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By Liu H, Chen S

Natroalunite is one of colouring minerals in kaolin. In this investigation, natroalunite, on which Ca(II) was adsorbed, was flocculated by HPAM and kaolin was depressed in suspension. The adsorption of Ca(II) on the natroalunite surface was studied by zeta-potential measurement and Auger Electron Spectroscopy analysis. Ca(II) was adsorbed more on the natroalunite surface than on the kaolin surface. The mechanism of Ca(II) adsorption was considered to be chemical adsorption on natroalunite and to be physical adsorption on kaolin. It has been found that Na6P6O18 and Na2Si04 can strongly affect Ca(II) adsorption on the surface of kaolin, but weakly on the surface of natroalunite. The effects of degree of hydrolysis and the molecular weight of HPAM, the effect of pH and the effect of Ca(II) have been studied. The kaolin ore, containing SO3 1.05 per cent has been processed with this method. The products only containing S03 0.36 per cent and the weight ratio of concentrate 52.27 per cent were Obtained.

Jan 1, 1993

By P. Farsangi, A. Hara

"Kidd Creek Mines places approximately 10 000 tonnes of consolidated rockfill on a daily basis. Consolidated rockfill is comprised of sized aggregate mixed with different ratio and amounts of binders. Consolidated rockfill, with closely controlled specification, is employed for subsequent pillar recovery and improved passive active/ ground support. With the same amount of cementing agents consolidated rockfill mass yields a higher, compressive strength, modulus of elasticity, cohesion, and angle of friction compared to a typical cemented hydraulic fill mass.The consolidated rockfill at Kidd Creek Mines is designed to sustain not only the gravitational loading of the overlaying fill material, but also to some extent the dynamic loading applied during blasting of the adjacent stopes and/or pillars.The quality control of materials used in Kidd Creek's rockfill system could be effected in three stages of handling: (1) at the surface backfill plant; (2) during transportation; and (3) placement of the fill.The emphasis in this paper is placed on individual stope backfill design and quality control measures at Kidd Creek Mines to place fill in large-scale open stopes which eventually could be exposed on all four walls during pillar recoveries."

Jan 1, 1993

By Conny Sjoberg, Finn Ouchterlony, Bjorn Jonsson

This contribution reports an investigation of the blasting damage in the contour of an access ramp to a Swedish underground laboratory for nuclear waste related studies. Near zone vibration measurements were made for 7 rounds and the results converted to a site specific scaling law. A simple engineering correction for the influence of the charge length wee developed and the resulting equations used to predict the damage zone depths of three different drilling and charging patterns.

Jan 1, 1993

By Joussemet R, Fabre F

The paragenesis of the Escuzar Mine (Andalusia-Spain) comprises: ò major constituents: celestite and carbonated minerals (abundant calcite and less frequent strontianite). ò minor constituents: sulphates (gypsum and anhydrite), clays and some iron oxides and hydroxides. The average content is at about 60 per cent SrSO4. Since liberation size was fine (from 30 to 50 ¦m), the flotation method was chosen. Laboratory batch tests have shown the relevance of using alkylsulphates with as long as possible hydrocarbon chains. The recovery obtained led to an expected 95 per cent SrSO4 concentrate with nearly 70 per cent recovery. Pilot plant tests (160 kg/h) have confirmed these results and attained a recovery of more than 65 per cent of a 96 per cent SrSO4 concentrate. Extrapolation to the industrial scale (14 t/h) has been successfully carried out : up to 600 t of a concentrate at more than 95 per cent SrSO4 has been obtained. Non optimised recovery has already reached 60 per cent for a 97 per cent SrSo4 concentrate.

Jan 1, 1993

Published information on technical and market developments in the uses of zinc tends to dwell very largely on two groups of uses of zinc - zinc coatings (mainly galvanising) and zinc casting alloys. These two groups account for two-thirds of primary zinc consumption. However, if total zinc consumption is taken into consideration, coatings and casting account for a little over half the total. Either way, the health - or otherwise - of these 'other' uses of zinc can have a substantial effect on the industry as a whole. The aim of this paper is to put the whole market picture for zinc into better focus, concentrating on the factors which can affect consumption in the 'other half' of zinc's markets: ò brass - the third most important market for zinc at around one million tonnes - responds to changes in the economic cycle. It has seen substantial changes in the balance between different forms of semi products, and, in Europe at least, some real market gains; ò zinc sheet - one of the original uses of zinc in Europe - has grown substantially in some countries, but remains almost unknown elsewhere; and ò zinc pigments and compounds are so numerous that - barring the substitution of zinc oxide in rubber - major overall changes in the market are unlikely. The paper examines these markets and assesses their potential and implications for zinc markets as a whole.

