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By Nagashi Ogushi

Geochemical prospecting method using stream sediments, soils and rock chips has been tested to see the applicability for the typical Kuroko field in Japan. Three independent anomalies have been detected in maps being shown by grav densities of cells which are represented by the results of factor analysis as well as distribution of minor elements scaled in logarithm. A small vein type mineralization which has outcrops could be attributed to the origin of them whereas the one near the surface of known Kuroko deposit to a coincidence. The addition of drill core geochemistry is required to complete the interpretation.

Jan 1, 1982

By G. X. Wang

The nonliving dried water hyacinth (E. crassipes (Mart.) Solms) roots were investigated for biosorption of cadmium and lead and other heavy metal ions in aqueous solutions. Dried water hyacinth roots, when suspended in solution, strongly and rapidly sorb several different metal ions. Factors such as reaction time, pH, initial concentration of metal ions, presence of other metal ions and biomass concentration were investigated. Metal ions, including Cd2+ and Pb2+, were bound to the root in a very pH-dependent manner, with the binding increasing after about pH 3. High levels of removal were obtained. The adsorption was shown to follow the generalized Langmuir adsorption equation. The relative affinity of the roots for lead is greater than for cadmium. The maximum sorptions of the roots were about 33 and 86 mg/g for cadmium and lead, respectively. Only 15-20 minutes were required for the process of uptake onto the biomass to occur. The batch sorption kinetics of the uptake of cadmium and lead can be described by an apparent first-order reversible reaction model. The roots could be regenerated after the metal ions were stripped. A solution of CaCl2 in acidic medium appeared to be the best eluant for desorbing the sequestered Cd and Pb completely at pH 3. The kinetics of the metal stripping process was quite rapid. Successful desorption of Cd and Pb from the biomass by acidic CaCl2 solutions revealed that the metal uptake phenomenon is reversible, implying physical sorption of Cd and Pb.

Jan 1, 1997

By David H. Dahlem

Uranium is a very mobile element geochemically and is widely dispersed in the lithosphere and hydrosphere. Under oxidizing conditions, it is particularly widespread and appears in all parts of the surface hydrologic system. As a result, this system is a leading candidate in uranium-resource assessments as a new base from which total resources might be estimated. No other sampling system provides the large volume geochemical capture as the continental hydrosphere and is as pervasive and non-selective regardless of rock type. However, the water system as a uranium metal sampler is not without drawbacks as the development of a National sampling program based on it has shown, In spring 1973, the National Uranium Resource Evaluation (NURE) was announced by the U. S. Atomic Energy Commission (AEC). The program was conceived to provide an evaluation of the domestic uranium resources and to identify areas favorable for uranium exploration. The specific NURE objectives are as follows (Bowyer, 1974): 1. To provide a preliminary evaluation of domestic resources and favorable exploration areas by early 1976, based on existing data. 2. To conduct a comprehensive evaluation of domestic resources and favorable areas by 1980, based on advanced state-of-the-art information. 3. To conduct an R&D program into new and improved procedures, equipment, and technology for uranium exploration and assessment. 4. To disseminate information on new exploration concepts and technology.

Jan 1, 1976

By Bo Arvidson

SALA MAGNETICS, INC. is now operating a 15 tph continuous high gradient magnetic separator, the SALA-HGMS® Mark III Carousel, as part of a complete mineral processing pilot plant installed at Sala's Cambridge headquarters. The Mark III can generate a maximum magnetic field of 18 kG making it possible to process even weakly magnetic, finely ground ores and ore tailings on a continuous basis at the performance level achieved in Sala's cyclic high gradient magnetic separators. Test results on iron ores, clay, and decoppering of molybdenum concentrate will be discussed. Bench scale tests have been performed on all of these materials using the SALA-HGMS® Model 10-15-20 Cyclic Magnetic Separator. A direct correlation may be made between cyclic and carousel results. Sala's Mark III Carousel high gradient magnetic separator is designed to permit scale-up to machines capable of processing two hundred (200) tons of ore per hour and more.

