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By Dmitri Nassyrov, In-ho Jung

"All relevant thermodynamic and phase diagram data in the CaO-Fe10-CaF2 system were critically reviewed. One set of model parameters describing the Gibbs energy of all phases has been obtained as a result of critical evaluation of the available data and optimization of the model parameters. The Modified Quasichemical Model was used to describe the interactions in the liquid phase. All calculations were performed using the FactSage thermochemical software.IntroductionSlags contaimng CaF2 are of significant interest to the steelmaking community. Notable examples of slags containing significant amounts of CaF2 include Electro-slag Remelting (ESR) slags [1] and mould flux for continuous casting [2]. The role of these slags is, among other things, to refine steel by absorbing inclusions and dissolved impurities. During slag-steel interaction, some iron from the steel will inevitably get oxidized and form iron oxides which will dissolve into the slag. With this in mind, it is important to understand the interaction between CaF2 and Fe,0 for accurate prediction of slag composition and process optimization. A thermodynamic optimization of the CaO-FetO-CaF2 was thus undertaken."

Jan 1, 2013

By Yong-ming Chen, Chao-bo Tang, Yun Li, Long-gang Ye, Sheng-hai Yang, Hao-tian Xue

In order to achieve high recovery of Cu and Co during cobalt-bearing copper sulphide ore smelting process, reducing agent (coke) and sulphidizing agent (pyrite) were added into molten smelter slag for reducing-sulphidizing smelting to product Cu-Co matte. Effects of reductive atmosphere, pyrite dosage, smelting temperature and smelting duration on Cu, Co, Fe distribution behaviours were investigated. The results show that the distributions of Cu and Co are mainly enriched in Cu-Co matte, and the distribution ratio, LCu and LCo, improve with increasing of coke amount or pyrite addition, whereas above 6 wt.% coke or 20 wt.% pyrite, Cu and Co tend to transfer from matte to cleaned slag. A properly high temperature(1300) and smelting duration(3h) are beneficial to the enhancement of the distribution ratio of valuable metals, and under the given set of conditions, LCu > LCo generally. However, an undesired high Fe contents in matte limit further increase of LCu and LCo.

Jan 1, 2015

By Wangzhi Zhou, Jian Xu, Jing Zhang, Xuecheng Gong, Mingsheng He, Guohua Xie

Graphite, which has a unique stack structure that enables a small friction coefficient, is used as one kind of the best hearth rolls to support and convey silicon steel strip in continuous annealing furnace. However, the buildup formation in/on the surface of carbon sleeve has always been a worldwide difficulty in the silicon steel industry. Based on the analysis of the microstructure, topography and composition of the buildups, combined with simulation experiments, the mechanism of forming buildups is discussed. The results show that buildups experience the process from nucleating to growing-up, and buildups are formed by nano liquid phase sintering (NLPS). Meanwhile, some countermeasures to reduce or prevent the formation of the buildups are proposed.

Mar 1, 2018

By Kurt Westerlund

The design of the economically most profitable and technically most feasible smelter process gas handling .and treatment as an integrated part of the total metallurgical process is discussed and exemplified, with alternative flow sheets including material and energy balances, investment and operating costs. Retrofitting and de-bottlenecking of existing gas handling lines will be described and exemplified. Methods of increasing total gas handling line availability will be described.

Jan 1, 1992

By C. B. Piazzarollo

Ceramic materials exhibit dispersion results after being subjected to various levels of stress, from the point of view of mechanical strength. With the focus on sustainable development and to improve the strength of these material, was incorporated ornamental rock waste into clay in up to 10% in mass to conform some samples, that was fired to 750ºC, 850ºC and 950ºC and submitted to technological tests. This paper presents an analysis of the technological properties of the samples through the use of Weibull statistic to determine which the best firing temperature for these red ceramic materials. The Weibull Modulus indicates a greater homogeneity for samples with 10R at 950ºC.

