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By Isabel F. Barton, MarkD. Barton, Christian A. Rathkopf

Molybdenite is the world’s principal source of rhenium (Re), a critical element in multiple high-tech applications. However, the Re contents in molybdenite vary by orders of magnitude on scales ranging from single grains to whole deposits. In order to better understand the systematics of this variation and what geochemical factors control molybdenite Re concentration, and hence overall Re resources, we examine global patterns in molybdenite Re contents through a compilation of > 3000 measurements of Re in molybdenite from > 700 mainly ore-bearing moderate- to high-temperature hydrothermal systems of different types. Our results are similar to but expand on those of earlier studies. Rhenium concentration in molybdenite has a lognormal distribution and varies systematically with type of geologic system, intrusive lithology, and Mo grade. The lowest-Re molybdenite occurs in greisens (geometric mean 1 ppm ± a multiplicative standard deviation of 9), quartz vein-hosted W-Sn deposits (2 ± 5 ppm), unmineralized granites and granodiorites (12 ± 8 ppm), intrusion-related deposits (24 ± 8 ppm), and porphyry W-Sn deposits (16 ± 11 ppm). Rhenium is most enriched in molybdenites from volcanic sublimates (23,800 ± 5 ppm), with skarn Fe and Au (560 ± 5 ppm and 540 ± 3 ppm respectively) and porphyry Cu and Cu-Au deposits next (470 ± 4 and 430 ± 7 ppm respectively). Among porphyries, skarns, and quartz vein-hosted deposits, Re is most highly concentrated in molybdenites from Cu and Au systems and its concentration decreases systematically through Cu-Mo, Mo, Sn, and W deposits. In nearly all cases, molybdenites from systems associated with intermediate igneous rocks contain more Re than molybdenites from systems of the same type with more felsic rock associations. The disparity between Re contents of molybdenite in felsic and intermediate systems is largest for porphyries, quartz vein-hosted, and skarn deposits and is near zero for subeconomic or barren granite and granodiorite Mo systems; felsic intrusion-related deposits have slightly higher molybdenite Re than their equivalents associated with intermediate intrusions. In most systems, molybdenite Re content does not correlate with metal grade, but may have an inverse correlation with Au grade in intrusion-related deposits (based on a small number of data points) and does exhibit a strong inverse correlation with deposit Mo grade. Dilution of Re through larger amounts (higher deposit grades) of molybdenite explains about 40% of this correlation, but the relative enrichment of Re in molybdenite from low-Mo deposits must also reflect some selective enrichment of Re/Mo in porphyry Cu systems compared to porphyry Mo systems. We found no evidence for secular increase or other systematic temporal variation in molybdenite Re content. The data regarding the use of molybdenite Re content as a proxy for mantle influence are ambiguous. Nearly all observed empirical correlations can be traced back to differences in redox state and sulfide concentration, the two geochemical factors identified here and by previous experimental work as the controlling influences on Re mobility under hydrothermal conditions. Hydrothermal systems with reducing conditions (W- and Sn-rich) tend to have low molybdenite Re even though compiled whole-rock data indicate that their source rocks have as much or more Re as those of more oxidized systems (e.g., Cu-rich). Vapor-phase exsolution, crustal assimilation, and mixing with external fluids may all enrich molybdenite Re concentrations in individual deposits and deposit types, but their extent and importance in overall hydrothermal concentration of Re is uncertain. Thus, it appears that the available molybdenite Re resource in an ore deposit largely depends on how the deposit’s redox and sulfidation conditions have varied over time and space during the timespan of hydrothermal activity. Oxidized, high-sulfide conditions tend to concentrate Re in molybdenite, whereas reducing conditions tend to leave Re dispersed at low concentrations in the bulk rock.