Jan 1, 1993

By William J. Francart, Gary J. Wirth

Fire detection capability in conveyor belt entries of coal mines has advanced considerably since the passage of the Federal Coal Mine Health and Safety Act. The advances in instrument technology and computer based monitoring have provided better fire detection than ever introduced in the industry. This paper discusses recent belt conveyor fires and detections in mines utilizing CO Monitoring Systems. Data from investigative reports is presented on belt entry fires from 1991 to the present.

Jan 1, 1993

By Li YQ, Yoon RH

The photoresponse of natural mineral pyrite and galena electrodes has been studied in aqueous solutions on freshly fractured surfaces (some fractured in situ) using moderate overvoltages. When fractured in situ, the electrode potential of both minerals instantly drops several tenths of a volt. Pyrite exhibits a spontaneous anodic photocurrent at fracture, which indicates upward band bending (depletion layer) on the n-type electrodes. The negative surface charge responsible for the depletion layer is believed to arise from a surface state that is intrinsic to pyrite surfaces, possibly modified by hydroxide ion adsorption. The flat band potential, Vty, of pyrite is at approximately -1.0 V (SCE) at pH 9.2 but to reach V(b, pyrite has to be cathodically decomposed. In contrast, galena assumes the flat band potential at fracture. Subsequent polarisation of galena at potentials positive of Vth produces an anodic photocurrent (upward band bending) and polarisation negative of Vro a cathodic photocurrent. Most of the galena electrodes studied were degenerate n-type and at potentials negative of Vtb, no cathodic photocurrents are observed, indicating the bands cannot be bent downward, consistent with the Fermi level at the surface merging with the conduction band edge near Vn,. Several were close to intrinsic, with the photocurrent changing sign near Vn,.

Jan 1, 1993

By W. J. Young, K. B. Macneill, C. N. Smith

"A BRIEF HISTORY OF THE MURRAY BROOK MINERAL DEPOSITDuring the mid-1950's intensive exploration activity in northern New Brunswick followed the discovery of the world class Brunswick base metal deposit. Using the prototypes of modern airborne geophysical and geochemical exploration techniques many mineralized areas in the Bathurst-Newcastle area were quickly identified. This base metal - silver camp is situated within the metavolcanic - metasidementary rocks of the Tetagouche Group which forms a roughly circular caldera-chaped voloanio complex of Ordivician age.One of the early results in the exploration history in the camp was the discovery of the Murray Brook Deposit by Kennco Explorations, (Canada) Limited. During routine ground checking of geophysical anomalies, most of which turned out to be graphitic schist, the discovery of some copper bearing float was made by the exploration team. This encouraged the company sufficiently to carry out a regional stream sampling program which lead to a large anomaly associated with a hematitic gossan. Diamond drilling of a weak Slingram anomaly over the gossan zone resulted in the discovery of massive sulphide lenses. This was followed in 1956-7 with an intensive drilling program. The result was the delineation of a potential ore body containing an estimated 23 million tons with an overall grade of 0.44% copper, 0.86% lead, 1.95% zinc, 25.73 g/tonne (0.91 oz/ton) silver, 0.28 g/tonne (0.01 oz/ton) gold. Within this package were higher grade zones of copper and lead-zinc mineralization approaching ore grades.A thick blanket of gossan was present and is reported to have caused the drillers considerable trouble as they attempted to penetrate it to get to the underlying sulphides. The gossan, consisting of iron oxides and silica fragments sits on top of the massive sulphides and attains a remarkable thickness of 45.5 meters (150'). Early work had suggested that the gossan was enriched in gold and silver. If this were the case and if the precious metal could be leached out with cyanide, then mining and recovering those values might be economic.With this in mind Northumberland Mines Limited optioned the property from Kennco in 1985. Preliminary leach tests indicated that indeed the gold in particular leached readily. Subsequent drilling of the gossan (using triple core barrel technology for better recovery of the easily ground core) indicated 1,536,363 tonnes (1,690,000 tons) with an average grade of 1.05 g/tonne (0.037 oz/ton) gold and 42.13 g/tonne"

Jan 1, 1993

By M. C. Furerstenau

Adsorption behavior of various surfactants on sulfide minerals is very much affected by the nature of the surface of the mineral. Since sulfides are naturally meta-stable, oxidation occurs when they are exposed to air, especially in aqueous environments. As a result. oxygen assumes a major role in sulfide flotation. Mechanisms of adsorption of various thiol collectors on sulfide minerals have been reviewed. The electrochemical behavior of various sulfide minerals has also been reviewed. Flotation behavior of galena, chalcocite, sphalerite, pyrite, chalcopyrite and pentlandite has been presented together with the. flotation of copper sulfide- nickel sulfide ore.