Jan 1, 1976

By Richard C. Travis, Edward C. Dowling

A detailed kinetic study of the flotation installation at the Metcalf Concentrator revealed a rougher flotation circuit operating under less than optimal conditions. Based on these results, a project was initiated to approximately double the rougher flotation capacity by increasing the installed volume from 780 cubic meters to 1,560 cubic meters. This project, which was completed in early 1991, replaced the existing cells with larger capacity cells. A comprehensive analysis of results demonstrates significant metallurgical benefits. INTRODUCTION/BACKGROUND The Metcalf Concentrator is located in Morenci, Arizona and is part of Phelps Dodge Morenci, Incorporated. Sumitomo Metal Mining of Arizona is a minority partner in the operation with 15% interest. The Metcalf Concentrator is the newer and smaller concentrator and operates in conjunction with the Morenci Concentrator. Operating capacity at Metcalf is currently 48,000 TPD of ore on a 365 days per year basis. The Metcalf Concentrator was commissioned in 1974 at a 30,000 TPD operating rate for the purpose of treating ores originating in the Metcalf Mine. The mine takes its name from the former town of Metcalf which was named for Robert Metcalf who was credited with discovery of the mineral district. The predominant ore mineral is chalcocite which occurs as a secondary enrichment closely associated with iron pyrite. The host rock is largely granodiorite and quartz monzonite. The original rougher flotation circuit consisted of a total of six rows of Wemco 8.5 cu. meter (300 cu.ft.) flotation machines treating pulp from the two grinding sections (Sections A and B). Each row was configured in a 4-4-4 arrangement. Shortly after startup the throughput rate was increased significantly without sustaining a recovery loss. This increase was achieved by raising the target value for the particle size of the cyclone overflow which is the rougher flotation feed. Shortly thereafter, the capacity of the pump and cyclone began to restrict further increases in throughput. After testing, two 66 cm. (26-in.) cyclones and a 12-in. X 12-in. centrifugal pump replaced the original classification equipment. As a result of these modifications, the grinding section could routinely process in excess of 42,000 TPD. Due to the increased tonnage rates, limitations in the rougher flotation circuit performance were observed. In an effort to improve the performance of rougher flotation with this higher throughput, the speed of the flotation mechanisms was increased from 230 RPM to 250 RPM. This change improved the suspension of the coarser feed and induced additional air into the pulp. It did, however, apply additional strain to the motors, shortening their life. At these elevated processing rates, it was found that the dart valves operated almost entirely at the top end of the control range and could not efficiently handle upsets from the grinding section. This was remedied by lowering the end overflow weir and allowing some of the tailings to overflow the end weir. However, in order to obtain acceptable recovery levels, the flotation pulp was maintained at a high level, adversely influencing the rougher concentrate grade.

Jan 1, 1993

By Harold L. Lovell

The current interest in sulfur recovery from coal measures is indicated by a recent report prepared for the Public Health Service (1) It was noted that the concentration of pyrites to a product containing 42-48 percent sulfur should be relatively easy with present equipment. It was also pointed out that a utility potential exists for the high-grade iron concentrate which results as a by-product of the consumption of pyrites in the acid-making process. However, economics, marketing characteristics, location, transportation, pyrite levels and coal characteristics all strongly influence the feasibility of fostering industrial development of such processes. The extent of pyrite recovery and product quality is intimately related to pyrite particle size and its degree of liberation, a consideration usually given greater emphasis in metal ore preparation than in processing coals. Consequently, fine crushing to nearly 20 mesh probably will be essential for maximum practical processing. It appears that any process separating pyrites from a coal must involve a reprocessing of the normal preparation plant refuse, although some yields can be attained from certain existing operations as products from, a shaking table or a jig. Further, the existence of millions of tons of coal refuse cannot be ignored as a mined source of raw materials. The recovery of saleable products from such wastes, although untried on a large scale under current conditions, not only offers a realistic source of sulfur but also would achieve a secondary refuse with the minimal contents of substances which incite and propagate the burning of organic and inorganic combustibles. These silicate materials, thus beneficiated, also offer some potential for economic utilization. Some significant tonnages of pyrites have been produced from coal measures in the past, but the experience was, in general, not consistent with current coal preparation practice. The processes involved did not include cyclones and heavy media; nor were they carries out under the sociological environment concerned with pollution as exists today.

