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By J. Roger Loebenstein

This report presents a U.S. Bureau of Mines study of the flow of arsenic-containing materials in the United States, based on the best data available in 1991, includes a consideration of arsenic as a byproduct of the processing of nonferrous metals, the fate of arsenic in manufacturing wastes, the quantity of arsenic used in products, tile fate of arsenic in dissipative uses, and the useful life of discarded products. Where possible, estimates are given of the amounts of arsenic lost from the materials flow. Arsenic byproduct of mining nonferrous metals. Historically, most U.S. production has been from the states of Montana, Washington, and Utah. The smelters in these states are believed to be the areas of the country where arsenic is most concentrated in the soil, tailings ponds, and waste dumps. Since the closure of the last domestic producer of arsenic in 1985, all arsenic has been derived from imported sources. Historically, arsenic was important in agricultural applications as an insecticide, herbicide, and cotton desiccant. As the environmental movement gained momentum and the toxicity of arsenic became better understood, most of the agricultural uses for arsenic were banned. Beginning about 1975, the use of arsenic as a wood preservative began to grow. After 1980, wood preservative uses became more important than agricultural applications. By 1990, 70% of the arsenic consumed in the United States was used by the wood preservative industry and 20% by the agricultural industry. The major source of domestic arsenic emissions in 1989 was from the U.S. copper processing indus¬try. About 7,800 mt/yr of arsenic was discarded in leach dumps, tailings, and slag. Another 800 mt/yr was liberated to the atmosphere and 1/100 mt/yr was exported in copper concentrates. On the consumption side, 9,200 mt/yr was lost, mostly from dissipative agricultural uses and the disposal of obsolete arsenical products.

Jan 1, 1994

Coal is a combustible, carbonaceous, sedimentary rock that is formed by the accumulation, compaction, and physical and chemical alteration of vegetation [Simon and Hopkins 1981; Bates and Jackson 1987]. Coal is classified according to its type, grade, and rank. The type of coal relates to the plant materials from which the coal originated. The grade of coal refers to the purity of the coal-or the amount of inorganic material (including ash and sulfur) left after the coal is burned [Bates and Jackson 1987; Stefanko 1983]. The rank of coal indicates its degree of metamorphosis and roughly correlates to the geological age of the coal or the geological environment from which it has been mined [Bates and Jackson 1987]. Rank also indicates the percentage of carbon in dry, mineral-free coal [Whitten and Brooks 1973] and the degree to which the coalification process has progressed [Larsen 1981]. The geological process of coalification begins with organic materials (e.g., celluloses, lignins, and other plant compounds that are deoxygenated and then dehydrogenated) and ends with coal of various geological ages, from lignite to anthracite [Larsen 1981]. Table 3- 1 presents the American Society for Testing and Materials (ASTM) classification of coals by rank. According to Parkes [1982], high-rank coal includes anthracite and semianthracite coal ("hard coal," with 91% to 95% carbon); intermediate-rank coal includes low-, medium-, and high-volatile bituminous and sub-bituminous coal ("soft coal," with 76% to 90% carbon); and low-rank coal includes lignite (with 65% to 75% carbon or less). The rank of coal tends to increase from the western to the eastern United States, with anthracite occurring primarily in eastern Pennsylvania [Schlick and Fannick 1971]. Most of the coal currently mined in the United States is bituminous [Given 1984]. A classification of the coal in the United States is provided in Table 3-2.

Jan 1, 1997

Develop rugged, cost-effective fire protection for hydraulic shovels and backhoes. Approach Automatic fire sensing and suppression systems were designed and built for use on hydraulic shovels and backhoes. How It Works A line-type temperature sensor is mounted in the machine's engine and hydraulic pump areas to detect the heat from a fire while it is still small and easy to control. Two systems were tested. In one, the inside of the sensor consists of two conductors separated by a ceramic material whose electrical resistance decreases with increases in temperature. When heated to a predetermined temperature) the control circuit responds to the resistance drop. In the second system, the detection element of the sensor is comprised of a thin metal tube containing a hydrogen charged metal hydride wire. The tube is sealed at one end and is connected to a sensitive pressure switch at the other end. When exposed to the heat from a fire, hydrogen gas released from the metal hydride wire actuates the pressure switch.

