Search Documents

By Robert E. Green, Robert A. Swanson

Ultrasonic attenuation and stress were measured simultaneously as a function of strain for aluminum single crystals tested in compression. The propagation mode and polarization of the ultrasonic waves were chosen with reference to the theoretical analysis presented in Part I. Good experimental agreement was found with this theory and with earlier experimental work in tensile tests. Support is given to the contention that ultrasonic -attenuation measurements are much more sensitive to the early stages of plastic deformation than are conventional stress -strain measurements. Dislocation meclzanisms are suggested which are compatible with both the present and the earlier experimental observations. A brief historical introduction of previous work concerned with the study of dislocation motion by ultrasonic-attenuation measurements has been given in Part I. The purpose of the present experimental investigation was to make use of the theoretical considerations from Part I in order to gain further knowledge concerning dislocation motions during plastic deformation. Emphasis was placed on the choice of propagation modes and polarization of the waves, such that interactions between these waves and dislocation movement on a specific slip system could be investigated. EXPERIMENTAL PROCEDURE Since the primary concern of this investigation was dislocation damping, other sources of damping were eliminated as much as possible. The test specimens were 0.5-in.-diam single crystals of 99.99+ pct pure aluminum grown from the melt by a modified Bridgman technique. Ultrasonic-attenuation measurements were made at a frequency of 10 megacycles per sec using a Style 56A001 Ultrasonic Attenuation Comparator manufactured by Sperry Products Inc. after a design by Chick, An- derson, and Truell.1 At this frequency the particle vibrations are essentially adiabatic and thermo-elastic damping should be absent. This frequency was selected since it was one of the frequencies used by Hikata et al.2 n conjunction with tensile tests on aluminum crystals, thus allowing direct comparison with this work. The use of quartz-crystal transducers insures that the amplitude of vibration is not sufficient to cause the break away of the dislocation loops from weak pinning points. The quartz-crystal transducers used all possessed a resonance frequency of 10 megacycles per sec and were thin circular discs 0.375 in. in diameter. X-cut crystals were used to generate the longitudinal waves and AC-cut crystals to generate the transverse waves. Aluminum was chosen as the basic material because it is a typical fcc metal whose deformation behavior is well-known and because the most recent work at the time the present research was initiated was that by Hikata et al. who used aluminum. The present tests were run in compression to see if such tests could be satisfactorily run in compression without being severely masked by grip effects.. A second reason was to compare the results in compression with those of the tension experiments of Hikata et at. Finally, shorter specimens could be run in compression with less over-all damping than in tension. All of the aluminum-crystal test specimens used were oriented for plastic deformation by single slip; i.e., they possessed the orientation having a maximum Schmid factor of 0.5. Because of the well-known time dependence 3 of plastic strain at constant stress, the test specimens were subjected to a quasi-static loading. Previous investigations4-' have indicated that attenuation after plastic deformation is also time-dependent, so any continuous loading of the specimen would show that changes in attenuation were also a function of strain rate. By loading the specimen to a given stress level and holding it constant until the recovery process was essentially complete, the time dependence was eliminated. The quartz transducer was permanently bonded to the aluminum crystal using Eastman 910 cement. Excess cement was removed from around the quartz with DMF (dimethyl formamide). Eastman 910 was found to be far superior for bonding, especially with regard to the shear-wave transducer, since it formed a solid bond which readily supports shear-wave propagation. The solid bond formed by the Eastman 910 cement also insured that the quartz

Jan 1, 1964

By Jon A. Hummer, Emanuele Cauda, George H. Schnakenberg, Aleksandar D. Bugarski, Samuel J. Janisko, Larry D. Patts

