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By Giovanni Principi

The activity of the ?Hydrogen Group? of Padova University, addressed to the study of materials for solid state hydrogen storage, is illustrated. Various Mg-based materials have been considered and are being studied: a) MgH2 and 0.5% mol Nb2O5 mixture ball milled under argon atmosphere; b) Mg-Ni-Fe intermetallic compounds prepared by short time ball milling of ribbons obtained by melt spinning and by long time ball milling of a mixture of MgH2, Ni and Fe powders; c) MgH2 ball milled in argon with Mm-Ni-Al (Mm = La-rich mishmetal) and Zr-Cr-Fe catalyst alloys. All the samples have been structurally characterized by X-ray diffraction (Rietveld refinement) before and after hydrogen absorption/desorption cycling and tested with a Sievert apparatus as regarding their thermodynamic and kinetic properties.

Jan 1, 2006

By G. G. Krishna Murthy

Interactions of wustite and hematite pellets with Fe-C melts were investigated experimentally by examining the effect of pellet size and bath temperature on the reduction rates of the pellets. Experiments were carried out in the temperature range 1473-1923 K. A flash X-ray equipment was used to obtain images of the melt surface during its reaction with an oxide pellet. The reduction rates were calculated using experimentally estimated time for complete reaction of a pellet, tR. The value of tR was determined employing gas mass flow rate, or pressure rise in the sealed furnace, versus time traces. The value of tR was the same for both wustite and hematite pellets of equal weight at or above 1723 K and it decreased with increasing melt temperature. But the reduction rate was substantially lower at temperatures below 1651 K, the melting point of wustite. The rates were defined as the rate of moles of oxygen removed from the pellet per unit area of bath free surface and it was found that the bath surface area affects the reduction rates. It was established that the overall reaction followed nth-order rate kinetics with the values of n falling between 0.3 and 0.4 for temperatures above the melting point of wustite. The apparent activation energy determined using the apparent rate constants obtained from the experimental data was 76.2 + 27.7 kJ/mol-O.

Jan 1, 1992

By Chuan-fu Zhang

In present work, the physical properties of molten FenO-MgO-CaO-SiO2 slags were measured .It is shown by the results that when the slag composition is as follow: MgO 8%~12%, CaO 2%~8%, Fe/SiO2 1.2~1.6, the viscosity of the slags decreases with the increase of temperature. When the Fe/SiO2ratio and the MgO content are fixed, the electrical conductivity increases and the viscosity decreases as CaO content increasing, while the content of CaO exceeds 6% its influence weakens. When the MgO content is 11% and the CaO is 6%, the viscosity of the slag decreases markedly as the increase of Fe/SiO2 ratio. Its influence to viscosity is inconspicuous when the Fe/SiO2 ratio exceeds 1.5. When the CaO content is 6% and Fe/SiO2 is 1.2, the electrical conductivity decreases with the increase of MgO content as temperature is below 1290, but increases when temperature is above 1290. When the MgO content is 11% and the Fe/SiO2 ratio is 1.2, the electrical conductivity increases with the increase of CaO content. When the CaO content is 6% and MgO content is 11%, the electrical conductivity increases as the increase of Fe/SiO2 ratio, while its influence weakens as the temperature increases continuously. The electrical conductivity rises when temperature increases at any slag content. The melting temperatures of FenO-MgO-CaO-SiO2 semi- synthesis slags from this work were below 1290.

Jan 1, 2006

By Li Chen

A new process, i.e. Ball milling--Neural leaching--Oxidation calcinations--Chloridizing distillation--Hydrolysis, was designed to recover germanium from the vacuum furnace slag produced in Shaoguan smelter. The suitable process and operational parameters were determined for the practical production.

