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By Reinhold Schulze

Thiourea is being applied as an industrial leaching agent for gold and silver only in a few cases. A CIP technique was developed which eliminates most of the obstacles against its use. Mild conditions for precious metals stripping from the loaded carbon simplifies process conditions in comparison to cyanide CIP technique. Examples are given.

Jan 1, 1998

By Donald R. East

There has been an increasing trend in recent months by regulatory agencies to require that estimates be made of the hydraulic head acting, under operational conditions, on the surface of primary leach pad liners. This move towards inferred performance standards, rather than specifying a prescriptive standard for all sites regardless of economics, is to be generally welcomed. The theory of flow on a sloped beach pad, which was developed by East et al, 1987 (Reference 1 and 3) has been refined and extended. Unitized curves have been developed by graphically displaying the seepage losses and resulting dissolved gold lost as seepage through the primary liner as an aid to pad liner selection and design. Very little information is available of actual hydraulic head profiles acting on the liners beneath heap leached ores. Attempts have been made to measure these by drilling from the top of the heap and installing piezometers at the base. With this procedure it is difficult to obtain accurate data due to the fact that the drilling operation itself creates a highly permeable vertical flow path which may not exist to the same degree elsewhere in the heap. Combined with the fact that it is almost impossible to ensure that the piezometer tip is sitting directly above the liner without the risk of causing some damage to the liner itself. The best time to install hydraulic head monitoring devices on the pad liner is during construction and when piezometers can be carefully placed directly above the liner and suitably protected hydraulic lines laid to ensure full hydrostatic head measurement with simple manometer devices.

Jan 1, 1998

By Thomas J. DeMull

Amax Gold's Sleeper Mine was brought to production as an open pit mining, cyanidation milling operation in March 1986. The Sleeper deposit is unique in that it contains zones of very high grade gold ore. Despite blending of ore, mill head grades have varied over a broad range. These grade variations were anticipated during mill design and affected, in particular, the sizing and selection of equipment for the CIP circuit. When grades proved to be even higher than anticipated, design operating parameters were adjusted shortly after start-up to accommodate the higher grades. Operating results have been excellent: during the first 18 months of operations the Sleeper mill has processed 375,600 tons of ore and produced 229,000 ounces of gold.

Jan 1, 1998

By Hans von Michaelis

Welcome to RANDOL GOLD FORUM 88. It is clear from the list of delegates and speakers that this conference will lead to excellent discussions of the latest developments in this fast-moving industry. Less than a year ago Randol International Ltd. published an eleven-volume report titled "Innovations in Gold and Silver Recovery - Phase 111". In the short space of time since then, many new developments have been noted, many of which will be described in this Forum. I believe that some of the more significant innovations currently under development are those that address the following:

Jan 1, 1998

By D. D. Carda, S. Dunn, W. E. Dunn, T. Storbeck

Gold chlorination which will be presented in this paper is limited entirely to the use of gaseous chlorine in a fluidized bed reactor at elevated temperatures in the absence of aqueous water. The only water used in this process is that which is used in scrubbing the effluents. Low temperatures are defined as those below 500°C. All experimentation for this paper was carried out on a laboratory scale, with all calculations extrapolated frpm this. Some of the data is drawn from work with other projects which have been operated at pilot and larger scale.

Jan 1, 1998

By Stuart Ratcliffe, Denis Kidby

The development of Vitrokele™ Technology over the last 10 years is reviewed with reference to mine site piloting and com­mercial applications. The first mine site piloting was conducted in Australia in 1989 followed by a further six continuous site trials in Australia, Canada and the USA. These major pilot plant studies are complemented by over 50 laboratory scale batch and pilot testwork programmes. The first commercial plant using Vitrokele™ Technology was the Connemara project commissioned in Zimbabwe in 1995. Subsequent to this, three commercial scale projects have been designed using Vitrokele™ to recover precious metals, base met­als and cyanide. The various projects are discussed with relation to the differ­ing flowsheets applied to each particular case.

Jan 1, 1998

By Donald D. Gullickson

The entire system is built around pre-designed and pre-engineered modules which are assembled to meet the metallurgical and production parameters of the project. The carbon vessels are the key to the flexibility of the system. The vessels are made of a coated mild steel, which allows the carbon vessels to be used in the adsorption, desorption and acid wash cycles. In the adsorption mode, the solution is pumped up-flow through four (4) vessels in series at 250 gpm fluidizing the carbon bed. When the carbon in the lead vessel is loaded, it is disconnected from the adsorption circuit via rubber hoses with quick-disconnect fittings. The second vessel is then made the lead vessel and a stripped carbon vessel is added to the end of the adsorption circuit.