By K. F. Unrug

Fractures of sedimentary rocks in the vicinity of the outcrop are commonly encountered around the world. Mine highwalls and numerous highway cuts give excellent views for detailed study of surface fractures. This paper gives an explanation of the origin of fractures as well as characterization of the distribution and extent of joint system with reference to lithologic composition of the rocks. Practical implications of the joint system affecting mine operations are described. Among the subjects discussed are: discontinuous deformation as an effect of surface subsidence, stability of mine portals and near outcrop underground operations, and stability of highwalls, when using highwall miners and strip operations. Some design procedures are recommended that can minimize the problems encountered in mining areas with intense joint systems.

Jan 1, 1994

By Schebek, J. Warsen

"Data and information from sustainable development (SD) reports can be seen as a promising and easily accessible source for an Life Cycle Assessment (LCA), i.e. for generic Life Cycle Inventory (LCI) data in particular. The reliability and comparability of LCA results crucially depends on the quality of LCI data, that is defined by specific normative requirements. In parallel the GRI (Global Reporting Initiative) provides a set of guidance documents for enhancing the quality, rigor, and utility of SD reporting with specific reporting principles that address similar issues on a company level comparable to LCI data quality requirements on the process level. In order to assess the general suitability of the fundamental reporting principles for LCI data quality purposes selected reports from mining and minerals (M&M) sector are assessed within a detailed analysis."

Jan 1, 2005

By D. W. Fuerstenau, S. Raghavan

This paper presents a brief summary of some of the thermodynamic aspects of flotation processes. Thermodynamic considerations that control interfacial and wetting behavior in mineral/water/air systems are discussed. Particular attention is given to the thermodynamics of collector adsorption.

Jan 1, 1976

By B. J. Arnold

During the past three years, coal samples covering a range of coal rank, ash content, size consist, grindability, and moisture content have been tested for their flow properties using a triaxial shear tester that measures the unconfined yield strength in a compressed sample of coal. The ratio of this unconfined yield strength to the sample bulk density is part of the equation used by handling system manufacturers to calculate the critical arching or critical ratholing diameter needed to ensure that coal will flow from bunkers or bins. This ratio also serves as an index to compare the flow tested. To test the applicability of the index to predicting problems with coal flow, a series of tests were conducted at CO Inc.'s Coal Quality Development Center (CQDC) in Homer City, Pennsylvania. Tests covering ranges in size consist, moisture content, and ash content were conducted by first filling a small two-ton bin with coal and then emptying the bin at a pre-set discharge rate. The actual discharge rate from the bin under the various conditions tested was measured. Samples of the coal discharging from the bin were collected. One sample was analyzed for ash, moisture, and size consist; another sample was sent to the Iowa state University for trivial shear tests (supplying an index measurement). Actual flowability results from the bin were then compared to the measured index to determine the applicability of the handleability index in actually predicting coal flow problems. This paper describes the correlation between handleability index and bin flow and explains the next stages of the project.

Jan 1, 1992

By A. H. Shapiro, W. –F. Leung

A decanter centrifuge of novel design was developed for the dewatering of fine-solids slurries having micrometer-range particles that form pastelike, flowable, hard-to-dewater cakes. The design combines a compound beach with a cake flow control structure that allows expressed liquid, from the cake in the dry beach region to be returned to the liquid pool while maintaining a high-solids throughput. To provide optimal performance with various operating parameters (i.e., feed rate, centrifugal gravity, pool, differential speed, concentration of feed solids and slurry type), the cake flow control is adjustable. The second part of the beach is preferably at a zero angle. Tests showed that the new design allows increases in solids dryness and solids throughput. Key words: Dewatering, Centrifuge, Slurry, Fine particles, Beach decanter, Cake-flow control

Jan 1, 2003

By C. Anastasiadis

The wettability of sandstone was investigated using the technique of dielectric spectroscopy in the frequency interval 1kHz-1MHz. The natural wetness of the material was modified to get two different sets of samples, one with sea-water wetness and the other with crude oil wetness. Measurements showed that the electric responses of water-wet and crude oil-wet samples were markedly different beside the fact that the dielectric response of both groups of samples obeys a general fractional power law. The dispersivity, of the complex permittivity component that expresses the material loss with respect to the electric field was found to be the most suitable parameter to check the wettability of the samples.