Jan 1, 2005

By Tao Zeng, Jianchao Li, Chang Jie, Jieyu Zhang, Jifang Xu, Kuochih Chou

"The densities of the selected quaternary Ca0-5%Mg0-Alz03-Si02 slag with low silica were measured by the Archimedean method in a wide temperature range from l 723K to 1823K. Slag compositions were chosen based on five different levels of Si02 content between 0.00 pct and 11.40 pct. The MgO content was equaled to 5.00 pct. The mass ratio of CaO/Alz03 was varied from 0.67 to 2.14. The effects of temperature, Ca0/Alz03 ratio and optical basicity were studied. It is shown that density decrease approximately linearly with an increase in temperature. With the same Si02 content, the density decreases with increasing of CaO/Alz03 ratio and optical basicity. Based on the experimental data as the boundary of the homogenous phase region predicated by F ACTSAGE software, the mass triangle model is used to calculate the density of selected limited homogenous phase region. The results showed that the mass triangle model is working well.IntroductionIt is of great importance to measure density of slag melt not only to the theory research for melt, which that is directly amenable to the structure correlations of molten slags, but also to the industrial application. Many metallurgy phenomena such as inclusion formation in molten melt and its removing, slag foaming, slag-metal reaction are closely related to the density of slag. Density is also required to estimate other fundamental properties, like surface tension, viscosity, and thermal conductivity from thermal diffusivity so that a relatively complete picture in regard to the behavior of high-temperature molten oxides could be made."

Jan 1, 2013

By K. D. Peaslee, V. L. Richards, C. H. Rawlins, S. N. Lekakh

"Steel-making processes generate carbon dioxide air emissions and a slag co-product. The aim of this project was to develop a functional sequestration system using steelmaking slag to permanently capture carbon dioxide emitted in steelmaking offgas. A possible parallel benefit of this process would be rapid chemical stabilization of the slag minerals with reducing swelling or leaching.This paper summarizes the original results of the project, including mineralogical and structural features of carbon sequestration with steel making slag, mathematical modeling of reaction phenomena using a modified shrinking core model, METSIM modeling of several possible industrial applications, a thermo-gravimetrical study of the reaction between slags and different gases, and design and testing for a lab scale apparatus consisted of two reactors.1. IntroductionThe U.S. produces 9-14 Mt of steelmaking slag annually, which represents approximately 10-15 wt. % of crude steel output.1,2 Primary uses for steelmaking slag include high quality mineral aggregate, Portland cement, unconfined fill, soil conditioning, and pH neutralization of abandoned mine drainage.3,4 The key factor prescribing slag use is the alkaline-earth metal (e.g. Ca and Mg) oxides content, which contribute to overall basicity and cementitious strength. However, as-produced steelmaking slag is chemically unstable. Calcium and magnesium oxides readily form hydroxides and carbonates through reaction with atmospheric gases. Both hydroxide and carbonate formation produce substantial mechanical swelling leading to heave failure in confined construction applications, thus many states dictate stockpile aging for 3-6 months prior to commercial use.5,6 Sequestration of carbon dioxide is a natural corollary to forced carbonation. The conversion of CaO/MgO to carbonates serves both to stabilize the slag, and permanently capture and store the CO2."

Jan 1, 2008

By Huaming Yang

The vanadium-doped SnO2 nanoparticle was synthesized by the co-precipitation reaction and subsequent calcination from the vanadium(III) chloride and tin(IV) chloride. The crystal size, pore size distribution, micrograph and properties of the nanocrystalline powders were examined by differential thermal analysis (DTA), thermogravimetric analysis (TGA), X-ray diffraction (XRD), desorption isotherm (Barrett-Joyner-Halenda method) and transmission electron microscopy(TEM). Thermal treatment of the precipitate powder at 600°C led to the formation of V -SnO2 nanoparticle of -10mm in crystal size. Most of the pores in the nanoparticle are about 5~15nm in diameter. Effect of doped vanadium on the crystal size of the nanopartic1e was discussed.

Jan 1, 2003

By M. Mujahid, A. Maqsood, M. H. Asghar, K Iqbal

"Thin film multilayer anti-reflection coatings (Si02/Si/Si02) having thicknesses 286/571/143nm were deposited by RF magnetron sputtering deposition technique on 0.5mm thick Si(100)-substrates. Post-deposition annealing is also carried out in the temperature range 150-650°C for 4hr at the rate of 10°C /min. Si Optical window was designed at 4.21lm wavelengths and correlated with modeling software. The films are transparent in the 3-51lffi band of the electromagnetic spectrum, firmly adhered to the substrate. The prepared multilayer thin films are characterized optically and structurally using a spectrophotometer, an atomic force microscope, x-ray diffraction and a scanning electron microscope. Optical and structural characterizations show that the %transmittance is between 60% and 75%, no appreciable change in crystal structure and roughness of coatings vary between 9 and 25 nm when annealed in the temperature range of 150-650oC. Local elemental characterization on the surface of the thin film was carried out using energy dispersive spectroscopy. The quantitative result of energy dispersive spectroscopy has also shown that the ratio of Si to 0 on the film is 0.67: 1.IntroductionSi02 thin films have unique properties in the interfaces with Si and most studied materials in the field of microelectronics and optical devices [1]. Multilayer thin films are using nowadays in the design and fabrication of the shrinking systems with a variety of fields such as optoelectronic devices. The physical properties and parameters can be controlled at scales of microns down to nanometers by using RF magnetron sputtering system [2].Silicon and Silicon dioxide are used as coating materials [3]. These thin films are laid on top of each other in SiO2/Si/Si02 order by RF magnetron sputtering on top of a substrate as given in Table 1."