Jan 1, 1967

By William A. Rehrig

During recent years, there have been frequent investigations on the geochemistry of biotite. This work has emphasized, and no doubt was prompted by, factors related to mineral exploration, particularly for those deposits of the porphyry copper type. A large number of papers have been devoted to the obtainment of trace-element data from plutonic biotite. These data have been used to extract primary geochemical information pertaining to the parent magna and the hydro-thermal system which together give rise to porphyry copper deposits. In two early works, Putman and Burnham (1963) and Parry and Nackowski (1963) analyzed base metal contents of ferromagnesium minerals, primarily biotite, from various barrenfmineralized plutons of the Basin and Range Province. One similar conclusion from the two studies was that the Cu, Zn, and Pb contents of magmatic biotite served as indicators of ore development within the granitic rocks genetically related to ore. This theme was then pursued vigorously by a number of authors until the present time. Results, however, have been contradictory, as reviewed by Coope (1974). For example, studies by A1 Hashimi and Brownlow (1970), Lovering et a1 (1970), Putman (1972), and Graybeal (1973) continued to support positive primary relationships between the trace-metal content (usually copper) of biotite and associated sulfide mineralization. By studying biotite in close spatial association will sulfide occurrences, Putman (1972) and Graybeal (1973) developed models for base metal partitioning in magmatic systems based on their discovery of inversely distributed copper between silicate (biotite) and sulfide phases. Conversely, research by Bradshaw (1967) and Blaxland (1971) plus the recent findings of Parry and Jacobs (1975) and Kesler et a1 (1975) found little if any evidence to support a correlation of biotite base-metal or

Jan 1, 1976

By Bronson Stringham

The close area! relationship of Cretaceous or later intrusive porphyries to larger hydrothermal deposits of Pb, Zn, Au, fig, Cu, Mo, Hg,, and U of similar age in the Basin Range Province, was statistically shown in a recent paper (Stringham1) During the past year this study has been expanded to cover p11 of the larger hydrothermal deposits of similar nature occurring in the entire western United States. The sandstone type uranium deposits of the Colorado Plateau and Wyoming have been excluded since considerable controversy exists regarding their origin. The close relationship between intrusives in general and hydrothermal ore deposits has long been-recognized, but the association involving intrusive porphyry only, was suggested in 1954 when Sales concluded that the formation of porphyry may be an intermediate stage of activity between the development of granitoid rock and certain types of copper deposits. However: he applied this concept to only a few copper deposits. The relationship appears to be true also for a great majority of the hydrothermal deposits of the other metals mentioned above of Cretaceous and later age, at least in the western United States. This situation then leads to the conclusion then when exploring for similar types of hydrothermal deposits of the metals considered one may feel reasonably sure that if an intrusive porphyry of considerable size is. not present he may be facing much greater risk of finding an ore body than if a prophyry were presents Since, there are many intrusive porphyritic rocks which do not seem to be associated with hydrothermal deposit, it is believed that some distinct value can come from the recognition of intrusive porphyry which might be barren as well as the intrusive prophyry which might be productive This paper deals with that problem.

Jan 1, 1960

By J. Harrison Daniel

More stringent dust standards, because of quartz in coal, have become a major compliance problem for the coal industry. Reducing quartz levels has become the major focus of the Bureau of Mines dust control research program. Results to date have identified hath the sources of quartz and prospective control technology. Control techniques are being developed for both room-and-pillar and longwall mining underground operations. Techniques include changes in face ventilation, mining cycle modifications, and better roof bolting dust control.

