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By DING TANG, JINGHE CHEN, Shuiping Zhong, CHEN KUANG

The Zijinshan gold-copper mine, located in Shanghang County, China, is a porphyry-type, low-grade ore deposit with a geological profile of upper gold and lower copper. Despite its low-grade nature, it has become one of the largest in production scale and most profitable nonferrous metal mines in China, which can be attributed to the successful application of hydrometallurgy as well as proper engineering design. A large-scale, open-air cyanide heap leach has been successfully implemented to recover gold under the humid and rainy weather conditions of southern China. Furthermore, according to the gold ore characteristics, a combination of gravity separation, carbon-in-leach and heap leaching processes was developed to improve gold recovery. In terms of copper extraction, copper ore of a grade higher than 0.25 percent is fed to the flotation plants to produce copper concentrate (gold is also enriched here), while copper ore of a grade lower than 0.25 percent undergoes heap bioleaching followed by solvent extraction and electrowinning to produce cathode copper. Additionally, a unique bioleaching system has been established at the Zijinshan Mine: low operating pH (0.8~1.0), high concentration of total soluble iron (~50 g/L), high temperatures (45~60 °C) and low activity of microorganism (~104/mL) in the pregnant leach solution (PLS). This review paper summarizes the practical experience acquired in developing the Zijinshan gold-copper mine and could be of use in other gold and/or copper plants.

By R. G. Church

Belle Ayr Mine was established in 1972 as the first large surface coal mine in the Powder River Basin of Wyoming. During the mid-1980s, it was eventually out-distanced in productivity by newer mines, and management recognized that the mine must recapitalize its major mining equipment and enhance its workforce flexibility in order to be competitive in the deteriorating market situation. Therefore, state-of-the-art haulage and loading equipment was placed into service, and a 12-hour rotating shift and a technician-based workforce was implemented. Belle Ayr Mine is located 29 km (18 miles) southeast of Gillette, Wyoming, in Campbell County (Figure 1). The mine is a part of AMAX Coal West, Inc., and with its sister mine, Eagle Butte, located 8 km (5 miles) north of Gillette, is a major contributor to the overall coal production of AMAX Coal Industries, Inc., headquartered in Houston, Texas. This paper addresses mine planning, recapitalization initiatives, and innovative workforce changes which propelled this large, surface coal mine to the forefront of productivity in the ever tightening low sulphur coal market.

Jan 1, 1994

By David Newman

"Horizontal stress can have a profound effect on the stability of an underground limestone mine. The presence of horizontal stress is usually determined once the mine has been developed and the orientation of headers and crosscuts are well established. Multiple attempts are typically made to control roof falls without re-orienting the mine. Once the decision has been made to change the orientation, pillar centers, mine opening widths, and the question of how to determine the correct orientation must be answered.A case history is presented to illustrate how geologic structure, ground conditions and roof falls in adjacent mines, the World Stress Map (Heidbach et al., 2016), in-mine measurement of “cutter” roof orientation, the orientation of strata offset (cats eyes) within borescope holes, and the diametral deviation method of determining horizontal strain from drill core were used to establish the most likely range of horizontal stress.The main headers were re-orientated in a direction parallel to the median of the range of horizontal stress. The crosscuts were angled 60° to the headers to avoid being perpendicular to the horizontal stress direction. Pillar centers and opening widths were increased in the favorable stress direction of the mains and decreased in the less favorable crosscut orientation. The major principal horizontal stress magnitude was estimated using the strain measurements from the diametral deviation method and elastic modulus obtained through testing.INTRODUCTIONOver the past decade, there has been a significant increase in the number of underground stone mining operations in the United States. As stripping ratios at surface quarries become uneconomical and reach the extent of the mineral boundary, coupled with the encroachment of urban development on previously rural mining operations, the remaining mine reserves are best accessed through underground development.Although the majority of underground limestone mines in the Midwest are in relatively flat lying deposits with minimal geologic structure, many Appalachian mines are in folded and faulted environments. Tectonic horizontal stresses associated with multiple orogenic episodes are locked in the formation and are released as the underground mine is developed.A common misconception is that horizontal stress impacts are more prevalent at shallow depths where the ratio of horizontal to vertical stress may be high. However, field observations and academic research indicates that horizontal stress conditions may be encountered at any depth due to the tectonic compression of the limestone formation (Esterhuizen et al., 2007; Dolinar and Esterhuizen, 2007; Iannacchione et al., 2003; Slaker, Murphy, and Miller, 2017; Kuhnhein and Ramer, 2004). This paper outlines mine design and layout guidelines for the mitigation of horizontal stress impacts on underground stone mining operations through a case history example. This approach to mine planning and the ability to anticipate horizontal stress can significantly improve future production of multiple levels (Newman and Newman, 2019). As underground stone production continues at deeper depths and in more geologically and geometrically complex mining conditions, an emphasis on ground control and the anticipation of horizontal stress can provide safer and more productive single and multiple level mining operations."