Jan 1, 2012

By Yun Li

In 1999 Yunnan Copper Corporation (YCC) decided to modernise their copper smelter and change the existing sinter plant I electric furnace process to a combination of ISASMEL T and electric slag cleaning furnace. The main aim of the project was to improve the environmental performance and decrease the energy consumption. Generally the project has been successful, partly attributable to the selection of a reliable and fully demonstrated technology. The design capacity for the ISASMELT furnace is 600,000 tonnes of dry copper concentrate per year. The furnace has been running smoothly since heat up in May 2002. YCC expended considerable effort in the preparation for plant operation. An extensive training program for key YCC personnel at the Mount Isa Copper Smelter improved their understanding of the process significantly and ensured successful hand-over of the technology. This paper describes the project history and summarizes initial operating results.

Jan 1, 2003

By Afrodite Ntziouni, Vassilia Kasselouri – Rigopoulou, Athanasia Kyritsi, Konstantinos N. Pistiolas, Stamatia Gavela, Konstantinos Kordatos, Lazaros Iliadis

"The present study deals with the production and characterization of rice husk ash (RHA) and its use in the synthesis of zeolite of type ZSM-5. Rice husk was combusted in various temperatures with aim to find the suitable conditions for the production of amorphous silica. The resulted amorphous silica ash was then utilized as a starting material for the synthesis of ZSM-5 zeolite using the low temperature and atmospheric pressure process. The method led successfully to the synthesis of highly siliceous zeolite of type ZSM-5. The produced material was characterized using x-ray diffraction (XRD) and scanning electron microscopy (SEM).IntroductionRice husk is a major by-product of the rice-milling industries and it is usually used as a fuel for steam generation due to its high calorific power. During its combustion, rice husk ash (RHA) is produced. Knowing that the annual rice world production is over 615 million tons (2005), thus resulting in a potential production of more than 22 million tons of RHA [1], it can be understood that the RHA disposal is a crucial issue towards the environmental protection. However, due to the high silica content, RHA can be used as an alternative cheap source of silica for many uses, including as filler in polymers [2], concrete [3] and synthesis of zeolites [4-7].The burning of rice husk in air results in the formation of RHA with content in SiO2 that varies from 87 to 97% depending on the burning conditions, the rice variety, the climate and the geographic area [8]. Some small amounts of inorganic impurities are always present in the ash along with unburned carbon. The unburned carbon can be removed from the ash by further heating treatments in high temperatures, but this usually leads to the crystallization of the amorphous silica to cristobalite and/or tridymite [9]. The crystallization of the contained silica of the ash is also occurred when the burning conditions of husk are uncontrolled [10]. This crystallization is a disadvantage towards the preparation of silicon based materials, because the silica ash is rendered inactive in its crystalline form [11]."

Jan 1, 2008

By M. Omneya El-Hussaini, M. Galal Abdel Wahab, A. Mohamed Mahdy, M. Fathi El Shahat

