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By E. D. Regad, W. E. Wallace, P. S. Mike, C. A. Hill, V. Vallyathan, M. J. Keane

"Respirable-sized quartz, a well-established fibrogenic mineral dust, is compared with kaolin in erythrocyte hemolysis assays aher treatment with saline dispersion of dipalmitoyl phosphatidylcholine, a primary phospholipid component of pulmonary surfactant. Both dusts are rendered inactive after treatment, but the membranolytic activity is partly to fully restored aher treatment with phospholipase Ai. an enzyme normally associated with cellular plasma membranes and lysosomes. Phospholipid-coated dusts were incubated for periods of 2-72 h at a series of applied enzyme concentrations, and the adsorbed lipid species and hemolytic activity were quantitated at each time for both dusts. Surfactant was lost more readily from quartz than from kaolin, with consequent more rapid restoration of mineral surface hemolytic activity for quartz. Interactions of surfactant and mineral surface functional groups responsible for the mineral-specific rate differences, and implications for determining the mineral surface bioavailability of silica and silicate dusts, are discussed. INTRODUCTIONMineral particles depositing in the lung acinus will contact an aqueous coating containing surfactant molecules spread on the air-liquid interface and dispersed within this hypophase; the primary components of that surfactant are diacyl lecithin phospholipids (King and Clements, 1972; King, 1982). Adsorption of this surfactant can suppress the cytotoxicity of mineral dusts (Marks, 1957). Suppression of hemolytic activity, a measure of membranolytic potential and an indicator of bioavailability of the mineral surface, of respirable-sized quartz and kaolin clay dusts with the adsorption of dipalmitoyl glycerophosphorylcholine or dipalmitoyl lecithin (DPL) has been measured (Wallace et al., 1985). Such contact and adsorption of pulmonary surfactant in vivo may provide a first defense system of the lung against respired dusts."

Mar 1, 1992

By Ann G. Kim

The Bureau of Mines estimated the methane content of a coal, which depends primarily upon rank and pressure, from the adsorption equation V kpn, where k and n are constants related to rank. By incorporating corrections for moisture, ash, and temperature, and estimating pressure and temperature as a function of depth, the methane content of coal in place can be estimated from the following equation: [ ] Values calculated with this equation generally are in reasonable agreement with direct determinations. By assuming a standard moisture and ash content, and using the hydrostatic head to estimate pressure, a graph of rank and depth versus gas content was constructed. Although estimated values were consistently high for several high-volatile bituminous coals from an area where the pressure is known to be less than hydrostatic, the estimated methane content for most coals shows reasonable agreement with values determined by the direct method.

Jan 1, 1977

By Jalna R. Zatko

The Bureau of Mines has developed and constructed an apparatus that is capable of measuring concentrations of high-molecular-weight polymers in solution at 10 ppm and less. A means for determining low concentrations of polymeric solutions was devised that was independent of slight fluctuations in solvent quality in order to measure polymers in effluent prior to recycling of the recovered solution. The concentrations of polymers ore related to a measured pressure drop observed during turbulent flow of the solution. Low concentrations of polymers of ethylene oxide and acrylamide (frequently used as flocculants for clay waste systems) in aqueous and salt solutions have been successfully measured on the apparatus constructed by the Bureau.

Jan 1, 1981

By J. G. Donaldson

The Bureau of Mines investigated the formation of boron and boron-carbide coatings by vapor-phase reactions. Optimum parameters were determined for hydrogen reduction of boron trichloride and for the fonnation of boron-carbide coatings on graphite by reaction with the depositing boron. At 1,300° C, about 85 percent of the boron was deposited. Tungsten substrates did not react with the boron deposit; other substrates reacted to various extents. The hydrogen reduction of boron tribromide was briefly investigated. Boron carbide was deposited at 1,300° C by adding methane to the boron trichloride-hydrogen feed gas. The chemical composition of the vapor-deposited boron carbide approximated B4C. A method of etching B4C was developed to study its microstructure. When boron was deposited on graphite at 1,500° C, very hard, uniform, strongly adherent coatings of B4C were formed that might be useful in rocket nozzle applications.

Jan 1, 1968

By John J. Mulligan

Ear Mountain is an isolated mountain mass that rises abruptly from the coastal plain on the northwest shore of the Seward Peninsula. Geologically it resembles the more accessible Brooks Mountain and Cape Mountain areas to the southwest, being composed of a granitic core surrounded and partly capped by metamorphosed sediments. The occurrence of lode- and placer-tin deposits in this area has been known since the early 1900's, when the Seward Peninsula region was prospected extensively for both gold and tin. The Federal Bureau of Mines investigated the tin deposits in the Ear Mountain area during the 1953 and 1954 field seasons. The objectives were to delimit the areas in which tin minerals occur, as a guide to future prospecting, and to determine the amount of tin in the known prospects. Work by the Bureau of Mines included both placer and lode sampling.