Jan 1, 2019

By Shankar Kumar, Arvind Kumar Mishra, Chitranjan Prasad Singh

Formulating a predictive model for blast-induced ground vibration (BIGV) has always been challenging due to the complex non-linear relationship between the BIGV and its influencing factors. Researchers have used empirical, artificial intelligence methods and numerical modelling methods to predict BIGV. In a dragline bench blasting, a massive quantity of explosives is used compared to other loading machinery, and the height of the bench depends on the size of the dragline. For effective utilization of explosives energy, decking is used to reduce the hazardous effects of blasting. In this paper, an attempt has been made for effective prediction of BIGV, and its mitigation on dragline bench blasting considering a deck length, stiffness ratio, hole spacing to burden ratio, hole depth to burden ratio, the distance of monitoring PPV from blasting site, Schmidt hammer rebound number of the bench to be blasted, and maximum charge per hole to total charge per blast. So artificial neural network (ANN) model and random forest (RF) model have been developed considering the parameters mentioned above. For the statistical performance of the predictive model, the coefficient of determination (R2) value is 0.8895, MSE is 22.84 for the ANN model, and the random forest (RF) model whose R2 is 0.8165 and MSE is 27.18. The sensitivity analysis results show that stiffness ratio, deck length, and Schmidt hammer rebound number are more influential parameters out of the selected parameters. The reduction of ground vibration with the introduction of decking led to a 3 to 15% reduction in ground vibration.

May 15, 2024

By Justin Reed, Sara Bewley, Dwight M. Kinnes, Maryam Sadeghi, Ed Hart

This study compares wet gravity and dry magnetic separation for preconcentrating an allanite-rich rare earth ore from the Halleck Creek deposit. Material in the –300/+86 μm size range was treated to define a flowsheet that maximizes total rare earth oxide (TREO) recovery. The ore is dominated by feldspar and quartz, with hastingsite, an iron-bearing aluminosilicate. Because hastingsite’s density and magnetic response closely match allanite, it is difficult to reject using conventional methods. Two separation approaches were evaluated: MG12 spirals for gravity concentration and an Induced Roll Magnetic Separator (IRMS) for dry magnetic upgrading. MG12 spirals performed well in the rougher stage but provided limited gains when used as cleaners. When IRMS was applied as the cleaner stage, TREO grade and recovery improved substantially, showing that a dry magnetic cleaner circuit can effectively replace the wet gravity cleaner step. MG12 spirals remain suitable for highcapacity rougher duty, but dry magnetic separation delivers higher selectivity, simpler operation, and eliminates water use—offering a more efficient and sustainable preconcentration route in water-constrained environments.