"Lead-zinc mineralization is distributed in Egypt along the Red Sea coast between El Qusier and Ras Banas. A representative sample from Um Gheig was collected and ground to -60 mesh for the mineralogical study. It contains hemimorphite (Zn2SiO4.H2O), sphalerite (ZnS), galena (PbS), calcite (CaCO3) and dolomite (CaMg(CO3)2) beside the gangue minerals gypsum (CaSO4.2H2O) and hematite (Fe2O3). Cadmium seems to be incorporated in the crystal structure of the zinc-lead minerals. The chemical analysis of Um-Gheig representative sample revealed that, it contains 16% zinc combined with 0.1% cadmium, 2.3% lead and 0.1% boron beside other elements.Pug and agitation leaching were performed on samples ground to -200 mesh to achieve the maximum dissolution efficiency of cadmium with respect to other elements. Cadmium leaching efficiency reached 90% by using 40% H2SO4 at S/L ratio 1/2 and stirring time 2 hours at 80o C. Cadmium was then separated as yellow precipitate of CdS from the sulfate leach liquor containing 0.9 g/l Cd, 145 g/l Zn, 0.15 g/l B and 0.01 g/l Pb. Separation of cadmium was carried out by direct precipitation using Na2S as well as H2S. The recovery of 94% cadmium free of zinc was achieved.IntroductionLead-zinc ores occur in Egypt in a few localities distributed along the Red Sea coast between El Qusier and Ras Banas. Um-Gheig Pb-Zn ore is a replacement deposit in limestone and calcareous sandstone in the basal series of the Middle Miocene rocks. The reserve of the ore deposits has been estimated by Soviet and German Experts to be about 900,000 Ton, Bishai [1]. As has been mentioned, zinc is a common element and cadmium is comparatively rare in almost zinc minerals. It was estimated that zinc is 200 times as abundant as cadmium. According to Bodas [2] about 2.1% of cadmium was carried by the Zn mineral hemimorphite (15.3% Zn) in Thailand. Also, Onal et al., [3] found that 164 g/t Cd was carried by Pb–Zn ore sample containing 10.17% Pb and 10.98% Zn from Aladag in Turkey. Cadmium metal has gained great importance due to its wide applications in civil and navy purposes as well as in nuclear field. It is characterized by its ability to absorb thermal neutrons during the chain reaction inside the nuclear reactors. It is also used in the manufacture of sheets which directed the chain reactions [4]."

Jan 1, 2008

By J. L. Johnson

The U.S. Department of the Interior, Bureau of Mines, investigated recovery of concentrates containing tin, tantalum, and niobium from the Kougarok deposit on the Seward Peninsula, AK. To date, 25 million lb of tin has been delineated in occurrences containing 0.36 to 1.32 pct Sn, and the resource potential is estimated to be as high as 25 million short tons at average grades of 0.75 pct Sn, 0.025 pct Ta, and 0,025 pct Nb. Deslimed ore was concentrated to 54 pct Sn, 0.3 pct Ta, and 0.3 pct Nb, with recoveries of 74 pct Sn and 44 pct Ta/Nb using a Humphrey's* spiral followed by a Deister shaking table. Tin values in the slimes were upgraded to a 5-pct-Sn concentrate using a Bartles-Mozley separator followed by flotation. The 5- pct-Sn was further upgraded by fuming to give a concentrate containing approximately 60 pct Sn. The recovery of the two products combined was 80 pct Sn and 46 pct Ta/Nb, A flowsheet with mill-design parameters resulted from the metallurgical testing. An economic analysis was made based on the proposed process.

Jan 1, 1990

By Wei Han, Zhenwei Liu, Jianhong Yang, Qingwei Qin, Tiejun Chen, Zili Huang

The preparation of industrial ammonium molybdate from molybdenum concentrate was conducted according to the process of roasting—leaching—purification—precipitation—crystallization. The optimum technological conditions were determined: the roasting temperature was 680 degrees C, the roasting time was 2.5 h; in the leaching process the alkali excess coefficient was 1.2, the reaction temperature was 80 degrees C, the liquid-solid ratio was 3:1, the leaching time was 3 h; the amount of (NH4)2S added into the solution was 1.1 times of the theoretical amount, the temperature was 80-85 degrees C, and the terminal pH was 8.5-9 in the purification process; the density of the solution was 1.4-1.6 g/mL, the pH was 1.5-2 in the precipitation process; temperature of dissolution was controlled at 80-90 degrees C. The recovery of the preparation of ammonium molybdate can reach 85.18%.

Mar 1, 2017

By Jiang Diao, Yong Qiao, Xuan Liu, Tao Zhang, Bing Xie

Adding CaO into the vanadium extraction converter is an effective way to decrease the dephosphorization burden in subsequent steelmaking process. The crystallisation process of spinel is one of the most decisive factors in the subsequent extraction. The theoretical calculation results show that the temperature of the peak total crystallization rate will decrease 5K with basicity increasing 0.1. The relation between cooling conditions and grain size of spinels is also discussed. It is found that low cooling rate and high basicity benefit spinel crystal growth. And the non-isothermal crystallization kinetics results indicated that the restriction factors of spinel growth is that solid crystals accept new components from liquid-solid interfacial. While the sample was cooled down to 1250 (1523K) at cooling rate of 5K/min, the crystal growth is consistent with Ostwald coarsening grew up law, and controlled by diffusion of particle.