Jan 1, 2005

By William J. Kohan

Milling has traditionally been considered more art than science. In the last 10 years, significant improvements in process equipment have been made and we are finally taking significant steps toward approaching grinding as a science. Two machines have been at the center of this development. These are the roll press and the high efficiency separator. The former can be considered as a new technology or adaptation of existing i.e. roller mill. The latter is clearly an improvement of existing technology. Other machines have been introduced to a lesser degree and later. Among these are the CKP and Horomill. The purpose of this paper is to provide an over- view of the currently available modifications for operating systems and options for new milling circuits with some comments on their application and history.

Jan 1, 1997

By Jamal Rostami, Jürgen Schmitt, Rohola Hasanpour

"Double Shield TBMs can be used in fast track projects for accelerated completion where there is limited information available on ground conditions and there are possibilities of encountering weak ground and shear zones. As such, the shielded TBMs are the primary choice of the machines in long tunnels, but face the possibility of entrapment in squeezing ground, which entails long delays and major risks. This paper examines the possibility of using ground improvement methods to increase ground strength, and thus, increase the capability of the machines to cope with squeezing ground conditions. In this study, 3D finite difference simulation of a shielded TBM in squeezing ground was performed to estimate the operational parameters including required thrust to get a machine out of an entrapment. This analysis was also used to evaluate the possibility of preventing machine jamming by the implementation of pre-excavation ground improvement to increase the strength of the ground. INTRODUCTION In order to face adverse tunneling conditions especially using a shielded TBM in squeezing ground, new shield designs, with extra thrust and torque, step shield geometry with reduced shield diameter from front to the back, and conical shape shields have been used. In addition, many of the new machines have the capability to implement ground improvement at distances up to 50 m ahead of the face in order to reinforce the ground and further increase in their chances to cope with squeezing ground conditions. While these features have been added to the machine, there has not been a thorough evaluation of their impact on improving the chances to avoid machine jamming in weak rocks at high depth, which is conducive to rapid convergence of the ground."

Jan 1, 2016

By G. Atesok, M. Hancer, M. S. Celik, O. F. Emrullahoglu

Multivalent ions are shown to activate the flotation of colemanite in the presence of sodium dodecylsulfate (NaDDS). Floatation recoveries versus barium ion concentrations exhibit three distinct regions of floatability. Adsorption, zeta potential and solubility mesurements under comparable conditions reveal that Region I is characterized by the uptake of Me2+ ions followed by electrostatic attraction of sulfate ions onto the oppositely charged surface. The improvement observed in flotation recoveries in Regions II and III is ascribed to surface and bulk precipitation of metal dodecyl sulfate onto colemanite, respectively. While the most soluble BaDDS ions yield the highest activation, the least soluble MgDDS achieve the lowest activation. It is postulated that metal ions depending on their solubility products with DDS are capable of activating the boron minerals.

Jan 1, 1993

By J. A. Murray

Maintaining satisfactory air quality in electrowinning tankhouses is problematic and costly, particularly as plant operating current densities have increased. Conventional approaches have not proved completely effective. These include the use of beads, hollow spheres, surfactants and coalescer devices. They require powerful ventilation systems to be installed. As workplace and environmental regulations become more stringent, containment of the acid mist at its source is more attractive. An electrode cap system based on this approach has been developed and tested in two commercial copper electrowinning tankhouses.