Feb 22, 2026

By M. A. Trevits

Methane gas is an ever-present problem facing the underground coal mining industry. Mine operators are mandated by law to maintain safe concentrations of methane gas within the mine environment. Ventilation is used by all mine operators to reduce gas concentrations. When gas emissions are such that ventilation alone cannot control the gas, methane drainage methods must be applied. In the 1970's, there was a concern that unprecedented gas emissions would be experienced as mine operators began new developments in the deep and gassy Blue Creek and Pocahontas No. 3 Coalbeds. Such concern was well founded as significant gas volumes are being emitted as these mining operations mature. In 1971, the O.S. Bureau of Mines began to tabulate and track the change in mine emissions. These data were extracted from the underground coal mine quarterly air quality-quantity inspections performed by the Mine Safety and Health Administration. At that time, approximately 6,560 Mm Id (231.7 MMcfd) of gas were emitted from 430 underground coal mines. It was determined however, that the mines emitting less than 2,832 m Id (100 Mcfd) contributed only 2.1 percent of the total daily gas flow. In 1988, underground coal mines emitted 8350 Mm Id (294.9 MMcfd) from 487 mines. This report evaluates the changing nature of U.S. mine gas emissions over the last 18 years.

Jan 1, 1993

By Jürg Künzle

Underground construction is a matter of dealing with the inherent uncertainty of subsurface geology. If the encountered conditions are less favorable than the expected ones, the execution of excavation, support, ground treatment or lining works is likely to require more or different efforts than anticipated, thereby delaying the works and increasing the costs. The 2019 first edition of the FIDIC Emerald Book model contract (FEB) addresses many of the issues to which underground works give rise, including those related to differing site conditions (DSC). This paper examines how under the FEB disputes arising from or in connection with DSC could or should be avoided.

Jun 13, 2021

By Joshua Cole, Joshua Sovechles, Christian Cardoso, Guillermo Bermudez, Martta Hirsi, Joshua Dettamanti, Rabia Abbasi

The implementation of technological advancements in flotation is key to optimize performance in mining operations. Consequently, flotation cell’s performance is highly dependent on the effectiveness of the mixing mechanism. A more efficient flotation mixing mechanism is likely to improve metallurgical performance and optimize energy consumption, which is the motivation for Metso’s journey to develop the latest iteration of FloatForce®. Looking to test the new design at plant scale, Metso approached the Kennecott Copperton concentrator, which is continuously looking for different venues to improve metallurgical performance. In this context, a test campaign was conducted to implement this new flotation mixing mechanism in their rougher circuit during 2024. The industrial trial consisted of several sampling campaigns assessing different operational parameters for comparison purposes around a 300m3 flotation cell. The effect of the new flotation mixing mechanism on the cell’s power draw was also studied. The results of this trial at Kennecott are presented in this paper. Overall new flotation mixing mechanism, FloatForce+ was seen to perform as well as the original FloatForce.

Feb 1, 2025

By Ron Allum, Ed VanDerPas

The application of high speed tunneling in a deep underground copper mine is essential for an ambitious expansion project at Magma Copper Company's San Manuel Mine. At stake is the future of over 1,300 employees at the largest producing full gravity block caving copper mine in the world. A joint venture of Frontier-Kemper Constructor's Inc. and Deilmann Haniel GmbH is helping create that future through the successful application of tunnel boring technology. This paper examines the details required to assemble, deploy and operate a 4.62 m open main beam tunnel boring machine (TBM) in a 1048 m deep operating mine accessible only by shaft.

Jan 1, 1995

By F. Wendling, J. A. M. Cano

To increase its product competitiveness in the foreign market, Samarco Mineracão S/A has developed, at its pilot plant, high-MgO pellets for performing direct reduction simulation tests. Additives, such as dolomitic lime and magnesite, were used for increasing the pellet MgO content. Comparative direct-reduction simulation tests were conducted in Samarco and foreign laboratories. The results show that direct-reduction pellets with satisfactory metallurgical properties can be produced and successfully processed at increased temperatures in direct reduction furnaces.