Jan 1, 2015

By Timothy W. Skszek, Adrian S. Sabau, Hebi Yin, Gerard M. Ludtka, Xiaoping Niu

"A constitutive model has been developed to predict the yield strength aging curves for aluminum casting alloys during non-isothermal age-hardening processes. The model provides the specific relationship between the process variables and yield strength. Several aging heat treatment scenarios have been investigated using the proposed model, including two-step aging recipes. Two-step aging heat treatments involve a low temperature regime to promote nucleation of secondary phases and a second step at higher temperature for the growth of the secondary phases. The predicted results show that a yield strength of approximately 300MPa might be obtained in a shorter aging time, of approximately 30 minutes. As a result, better mechanical properties can be obtained by optimizing the time-temperature schedules for the precipitation hardening process of heat treatable aluminum alloys.IntroductionA356 is one of the commercially heat treatable aluminum casting alloys, and T6 is one of the heat-treated conditions to improve mechanical properties. The first stage of a T6 temper is solution treatment at an elevated temperature, generally in the range of 480 - 540°C. After solution treatment, the cast part is typically quenched in water/air to retain the solute-rich homogeneous matrix chemistry at room temperature. Subsequent ageing treatment stages capitalize on this super-saturated solid solution to generate controlled dispersions of very small strengthening precipitates within the matrix of Al grains [l]."

Jan 1, 2013

By Mike Dry

While McCabe-Thiele plots are useful for designing single-component solvent extraction systems, not least because of their simplicity, they are less useful for multi-component solvent extraction. This paper presents a relatively simple method, compared to other approaches, for modelling solvent extraction as chemical equilibrium reactions between the various aqueous and organic species. The essence of this approach is how values for the equilibrium constants can be extracted from standard laboratory data. Synergistic solvent extraction of nickel is used to illustrate the method.

By Mario Sanchez, Jose Palacios, Fernando Parada

Carbon steels have less than 0.02% copper and have low atmospheric corrosion resistance. The addition of at least 0.20 wt% Cu improves this property. Also, 0.8 wt% Cu in steel shows a hardening potential for developing high strength corrosion resistant steels. Copper slags containing 42–45% of iron, silica and minor amounts of copper were used for producing Fe–Cu alloys by reducing the oxides contained in the slag to obtain a Fe-0.84 wt% Cu alloy, which could be suitable as feeding material to manufacture a corrosion resistance steel, and also would be an alternative for minimizing the copper industry ’s environmental impact, and to introduce the application of the Circular Economy concept to the natural resources exploitation, especially in countries where their economy is strongly based in mining and metallurgical extraction.

Mar 1, 2018

By I. H. Bonekamp

Norddeutsche Affinerie has operated an Outokurnpu type flash smelter for more than 25 years. In recent years, the concentrate smelting capacity was increased to 750,000 tpy, double of the initial design capacity. Maintaining this high performance level requires very good metallurgical process control. It is not enough to base this control on thermodynamics and kinetics since the furnace is highly dynamic. Understanding these dynamics and being able to quantify them can have significant financial benefits. A mass and energy balance model was developed and is discussed based on measured data. At this time the model is based on the major elements copper, iron, sulfur and silica. With it is possible to quantify the differences of the various material streams such as matte, slag, flue dust, matte carry-over to settling furnace, etc. Comparing the reconciled energy balance model with the fundamental thermodynamic model makes it possible to quantify the dynamics. These dynamics are related to input parameters using methods such as statistics and neural nets. In the future this database will be used to improve the understanding of the dynamic process as well as the dynamic process control.