A series of engine/dynamometer tests was conducted to assess the effects of three types of uncatalyzed diesel particulate filters (DPFs), a diesel oxidation catalytic converter (DOC) and three types of high temperature disposable filter elements (HT DFEs) on the concentrations and size distribution of diesel aerosols and concentration of nitric oxides in underground mine air. Tests were conducted in the NIOSH Diesel Laboratory at the Lake Lynn Laboratory experimental mine, a facility developed to allow evaluation of these and other control technologies directly in an underground environment. The aforementioned technologies are evaluated by comparing the aerosol and gas measurements in the mine air 60 m downstream of the exhaust from a naturally aspirated, mechanically controlled engine fitted with the tested systems or muffler and operated at four steady-state engine speed and power modes. The tested DPF and HT DFE systems caused a 10-fold reduction in total mass concentrations of aerosols. The size distribution and number concentration measurements showed that all tested DPF systems and HT DFE elements effectively removed accumulation mode aerosols (D50>30 nm) for all test modes. An increase in peak number concentrations of nucleation mode (D50>30 nm) diesel aerosols is evident for some of tested DPF systems when engine was operated at high-load modes. The effects of uncatalyzed DPFs on nitric oxide (NO) and nitrogen dioxide (NO2) concentrations are found to be minor. A four-fold increase in percentages of NO2 in total nitrogen oxides (NOx) over baseline case was observed for the DOC when the engine was operated at high-load modes. The findings from this study should contribute to better understanding the potential for various control technologies to reduce exposure of underground miners to nano and ultrafine aerosols. In addition, detailed physical characterization of diesel aerosols made directly in occupational setting should foster a better understanding of the health risks associated with exposure to nano and ultrafine diesel aerosols.

By J. MacFadyen

The U.S. cement industry, including Puerto Rico, again set a record in terms of production and shipments. The increase in shipments came primarily from imports of portland cement as domestic production from produced and imported clinker gained only 1.9 Mt (2.1 million st). Clinker production as reported to the U.S. Geological Survey (USGS) was 88.6 Mt (97.6 million st), an increase of 1 percent. Gray and white portland cement production from domestic and imported clinker, estimated at 93.5 Mt (103 million st), was up 1.9 Mt (2.1 million st). Masonry cement shipments of 5.5 Mt (6 million st), which equates closely to production, was up 6.3 percent. Blended ce-ment shipments were up 35.9 percent from 2004 at 2.35 Mt (2.6 million st).

Jan 1, 2006

By Márcia Maria Salgado Lopes

Este trabalho busca avaliar a utilização do resíduo de granito, como pigmento, em tintas para construção civil, que atendam aos requisitos de uma tecnologia social. Inicialmente, caracterizou-se o resíduo, para determinar a potencialidade de uso desse material em tintas. Para a produção das amostras de tintas, definiu-se um modelo experimental, baseado na variação das proporções dos componentes da mistura. Nesse modelo, as proporções de pigmento e resina foram definidas de acordo com a faixa de variação de PVC (Pigment Volume Concentration) esperada para uma tinta fosca. Já a proporção de água variou, de modo a se manter a viscosidade dentro de uma faixa que permitisse a boa aplicação da tinta. Em seguida, foram realizados ensaios de determinação do poder de cobertura e resistência à abrasão para cada uma das amostras. Verificou-se que, o resíduo de granito apresenta características que o habilitam a ser utilizado, como pigmento, em tintas. Notou-se ainda que foi possível produzir misturas com elevados teores de sólidos e que o PVC exerceu grande influência sobre o desempenho das tintas. Entretanto, os resultados dos ensaios de determinação de desempenho indicaram que em nenhuma das misturas produzidas foi possível atender simultaneamente aos requisitos estabelecidos pela ABNT NBR 15079:2011.

