phase and from the formation of the 7 phase (Cu,As). The techniques used were microscopic observation, thermal analysis by dilatometry, and X-vay diffraction. The formation of the 7 phase gives rise to a ternavy pevitectoid veaction; the decomposition of the y phase gives rise to five transitional reactions. The temperatures of almost all these reactions could be determined; in the most favorable cases , the accuracy of this determination was of 11.5-C. The 7 phase is stabilized by tin additions, the arsenic atoms being replaced by tin atoms up to 35 pct; this has allowed the preparation of pure j) phase and the confirmation, by extrapolation, of the conrposition of this compound in the Cu-As diagram. In the first part of this work, the solidification reactions in the Cu-Sn-As phase diagram were studied. In the copper corner, the structure of the alloys presented the evidence of reactions in the solid state: on the one hand, all the alloys containing the y phase of the Cu-Sn diagram showed, under the microscope, that this phase had formed different decomposition products after complete solidification; on the other hand, the appearance of the 7 phase of the Cu-As diagram necessitated the introduction of a peritectoid formation reaction. The study of the decomposition of the y phase has been done by preparing about forty alloys that were homogeneous y at high temperature. The formation of the 7 phase has been studied by means of a few alloys with a composition near the homogeneity field of this phase at room temperature. The part of the Cu-Sn phase diagram of interest for this study is represented by Fig. 1, with the phase designation which will be used in the remainder of this paper; it is drawn after Hansen and Anderko.' The Cu-As diagram has already been presented in Part I of this work; the significant features of this study are the existence of the arsenides CusAs and Cu5Asz, and the formation of a compound CUEAS, designated as the 7 phase, by a peritectoid reaction at about 325°C. EXPERIMENTAL METHODS The fundamental technique for the investigation of this part of the Cu-Sn-As constitution diagram was microscopic observation; the greatest part of the observed alloys has also been subjected to thermal analysis by dilatometry; a few selected alloys have then undergone an X-ray analysis by powder diffraction. Alloy Preparation. The alloys were prepared from the same products as in Part I of this study: cathode copper, arsenic with a purity better than 99.5, and tin with a purity of 99.98. The fusion of the ternary alloys was realized from

Jan 1, 1967