Jan 1, 1959

By Stephen A. Swan

Bureau of Mines research has not included analyses of mining dredge safety since 1948. Because of the increasing use of dredges, 63 fatal accidents and several hundred nonfatal injury accidents involving dredges were examined. Also, 31 working dredges and 3 dredge manufacturers were visited to acquire qualitative information. Drowning accidents represented 59 pct of the fatalities and are delineated in detail. Also, countermeasures against other hazards are discussed.

Jan 1, 1985

By Wilbur A. Haley

The demand on the nation's reserves of high-quality coals suitable for metallurgical purposes is resulting in the rapid depletion of some of the thicker coal beds. These beds are thick enough to permit the use of modern mechanized mining equipment. Many of the thin beds are not being mined at present. In limited areas where the coal is less than 36 inches thick some beds are mined by various conveyor methods. Usually, the room-and-pillar system or some modification of it is used, and often no attempt is made to extract pillars. Consequently, an appreciable quantity of a valuable resource is lost. Many steel companies and coal operators consider reserves of low-and medium-volatile coking coals to be critical, especially in areas where the thin beds are not being mined by modern mining methods. To improve recovery and to promote more-extensive mining in thin beds, methods and devices that are new to American coal mining but applicable to the mining of thin coal beds should be tried. As one of the functions of the Bituminous Coal Mining Section of the Bureau of Mines is to promote improved mining practices and efficiency in the interest of conservation, research in that line is necessary. In 1945 coal planers were observed in operation in Germany by a Bureau engineer member of Solid Fuels Mission to Germany. Planer designs and history of early developments and operations were published. In 1949 an improved planer was again studied by Bureau engineers, and its adaptability to certain conditions in the United States, especially thin beds of friable coal, was considered practicable. After the war the planer was improved, in design and for several years has been operating successfully in the Ruhr. Because of the conviction that the device would be successful, both from the standpoint of conservation and operational prodl1ctivity, under certain conditions in the United States, the Bureau of Mines, through the Bituminous Coal Mining Section, entered into a cooperative agreement with the Coal Division of Eastern Gas & Fuel Associates and Mining Progress, Inc. The purpose of the agreement was to conduct an experiment in modified longwall mining, using a new-type German-built coal plow or planer, known as the Loebbe Habel, supplied by Mining Progress, Inc. The experiment was made to determine if this type of mining equipment operated on a longwall face could be adapted to some of the thinner American coal beds. Such an experiment also would afford many opportunities to study the possibilities and principles of this type of equipment as well as the many factors involved in the mechanical mining of a longwall face.

Jan 1, 1952

By R. V. Ramani, S. Shankar

"A convective dispersion model has been utilized to calculate the real-time airborne dust concentration in mine airways using re-entrainment as the only source term for airborne dust. It incorporates two important sources of re-entrainment in mines -- air velocity and movement of objects. The model has a sink term accounting for the deposition of particles along the airway. The model is solved using a finite difference scheme which is coded for computer. The computer model outputs airborne respirable and total dust concentrations along the airway as a function of time. The real-time and average gravimetric concentrations from several in-mine experiments were compared with the results from the simulation of the experimental conditions. This model can be used for estimating airborne dust entrainment due to air velocity, equipment movement, and persons walking. INTRODUCTIONEdwards and Ford (1988) developed a model for coal dust explosion suppression and utilized a predetermined value of threshold velocity for flowing air to pick up dust from floor. Depending on the strength of the removal forces, re-entrainment can increase the airborne dust concentration in mine airways. The most prevalent forces causing re-entrainment in mine airways are the drag and lift forces due to flowing air, and removal forces due to the movement of persons and vehicles. Shankar and Ramani (1991) have investigated the unique characteristics of the re-entrainment phenomenon in mine airways. Experiments on re-entrainment of coal dust particles were conducted in mine airways, and in a wind tunnel (Shankar and Ramani, 1994a, and 1994b). The results from the two experimental studies were found to compare well (Shankar and Ramani, 1995). There is no reported model to determine the airborne dust concentrations due to airflow or persons walking under conditions existing in mines. The present study is a part of a continuing research project in the Generic Mineral Technology Center for Respirable Dust on the spatial and temporal behavior of airborne dust in mine airways (Ramani, 1983)."

Dec 1, 1996

By Richard G. Burdick

This Bureau of Hines report describes an interface between a minicomputer and peripheral device, The logic used to develop the device is discussed briefly, after which the device is described in detail; complete construction and operational details are given. The report should aid both in duplicating this device and in designing similar devices for different uses.