Jan 1, 1993

By C. Patrick

Longwall face-to-face transfers can cost over $100 per minute in lost production potential and $100,000 for personnel and supplies. Such high cost makes extensive planning and control of the transfer process a critical necessity for the economic feasibility of longwall operations. This paper reports operations research techniques used for the analysis and modeling of longwall face-to-face transfers. Transfer data has been collected from companies who operate over 30% of the total U.S. longwall faces. Comprehensive sequence networks of existing longwall transfers were developed; simulation models of transfers under varying conditions were generated; and, the economics of general transfers and time-cost tradeoffs in the transfer procedure were investigated.

Jan 1, 1993

By Susan T. Bagley, Kenneth L. Rubow, David H. Carlson, Bruce K. Cantrell, Winthrop F. Watts

Permissible exposure limits (PELs) have been established for gaseous pollutants, carbon monoxide (CO), carbon dioxide (CO2), nitric oxide (NO), nitrogen dioxide (NO2), and some gas-phase hydrocarbons emitted in diesel exhaust. There is, as yet, no PEL recommended for diesel exhaust aerosol (DEA), nor is there a standard method for sampling this aerosol. The University of Minnesota and the U.S. Bureau of Mines have collaborated to develop a personal diesel exhaust aerosol sampler (PDEAS) which utilizes size-selective inertial impaction and gravimetric analysis. During the field tests of this sampler, numerous air quality measurements were made in underground coal mines that use diesel equipment. The mine mean DEA concentrations for the five mines surveyed, determined with the PDEAS in the haulageway, was 0.89 mg/m3 with a standard deviation of 0.44 mg/m3. DEA contributed 52 % of the respirable aerosol at this location. In three of the mines filter samples were collected for DEAassociated polynuclear aromatic hydrocarbons (PAHs) and biological activity determinations. Two of the mines were also monitored for the major gaseous constituents found in diesel exhaust. In general, the PAH and biological activity levels were similar for all three mines, and indicate that up to 25 % of the haulageway concentrations may be contributed by outby diesel vehicles. Measured concentrations of CO, C02, NO, NO2, and SO2, were well below regulated levels. INTRODUCTION Diesel exhaust contains pollutant gases, such as carbon monoxide, carbon dioxide, nitric oxide, nitrogen dioxide, and gas-phase hydrocarbons, as well as DEA. Much of the health-related concern focuses on DEA and associated organic compounds (Watts, 1992a). A wide variety of these PAHs have been identified and some are known carcinogens and/or mutagens. The U.S. Mine Safety and Health Administration (MSHA) has proposed new PELs for these and other contaminants (MSHA, 1989). MSHA has also published an advance notice of proposed rulemaking to establish a separate PEL for diesel particulate (MSHA, 1992). The U.S. Bureau of Mines has collaborated with the University of Minnesota to develop and field test a PDEAS. The PDEAS is a three stage sampler based on the MSA' personal respirable dust sampler. It utilizes a respirable cyclone preclassifier followed by a 0.8 µm cut point impactor and afterfilter operating at a flow rate of 2 L/min. Respirable aerosol greater than 0.8, µm in size is collected by the impactor while DEA, less than 0.8 µm in size, is collected by the afterfilter. Hence, gravimetric analysis of the afterfilter permits measurement of DEA concentrations. This development and laboratory evaluation of the PDEAS were described previously by Cantrell (1990) and Rubow (1990). During field tests of the sampler, numerous air quality measurements were made in continuous miner sections of five underground coal mines that use diesel haulage equipment. These air quality measurements included levels of selected PAH and biological activity associated with DEA collected in the intake and haulageway areas of three of the five underground mines, and CO, CO2, NO, and NO2 in two of the mines. The objectives of this paper are to present the DEA and associated pollutant concentrations measured in these mines and to assess the impact of diesel face-haulage equipment on underground mine air quality. MINE DESCRIPTIONS The mines used for the PDEAS evaluation were designated J, K, L, N, and 0. Mines K, N, and 0 are located in the Western United States, while mines J and L are located in the East. Each mine produces high volatile, bituminous coal with shift production levels varying from 500 to 2000 tons/section. Seam heights varied from 1.5 to 3.0 m. Mines K and N use continuous mining to develop longwall panels. The others are strictly room-and-pillar operations using continuous miners. The number and types of diesel-powered vehicles used at these mines were described by Watts (1992b). Mines J, K, N, and 0 use diesel power to assist in a wide range of activities in addition to coal haulage. These included road maintenance, personnel and materials transport, lubrication, and welding. Mine L used only three diesel-powered shuttle cars to haul coal. SAMPLING AND ANALYSIS METHODS Aerosol Measurements Aerosol samples were collected in the mine portal area, the clean air intake to the continuous miner section, the haulageway one crosscut inby from the feeder breaker and belt, in the return airway, and on selected personnel. The haulageway sampling site was located near the point where the diesel-powered shuttle cars turn around to dump their loads. Additional respirable and DEA samples were collected and have been reported by Haney (1990).