Jan 1, 1998

By Donald D. Haas

Contract mining has a definite place in the mining industry, both in the United States and around the world. A mine owner should evaluate the utilization of contract mining in the devel­opment and production of mining properties. This evaluation of contract mining should be performed at various times in the life of a mining prope1iy from the development and initial operation of a new mining project, periodically throughout the mine's life, and at mine closure. Many factors must be considered in ana­lyzing and evaluating the potential of contract mining and those factors are both quantitative and qualitative. Quantitative factors are those factors for which costs or measures can be determined or estimated objectively; and qualitative factors are those factors for which costs or measures must be determined subjectively and do not lend themselves to objective determination or estimation. Some of the qualitative aspects may provide only yes, maybe, or no answers while others will provide a tendency or partiality toward one answer or the other without a quantified cost. The major quantitative aspects include operating and capital costs, monitoring costs, capital preservation, acquisition and disposal of new and used equipment, direct payroll and administrative costs, recruiting and training costs, and employment and termi­nation of staff and hourly personnel. The major qualitative areas include corporate philosophy, risks associated with capital and operating costs, financing the project, operating control, operat­ing flexibility, recruiting and training of personnel, employment and termination, administrative concerns, and owner/contractor relationship.

Jan 1, 1998

By G. I. Voiloshnikov, V. E. Dementyev

Wide use of adsorption methods for metal recovery is one of the most important achievements of gold metallurgy of the last decades. Anion exchange resins or activated carbons may be used as adsorbents. This paper presents a brief overview of IRGIREDMET effotts on development, testing and implementation of techno­logical flowsheets using both adsorbent types and attempt to compare their technological properties. IRGIREDMET Institute was founded in 1871 as a laboratory for gold smelting and gold ore testing. In 1930 it obtained the status of the Research Institute. IRGIREDMET functioned as leading research center for gold mining industry in the former Soviet Union. At present it is the Open Joint Stock Company dealing with all s01t of research and design works for gold min­ing (ranging from geology to gold refinery). IRGIREDMET started development of ion exchange technol­ogy in 19641• The first stage of work (1964-1970) including development of principle flowsheet of RIP process was carried out jointly with the Moscow VNIIKHT Institute (All-Russian Scientific Research Institute of Chemical Technology)2• The flowsheet of RIP process is presented in Fig. I and includes the following basic operations: gold adsorption from pulp; washing of loaded resin; acid treatment; thiourea adsorp­tion; gold elution by acid thiourea solution; resin washing to remove thiourea; alkaline treatment of resin; resin washing and gold recovery from eluates by electrowinning. The technology developed and equipment used were tested for treatment of clayey ore of Kuranakh deposit at a pilot plant of the Lebedinsky gold complex ("Aldanzoloto" company, Yakutia, Russia). The pilot plant throughput was 200 t/day. At the same time IRGIREDMET conducted the tests on ion exchange technology for ore and concentration products of oper­ating gold plants and for ores of new deposits. Laboratory and pilot plant tests were done and developed initial data and process design criteria for designing of 15 plans of the former Soviet Union. In the course of this work a great number of newly synthe­sized anion exchangers including strong and weak base resins was studied, the peculiarities of anion exchange resins using two different raw material types ( ores and concentrates includ­ing clayey, carbonaceous, silver bearing, arsenic, antimony and base metals bearing products); some theoretical regularities of adsorption process were investigated; the technology of two stage adsorption of gold and silver from silver gold ore, improved flowsheet for gold elution and resin regeneration, design of adsorption equipment including pulsation columns, design of electrowinning cells were developed; conditioning technology for pulp with complex ion composition prior to gold and silver adsorption was developed, etc.3·8• IRGIREDMET specialists took part in commissioning of practically all the plants in the former Soviet Union using RIP and RIL process including Lebedinsky, Kuranakh, Sovetsky, Karamken, Matrosov's plant and Mnogovershinny plants. Due to this works RIP process became standard technology for Russia and the CIS.

Jan 1, 1998

By J. E. Wennen

Screens serve several important functions in CIL and CIP processes for gold extraction. One important screen application known as interstage screening allows slurry to be continuously transfered through a series of CIL or CIP tanks while retaining activated carbon in the tank. In some cases, this has been accomplished by using airlifts to carry slurry containing activated carbon to an external screen which separates carbon as oversize and returns it to the tank by gravity. The undersize slurry advances to the subsequent tank. More recently this has been accomplished using launder screens and Kambalda type screens. These are essentially static screens that rely on air blasts or mechanical sweepers to clear carbon away from the screen surfaces.