Jan 1, 1996

By S. K. Kawatra

In most operating coal-cleaning plants, a significant amount of pyrite is recovered in the froth during flotation of high-sulfur coal. Reducing the pyrite recovery first requires that the primary recovery mechanism should be Identified, as different measures are required for reducing entrainment, locked-particle flotation, or true hydrophobic flotation. In this paper, evidence is presented which suggests that hydrophobic flotation is not an important mechanism for recovery of liberated pyrite from freshly-ground coal when the collector is a neutral oil, and that the bulk of the floated pyrite occurs either as a result of simple entrainment or by mechanical locking with floatable coal particles. Column flotation results are also presented which show that significant sulfur reductions can be achieved by reducing levels of entrainment.

Jan 1, 1992

By J. C. Motz

The advantages of producing a fine mill feed have been recognized for many years. The extent to which fine crushing can be carried out will vary and depends on the ore characteristics, plant and crusher design. Unfortunately, the ore characteristics are generally beyond our control, so the concentration of effort lies primarily on the plant arrangement, equipment design and operation Where fine crushing should stop and grinding begin is controversial and is influenced greatly by personal opinions and experiences. Often, this break point will be different if consideration is being given to a new plant in comparison to a modest expansion. Most new plant designs employ the largest and most efficient equipment. The modification of existing plants becomes more complex because of the space requirements and the related equipment already in operation. Fine crushing is, of course, a relative term. Obtaining a final crusher product of minus 3/4" is commonplace today and can occasionally be obtained in an open circuit final crushing stage.

Jan 1, 1980

By Robert E. Goodwin

As man's need for minerals continues to grow and as the known mineral deposits become depleted, it may be expected that these increased demands will result in greater exploration for additional deposits and at continually increasing depths below the earth's surface. As labor and material costs continue to rise, the need for more economic material handling will be emphasized. The quest for heavier payloads, safely moved at faster speeds from deeper mines, will be vigorously pursued. Strenuous efforts are, therefore, being made in the wire rope industry to develop ropes with greater strength-to-weight ratios than presently available while maintaining the dependability and long life being received from the conventional rope manufactured today. For many years, high quality rope wire has been manufactured from rods of selected steel compositions. Carefully-controlled wire drawing combined with proper heat treatment has resulted in high quality wire and wire rope throughout this period. Refinements in the rod produced from specially-selected high carbon steels combined with the latest improvements in wire drawing and heat treatments have made it possible to manufacture higher strength rope wire of uniform composition and structure that is suitable for use in Special High Strength wire rope.

Jan 1, 1970

By E. B. Kroeger

One of the problems encountered when constructing a roadway is the planned route often needs to cross soils that are soft and highly compressible. An approach to dealing with soft and compressible soils is to construct the fill from lightweight materials, thereby reducing the stresses on underlying soils. Most lightweight fills have approximately the same cost, so the most important consideration when choosing a lightweight fill is that the material properties of the lightweight fill match the conditions existing at the site. Expanded polystyrene (EPS) has been used as a lightweight fill material for more than 30 years. The EPS used for road fills is typically in the range of 0.5 to 2 lb/ft3, and has a compressive strength of in the range of 10 to 30 lb/in2. If a higher strength material is needed, then the material density is increased, which also adds to the cost of the material. Another type of lightweight fill material that is commonly being used is lightweight aggregate (LWA). LWA can be created by passing slate or shale through a rotary kiln or reheating coal fly ash with other materials to form pellets or aggregate. Several companies throughout the U.S market these materials under a variety of names. LWA can have a unit weight from 45-80 lb/ft3. For sites where trucking granular fill does not pose a problem, this material may be an alternative to EPS. One of the drawbacks to using LWA is the availability of the material. Only a few companies are manufacturing LWA, so it may not be available or may be cost prohibitive in certain areas of the country. Lightweight flyash blocks have been produced which may fill the gap in unit weight between the EPS and LWA. Blocks have been produced with a unit weight as low as 30 lb/ft3. They are relatively inexpensive, easy to handle, and have a moderate compressive strength. Although the unit weight is dramatically higher than EPS, the strength is also higher. If lateral stabilization of the fill is a problem, then geofabrics or grids can be incorporated into the design to add lateral strength.