Jan 1, 2016

By O. C. Gaspar

The mineralogical and textural characteristics of the volcanogenic massive sulphide ores from the Aljustrel and Neves-Corvo deposits have been studied by ore microscopy techniques since 1977. Several ore types have been recognized, and the ore paragenesis, ore textures, and behaviours of different ore types during grinding and concentration processes, have been determined. An ore classification was established for use in metallogenetic studies, ore reserve calculations, selectivity during mining, and control of the ore beneficiation processes. In addition, an empirical method was developed for supplying, on time, the qualitative and semi-quantitative information needed for processing the Aljustrel ores and for optimizing the Neves-. Corvo copper and tin concentrators.

Jan 1, 1991

By Francois Barthelat, Sam Goroshin, David Frost, Alexander Cappozi, Atefeh Nabavi

"In this study, a novel chromium–chromium sulfide cermet was produced by self-propagating high-temperature synthesis (SHS). Conventional techniques for manufacturing metal sulfides are complex, environmentally harmful, and not suitable for producing complex-shape articles. To overcome these disadvantages, a new method for the preparation of the metal-sulfur precursor charge is proposed, which can be described as reactive casting. The first cermet samples produced with the SHS process were found to be very porous, brittle, and have low mechanical strength. The possible sources for the generation of porosity were identified and analyzed and the process for manufacturing the cermet was modified. By improving the manufacturing process, the porosity inside the produced cermets was reduced from 70% to 12%.IntroductionMetal sulfide composites are in high demand in the chemical, metallurgical, and electrical industries because of their valuable characteristics such as hardness, semi-conductivity, electroluminescence, infrared transparency and catalytic properties. Current manufacturing methods for metal sulfides usually involve one of two different principal methods, including a complex multistage wet chemical process involving the precipitation of the corresponding salts from an aqueous solution with hydrogen sulfide, or hot sintering of the respective elemental reactant powders in a resistive furnace in a high-pressure inert or hydrogen-sulfide atmosphere [1, 2]. These conventional methods for synthesizing ceramic metal composites are complex, extremely time and energy consuming, environmentally harmful, and rarely able to manufacture articles with complex shapes. Therefore, in order to overcome these disadvantages, self-propagating high-temperature synthesis (SHS) was considered as an alternative method that offers significant improvements over the traditional cermet manufacturing methods [3]. SHS, which is a relatively new and attractive method for producing a wide range of advanced materials, is based on the self-sustaining feature of the highly exothermic reactions of the reactants. The SHS process results in high product purity, since the high temperatures generatedin the reaction cause any impurities to volatilize [4, 5]. SHS has low energy consumption and doesn’t require an external energy source and complex equipment, and it is self-contained [1, 5]. Since combustion synthesis has low power requirements, it is one of the few methods of materials synthesis that is feasible in outer space. Also, the process has a low cost and is capable of directly synthesizing articles with the desired shape, size and structure [5, 6]. The chemical reactions associated with SHS are typically completed in a few seconds leading to the formation of the condensed product. The high reaction rates and relatively rapid cooling in SHS reactions can avoid undesirable grain growth in products which often occurs with the conventional sintering method [3, 5, 7]. The traditional method for sample preparation in the SHS technique is to compact the reactant mixture powders in a steel die by a press to a typical density of about 80% of the theoretical maximum value, before igniting the mixture [8]. This method requires a large compression force to increase the green density and to minimize any pores in the green compact. To overcome these disadvantages, a new method for the preparation of the precursor charge in metal-sulfur by SHS is proposed which can be described as melt casting of a reactive mixture, or reactive casting in short."

Jan 1, 2012

By Wen-Ming Chien

Low temperature X-ray diffraction and thermal property studies of the solid-solid state phase transition for the polyalcohols (pentaerythritol (PE), pentaglycerine (PG) and neopentylglycol (NPG)) thermal energy storage solid solutions have been investigated by using X-ray diffractometry and differential scanning calorimetry (DSC) methods. X-ray diffraction studies on polyalcohols solid solutions, PE-NPG and PG-NPG, are from ?10oC to 50oC. XRD results shows the + mixed phase at the related low temperature (?10oC) for both PE-NPG and PG-NPG solid solutions. At high temperature range, XRD results show phase for PG-NPG solid solution and + mixed phase for PE-NPG solid solution. There are only two Bragg peaks, (111) and (200), shown in phase XRD patterns. The polyalcohols solid solutions have been cycled 5 times between -20oC to 100oC at different DSC scan rates to study the phase transition properties. DSC results of both PE-NPG and PG-NPG solid solutions show that the solid-solid state phase transition is near room temperature. Details of low temperature phase transition XRD and DSC results of PE-NPG and PG-NPG solid solutions will be presented