Jan 1, 1994

By David J. Hatem

Tunnels and underground projects are inherently more risky than vertical projects, which typically utilize more conventional design and construction approaches and are undertaken in the context of relatively ascertained and defined conditions. On tunnel and under-ground projects, there are a host of special risk factors, including unknowns and uncertainties as to the physical and behavioral characteristics of the ground, the inextricable interdependence and necessary interaction of design decisions and construction means and methods with those ground conditions as well as the manner in which risks are allocated among project participants for un-anticipated subsurface conditions. Public-private partnerships (PPP) projects, in their own respects (and independent of any major subsurface component), pose significant risk for all private sector participants. The main driver of owners to procure projects using PPP is financial, as often all, or substantially all, of the design and construction risk are transferred to the private sector consortium, including the design-build (D-B) team. For a concerning number of those public owners, that risk transfer regime includes rather onerous and aggressive contractual terms that allocate to the private sector participants substantially all risks associated with the encountering of unanticipated subsurface conditions. These aggressive risk allocation provisions, while directly impacting project participants upstream of the consulting engineer, have an indirect and corresponding risk intensifying effect upon consulting engineer professional liability exposure. There are many factors that result in increased professional liability exposure for consulting engineers involved in PPP projects. The more prominent and prevalent of those factors fall into the following categories:

By Raja V. Ramani

Worldwide, promulgation and enforcement of health and safety laws and regulations have been the primary means of ensuring minimum and uniform standards of health and safety in the mining industry. In U.S. coal mines, a new era was ushered-in in 1969 for the control of health hazards from respirable coal mine dust. Since then significant progress has been made on all aspects of the respirable dust problem-its definition, monitoring, reduction, and control. In the intervening years, our ability to monitor, analyze, and characterize the mine atmospheric environment and the health of miners has increased many fold. Also, advancements in production technology have far outdistanced enhancements in environmental control technology. Therefore, questions are continuing to be raised on the adequacy of the characterization and control measures with regard to both the airborne respirable dust in mines and the health effects of respirable dust. Late in 1995, the Secretary of Labor appointed an Advisory Committee on the Elimination of Pneumoconiosis Amona Coal " Mine Workers (Dust Advisory Committee) to review the progress towards elimination of coal worker's pneumoconiosis (CWP) and silicosis, and in the program to control respirable coal mine dust in underground and surface mines, and make recommendations including improved standards and other appropriate measures for the control of exposure to airborne coal mine dust. The Committee's report was released in October, 1996. In this paper, a summary of the recommendations of the Committee is presented. A brief discussion of the background, and the issues and findings leading to the recommendations is also presented. The Committee concluded that the progress made towards making mines safer from the health hazards of respirable coal mine dust is substantial but that it is not sufficient to achieve the intent of the 1969 Coal Act. The Committee's recommendations encompass a wide range of issues addressing permissible exposure limits (PELS), sampling, dust control plans, hazard and medical surveillances, role of miners, training, and research and development.

Jan 1, 1997

By John W. Stevenson

At the No. 4 Mine of Jim Walter Resources in Tuscaloosa County in the North Central part of the State of Alabama, the Mary Lee and Blue Creek coal beds lay 2000 feet below the surface. The quantity of methane gas stored within the coal bed reservoir at this depth and released during development mining necessitates that each coal producing section be ventilated using large air quantities approaching 100,000 cfm. In order to meet coal contractural commitments in the early stages of mine development by installing the necessary number of continuous mining machine units and to develop the mine to projected air shaft sites, high pressure, large volume mine ventilating fans were required. This presentation discusses the installation start-up and changeover procedures when two size GAF 31.5-28-1 TLT-Babcock 3500 Horsepower fans with adjustable pitch in flight blades were put on line while phasing out two Jeffrey Mining Machine Company 8HUA 117 Fans. A graph will be presented to depict the most economic diameter shaft size under 2000 feet of cover with different air quantity requirements.