Jan 1, 1999

By Md. Z. Quadir, M. Ashraf, A. A. H. Ameri, J. P. Escobedo-Diaz

The quasi-static mechanical response of hot rolled lean duplex stainless steel 2101 (LDSS 2101) in rolling, transverse and normal directions under compression loading has been investigated for its perceived anisotropic behaviour. Microstructural characterization is performed by optical microscopy and Electron Back Scatter Diffraction (EBSD) to qualitatively define the influence of the texture by using Taylor factor and grain sizes, and phase boundaries by utilizing the modified Hall-Petch formula. It was observed that LDSS2101 does not show anisotropic behaviour in terms of the mechanical strength but it has a clear anisotropy in the lateral strains; the microstructural explanation of this response may result from the phase boundaries strengthening.

Mar 1, 2017

By M. Kawakami

In the blast furnace, the reduction of iron oxide and gasification of coke occur simultaneously. It is well accepted that the gasification reaction controls the simultaneous reaction. Therefore, it is important to develop highly reactive carbonaceous materials. It is also known that the reaction is accelerated catalytically with the addition of some materials. In the present work, the catalytic effect of iron, nickel and CaO on the gasification of graphite and coke was examined. The catalytic effect of iron, nickel and CaO on the reaction rate of graphite was noticed The effect was larger at lower temperature. At 1373 K, the effect almost vanished. The effect was larger in the order of CaO, iron and nickel. The reaction rate of de-ashed coke increased by the addition of iron and nickel. The effect of iron was larger than that of nickel. The effect was larger at higher temperature, which was contrary to the case of graphite. The reactive surface area increased also by the addition. Therefore, the catalytic effect on reaction rate might be attributable to the increase in the reactive surface area.

Jan 1, 2006

By Hebi Yin

A coupled cellular automaton (CA) - finite element (FE) model was developed to calculate the growth of dendrites during the solidification of cubic and hexagonal metals. The model solves the conservation equations of mass, energy and solutes in order to calculate the temperature field, solute concentration and the growth morphology of dendrites, including the grain structure and the dendritic microstructure. Validation of the model was performed by comparing the simulation results with calculation results from previously published works, showing qualitatively good agreement in the dendritic morphology. Application to magnesium alloy AZ91 illustrates the difficulty of modeling dendrite growth in hexagonal systems, observed as deviations in growth direction caused by mesh-induced anisotropy. The model was applied to the simulation of small specimens with single- and multiple- equiaxed grain growths and columnar grain growth in directional solidification. The influence of cooling rate and some kinetics parameters on the grain morphology are also discussed.

Jan 1, 2009

By Jianguo Yin, Xuejiao Zhou, Xiaoyan Xiang, Wenqiang Yang, Xiaoli Yuan, Juan An, Wentang Xia

Low grade phosphorus-containing iron ore (LGPIO), a raw and wasted industrial solid material was used as an adsorbent to remove Cd(II) ion from wastewater. The effects of initial pH value, adsorptive time, initial Cd(II) ion concentration, adsorptive temperature and LGPIO dosage on the Cd(II) ion removal efficiency were studied. The results show that the Cd(II) ion removal efficiencies exceed 99.8% and Cd(II) ion concentrations are less than 0.10 mg/L under the pH value 6, temperature 20 °C, adsorptive time 90 min, initial Cd(II) ion concentration 50 mg/L, particle size <0.15 mm, adsorbent dosage 50 g/L and stirring speed 290 r/min. After Cd(II) ion removal reaction, the Cd(II) ion concentrations completely complies with the requirement of national discharge standard of water pollutants for cadmium and zinc industry (GB 20466-2010) (TCd(II) = 0.1 mg/L) in China. Therefore, it can be concluded that LGPIO is a new low-cost adsorbent which is suitable for the adsorption of Cd(II) ion from wastewater.