Jan 1, 2006

By Shadia J. Ikhmayies

"Tin oxide (SnU2) thin films of thicknesses in the range 100-600 nm were prepared on glass substrates by vacuum evaporation at ambient temperature. The films were characterized by transmittance measurements, X-ray diffraction (XRD), scanning electron microscope (SEM) observations and energy dispersion X-ray analysis (EDAX). It is found that the films have high transmittance and non sharp absorption edges. XRD diffractograms showed that the films are amorphous and the SEM micrographs showed that the surfaces are smooth, uniform and well covered with the material. The EDAX analysis showed that the films are deficient in oxygen. Indirect optical bandgap energy and Urbach tailing in the bandgap was observed, and the width of the tail, which is related with disorder and localized states, was estimated.IntroductionTin oxide is an n-type wide bandgap semiconducting material with a direct bandgap energy of 4 eV and an indirect bandgap of 2.6 eV [1], where inherent oxygen vacancies act as an n-type dopant [2], Tin oxide thin films have been used for transparent electrodes in photoelectric conversion devices namely amorphous silicon solar cells, liquid crystal displays, gas discharge displays, etc. [3]. Perfectly amorphous thin SnO2 films show good electrical response to reducing gases in air and could, hence, be applied to construct semiconductor gas sensors where the metal oxide films function as a monograin-eqivalent active layer [4]. Amorphous SnU2 can also be used in extended gate field-effect transistors (EGFET) as a pH sensor, where the sensitive part is made of the SnO2/Al structure. This device can be used to detect and to quantify any kind of substance that can produce or consume protons, like an enzymatic reaction, therefore showing a large range of applications as biosensors [5].There are different methods to prepare SnO2 films, such as atomic layer deposition (ALD) [6], reactive magnetron sputtering [7], chemical vapor deposition [8, 9], dip coating [10], spray pyrolysis (SP) [3, 11-14], and evaporation [8], The thermal evaporation method was chosen to produce SnO2 thin films in this work because deposition by this technique does not present any compositional problems. In addition, it is a low temperature technique, which increases the probability of producing amorphous films. To increase this probability, the films were deposited at ambient temperature."

Jan 1, 2012

By F. Elgersma

A high purity electrolysis solution is essential for hydrometallurgical zinc winning processes. For this reason ferric iron containing compounds such as jarosite are precipitated as iron and impurity collector during the calcine leaching. Jarosite thus forms a chemical waste and creates environmental problems. This research contributes to the development of a wet jarosite treatment process, where less contaminated jarosite is produced which can act as an iron source. The present work studies jarosite precipitation kinetics and the uptake of zinc cations in batch and continuous experiments. The distribution coefficient for zinc in continuous experiments is constant for a wide ratio of zinc over ferric ions in the solution. Addition of NH, + ions in batch experiments accelerates the conversion rate equivalent to the driving force increment. Addition of 50,2-ions above the stoichiometric ratio increases the conversion rate less then could be expected from the increase in the estimated driving force. Zinc ions tend to retard the conversion rate. An increasing reaction temperature increases the conversion rate. Below 75 ?C the conversion rate approximates zero.

Jan 1, 1990

By Feng Wang, Guojing Shi, Yangyang Xie, Zizong Zhu, Qiang Wu

The coal chars from northwestern part of China are characterized with high reactivity and low strength after reaction. Four type of coke-making coals selected from northwestern part of China were studied by proximate analysis, ultimate analysis, vitrinite reflectance analysis, and FTIR with curve-fitting analysis to obtain information on their chemical composition and chemical structure. The results show that the studied coals have relatively high values of final contraction of coke residue index (x) and relatively low values of maximum thickness of plastic layer (y) and average vitrinite reflectance. Based on the curve-fitting analysis of FTIR spectra, the aliphatic carbon (Cal), the aromatic carbon (Car), and the molecular structural parameters such as CH2/CH3, fa, Hal/Har, and (R/C)u are determined. The results of curve-fitting analysis indicate that the studied coals are characterized by a large amount of oxygen-containing functional groups and aliphatic side chains.

Mar 1, 2018