Jan 1, 1993

By Tom Wynne

In order to shorten the time required and improve safety for a longwall face move, a 36-ft wide longwall recovery room was predriven. The room was supported with specialty bolts, trusses and concrete cribs. Rock mechanics instrumentation was implemented to evaluate the adequacy of the whole recovery system. This included instrumented roof bolts, entry convergence, load cells, and abutment stress in the surrounding pillars. This paper describes the methodology of support and instrumentation designs, and monitoring and evaluations. The results indicated that this method offers the safest and yet faster longwall recovery so far. But the rock mechanics monitoring also indicated some improvements are desirable in the truss system and concrete crib layout.

Jan 1, 1993

Back at the turn of the century, the Eastern Goldfields region of Western Australia was entering its moment of glory. Development was going ahead at a cracking pace and miles of shaft and drives were being opened up. On the Great Boulder Gold mine alone, records show that there were two kilometres of shaft and 30 kilometres of -driving completed in the first five years of operation.Similar statistics were being achieved by hundreds of other mines on the Golden Mile and in other districts in WA.

Jan 1, 1993

Amax Coal Inc. Colowyo Coal Company Continental Conveyor & Equipment Company Crane & Hoist Sales Cummins Southwest, Inc. Energy West Mining Company Paul J. Epley The Falkirk Mining Company Fleischli Oil Company T. J. Gundlach Machine Company Halbach & Braun Hemscheidt Corporation GH Hensley Ingersoll Rand Jennmar Corporation Joy Technologies K & P Sales Engineers, Inc. Kennametal, Inc. Kerr-McGee Coal Corporation L & H Welding McLanahan Corporation National Coal Association The North American Coal Corporation Northwestern Resources Company Peabody Western Coal Company Phillips Machine Service, Inc. Pincock, Allen & Holt The Pittsburg & Midway Coal Mining Co. Ramsey Technology, Inc. Roberts & Schaefer Co. Rust Tractor Company Salt River Project Schroeder Industries Smith, Barney, Shearson Snowmass Resort Association Southern Pacific Lines Stamler Corporation TerraMatrix TIC (The Industrial Company Wyoming, Inc.) Trapper Mining Inc. Wagner Equipment Company Western Energy Company Wheeler Machinery Company

Jan 1, 1993

By Lu T. K

A new type of rockbolting system, the self drilling rockbolt, has been studied to develop a 'single pass' bolt for use in rockbolt installation in underground engineering. This single pass bolt forms the basis of a Rapid Face Bolting system which will reduce the amount of time spent in securing a roof during the operation of a continuous miner in the development of a panel.The installation efficiency and anchorage tests were performed in the laboratory on the self drilling bolt and the traditional resin anchorage. bolt. The results of both bolts are cmmnared.

Jan 1, 1993

By Zamel G. I, Zenari L. P

Technological developments in modem Tunnel Boring Machines (TBMs) and associated back-up equipment are offering significant alternatives for mining operators to consider, in the selection of equipment for coal mine development drifts, roadways, longwall gate roads as well as metalliferous mining declines and development drives.Greater flexibility in handling variable ground conditions, muck disposal and radius of turn as well as advance rates, are just some of the areas where modem TBMs can accomplish the flexibility that mine operators require to achieve cost-effective developments.Compact TBMs are achieving this acceptance because of the fundamental design of a shielded machine containing electrics and hydraulics within the forward shell, ability to achieve tight radius of curvature and grades, and ability to provide highly flexible support systems to meet all possible ground conditions.However, a single TBM design will not suit all mine developments, as each development method - while having common goals with all mine developments - will also require certain unique criteria to be fulfilled.