Mar 1, 2017

By Carlos Maurício F. Vieira, Gabriel Oliveira Glória, Maycon Sidney Gomes de Camargo, Sergio Neves Monteiro, Fábio da Costa Garcia Filho, Maria Carolina Andrade Teixeira, Frederico M. Margem

The society is increasingly the concern about the ambiental impacts, and demand for eco-friendly materials. The composites reinforced with synthetic fibers are been replaced by composites reinforced with natural fibers because of the environmental advantages. Besides the environmental advantages, those fibers have economical and properties advantages, like the low density and cost. Composites with up to 30%of PALF fibers were tested. The analyzed parameters were the loss modulus, the storage modulus and the delta tangent. The test was conducted in the temperature interval from 25 to 195 °C in a DMA equipment operating at 1 Hz of frequency under a nitrogen flow. The results showed that the incorporation of continuous and aligned PALF fibers tends to increase the viscoelastic stiffness of the epoxy matrix. Contrasting this, minor changes occurred in both the glass transition temperature and the damping capacity of the structure as measured by the tan delta peaks.

Mar 1, 2018

By Hongbo Zhao, Jun Wang, Wenqing Qin, Guanzhou Qiu, Xueduan Liu

Bio-hydrometallurgy technology was applied for the extraction of copper from the raw ores of Chambishi Mine in Zambia. A copper extraction of 93.29% was obtained for small scale column bioleaching within 63 days, while a copper extraction of 89.05% was achieved for large scale column bioleaching in 90 days, thus confirming the amenability of the raw ores for effective extraction via bioleaching. The bacteria were cultured in a 6-stage enlarge cultivation. The bacterial cultures with cell concentration of more than 1×108 cells/mL were added into a spray pond of sulfuric acid to be applied in the dump leaching, and a copper extraction of about 50% was achieved within 2 months. The production report revealed that the copper extraction increased by approximate 20%, and the acid consumption was reduced to around 35% as a consequence of adding the bacteria. The industrial demonstration of the bio-hydrometallurgy technique is now well established in Zambia, and further applications of bio-hydrometallurgy in both Zambia and Congo are currently in progress.

Jan 1, 2015

By Dachun Liu, Xuepeng Li

Smelting-acid leaching process is a way to treat high-content arsenic containing copper dust. However, smelting makes a low recovery of valuable metals and acid-leaching produces large amounts of arsenic-iron slag. Arsenic sulphuration volatilization at low temperature was studied, followed by pressure leaching to selectively recover Cu, Zn, and In from copper smelting dust while minimizing arsenic contamination.

Mar 1, 2017

By Toshiaki Akahoshi

Keywords: Wasted catalyst, Hydrodesulfurization, Ammonium vanadate, Ammonium molyb-date, Hydrometallurgical process. The fundamental reactions have been investigated in order to develop a hydrometallurgical process for recovery of molybdenum and vanadium from wasted catalysts generated in the hy-drotreating desulfurization of heavy oil. The principal steps of the process are a mild oxidation roasting of the waste catalysts at temperature around 500°C, leaching of the target metal components with dilute ammoniacal aqueous leachates, selective precipitation of vanadic acid, and ammonium molybdate precipitation. The selective recovery of vanadium as vanadic acid is successfully performed using ammonium sulfate as a salting-out agent. Recovery of ammonium molybdate is based on large dependence of solubility of ammonium molybdate in ammoniacal solutions upon temperature and ammonium salt concentration. In this process, the solution after recovery of vanadium and molybdenum is recycled to the leaching stage of the roasted materials, and the ammonium salts in the process liquor is in the repeated use. Employment of am-moniacal system makes it possible to operate the roasting at much lower temperature than that for the currently operating process.