Jan 1, 1998

By David J. Collins

The emergence of activated charcoal adsorption as the most popular recovery method for precious metals, has led to numerous innovations aimed at increasing the efficiency of the process. This article describes a change in traditional charcoal transfer methods which will aid in reducing charcoal attrition losses. Studies have shown that significant charcoal attrition takes place during transfer, be it when using airlifts or centrifugal pumps. Tests conducted at Pinson Mines indicated a 4 to 8% loss to the minus 20 mesh fraction of charcoal after three (3) hours of pumping charcoal. Tests conducted while the author was at Jerritt Canyon indicated that charcoal transfer was a major contributor to charcoal losses; a decrease in the amount of coarse charcoal (plus 12 mesh) and an increase in the amount of finer charcoal (minus 16 plus 20 mesh) was noted as charcoal was moved to the head of the adsorption circuit.

Jan 1, 1998

By John Litz

The term "refractory gold ores" refers to a wide number of ore types which are not readily amenable to direct cyanidation. A number of processes have been used commercially, and a number of others have been proposed and in many cases pilot tested. The selection of the appropriate process for an ore should not be arbitrary. Ore grade may preclude some processes, but a good understanding of the ore mineralogy can guide the selection. Many present gold operations and many potential gold operations have faced or are facing problems with refractory gold mineralization. We at Hazen Research have had the opportunity to perform bench testwork and in some cases, pilot plant testing on a number of refractory ores. The data included in this paper are excerpted from the testing of fifteen ores which cover a wide range of mineralogical compositions. This paper is not intended to be a treatise on the processing of refractory gold ores. In many of these gold projects, not all of the standard process alternatives were evaluated, nor was adequate mineralogical work performed. Such is the dilemma of contract research. "If I believe that I don't need it, why should I pay to have it done." The intent of this presentation, therefore, is to show how different ores respond to the various processes, and to demonstrate that one must have an open mind when developing a process for a specific refractory gold ore.

Jan 1, 1998

By Ray Soper

Important progress has been made in developing the K-Process as an alternative to cyanide as a method of recovering gold from ores and other materials.

Jan 1, 1998

By C. Botha, M. J. Walls, C. T. O'Connor

The role of copper sulphate in the flotation of pyrite has been studied. A survey of a number of pyrite flotation plants using copper sulphate showed that in correct dosages, it was able to increase both grades and recoveries. This was confirmed in batch tests. Copper sulphate had no significant effect on the rate of adsorption of PNBX onto pyrite. Copper adsorbed irreversibly onto the pyrite when the latter was slurried in a copper sulphate solution. Copper sulphate had a significant effect on the maximum froth height obtained in static three-phase froth tests. Proposals to explain these observations are made.

Jan 1, 1998

By David Green

Outokumpu introduced Flash Flotation in the early l 980's for the recovery of floatable material from grinding circuits. The devel­opment came as a result of surveys made in the company's own concentrators, initiated to find ways of improving recoveries with increasingly complex and lower grade feeds. Hydrocyclones make a separation on the basis of particle size and mass, resulting in the "over collection" of fine grained, high S.G. particles. Minerals such as pentlandite, galena and gold are easily caught in the circulating load around the mill until they are overground and rendered more difficult to collect. In the case of downstream flotation this may simply involve a reduction in the rate coefficient due to the finer sizes or, as is commonly experienced in gold operations, the mate­rial is slimed and coated onto non-floating gangue and is eventual­ly lost to tails. At the time of Outokumpu's plant surveys, it was a relatively common practice, particularly in Pb operations, to have a flotation section fed directly from the secondaiy mill discharge. This is called unit flotation and certainly provided an improvement but very high wear rates and frequent sanding out of the cells was com­mon. The development of the SkimAir® Flash Flotation cell by Outokumpu provided a subtle but quite dramatic departure from the unit cell approach. Now it was possible to feed cyclone under­flow into a special purpose-built flotation machine and recover a final grade concentrate from the grinding circuit (see Figure I). The cell was designed to handle the coarse circulating load, per­mitting the coarsest fractions to be short-circuited back to the mill and retain the floatable sizes for a nominal time of 30 seconds to several minutes. The short retention time was possible largely due to the relatively clean content of the cyclone underflow stream. This means that the fine gangue is not present except in small quan­tities and most of the fine to mid-size paiiicles are higher S.G. and more likely represent valuable mineral. This condition provides for very high rate coefficients. Typical operations would recover 40-60% of the valuable mineral in this fashion and improvements in recovery were typically from 2-5% for sulphide minerals to the 5-20% range for gold and silver.