Jan 1, 1982

By H. R. Hernandez-Guerrero, S. A. Robles-Salazar, M. Marín-Pasillas, P. J. Pompilla-Rosales

Peña Colorada is a company dedicated to the exploration, exploitation, and beneficiation of iron ore, serving the national steel industry. Established in 1975 as a stateowned enterprise, it transitioned to operating as a private organization in 1991. It is jointly owned by two investors, ArcelorMittal and Ternium, each holding a 50% stake. The mining operation is situated in the municipality of Minatitlan, in the northwestern part of the state of Colima, Mexico (Figure 1). It comprises an open pit mine and a concentrator, covering an area of approximately 2,300 hectares. The pellet mill is in the town of Manzanillo, Colima state, a port on the Pacific coast, about 46 km southwest of the mine. The pellet mill occupies its own property with a total area of 60.4 hectares. A gravity-driven concentrated slurry pipeline connects the mine and the pelletizing plant, located at an average elevation of 1,020 meters above sea level and 20 meters above sea level, respectively. Currently, Peña Colorada produces 4.1 million tons of pellets and 0.4 million tons of iron concentrate annually. In 2018, due to a change in the cutoff grade, the processing volume of the beneficiation plant increased from 9 million tons to 16 million tons annually. This led to a greater amount of information to process and characterize the ore extracted from the pit before its processing in the beneficiation plant. Consequently, Peña Colorada sought new ore control technologies to enhance ore selection, optimize human resources and data management, as well as minimize discrepancies between planning and execution. To ensure adherence to quality agreements with stakeholders, it is crucial to understand the ore characteristics before initiating mining activities.

Feb 1, 2024

By Mark J. Zdunczyk

"Frac sand is industrial silica sand much like glass, foundry, filtration and blast sand. The sand must meet certain specifications set forth by the industry that consumes the product. The production and consumption of frac sand has experienced record growth in the last 10 years because of new oil and gas drilling, new horizontal well drilling, multi-stage fracturing and the stimulation of older wells that have little or no production. Frac sand is needed to “prop open” the fractures in the rock reservoirs to allow oil and gas to flow out more freely.According to the U.S. Geological Survey (USGS), the estimated production of frac sand in 2015 was 71 percent of the total production of industrial silica sand or 67.4 Mt (74.3 million st). This is a decrease of about 12 percent from 2014. However, the silica sand industry and other industry sources estimate only 50 Mt (55 million st) of frac sand were produced in 2015. In recent years both the USGS and industry studies have been very close in estimating the production of frac sand but with the recent downturn in frac sand production, perhaps, reporting to the USGS was not as accurate. These discrepancies may be that the USGS statistics are based on voluntary reporting by the industry and some companies report their approximate production, others may not. It is always difficult to obtain accurate production figures of any industrial mineral or construction aggregate operation as most companies tend to keep those figures somewhat confidential. It is certainly accurate to report that the production of frac sand had decreased since the last quarter of 2014 and through 2015. The oversupply of oil and natural gas has led to this decline in frac sand usage. Oversupply has idled drilling rigs and well completion activities. World Oil Magazine reports that 2015 was the worst year for rigs in a quarter century. The only wells being completed are those that have contract agreements to do so, others have been capped. Very few new wells are being drilled. Since about 98 percent of well completion is sand and water, the sand supply has caught up with the demand. There are some bright spots in the “oil patch” as the Permian Basin in Texas and the Woodford Shale in Oklahoma have kept pace somewhat with drilling and completion. It has been reported that the frac sand producers in the Brady-Voca, TX area are producing to nearly capacity. The northern frac sand producers like those in Wisconsin, Illinois and Minnesota are feeling the downturn because of the cost of shipping sand to these moderately active basins and plays. The “rule of thumb” is that freight is 2/3 and sand is 1/3 the cost."