Jan 1, 1980

Develop a method for control of groundwater inflow to chronically "wet" sections of underground coal mines, in order to reduce groundwater interference with mining activity and to minimize acid mine drainage. Approach In eastern coal regions, groundwater stored in fracture zones in the rock mass can create a significant water problem for underground mining operations. Fracture stored inflow to mine workings impedes mine productivity since storage water sources usually release at the active face, creating the poor mining conditions typical of a "wet" section. Fracture water can also contribute to AMD problems when the water subsequently contacts sulfide minerals in the coal, The Bureau of Mines has developed a mine-dewatering method that eliminates many of the problems associated with mine water inflow by draining these fracture zones before the water can reach the developing face and interfere with mining activity. How it Works The dewatering method removes large volumes of the stored groundwater through high-capacity pumping from a minimal number of wells placed strategically on fracture traces (the surface expressions of fractured rock zones). These fracture traces are located through low-level aerial photographic and geologic investigation. As shown on the map, dewatering wells are sited precisely on fracture trace intersections in order to take advantage of the increased pumping capacity gained from these zones of high permeability. Once well drawdown indicates that the stored water is depleted,

Jan 1, 1983

By Michael S. Wieland

The work-principle from thermodynamics was used to formulate a model for predicting toxic fumes from mining explosives in underground chamber tests, where rapid turbulent combustion within the surrounding air noticeably changes the resulting concentrations. Two model constants were required to help characterize the reaction zone undergoing rapid chemical transformations in conjunction with heat transfer and work output: a stoichiometry mixing fraction and a reaction-quenching temperature. Rudimentary theory with an unsteady uniform concentration gradient was taken to characterize the combustion zone, yielding 75% for the mixing fraction. Four quenching temperature trends were resolved and compared to test results of ammonium nitrate compositions with different fuel-oil percentages (ANFO). The quenching temperature 2345 K was the optimum choice for fitting the two major components of fume toxicity: carbon monoxide (CO) and total nitrogen oxides (NOx). The resulting two-constant model was used to generate comparisons for test results of ANFO compositions with additives. Though respectable fits were usually found, charge formulations which reacted weakly could not be resolved numerically. The work-principle model yields toxic concentrations for a range of charge formulations, making it a useful tool for investigating the potential hazard of released fumes and reducing the risk of unwanted incidents. Keywords: Toxicity; Fumes; Explosives

To develop an explosive charge that will effectively break rock in underground mines and that can be safely fired without the use of blast-holes or the need for stemming. Approach The Bureau of Mines developed a non-incendive, cylindrically-shaped explosive charge that will not ignite gassy or dusty atmospheres, even methane-laden air. How It Works Firing unconfined explosive charges in underground mines is prohibited by law since detonation in gassy or dusty atmospheres is extremely dangerous. However, there are advantages in using unconfined charges from both a safety and a production standpoint. Explosives can effectively break up large boulders, rocks and slabs when leveling roof falls and can dislodge overhangs which miners would other-wise have to dislodge manually, exposing themselves to

Jan 1, 1983

By J. F. Barkley

"In the course of the Government's Fuel Economy Survey of its own power plants, studies and tests have been made of various oil-burning equipments under power-plant boilers. There are now many types of burners being offered in the relatively limited field of power-plant use. The majority of the types used may be grouped into two general classes- those using steam to effect the atomizing of the oil, and those using mechanical means.Burners using steam have had the most prominence in this field for a long period. The mechanical atomizing type of burner successfully applied on shipboard, however, pointed to a possible betterment in land work. The vision presented itself of a burner that would need no steam for atomizing that would permit of air inlets or registers compactly arranged as a part of the entire burner, and that would only require the natural stack draft usually available in land boiler furnaces. Hence, rather recently there has been much development along this line, resulting in various types of burners.In Table 1 are grouped test items chosen from many tests showing representative analyses of the products of combustion obtained with various burners installed in various types of furnaces. In all these tests the burners were handled by experts and represent practically the best attainable for that particular arrangement. The boiler efficiencies ranged from 70% to 80%. It will be noted that the burners using steam for atomizing were able to secure slightly better 002 and less 02 without the presence of CO."