Jan 1, 2003

By A. R. Negele

Kaolin-based pigments are the most widely used pigments in the paper industry. Several types are available and include standard hydrous, delaminated, calcined, chemically-structured, and most recently, composite pigments. Within each category, a spectrum of products is available to satisfy the application requirements of paper producers. The paper industry has a broad range of applications including fillers in woodfree and groundwood-containing papers, pigmented size press applications, ultra-lightweight and lightweight coated papers, coated merchant papers, cast coated papers and coated paperboard. Each application has its own set of performance criteria and suppliers must work with mills to identify appropriate product(s) to fulfill these requirements.

Jan 1, 1993

By W. A. Steingraber

This paper discusses the application of deep well disposal techniques to the problem of disposing of large volumes of low level radioactive wastewaters generated by the in situ uranium mining industry in Seth Texas. Data is presented on wastewater composition and volumes, geologic and hydrologic parameters of the disposal reservoirs, tell construction techniques, well operation, well monitoring requirements, and critical factors in evaluating the Safety and environmental impact of a deep injection well system.

Jan 1, 1980

By Clyde N. Garman

The Homestake-New Mexico Partners consist of Homestake Mining Company of Lead, South Dakota; Rio de Ore Uranium Mines, Inc; United Western Minerals Company; White, Weld and Company; J.H. Whitney; San Jacinto Petroleum Corporation; and Clyde Osborn, Homestake Mining Company is the general partner, the others are limited partners. The Rio de Ore Uranium Mines, Inc. has. a mine in the Ambrosia Lake area; this was the first mine to go into production in this area. The United Western Minerals Company also has a mine in the Ambrosia Lake which is operated as a "farm out" from the San Jacinto Petroleum Corporation. These mines are the principal sources of ore for the mill. This group was the first to obtain a contract with AEC to make uranium concentrate from Ambrosia Lake ores and the first to have a mill in operation specifically for these ores. With Clyde Osborn as the sparkplug and co-ordinator holding the ore suppliers of, this group together, a contract with AEC was agreed on as to its essential points by mid-summer, 1956, At that time, there was no general partner and no financing, so me formal contract could be signed. By December, 1956 when the contract was signed and the present partnership officially formed, much of the basic engineering was done and purchasing of main elements of the mill waited on the formalizing of agreements, at the specifications and sizes agreed on previously. Ground for the mill was broken in April, 1957. The sampling plant went into operation in October and ore was first fed to the ball mills on February 5, 1958, ten months after construction actually started. Filling of the circuit with sodium carbonate bicarbonate solution had begun a week before that.

Jan 1, 1959

By W. K. Summers

During the past few years monitoring systems have been installed to measure the effects of environmental changes on the ground-water resource. The design of a monitoring system depends upon the designer's perception of how the environmental factors merge with his perception of the ground-water flow system. The validity and representativeness of measurements made during a monitoring program depend upon the validicy of the designer's perceptions and concepts. To optimize the design of a ground- water monitoring program the designer should make preliminary measurements to confirm his assumptions.

Jan 1, 1985

By James A. Kiger

We at Colowyo would like to thank you for the opportunity to share with the Society of Mining Engineers of A.I.M.E. the progress of reclamation at Colowyo Coal Company's multiple seam open pit coal mine which is a general partnership of W.R. Grace and Co., and the Hanna Mining Co. First, a brief history of Colowyo Coal Company (Colowyo). The Colowyo operation is located approximately 28 miles southwest of Craig, Colorado, which is in the northwest corner of the state. The Colowyo operation produces coal from a Federal Coal Lease, a portion of which has experienced previous coal mining by underground methods. The underground coal mines were known as the Red Wing Mine and The Streeter Mine, and supplied coal to numerous locations in the Rocky Mountain region.

Jan 1, 1984