Jul 1, 2016

By J. Restrepo, N. Ripepi

"The International Organization of Standards defines risk as “the effect of uncertainties on achieving objectives (15).” In mining, many uncertainties can influence the outcome of personal or professional objectives and are often difficult to predict. Risk management, the minimization and control of adverse effects from exposure to identified risks, is a well-established concept that can summarized as “being smart about taking chances” (12). Risk management now consists of management processes unique to numerous organizations across many industries, as varying sectors encounter a variety of needs, including the analysis and mitigation of risks related to physical security, product liability, information security, various forms of insurance, regulatory compliance, and workplace safety (12). The reoccurrence of multiple fatality events in the US mining industry, especially the underground coal sector, suggests an opportunity for improved methods of major safety hazard identification, assessment, and mitigation. A risk management approach would include ready identification and mitigation of these risks, inclusive stakeholder engagement, and rapid integration. While many solutions to reducing the risk of mine disasters have been proposed including stricter regulation and improved technology, a comprehensive risk management approach has yet to be fully integrated in the US mining industry. In December of 2006, R. Larry Grayson of the National Mining Association’s Mine Safety Technology and Training Commission called for “a new paradigm for ensuring safety in underground coal mines, one that focuses on systematic and comprehensive risk management as the foundation from which all life-safety efforts emanate (7).” A risk management approach has already been implemented with success in Australia’s minerals industry as part of a transition during the mid-1990s from a prescriptive based health and safety attitude to a more proactive, duty-of care [risk-based] philosophy (13, 16, 17).FUNDAMENTAL ELEMENTS OF RISK MANAGEMENT TECHNIQUES The fundamental components of a comprehensive risk assessment/management program are well-established within the realm of mining health and safety. Figure 1 depicts the elements of a typical mining hazard management framework. The first step in any safety-based risk management system is to identify and assess hazards by their location, nature, and magnitude within a mine. Next, a decision is made about choosing to eliminate, mitigate, or tolerate each hazard. Ideally, a hazard will be eliminated during the design stages of mining, though dynamic mining conditions often require continuous improvement and reevaluation of existing hazard controls. If elimination is not possible, hazard mitigation actions can consist of methods, rules, equipment, competencies, or other mechanisms. If a hazard is simply tolerated, as many inherent mining hazards must be, then specialized administrative controls must be utilized to minimize losses. During this process, the performance of each action is monitored and modified as needed (13)."

Jan 1, 2015

By A. J. S. Spearing, B. Forbes, T. Kostecki, A. Hyett

Improving upon the past understanding of the interaction between installed rock bolts, the immediate roof and sidewalls is vital for the implementation of sound support system design, as this has a direct impact on rock-related safety. This is the primary goal in rock-bolt-related research. The earliest research in this field concentrated on limited laboratory and in situ measurements accompanied by theoretical analyses, based on the Kirsch equations. This represented the initial insight into understanding relative ground movements and their impact on primary support. However, these studies were far from complete. More recently, major technological advances in computing power within the mining industry has changed the scope from theoretical analysis to computer simulation. Even with these advancements our understanding of rock bolts in situ and in the laboratory has not progressed, particularly concerning bending and shear. To measure the behavior of rock bolts, the widely accepted practice is to populate the bolts with an array of strain gauges. Historically, resistive foil strain gauges or long displacement sensors have been used. Additionally, all instrumented rock bolts have used only two diametrically opposed slots. Rock bolts instrumented with these methods have significant shortcomings, one of which is the inability to capture shear and bending. The shearing and bending of rock bolts are particularly common in tabular soft rock mining, such as coal mining. This paper discusses the use of three slotted rock bolts, cut diametrically 120º apart, and two new optical fiber technologies populated along the entire rock-bolt length.