Feb 1, 1926

Coal miners, especially roof bolter and continuous miner operators, work in a hazardous underground environment where they are often exposed to poor roof conditions. Nearly 500 rock fall injuries are reported each year, and 99% of them are caused by rocks falling from between the roof bolts. These loose rocks that injure miners are usually just a few inches thick, but on average weigh 280 pounds. NIOSH has found that most rock fall injuries can be prevented by installing roof screen during the bolting cycle. Roof screen is a sheet made of steel wires in a grid pattern. When screen is bolted up against the mine roof, it provides far more coverage than any common surface control used in the mines today. Because more mine roof is covered, there is less chance that a rock will fall and injure a miner. The facts about roof screen are shown in the new NIOSH video entitled “Make It Safer With Roof Screen.” Using extensive underground footage, the 7-minute video shows how well screen keeps loose rock from falling in difficult roof conditions. Techniques for installing screen from both outside-controlled and walk-thru roof bolting machines are shown. The video also provides safe handling tips, best practices, and information about machine technology that can greatly improve material handling. Throughout the video, a coal mine safety manager and a shift foreman talk about the tremendous difference that roof screen has made at their mines. An instructional booklet supplements the video with additional information. It presents compelling data from mines that have practically eliminated rock fall injuries with a roof screening program. Other sections of the booklet discuss in greater detail roof screen installation, tips for manual screen handling, a material handling system for roof screen, and use of the personal bolter screen, which can be easily handled by one person. Screen specification and custom ordering are described, including the sizes of screen, grid sizes, reinforcing (indicator) wires, edge cut options, and screen strength. A list of additional sources of information is also provided. Nearly every mine eventually encounters poor roof. Screen is one of the most powerful control techniques available. This new video will help make mine managers aware of screen, and it can help them in developing a roof screen installation program. It also serves as an information source and teaching tool for safety managers and trainers. The video can easily be integrated into new miner training programs or annual refresher training.

Mar 1, 2005

By William G. Gruzenaky

The separation of yttrium and the individual rare-earth elements (lanthanons) from mixtures in which they occur has been a difficult problem through-out the years. Because of the increased interest in the various uses of these metals, the economy of their production may become of great importance. Studies relative to this problem, undertaken at the Federal Bureau of Mines Albany Metallurgy Research Center, resulted in the development of a solvent extraction method by which yttrium can be separated from the rare-earth metals. A separation factor of 10.93 was obtained between yttrium and cerium from a single-stage extraction, and a factor of 1.78 was obtained between yttrium and erbium from a multistage system. The valuable metals were extracted from euxenite by caustic soda fusion or by chlorination, and several separation methods were investigated. Partial separation of the yttrium and rare-earth element fraction was made by chemical methods and by solvent extraction. Thermal decomposition of aqueous rare-earth nitrates or selective ignition of yttrium and rare-earth oxalates yielded a fraction enriched in cerium. A fraction enriched in the light rare-earth elements resulted from a double sulfate precipitation, whereas a potassium ferrocyanide pr cipitation yielded a fraction enriched in yttrium. Precipitation with dimethyl phosphate yielded a fraction enriched in yttrium and heavy rare-earth elements. Enriched fractions were obtained with several solvent extraction systems. A system consisting of rare-earth nitrates, nitric acid, and tri-n-butylamine-3 methyl-2-butanone favored the separation of yttrium from the heavy as well as from the light rare-earth elements.

Jan 1, 1961

By E. J. Gleim

In the movement of self-controlled direct-current machinery, particularly shortwall cutting, machines, from one place to another in coal mires, "nipping" or it stinging" has been practiced quite commonly. These terms refer to the method of obtaining current for propelling or tramming the machines along trolley haulageways by sliding the trolley trip (hook or nip), which terminates one conductor of the trailing cable, along the trolley wire. This is usually done by the machine operator or runner while sitting on the machine truck and holding the nip terminal against the trolley wire as the machine travels along the rails. This procedure is objectionable for several reasons. Under the best conditions, the area of contact between the nip and trolley wire is snail end, consequently, sparking and flashing ore most likely to be continuous as the machine proceeds. This is undesirable, not only because of the detrimental effect of electric flashes upon eyesight, but because of the pitting and roughening the trolley wheels which decrease the efficiency of current collection by locomotive trolley wheels and shoes and at the same time shorten their useful life by increased wear.