Oct 30, 2017

By Ben-Zion Weiss, Melvin R. Meyerson

Chromium diffusion coatings on commercial Armco iron lead to carbide precipitation at the grain boundaries in and below the coatings. High compressive stresses are introduced into the coating and, as a result, tensile stresses are introduced into the base material below the coating. In coated samples, fatigue cracks form at the grain boundaries below the coating after only a limited portion of the total lifetime (5 to 10 pct). Residual tensile stresses and a stress concentration caused by precipitated carbides seems to be responsible for early crack nucleation. Stage I of Propagation may be divided into two substages: I-a in which the crack Propagates along grain boundaries, and I-b in which the crack propagates along slip boundaries according to a shear mode. In uncoated samples, the cracks form at slip bands after 40 to 50 pct of the total lifetime. In coated samples the Propagation process takes longer than in uncoated samples because of the moderate rate of crack extension until the crack breaks through the coating. The chromium-diffusion coating causes little if any increase in fatigue life. CHROMIUM diffusion is one of the most popular processes used to apply coatings to iron alloys. This popularity stems from the fact that the diffusion treatment is comparatively easy to carry out, and it improves certain surface properties such as corrosion and wear resistance as well as some other properties. Very little effort has been devoted to the investigation of the effect of chromium-diffusion coatings on mechanical properties and particularly on fatigue properties. Since the chromium coating usually represents a small fraction of the total volume of the base material it is generally assumed that the macro properties are dependent principally on the base material rather than the coating. Insofar as fatigue is concerned, there are indications that the fatigue life of the chromium coating is not less than that of the basic material and the fatigue properties are generally not reduced by it.' But chromium diffusion causes drastic structural and chemical changes in the region of the material surface2-4 which introduce additional residual stresses. Such changes must affect fatigue crack nucleation and may sometimes affect the initial stages of propagation. Furthermore, it is conceivable that the secondary stages of the crack propagation could be influenced by some irreversible structural changes in the core of the material, which stem from the long-time heat treatment at high temperatures required to apply the coating. This paper analyses the structural and compositional changes produced in commercial Armco iron by a chromium-diffusion coating and the effect of the coating on fatigue crack initiation and propagation. EXPERIMENTAL PROCEDURES The investigations were carried out with commercial Armco iron. The chemical composition of the iron, the number of specimens tested, the grain size produced during chromizing and heat treating, and the thickness and microhardness of the chromized layers are shown in Table I. Samples were chromized by a gas diffusion process. The temperature and time of the diffusion coating process were chosen according to a previous grain growth study. It had been found that at a temperature of 970°C and a holding time of between 3 and 9 hr there are practically no changes in grain size. To describe the grain size more accurately the ASTM method5 was supplemented by a statistical analysis of the mean volume diameter as outlined by Fullman6 and The The mean volume diameter was deter- mined from D = p/2m where D is the mean volume diameter, and m is the mean reciprocal value of grain diameters as seen on the micrograph. The shape and the size of the asymmetrical sample, see Fig. 1, were chosen so as to facilitate the study of fatigue crack initiation. Before coating, the samples were machined and the surface of the groove was polished. After chromizing, the two side surfaces were machined and polished so as to retain the coating only on the top surface of the groove. Residual stress in the chromized layer was measured on the top of the grooved section of the specimen after the diffusion process. The inclined incident X-ray beam procedure was used.9'10 The computations were performed with the initial assumption of a zero surface normal stress component. An electron microprobe analyzer was used to obtain the relative amounts of chromium and iron con-

Jan 1, 1970

By Ernest Baafi

A simulation model RoadSIM using the ARENA modelling system has been developed to evaluate roadway development options for a given development panel configuration. The RoadSIM simulation system has provisions for variability/randomness in operations including cutting and loading at the face, tramming and discharge of coal to the boot end and availability of equipment. The modelling system provides a means for assessing the operational limitations of roadway development practices at a particular coalmine. It is a ?what if? tool that allows a range of equipment, configurations and operating practices to be assessed in terms of achievable advance rates and equipment utilisation. Output from the system is in the form of a dynamic visualisation as well as summary reports and detailed logs of operations over time.

Oct 1, 2009

By Enrique Garay

Actualmente el geólogo de mina toma información rutinaria, mapea los bancos de la mina, los taladros para voladura y loguea los núcleos de perforación y fragmentos del aire reverso. Para la localización en el campo utiliza un GPS que tiene una estación en tierra que permite triangular en tiempo real. En ese sentido, el presente texto señala la importancia de la función del geólogo y las herramientas de campo que utiliza para la exploración y la definición del modelo geológico en la mina Pierina. Así para la digitalización del mapeo geológico utiliza el programa AutoCad, en el caso de mapeo de taladros para voladura emplea un Colector de Datos que posee una hoja de calculo que permite recoger datos del tipo de alteración, porcentaje de arcillas, dureza y tipo de mineralización. Finalmente, la información que genera el geólogo de mina es útil para diferentes usuarios ya que sirve para mejorar el cálculo de reservas, manejar el control eficiente del minado de mineral y desmonte, así como generar el soporte geológico a los geotecnistas responsables del estudio de estabilidad de taludes del tajo abierto, así como desde el punto de vista ambiental es posible definir zonas con potencial de generar drenaje ácido de rocas.