Jan 1, 2005

By Wei Gao, Qing-cai Liu, Cun-fang Lu, Huimin Zheng, Jian Yang, Chun-ling Yao

"Mercury in flue gas of coal-fired plants was concerned as another serious pollution when sulfur dioxide pollution was controlled now. The adsorbent made from fly ash by thermal precipitation sulfur to remove mercury in fuel gas from coal combustion plant, SEM, BET, TGA and other measurement methods were used to characterize the effect on surface morphology, sulfur distribution and specific surface. High temperature deposition furnace was applied to increase sulfur content in fly ash based adsorbents produced in lab. The study found that sulfur attached to the adsorbent surface, mesopore and microporous structure, increasing its sulfur content of adsorbent. Sulfur was filled in interspace as small molecule S2, S5, increased their surface area and enhanced their adsorption capacity. The specific surface area increased by thermal precipitation sulfur, and specific surface area which increased with increasing temperature.1. IntroductionThe mercury emission caused by human activity has accounted for 10%-30% of total mercury emission all over the world[11, and the emission from coal-fired power plant have a huge proportion of these emission caused by human activity. Active carbon microstructure and surface morphology play an important role in its adsorption capability, which offers the potential for controlling environmental pollutant, such as sewage, fuel gas, atmosphere and et al [2,31, because it is a material with high specific surface area that long been considered as an excellent adsorbent. At present, include activated carbon, fly ash, calcium-based sorbents and other novel adsorbents. The adsorption capacity and production cost were very important in the process of mercury removal by adsorbents, so the mercury removal has focus on developing adsorbents of highly-efficient. In particular, the waste of metallurgical from coal combustion and the others have a significant advantage about the cost, and they have the highly-efficient in mercury removal after modified to enhance their adsorption capacity, such as fly ash of coal-fired. Apart from specific surface area, element content, pore structure, and surface morphology of activated carbon have great effect on its adsorption ability. Compared to adsorbents without modification, active carbon impregnated with other elements, such as chlorine, sulfur, bromine and et al. had more excellent characteristics to remove specific pollutants."

Jan 1, 2011

By A. Galvan

High rate compressible media filter (CMF) tests produced exceptional total suspended solids (TSS) removal at hydraulic loading rates ranging from 97.8 to 122.2 m/h. The compressible media is manufactured from a robust resin fiber that can withstand low pH and temperatures up to 149 °C. The media porosity can be varied by applying compression onto the media. At 40% compression, the CMF can remove particles greater than 4 μ. Three synthetic test-samples were generated by Hazen Research Inc., (Golden, Colorado) to simulate the copper Pregnant Leach Solution (PLS), Raffinate and Electrolyte solutions used for the testwork conducted at their facility. The preliminary results showed that the CMF was very effective in removing TSS without the use of chemical conditioning from the above test-solutions with efficiencies of 98%, 97%, and 96%, respectively. Given the remarkably high hydraulic loading rates, the industrial equipment footprint would be minimized appreciably over conventional clarification and alternative filtration systems.

By Mitsuru Tanahashi

Oxidation removal of boron from molten silicon by injecting oxygen and highly basic CaO-CaF2flux powder has been investigated with special attention to the dynamic behavior of the injected flux particles and gas bubbles. Since oxygen gas is injected into the melt, high oxygen partial pressure is maintained at the flux-O2-Si interface and the removal of boron proceeds under nonequilibrium conditions. By applying this process, boron concentration in metallurgical-grade silicon can be reduced to a single-ppm level. In this paper, the effects of the dynamic behavior of the flux particles injected into the silicon melt and the area of the reaction field (the flux-O2-Siinterface) formed in the vicinity of the flux-gas exit of the injection nozzle on the rate of the boron removal are discussed from the viewpoint of process dynamics. The experimental results clarified that the boron removal rate is affected by the kinetic energy of the flux particles which is determined by the injection conditions, such as the gas-flow rate of oxygen and the size of the flux particles. At higher oxygen gas-flow rates, the injected flux particles are expected to possess a significantly high kinetic energy such that they penetrate the O2-Si interface formed at the nozzle exit, which results in the formation of a new reaction field for boron removal. On the other hand, at lower gas-flow rates, the injected flux particles possess too low kinetic energy to penetrate the interface. In this case where the formation of the reaction field is limited, it is shown experimentally that the rate of the boron removal is constant, independently of the flux injection rate.

Jan 1, 2006