Jan 1, 1939

By B. J. Scheiner

The Federal Bureau of Mines has successfully demonstrated an electrooxidation-solvent extraction-carbon adsorption process for recovering molybdenum and rhenium from offgrade concentrates. The flow sequence consists of dissolution of metal values by electrooxidation, liquid-solid separation by thickening, acidification and chlorate ion removal by sulfur dioxide treatment, solvent extraction to concentrate the molybdenum and rhenium, separation of molybdenum and rhenium by carbon adsorption, and metal recovery by crystallization. Molybdenum and rhenium were recovered as ammonium paramolybdate and ammonium perrhenate. Electrolysis of brine-concentrate pulps to generate a hypochlorite oxidizing agent in situ resulted in the dissolution of 98.9 and 99.1 pct of the molybdenum and rhenium, respectively, at an energy consumption of 13.7 kwhr/lb of molybdenum extracted.

Jan 1, 1976

By J. E. Zeilinger

This Bureau of Mines report describes the preparation characteristics of three samples collected from the Kidney seam, in the Northern Field of the anthracite region. Removal of the sink 1.70 specific gravity material from the samples collected would result in greatly reduced ash contents at yields in excess of 90 percent. The Kidney seam, in the locations sampled, proved to be a low-ash anthracite containing an unusually high percentage of float 1.45 specific gravity material.

Jan 1, 1970

By Walter J. Frank

Thls report summarizes work done under Bureau of Mines contract H0357100, "Development of a Crimp Connector for Trailing Cable Splices." The purpose of this effort was to establish optimum connector design conditions to meet flex cycle, pullout and electrical resistance criteria on phase power conductors. Field testing of "optimum design" connectors is briefly discussed. One of the primary objectives of contract H0357100 was to enable one to design better performing phase conductor connectors. Illustrating the practical significance of this 1s a discussion on the development of a new splice kit for trailing cables. The connectors in this kit were designed in accordance with the design methods described in the contract final report. Kit components, test data, and a connector installation tool are also discussed. The successful effort on the phase connector has resulted in contract H0377042, entitled "Design and Testing of Joining Sleeves for Trailing Cable Ground and Pilot Wires." The purpose of this contract (currently in effect) is to improve ground-conductor and pilot-wire performance. Significant findings to date are discussed.

Jan 1, 1979

By J. F. Barkley

The following questions and answers were prepared principally to supply information in answer to general inquiries received by the Bureau from those contemplating the use of propane and butane fuels . Primary or basic information only is covered; this usually gives enough guidance for most inquirers . To those who wish information of the treatise type , the handbook , Butane- Propane Gases , published by the Jenkins Publications , Inc. , 1709 West 8th Street , Los Angeles 14, Calif . , is suggested .

May 1, 1949

By Jeffrey Johnson, Thomas Brady, Radford Langston, Mary MacLaughlin, Hendrik Kirsten

The magnitudes and directions of in situ stresses affect the stability of mine openings, as well as the type and amount of ground support needed to maintain a safe working environment for miners. Using hollow inclusion stress cells, researchers from the Spokane Research Laboratory of the National Institute for Occupational Safety and Health obtained two in situ stress measurements from the face of two footwall lateral drifts at the Stillwater Mine near Nye, MT. The first measurement, obtained in 1997, was collected under the valley beneath the Stillwater River. The second measurement was obtained in 2002 under the main frontal massif of the Bear tooth Mountains in the western sector of the mine. Although few data are available, the major principal stress under the valley has been recorded as nearly horizontal in a north-south direction perpendicular to the ore body, while beneath the mountains, stress runs east-west parallel to the ore body. This paper documents the measurements, describes the in situ stress state, and discusses a finite-difference analysis of the biaxial test.

By W. P. Diamond

It is estimated that more than 1 trillion cubic feet of methane is contained within the coals of the Mary Lee group in Jefferson, eastern Tuscaloosa, and southern Walker Counties, Ala. Most of this methane will be encountered by mining. Coals of the Mary Lee group are presently being mined at depths exceeding 1,000 feet and will in the near future be mined at even greater depths, where the problem of methane gas affecting the mining operations will be acute. It is calculated that approximately 90 pct of the methane is at depths greater than 1,000 feet, and over half of the gas is contained within only 12 pct of the study area which is under more than 1,500 feet of over-burden. Degasification in advance of mining will increase mine safety, reduce ventilation expenditures, increase productivity, provide an additional energy source, and make it possible to mine parts of deep coalbeds that probably could not otherwise be mined.