Jan 1, 1985

By Bruce D. Hanson

A computer model capable of simulating the basic production system in a variety of underground mining methods has been developed at the Twin Cities Mining Research Center. This Bureau of Mines paper describes the simulation of the basic production system at the working face, which includes drilling, blasting, mucking, and roof bolting. The model is event-oriented; that is, the status of the system is updated at the occurrence of an event. All event or activity times, including failure and repair of equipment, are treated as stochastic variables. A location dimension, in addition to the time dimension, is used, allowing the simulation of multiple location systems. To aid the user in determining the efficiency of his system, the model provides several reports. An event or activity report gives the frequency of occurrence total active time, and cumulative delay statistics for each event. An equipment report delineates the availability and utilization of all equipment. A production report provides information on various performance measures such as tons produced and holes drilled. The cost report gives the cost of various elements in the system. Operating data from an actual mining situation were used in validating the model. In addition to the description of the model, examples of simulation experiments which were performed on a room-and-pillar mine system are given. Use of the model to determine methods for improving the efficiency of the system is discussed.

Jan 1, 1974

By A. K. Sinha

Ever since electricity was introduced, electrical injuries and electrocutions have continued to occur regularly in coal mines. An analysis of the two hundred cases of electrocutions which occurred during 1956 to 1970 indicated that over 50 percent of the incidents were caused by the ineffectiveness or lack of electrical grounding. Research shows that various types of arbitrarily designed ground beds are in use and that the ground resistance and current are often very high and subject to wide seasonal variations. The results of a recent research are discussed in this paper.

Jan 1, 1980

By W. J. Turbeville

The subject of this discussion is timely. The U.S. phosphate industry is suffering the throes of depression. It's plight is a matter of widespread concern. The future role of the U.S. industry in world markets is of particular interest. If we should prognosticate phosphate supply-demand on the basis of recent history, we would face a puzzling choice of scenario. In 1980, perhaps the best year ever for U.S. phosphate, 54.6 million metric tons of phosphate rock entered the market place. Of this, more than half was exported -- divided almost equally - as rock or phosphate fertilizer. During the last half of 1981 the situation had begun to change.

Jan 1, 1983

By Donald C. Violetta

During 1963 more than 200 million tons of coal was consumed by the public utility industry. Ash residual, from the burning of this coal has caused disposal problems. In order to prevent air pollution, dust collection systems have been installed to suppress the fine ash emitted from boilers before it is discharged into the atmosphere. The collected ash, called fly ash, must be removed from the dust collection facilities and disposed in some manner, usually at a substantial cost to the utility. Many years ago fly ash disposal was not a serious problem because the demand for power was relatively low and coarse coal was burned on stoker type traveling grate machines. The low burning rates utilized on these grates did not produce large quantities of air-borne coal ash while the mechanics of this system of burning resulted in a clinkered residue of cinders. Both of these conditions resulted in the production of only small quantities of fly ash. As the demand for electricity increased, a method of burning pulverized coal was developed and was introduced to the public utility industry in 1918 at Milwaukee, Wisconsin.1 This method of firing was considered a significant advance in steam electric generation as it (1) permitted the use of coals that could not be economically fired by other methods and (2) has generally resulted in improved efficiency, greater generating capacity and lower costs.2 The utilization of larger generating units using pulverized coal substantially increased the quantity of fly ash which resulted in a' more severe disposal problem.

Jan 1, 1966

By Howard N. Egan

EASTERN COAL CORPORATION is located in the heart of the Appalachian Mountain area of extreme Eastern Kentucky, The mountains are of sedimentary origin, and have been deeply eroded by streams as the area has been thrust up during geologic time. There are many seams of coal interspersed between beds of shale and sandstone. While some of the seams are thin, there are a number that can be economically mined. We are mining the Pond Creek, or No. 2 Gas Seam, at a rate in excess of 6,000 tons per day. Our central preparation plant utilizes tromp baths for the plus 3/8" size and Rheolaveur for the minus 3/8" portion. No provision was made to recover the fine coal, which was included with the plant effluent pumped to a 12 acre refuse pond. The pond is impounded behind the coarse refuse dump. This pond rose 15 feet last year. Obviously, no pond could stand many years at this rate. Limited pond space in this rugged area of steep hills and narrow valleys dictated a revised disposal method. Our first thought was that it would be necessary to dry the fine refuse sufficiently to permit inclusion with the coarse refuse, which is hauled uphill by monitor and then trucked to final disposal.