Aug 25, 2002

By Andre Vien, Jean-François Dupont

"Over the past several years, Svedala has developed a continuous charge monitor (CCM) for tumbling mills. It consists of a strain gauge embedded into a rubber lifter and associated electronics. This paper describes the installation and use of such a device on a SAG mill at the Holt-McDermott Mine. Comparison to measured static volumetric load and bearing pressure and inclusion of the measurement into a control strategy and its potential for condition monitoring is discussed. INTRODUCTIONWhile the measurement of load is very important in all kinds of grinding applications, the biggest benefits are expected from AG and SAG milling. This is what motivated Holt-McDermott to take a closer look at this problem, with a view to optimizing SAG mill performance.In many cases, the SAG mill control problem can be stated as maximizing throughput while avoiding a volumetric overload, with the other constraints (e.g. power, grind size, upstream/downstream equipment constraints, etc.) playing a less important role. This is certainly true at Holt-McDermott where the SAG mill is the production bottleneck about 90% of the time, and anything that can be done to increase SAG mill throughput will have a significant impact on operating profit.Although the goal of maximizing throughput while avoiding volumetric overload is simple to state, it has proven to be much more difficult to achieve. The mineral processing industry has expended a great deal of time and effort to devise control strategies in the pursuit of this objective. While much progress has been made, there is still room for considerable improvement. Across the industry it is probably fair to say that overloads occur relatively infrequently, but the real losses accrue as a result of the tendency to run rather conservatively."

Jan 1, 2001

By Dhanaji S. Chavan, Thallak G. Sitharam

"It is well known that sites comprising of saturated loose sand undergoes large deformations, due to liquefaction, during seismic shaking. To cope with this, different mitigation techniques such as vibroflotation, deep dynamic compaction, compaction grouting, deep soil mixing etc. have been used in practice. However, as all these methods are costly, a new mitigation technique is required. Air injection has emerged as a new mitigation technique in which air is injected into the saturated loose sand. The introduced air makes the pore fluid mixture compressible and results into decrease in the generation of excess pore water pressure during seismic shaking. This paper reviews the laboratory and field studies performed to investigate the effect of air injection on liquefaction resistance. In addition to this, previous research in the direction of desaturation has evolved different techniques to generate gas in saturated sand. These techniques have also been discussed in the present paper. All the field and laboratory studies have shown that even a slight decrease in the degree of saturation increases the liquefaction resistance significantly.Keywords: desaturation, air injection, liquefaction resistance, pore pressureINTRODUCTIONEarthquake events in the past, caused liquefaction of loose saturated sands at many sites in the world. The consequence of liquefaction varied from small deformations to catastrophic failures such as flow slides, lateral spreading, sand boiling etc. (Kramer, 1996). To reduce the liquefaction potential of such soils, different mitigation techniques have emerged across the world. Some of the most widely used mitigation techniques are vibroflotation, deep dynamic compaction, compaction grouting and deep soil mixing (Idriss and Boulanger, 2008).Yoshimi et al. (1989) found that the liquefaction resistance of partially saturated sand is significantly higher than that of saturated loose sand. Further, Pietruszczak et al. (2003) proposed desaturation of the saturated loose sand as a new liquefaction mitigation technique. It is observed that the liquefaction resistance of sandy soil is enhanced significantly owing to the desaturation caused during construction of sand compaction piles (Ishihara et al. 2003). Over past few years research is being carried out on desaturation of sandy soil and its liquefaction resistance ( Ishihara et al. 2003; Okamura and Soga 2006; Yegian et al. 2006; Yegian et al. 2007; Takemura et al. 2009; Eseller-bayat et al. 2013; He et al. 2013; Marasini and Okamura 2015; Zeybek and Madabhushi 2016). As a result of this, different techniques of desaturation have also emerged. Different studies conducted in this direction and their outcome has been discussed in the section to follow."

Jan 1, 2017

By Karen Mikkola, Gerald Luttrell, Jaisen Kohmuench, Glen Oswald, Michael Mankosa, Tracy Westerfield

Hydraulic separators are commonly used for particle size classification and gravity concentration of minerals and coal. Unfortunately, the efficiency of these processes can be quite low due to poor equipment design and variations in feed consistency. To help alleviate these problems, an industry-driven R&D program has been undertaken to develop a new generation of hydraulic separators that are more efficient and less costly to operate and maintain. Two of the most promising technologies, the CrossFlow and HydroFloat separators, have now been tested at industrial sites. The data obtained from these sites have been used to illustrate the potential performance improvements that can be realized through the application of these high-efficiency separators.