Jan 1, 1976

By Stephen Krickovic

A methane emission rate study was conducted in 1969 on a longwall section of a Lower Kittanning coalbed mine in central Pennsylvania. The longwall face was mined with a drum shearer between developed headings on the head end and headings on the tail end that were driven with a ripper-type continuous miner as needed. The study was conducted over 22 consecutive shifts (7-1/3 days). The average methane emission rate from the Lower Kittanning coalbed during mining at the face and developing the headings at the tail end of the face was 34 Am. Caving of the gassy overlying strata as the result of mining at the face increased the methane emission to rates ranging from 702 to 1,049 cfm.

Jan 1, 1971

By A. M. Dale, J. Standeven, B. Evanoff

Tool manufacturers continue to incorporate new designs to the internal mechanism of tools in order to decrease the vibration that is delivered to the hand during operation. Modification of some tools to minimize tool vibration is not easily resolved through internal tool design. For this reason, vibration damping materials applied between the tool and the hand are a simple alternative. The damping materials may be applied to the area of the tool directly contacted by the operator or in a glove containing a vibration absorbing pad. These interventions are developed specifically to damp vibration but are not necessarily produced and tested under the same work conditions that a company may expose their workers. Therefore, it is important to test the value of the proposed interventions for the specific applications. This study evaluates the effectiveness of anti-vibration interventions currently in use at a local manufacturing company. Methods The design of this study evaluates the vibration energy produced at the tool handle and from the back of the operator’s hand. Each operator performed a series of fastener installations in metal using several interventions and one series with no intervention as a control. Four of the interventions were gloves containing anti-vibration material and the fifth intervention was an anti-vibration material wrapped around the tool handle. The protocol for wrapping the tool handle was developed and is part of the equipment procedure at this manufacturing company. Test conditions mimicked production work conditions including similar materials, fasteners and technique for installation. Vibration values were collected using 3 tri-axial accelerometers with one firmly glued to the tool handle close the hand grip as recommended by ISO 5349. A second accelerometer was placed on the top of the pistol shaped tool. The third accelerometer was attached to the back of the hand close to the third knuckle using double sided tape. Results Preliminary results for 3 volunteers show a difference between the vibration values of the control condition (mean hand vibration on bare hand = 1.77 Gs) compared to all of the interventions (p=.0001 using Mixed Procedure, Tests of Fixed Effects). The graph below shows individual trials for each subject for each condition. Glove 3 with the air bladder insert shows large variability between subjects (Range = 0.84-3.33 Gs). The other interventions show much less variability both within subjects and between subjects indicating consistent response with use of the intervention.

Jan 6, 2006

Prevent the explosion of methane gas or coal dust by replacing air with inert gas inside highwall mine excavations. Approach Use combustion gases as a source of inert gas with low oxygen content to blanket the cutting, head of highwall mining machines. This gas is placed strategically at the collar of the excavation where it enters the hole to replace the mined coal volume. The elimination of oxygen from the hole prevents explosions of gas or dust. How It Works Highwall mining methods arc used when surface mining becomes uneconomical. One method of highwall mining involves use of a horizontal auger to enter the coalbed from a surface mine bench. The coal is mined in a series of horizontal, parallel, and large-diameter holes. Historically, little methane has been associated with auger mining. However, mining technology has extended the reach of auger mining, which can increase the occurrence of methane. Methane explosions at auger mining operations have been increasing. Methane has been the primary fuel source of these ignitions, but coal dust also may have been involved.

Jan 1, 1993

Reduce injuries caused by slips and falls from large haulage vehicles. Approach Replace the flexible-cable or chain-type lower ladder steps, with steps that extend closer to the ground and do not sway when stepped on. Modify dimensions of entire ladder to new industry recommendations. How It Works New lower ladder steps are supported by side pieces made of pretensioned, solid-wound, coil springs fabricated from high strength steel. Unlike conventional crash-resistant steps, which flex or swing freely when stepped on, the spring supported steps can maintain the same inclination as the fixed upper portion of the ladder while supporting an average-weight operator. The steps are also highly resistant to collision damage because they yield on impact if rammed into obstructions such as rocks or berms. See photograph.

Jan 1, 1980