Jan 1, 1967

By Edwin B. Wilson

Electric power generation remains the greatest market for coal in the United States. In 1967, about 272 million tons of coal, amounting to over 51 percent of total coal consumption, were burned to satisfy this nation's hugh demand for power. The size of the utility market is currently five times that of 1941 and continues to grow with the demand for more and more energy. A major reason for this strong market has been the ability of the coal industry to supply a superior product for combustion while maintaining competitive prices. Now that the coal industry is engaged in intensive competition with nuclear power for future energy demand, it becomes ever more imperative that superior coal products are produced. One important problem when burning some coals is a liquid phase corrosive attack on boiler tube metal in the superheater and reheater areas of the furnace where steam temperatures may exceed 1050°F.

Jan 1, 1969

By Charles Banks Belt

In 1925, Niggli (1925, pp, 1-69), formulated a physico-chemical, explanation for the origin of hydrothermal ore deposits, from a concept that had appeared earlier in the literature in the writings of Von Groddeck, Stelzner, Beck, de Launay, Kemp, and Lindgren. Niggli proposed that pressure at depth could force volatiles from deep-seated magmas. The volatiles would In turn form pegmatites and then ore deposits as the fluids cooled. This is one view of a general theory of ore genesis that gained secondancy for years among such prominent geologists as Fenner (1926, p, 697) and Emmons (1936, pp. 29-70). It was, proposed that ore deposits were precipitated from solutions or fluids that had escaped or been separated from a deep-seated magma by means of liquid immiscibility or crystallization or gas transfer. This theory is based on the presence of igneous rocks close in space and age to hydrothermal ore deposits in many mining districts of the world. As is well known, there are many ore deposits apparently of hydrothermal origin that are neither spatially nor chronologically related to igneous rocks, In still other localities where there are no hydrothermal ore deposits, igneous rocks occur that are similar in composition to those in mining districts. In view of such facts, the applicability of the Niggli theory to all hydrothermal ore deposits may well be questioned. The chief purpose of this paper is to test the Niggli theory by studying the primary petrology, hydrothermal alteration, and distribution of copper and zinc in silicic igneous plutons supposedly genetically related (in the Niggli sense) to nearby hydrothermal ore deposits, Silicic Tertiary plutons in three New Mexico mining districts were chosen, the Hanover-Fierro intrusive at Hanover and Fierro, the Granite Mountain pluton at Magdalena, and the four outliers of the Lordsburg stock at Lordsburg. First, it had to be established whether the observed plutons were or were not the source of the adjacent ore deposits. This was done by studying the relation between the copper or zinc distribution-and the primary or secondary features in the plutons studied, and the time relations between instrusion and ore deposition. Primary igneous features of a pluton are defined as the minerals, texture, shape, and character of the pluton which were formed prior to the complete solidification of the rock, secondary features include all changes that took place in a pluton after solidification. They are identified by their cross cutting nature or as replacing primary minerals, Under the Niggli concept, it is proved that the ore ions did not originate from the parts of the pluton now visible as immediately adjacent to the ore deposits; it must then be established, if possible', that the ore ions were separated from deeper parts of the intrusive, Some idea as to whether the copper or zinc ions originated from a related magma at depth may be gained by a comparison between the primary (that is, pre-alteration) zinc and copper abundances found in ore localizing intrusive studied and the average abundances for copper and zinc in silicic igneous rocks most recently given in the literature. Finally, the relation between ore deposition and hydrothermal alteration was studied on a regional as well as on a local scale.