Jan 1, 2005

By William H. Dresher

Introduction A subject long debated but rarely resolved involves the interaction between the academic community and industry in the sponsorship and conduct of research. The subject is, unfortunately, too often treated as a controversy involving ethics and the profit motive. But, in fact, the two branches of society - industry and academia - are necessarily part of the same system. In the last 25 years, the realization has developed that research alone is not sufficient to bring about use of those results to benefit society through productivity gains and economic growth. The flow of events shown in Fig. 1 was generally believed to be the steps required for reaping the benefits of research. Today, research still has the very important role of creating new information or new ideas. However, it is recognized to be but one of many steps in a process that we now refer to as technological innovation. Charpie (1967) said, "Technological innovation is the driving force behind economic growth in the US. In this context, innovation means the process by which a new idea is successfully translated into economic impact within our own society, by providing better products, and simultaneously creating new jobs in the manufacturing of those products. Only after an investigation is put into sufficient use to have an economic effect, is it termed an innovation." One of the best depictions of the technological innovation process is shown in Figs. 2 and 3. These are adapted from Haeffner (1975), and modified by the Committee on Mineral Technology of the National Research Council (1981). Figure 2 identifies the many steps involved in the process. It designates a generalized form for interaction between the academic community and industry. Figure 3 identifies the steps in the "innovation activity" box of Fig. 2. Academia is generally responsible for developing of new knowledge and ideas, as well as maintaining and enlarging the collected body of scientific knowledge. Industry is responsible for developing new products, methods, and processes. Both institutions operate for the benefit of society, but under different driving forces. In academia, the driving force is the achievement of academic excellence. In industry, the driving

Jan 10, 1984

By Forrest T. Moyer

THIS CHAPTER of the Minerals Yearbook contains injury experience and related employment information for the coal-mining, coking, oil and gas, peat, and native asphalt industries in the United States for 1963. No attempt has been made to combine these data and present injury-frequency rates reflecting the mineral-fuel industries because the hazards of the separate industries are not comparable. Tabulations showing the trend of injuries and employment for all mineral industries are presented in Volume III of the Minerals Yearbook. COAL Injury experience of the coal-mining industry was improved slightly in 1963, as measured by the 2-percent decline in the Injury-frequency rate. Although the total number of fatal and nonfatal injuries increased 1 percent, the greater proportional increase of 3 percent in man-hours worked accounted for the improved frequency rate. Employment and injury data for 1963 are based on final data for anthracite mines and preliminary data for bituminous coal and lignite mines.

Jan 1, 1964

By W. Kint

More than 10 years ago, one of MECS?s current partners KVT developed the so called SULFOX process for cleaning waste gases containing sulfuric compounds. In this Wet Acid Process (WAP) compounds such as SO2 and H2S, CS2, COS are oxidized over catalyst bed(s) to SO3 and finally sulfuric acid is formed. The individual plants are designed according the feed gas concentrations and customers requirements to keep the investment and operating costs as low as possible. MECS strongly believes the technology we propose will meet all your expectations. Thanks to our vast experience in the construction of sulfuric acid plants (MECS built over 800 sulfuric acid plants worldwide) we were able to design you a very reliable installation. MECS is offering the metallurgical industry, besides our conventional acid plant technology (for strong SO2) and our DynaWave? scrubbing technology (for very low SO2), a SULFOX wet acid plant (for the mid range SO2 concentrations) including an optional upstream DynaWave gas cleaning plant if required. See the figure below. Besides providing advanced technology, MECS is the only company who designs and manufactures its own key critical equipment. We manufacture our own catalyst, mist eliminators, acid distributors and coolers. Because of our in-depth technology knowledge, we understand the critical aspects necessary for making optimum equipment designs. With this combined supply of technology and key critical equipment, we can make a single overall guarantee second to none other in the world.