Jan 1, 1998

By Norman Haber

The Haber Gold Process (HGP) is a proprietary. hydrometallurgical extraction methodology that was developed in 1983-1984 by Norman Haber and Dr. John Lee of Haber, Inc., a small public company in Towaco, New Jersey specializing in hydrochemical process development for precious metals. It was pilot tested repeatedly in 1985 at our pilot plant in Tombstone, Arizona, with different types of gold bearing mineralization. Both Pincock, Allen and Holt (USA), and PA Technology (Australia) were involved with some of these pilot tests. The ores tested included easily cyanide-extractable oxide type gold ore from Australia, marginal heap-leach type ore from Cripple Creek, USA, and a hematite bearing ore from California. In all cases, extraction time was 6 hours or less yielding 90-99% recoveries of assayed gold values. The HGP operates as a lixivient which parts the gold from the rock matrix, yielding gold in solution in a fully recoverable form. Both precipitation methods, such as zinc participation or Carbon in Leach systems ( or Carbon in Pulp) have been shown to be feasible with this technology for the recovery of gold from the pregnant solution. Both batch vat leaching as well as continuous processing are realistic for use with the HGP. It has also been considered that the HGP might also benefit heap leaching due to several advantageous factors over cyanide. One such consideration is that the HGP can operate effectively with acidic ore types. The use of cyanide with such ores often requires attention to pH and neutralization with lime. This tends to reduce and even clog the permeability of the leach bed.

Jan 1, 1998

By Robert C. Dunne

Nearly one third of Australia's total gold product is produced in the Kambaloa - Kalgoorlie - Leonora Goldfields. There are presently some 25 gold mines in the area with the possibility of another six plants being constructed in the next year. Details of the gold extraction techniques used on these mines will be discussed and certain innovative technologies and problem areas will be highlighted.

Jan 1, 1998

By Tan Xiang-Kun, Liu Ming-dong, Yao Dun-Pu

Since the 1980s, heap leaching of gold and silver ores has been developing rapidly and experienced widespread use in China because of its lower capital and operating costs, less time consumed in construction and specific applicability to small-to-medium scale mining operations and low grade ores. Ores treated include ordinary oxidized ores, refractory sulfide ores and even those containing deleterious elements (such as arsenic or antimony) and/or carbonaceous substances. In addition to chemical leaching agents, some micro-organisms (e.g. T-ferrooxidians and T-thiooxixians) and their biochemistry mechanism have been equally emphasized. To overcome the adverse effect caused by excessive content of fines and slimes, research and pilot experiments of agglomeration-heap leaching are currently underway at two gold mines in South China and their encouraging preliminary achievements will be briefly described as illustrations in this paper. It could be expected that heap leaching of gold and silver ores holds promise and will play an increasingly important role in China's gold industry.

Jan 1, 1998

By Daniel W. Kappes

Until recently, the general expectation among mining compa­nies and financial analysts has been that the price of gold would remain on a generally upward slope. The recent drop in the price of gold has caused many people to re-think the issue. Of course, the price of gold is singularly difficult to predict, so it is difficult to tell which concept is correct. In the present financial situation, however, many junior gold companies are faced with the reality that money is hard to raise, and many senior gold companies find that they are facing a period of corporate losses even though they own solidly producing mines, As engineering consultants, Kappes, Cassiday has recently received several requests to review conventional milling projects to see if heap leaching is a more viable option. In regard to straight financial criteria such as return on investment and net present value, the question is usually fairly easy to answer. However, corporate decisions must often be based on less definable criteria. For instance, new stock issues tend to be more successful if they are larger, which tends to favor milling operations over heap leaches. The corporate issues are often subjective and difficult to generalize about, so I will con­centrate in this paper on a few financial concepts.

Jan 1, 1998

By C. S. Caldwell, L. C. Thompson

Mine closure and reclamation issues have evolved over the past several years becoming further complicated by stricter standards and by the cmrent economic climate and price of gold. Many mine permits are calling for more stringent remediation of spent ore heaps and tailings. Leachate solution water quality must meet strict discharge criteria for multiple parameters besides cyanide at mine closure. Closure standards are more difficult to meet and most mines do not have an increased budget at the end of mine life to deal with the falling standards. These issues make additional gold recove1y at the end of mine life a critical problem in financing some closure operations. Another issue is the length of time that must be budgeted for heap rinsing operations. Innovative biological processes developed and applied by Pintail Systems, Inc. at numerous mine closures have indicated that bio-processes can significantly enhance gold recovery dur­ing heap cyanide bio-detox over the recoveries expected from rinse operations. If heap rinsing can be eliminated or reduced and if gold recovery can be improved at the end of mine life, many mine closures may be possible with processes that pay for themselves or generate profit. Additional advantages of the bio­detox technology is that it can be engineered to treat multiple contaminants besides Weak Acid Dissociable (WAD) cyanide. Other contaminants treated in heap process solutions include nitrates, ammonia, heavy metals, thiocyanate and total cyanide. At the Cripple Creek and Victor Mining Company Ironclad Mine near Victor, CO, 5 million tons ofrinsed, heap leached spent ore were biologically detoxified to reduce cyanide content, enhance gold recovery during bio-detox and to reduce dissolved metals in heap leachate solutions. During the bio-detox treatment period a substantial improvement in gold recovery allowed the detox oper­ation to operate as a profit center. Final gold recovery was at least twice what was expected from a normal rinse operation.

Jan 1, 1998