Jan 1, 1958

By Albert W. Deurbrouck

The coal reserves in the United States are estimated to be in excess of 300 billion recoverable tons, and current projections of energy requirements indicate our increased dependence upon these reserves. The Department of Energy's Energy Outlook for 1984 projects that coal consumption in the United States will increase from 737 million tons in 1983 to 958 million tons in 1990, and then to 1,110 million tons in 1995 (Table 1). As shown in this table, the future utilization of coal in the United States is closely tied to the electric utility market, a market that consumes about 85% of the coal produced. Be- cause of this dependence on the utility market, the uncertainties of new environmental regulations, particularly those concerning sulfur emissions, could have a significant adverse impact on future coal demands in the United States. SULFUR IN U.S. COALS Most of the Nation's coal reserves contain too much sulfur to be fired directly and meet existing emission control standards. In Table 2, the sulfur contents of the coals of the eastern United States are summarized by sulfur levels according to regions. While the coals of some of the eastern regions are predominantly high in sulfur content, it is important to recognize that large tonnages of coal with relatively lower sulfur content are available in these regions. Furthermore, an often significant portion of the sulfur occurs in the form of iron sulfide (Fes2 or pyrite). Because pyrite occurs as discrete particles of high specific gravity, it can often be removed by simple, inexpensive physical coal beneficiation techniques after being liberated by stage crushing. The potential for physical removal of pyrite by conventional specific gravity processes combined with stage crushing is summarized in Table 3 on a regional basis.

Jan 1, 1986

By James E. Lawver

Response surface methodology is a well-known and powerful technique for determining optimum conditions in flotation systems. One disadvantage is the onerous task of the numerical calculations and curve platting. This paper describes a system in which the investigator simply selects the range of several flotation variables after which the design of the experiment, data analysis, generation of response surface equations, and response surface plats are automatically carried out using a digital computer and a computer-driven curve plotter. Several typical response surfaces of important variables in phosphate flotation are presented as examples. An overview of the flow charting of the system is provided in the addendum.

Jan 1, 1978

By G. R. Goldak

All of Canada's older uranium mining areas have been intensively prospected and known outcrops have been repeatedly examined. The only ground in these areas which has not been explored is that which is covered by water or other overburden. The discovery of new mines in these areas will, in the author's opinion, depend on the development of new geophysical or geochemical tools capable of locating uranium deposits which are-buried beneath tens to hundred of feet of overburden. Such tools would be extremely useful in Saskatchewan's Cluff Lake and Wollaston Lake areas. Uranium has recently been discovered in significant quantities in these regions but exploration is made extremely difficult and expensive by an almost uniform overburden cover. The author's experience has been confined to Canada but apparently a subsurface uranium prospecting method could be widely exployed in the western United States and Australia as well. Radon-222 measurements have been used for more than a decade on practically a worldwide basis in an attempt to obtain a useful method for subsurface uranium prospecting. It is well known that ha-222 produced by buried uranium deposits can diffuse through an overburden cover so that it can sometimes be detected at surface. An advantage of this method of prospecting is that Rn-222 can be detected with a simple scintillation, ionization or semiconductor detector. One of the essential weaknesses of the method is that the mean diffusion path length of Rn-222 is limited by its very short (3.8 days) half life. For a deeply buried deposit, vitually all of the Rn-222 atoms will decay before reaching surface and, therefore, such deposits cannot be expected to produce a detectable radon anomaly. Thus, except in unusual cases where groundwater or ground air flow assists the movement of radon towards surface, the depth of exploration is probably limited to ten or twenty feet of overburden cover. The high solubility of Rn-222 in water is also a source of difficulty. In an area where overburden covers bedrock with water saturation of the lower overburden levels, the radon will simply dissolve in the groundwater, and soil gas readings at surface will indicate falsely low

Jan 1, 1974

By Daniel A. Wasson

A review of the history of boosters is given with examples of the prominent types that have been made commercially. The performance and design features of protected core boosters are discussed in detail. A new gel booster is discussed with its advantages to the mining industry. Booster size, hole configuration, performance and safety aspects are reviewed. Important features of boostering in above ground and underground blasting are related to an economic analysis. This presentation will cover different types of boosters commonly used in mining. However, for the purpose of this paper a few terms need to be defined to clarify the action of different parts of a priming system. Booster* - "Any unit of explosive or blasting agent to be used in a charged hole for the purpose of perpetuating or intensifying the initial detonation". Primer* - "A unit, package or cartridge' of explosives containing a detonator or detonating cord which is used to transmit detonation to other explosives or blasting agents". Detonator - A device for initiating a detonation from a flame or a small electric current, the former being represented by a fuse cap and the latter an electric blasting cap.

Jan 1, 1981