Jan 1, 2009

By R. W. Hertzberg, F. D. Lemkey, J. A. Ford

The effect oj unidirectional solidification upon the microstructural, crystallographic and mechanical characteristics of high -purity A1-A13Ni eutectic a1loy specimens has been investigated. varying the growth rate caused the morphology of the Al3Ni phase to gradually change from platelets to rods. In addition, the effect of increasing the rate of planar liquid-solid interlace movement is to decrease the Al3Ni rod diameter and inter-rod spacing. The platelets and rods grow approxinlately parallel to each other and are aligned in a faulted substructure. A single unique crystallographic relationship hetween the A1 and ASNi phases was found and may he descrihed as : interface {001} Al3Ni {331} Al and growth direction <010>Al3Ni || <110> Al The platelet interlace and the aligned rows of rods are both uniquely defined by the above statements. Alignment of the Al3Ni phase by unidirectional solidification has given rise to a threefold increase in strength over that exhibited by specimens with an as-cast microstructure. These results illustrate the possible use of this eutectic alloy as a zohisker -reinforced structure. It has been demonstrated by Winegard et al.,1 Kraft and Albrighht,2 Chilton and winegard,3 Chad-wick,4 Yue,5 Tiller,6 and others that a planar liquid-solid interface may be established in binary eutectic alloys by proper control of heat flow during the solidification process. The unidirectional movement of such an interface results in a eutectic mi-crostructure consisting of an essentially parallel array of the two phases over an entire ingot. Two dominant phase micromorphologies have been produced using this technique: that of substantially parallel alternating lamellae of each phase or long thin parallel rods of one phase imbedded in a continuous matrix of the other phase. While not all eutectics can be controlled in this manner, it has been shown that a "normal" eutectic may, under properly controlled conditions of purity, liquid and solid thermal gradients, and solidification rate, be forced to solidify with essentially parallel phase particles. Kraft and Albright2 have demonstrated that, when the growth rate is too rapid or when the thermal gradient in the liquid at the growing interface is too low, a layer of constitutionally supercooled liquid, formed by impurity build-up, will stabilize a cellular rather than a planar interface. The unidirectional movement of the cellular interface forms the macrostructure of eutectic colonies.7 Chilton,3 Chadwick,4 and Tiller,&apos; studying eutectics of zone-refined Pb-Sn, A1-CuAl2, Zn-Sn, and Cd-Zn systems, noted that in the absence of impurities a planar interface is stabilized even when rapidly solidified. Although it is generally agreed that impurities break down a planar interface to form the eutectic-colony macrostructure, at present the origin of the varying micromorphologies (i.c., plates or rods) in a given normal eutectic alloy is not completely understood. Tiller8 has predicted that the micromor-phology produced may be dependent on solidification rate (i.e., at fast rates a rodlike structure is preferred whereas at slow rates a lamellar structure should form), and also suggested that rod formation may be favored at large phase-volume ratios. yue5 has experimentally verified Tiller&apos;s prediction in the eutectic Mg-Mg17Al12 by observing a lamellae-to-rod transition with increasing growth rate where the phase-volume ratio was approximately 2.3:1. However, Hunt and chilton9 more recently unidirec-tionally solidified over a wide range of growth velocities six different eutectic systems with phase-volume ratios between 12:l and 2.7:1 and observed no lamellae-to-rod transition. chadwickl0 has proposed that the change in micromorphology in some eutectic alloys is due entirely to the presence of impurities and further states that the lamellar structure is the characteristic structure of pure eutectic alloys even when the phase-volume ratio is as great as 12:l. Kraft11,12 has shown that the parallel lamellae in certain eutectic alloys assume a unique crystallographic relationship during unidirectional growth. This preferred crystallography may be developed

Jan 1, 1965

The dissolution of the naturally occurring mineral zircon (ZrSiO4) is examined after ball milling it with magnesium oxide for up to 100 hours in a laboratory mill. There was little effect on the solubility for the initial two hours where size reduction of the zircon was considered to be the dominant effect. Beyond two hours the dissolution increased as a function of the square root of milling time. X-ray diffraction of the powders did not reveal the identity of the soluble phase. However, a nanocrystalline phase was present after milling and this is thought to be the soluble phase.

Jan 1, 2000

By J. F. Stenebråten, W. P. Johnson, D. R. Brosnahan

Carbonaceous material (CM) from ores of varying preg-robbing activity from Barrick Goldstrike Mines Inc. (BGMI), Nevada, was characterized in terms of its functional group content, hydrocarbon content, elemental composition, and humic acid content. FT-IR analyses showed neither the presence of hydrocarbons nor of carboxylic, phenolic, or sulfhydrol functionalities. FT-IR bands present included C=C stretching in aromatic rings and C-O-C stretching, indicating presence of oxygen as ether linkages in the carbon matrix. Calculated atomic oxygen to carbon (O/C) ratios did not reveal a trend between maturity of CM and preg-robbing behavior, possibly due to low resolution of electron microprobe analysis. However, the atomic O/C ratios agree with other chemical analysis, indicating that the organic carbon is very mature, similar to or higher in grade than anthracite coal.