Jan 1, 2015

During the past 20 years, FKC-Lake Shore, located in southern Indiana, has been working with Contitech, the German conveyor company, to push vertical conveyor technology to new depths and open up additional opportunities for underground mine owners. Historically, the underground mining industry has largely been unable to realize the benefits of these efficient systems due to the design limitations in maximum depth and capacity. Until recently, only relatively shallow depth mines with low production rates have been a ?t for a vertical conveyor system. This, however, is changing with technical advancements in the Pocketlift system. With each milestone, a new vertical conveyor record is set for depth and capacity. For instance, in 2002, FKC-Lake Shore set one such record with the installation of a Pocketlift system at a mine in the Illinois coal basin with a lift height of 273 m (896 ft) and a production rate of 1.8 kt/h (2,000 stph). Although it was unthinkable at that time, today?s vertical conveyors are capable of reaching lift heights up to 700 m (2,300 ft) with an average production rate of 450 t/h (500 stph). These new lift heights and production rates are opening the technology to more potential mine owners and shifting the way people look at moving material in the future.

By James H. Nulty, Joseph S. Roti

INTRODUCTION During a recent panel discussion on the topic of millwater antiscalants, the question was posed: "What would you like to see in the future?" Answer: 'We need an antiscalant that: can be fed without a pump (no maintenance), functions on residual basis (no fault), can be tested for colorimetrically in sub-part-per- mi 11 ion concentrations (no guessing) and will recycle back to the mill from tailings (no cost).” Impossible? Based upon today's level of technology, such a product does not exist. However, a few of the qualifications listed above are certainly food for future thought. Meanwhile, progress is being made in upgrading three essential elements in this critical area of ore processing. They are: 1. Antiscalant reagent research and development. 2. On-line monitoring programs. 3. Reagent storage and feed systems. The objective of this paper is to out- line the current direction being taken in each of these areas and to present case histories as examples of how theory has been applied in field situations to better improve operations. LABORATORY SCREENING TESTS Recent technical papers have explained the various generic chemical raw materials which are available in the marketplace. While the merits of each chemical component are open to debate, the processes used by most major reagent suppliers to evaluate products in the laboratory are fairly standard. Common techniques incorporate both static and dynamic conditions in the search for the most cost effective product. Static Test Perhaps the most common test procedure used is based upon NACE Standard Test Method 03-74, which is "a laboratory screening test to determine the ability of scale inhibitors to prevent precipitation of calcium sulfate and calcium carbonate from solution." The objective of this test is to measure the change in calcium ion concentration in a container of saturated stock solution prepared from calcium chloride and sodium carbonate which is heated in a water bath. After 12 hours at constant temperature (160°), the mother liquor is pipetted into a beaker and a titrated for gm/l of unprecipitated calcium ion. A simultaneous test is performed on stock solution with antiscalant added. The results are then charted to determine the most effective antiscalant (with respect to preventing precipitation of calcite). It should be noted that this procedure examines only the ability of a chemical additive to retain calcite in a saturated solution where thermal stress is applied. This is commonly referred to as sequestration or stabilization. It has been documented that products which act in this manner (i.e., inorganic and organic phosphates) are good scale inhibitors. However, low molecular weight anionic polymers function in a much different manner by distorting calcite crystal size, shape and charge density, thus preventing scale formation. Because of this different mode of operation, static tests may not prove conclusive where polymers and sequestrants are being compared. The simplicity of this test makes it easily adaptable for field use, although modifications are often made.

Jan 1, 1986

By Eti Purwaningsih, Widi Astuti, Erik Prasetyo

Increasing demand for high-grade manganese (Mn) ore has led to the practice of selective mining, which produced low-grade Mn ore as waste and in the long term could lead to environmental pollution. Research had been carried out to extract Mn from low-grade ore, which mostly exists as black Mn(IV) oxide (MnO2). Most extraction methods involved the reduction of insoluble MnO2 to soluble Mn2+ in acidic media. Metals other than Mn are also transferred to the pregnant leach solution (PLS) during the leaching process, especially iron (Fe). Due to high Mn concentration in PLS, precipitation is considered the best method to isolate Mn from PLS compared with solvent extraction and ion exchange/absorption. However, due to unselective leaching, the presence of Fe in the PLS makes the Mn separation and purification difficult. Therefore, in this research, the parameters affecting the selectivity of Mn over Fe in leaching process were investigated.