Jan 1, 1993

Planning for the Macraes Extension project highlighted the need for additional tailings storage availability. The possible solution of developing new tailings impoundments in Northern Gully, in tum, led to concerns being expressed by the regUlatory authority over the assimilative capacity of Deepdell Creek. Philosophical differences over the appropriateness of applying a seepage model used to set standards in consents for the original project resulted in the company re-evaluating the whole monitoring system associated with tailings disposal and seepage control. Re-evaluation indicated problems arising from the existing in-stream water quality monitoring in respect of protection of the aquatic ecological system and verifiability of results. A new monitoring system was designed relocating the compliance monitoring point out of the stream and into the gully containing the tailings impoundments giving greater certainty of monitoring results to all parties and providing improved protection for the aquatic ecology of Deepdell Creek.

Jan 1, 1993

The population and the per capila consumption of mineral resources have both grown dramatically during the century past. It is argued that growth will continue through the century ahead but that the magnitudes of undiscovered resources are probably adequate to meet demands. The challenge that the mineral explorer of the future will face is finding deposits beneath several kilometres of barren rock.It is further argued that the principal challenge that society will face in the century ahead is the amelioration of environmental stress.

Jan 1, 1993

By Gordon] [Reavis

Halliburton Services and Brown & Root have developed a unique foundation system that blends oilfield and construction technologies to construct deep foundations which offer significant advantages across a variety of soil profiles. This highly efficient system is being developed to meet the construction industry's needs into the 21st Century. Based on a concept initially introduced to Halliburton Services by V.L. Schellhorn in 1987, Halliburton combined their existing cement slurry mixing and pumping technology with oilfield drilling practices and a new tool design to field test the viability of the concept. Results looked encouraging, and Halliburton asked it's sister company, Brown & Root to evaluate and further develop the process. With Brown & Root's knowledge of the construction industry, the original concept has developed into a viable and efficient foundation construction system.

Jan 1, 1993

By Y. Prevost, D. Verhelst

"A computer-assisted process control system for the Noranda Process Reactor Wa5 installed at the Home smelter in 1991. Operating as an advisory tool for the furnace operators, and using a flexible oxygen balance as the basic building block of the computer program, the new control system has helped to reduce the variability in the grade of the matte produced by 50% . The smelter is currently operating at a 72% copper matte, with a standard deviation of between 1.0 and 1.3, while treating a wide range of concentrates, secondary materials and scrap. Enhanced process control has allowed for longer reactor campaigns, and improved stability of the converting operation.This paper reviews the feed classification and blending practice used at the smelter, outlines the strategy of the new computer control system, and summarizes the benefits realized since the implementation of the system in early 1990.IntroductionUntil 1989 the Noranda Home smelter operated as a multi furnace smelter, at one time having three hot-charge reverberatory furnaces, and finally operating with one wet-charge reverberatory furnace and one Noranda Process Reactor. In 1989 the final reverberatory furnace was closed and the Reactor became the sole smelting vessel, treating around 750 000 tonnes of concentrate, secondary materials, and scrap per year. At the time of the start-up of theNoranda Reactor in 1973, the vessel was capable of treating 750tonnes per day of a heterogeneous mixture of copper concentrates, fluxes and secondary materials to produce copper in one operation. Through process improvements, and the introduction of additional oxygen in 1982(pannell and Mackey, 1988), the daily tonnage increased to 1800 tonnes by 1988. The operation had also been changed to produce a high-grade matte instead of copper. Figure1 illustrates the main features of the reactor, a cylindrical vessel which is charged at one end and tapped at the other. The matteis subsequently processed through Peirce-Smith converters and anode furnaces before being cast into copper anodes. Figure 2 outlines the progressive increase in the furnace smelting capacity. Over this period the percentage of secondary materials, and scrap feeds also increased to approximately 110 000 tonnes per year, or 15% of the total new feed input (Bedard et al., 1991). Now operating wholly as a custom feed operation, the Home smelter can treat over 2200tonnes per day of new metal-bearing material."

Jan 1, 1993