Jan 1, 1999

By Steven D. Knudsen, Dale S. Preece

Computer modeling of the blasting process can aid in gaining an understanding of the physics controlling the process. The sequence of events in a blast occur so rapidly and in such a violent environment that measurements are still difficult to obtain. Computer modeling using a program such as DMC [Taylor and Preece, 1989a, 1989b] can provide insights into the physics of the rapid and violent events associated with a blast. DMC has been used to simulate crater blasting @‘teece, 199Oc] and the blasting of Oil Shale for modified in-situ retorting [Freece, 1990a, 1990b]. This paper will address the influence that damping has on the velocity distribution in the rock mass during the rock motion phase of a blast. Since velocity distribution is a controlling factor of muck pile shape, damping also conbibutes to muck pile shape.

Jan 1, 1992

By M. J. Michaud, M. J. Lavigne

"A cornerstone of any successful mining project is an understanding of the mineral assemblage and metal distribution comprising the deposit. Knowledge of the precise mineral/ metal zoning enables an operation to utilize different mining and processing methods optimized for different parts of the deposit. The Lac des Iles mine, located in northwestern Ontario, is one operation that depends on a good understanding of these issues. Current resources for the Roby Zone total 94.1 Mt grading 1.66 g/t Pd, 0.18 g/t Pt, 0.14 g/t Au, 0.062% Cu, and 0.053% Ni.The Roby Zone occurs within the gabbroic portion of the Lac des Iles intrusive complex and consists of three compositionally and texturally different ore types with variable PGE, base and precious metal contents. PGE occur as sulphides and bismuthotellurides in net-textured sulphides, coarse sulphide blebs and as finegrained inclusions within secondary silicates.Knowledge of the precise mineral/metal zoning has directly and indirectly improved several operational aspects, including resource modelling, mining, and processing. For example, metallurgical recoveries have been increased by up to 3% to 5% and concentrate grades have increased by up to 100%. IntroductionLac des Iles Mines Ltd., a wholly owned subsidiary of North American Palladium Ltd., owns and operates a 3000 t/d open pit mine and concentrate facility, located 100 km north of Thunder Bay in northwestern Ontario. The Lac des Iles PGE-gold-copper-nickel mine has been in commercial production since 1993 and in 1997, produced 1.8 million grams of palladium, 127 000 g of platinum, 114 000 g of gold, 438 000 kg of copper and 354 000 kg of nickel (North American Palladium Ltd., 1998).Under the Industrial Research Assistance Program (IRAP), a two-year study of the mineralogy of the Roby Zone was undertaken with a goal of improving the profitability of the mine. Geological mapping, petrography and geochemistry of the Roby Zone were completed during this study. Utilization of the detailed mineral/metal zoning identified as part of this study was implemented at the mine and shown to positively impact many operational aspects including mining and processing."

Jan 1, 2003

By K. S. Lackner, T. M. Yegulalp

We present a review of research and development for coal based clean energy systems aiming for zero emissions to the atmosphere. These systems can utilize all kinds of coal or other solid carbon sources such as tar sands as well as liquid hydrocarbons. The chemical energy of carbon is transferred to hydrogen and used in power generation, in fuel cells, or hydrogen combusting turbines. The waste products of these future power-generating systems are ash, sulfur compounds and CO2. We also summarize current and developing technologies for processing of CO2to produce mineral carbonates for permanent disposal, and associated byproducts.

Jan 1, 2003

On the Kinetics and Equilibrium Models for Biosorption of Ni(II) onto a Gram-Positive Bacteria Strain, Rhodococcus opacus, for Environmental Applications The aim of this fundamental study was to evaluate the biosorption of Ni(II) from aqueous solution streams onto a Rhodococcus opacus strain through kinetics and equilibrium isotherms studies. The biosorption of nickel achieved its highest value in a pH around 5. The experimental data evaluation was carried out focusing three two-parameter models, as: Langmuir, Freundlich, Dubinin - Radushkevich. In order to determine the best isotherm fit, three error analysis methods were used to assess the data: correlation coefficient (R2), residual root mean square error (RMSE) and Chi-square test. The error analysis established that the Freundlich model fits better the nickel biosorption data. Maximum uptake capacity of nickel reached a value around 7.63 mg.g-1 for R. opacus. The biosorption rate was fast and achieved a removal of around 79 per cent of Ni(II) in the first 5 minutes at room temperature (25 ¦ 2¦C). The experimental kinetics data was evaluated considering two models (pseudo-second order and pseudo-first order). The error analysis established that the pseudo-second order model better fits the data.

Sep 13, 2010