Jan 1, 1975

By L. A. Neumeier

The Bureau of Mines investigated hot-rolling and forging characteristics of experimental ductile iron castings, both sand and permanent-mold, made with charges containing up to 70 pct foundry pig iron and 95 pct steelmaking pig iron. Between 1,550° and 1,950° F, most castings could be rolled to 90-pct reduction or forged to 70-pct reduction without serious cracking. Charge and composition have less bearing on workability than on subsequent properties. Permanent mold castings could be worked as readily as sand castings at 1,750° and 1,950° F. Plasticity improved with temperature. Small billets were also forged cold to 50-pct reduction without cracking. With equivalent nodularity, composition affects properties of wrought materials by altering matrix structure and strength. Properties vary with reduction and improve with increasing working temperature. Rolled material has high strength and anisotropy, and low ductility, particularly in the trans-verse direction. Annealing reduces strength and improves ductility, but anisotropy persists. At 70-pct reduction, impact resistance in the longitudinal direction is about twice that in the transverse. Annealing roughly doubles impact resistance. Deformation enhances damping capacity. The feasibility of die-forging and bar-rolling of ductile iron was evaluated in trial tests conducted under a Bureau contract. Although workability and ductility of ductile iron are inferior to those of steel, more advantage could be taken of ductile iron's plasticity to work rough shapes to final dimensions.

Jan 1, 1980

Many USBM research and information products are available through the systems or formats listed below: Mines FaxBack: Return fax service. 1. Use the touch-tone handset attached to your fax machine's telephone jack. (ISDN [digital] telephones cannot be used with fax machines.) 2. Dial 202/219-3644 3. Listen to the menu options and punch in the number of your selection, using the touch-tone telephone 4. After completing your selection, press the start button on your fax machine. Mines Data: Computer bulletin board. Log on via modem through 202/501-0373, or call 202/501-0406 for technical assistance. CD-ROM: This USBM disk is updated quarterly and sold by GPO's Superintendent of Documents. For information on the latest product, please contact Rodger Wedgeworth, 202/501-9557. Internet/World Wide Web: Text and graphics. Access via PC-based browsing software such as Netscape or Mosaic. Universal Resource Locator (URL) is: http:/www.usbm.gav Internet/Gopher Server: Text and tables only. Using Gopher client software, access via port 70 as follows: gopher.usbm.gav Internet System Administrator: webmaster®usbm.gov (or contact your local System Administrator).

Jan 1, 1995

By Edward F. Divers

The Bureau of Mines recently tested a sideboard device that is designed to act as an extension of conventional brattice, thus improving face ventilation of developing room-and-pillar-type coal mining. In these laboratory tests, an 8-foot-long rigid sideboard was mounted vertically along the left fender of a full-scale-model ripper-type continuous mining machine, rising to the mine roof to provide an air seal. It extended from the auger support frame pivot point outby along the fender. A novel water spray manifold was used to form an air seal between the sideboard and brattice. Tests showed improvement in face ventilation with the prototype device, and also demonstrated that water sprays can form an effective air seal over a fairly wide pressure range. Based on this preliminary study, subsequent improvements may make the sideboard concept much more effective, thus affording a simple, inexpensive technique to improve the effectiveness of face ventilation.

Jan 1, 1979

By Phillip R. Moyle

In 1985 the U.S. Bureau of Mines evaluated the mineral resources of the Sheep Creek West Wilderness Study Area (ID-111-36A), Owyhee County, ID, for the U.S. Bureau of Land Management. The Wilderness Study Area consists of 11,680 acres centered approximately 20 miles south of Grasmere, 10. It contains no mines, claims, or prospects. No mineral resources were identified; however, a geode occurrence within and adjacent to the Wilderness Study Area, and minor amounts of placer gold along Sheep Creek, may be of interest to rorkhounds and recreational gold panners.

Jan 1, 1986

By Andrew B. Cecala

This U.S. Bureau of Mines report provides a detailed description of the Bureau-designed modified shearer clearer system. Engineering drawings are provided for all major components of this system. The modified shearer clearer system is a revised version of the original system and is intended to improve the ventilation around both cutting drums. The original shearer clearer technique was solely a dust control technique that has been effective in lowering shearer operators' dust exposures. The technique uses a series of water sprays that not only knock down a portion of the dust cloud but also act as small fans that move a substantial amount of air and keep the dust cloud from dispersing over the shearer body. The modified version is composed of two additional spray blocks for improved air movement around both cutting drums, thus lowering methane levels and the likelihood of an ignition. A laboratory study performed with the modified version in a full-scale longwall gallery resulted in a 73-pet reduction in methane concentrations at the shearer machine for both cut directions. The air-moving capabilities of the system provide more turbulence at the cutting drums and reduce methane levels.

Jan 1, 1994

By Robert A. Jankowski

Through laboratory and underground studies, the Bureau of Mines has evaluated the use of passive barriers (dust shields) to help confine dust generated by longwall shearers to the face area. Laboratory studies focused first on selection of the optimum barrier design, which proved to be a simple, gobside barrier (made of conveyor belting), coupled with a headgate splitter arm, which was found necessary to prevent the dust cloud from entering the walkway at the headgate end of the shearer when cutting tail to head. Further laboratory testing was done to determine whether using passive barriers in combination with different water-spray dust-reduction methods, including the shearer-clearer system developed by the Bureau, would improve dust reduction over that from using the water sprays alone. It was found that the combination of gobs ide passive barriers plus the full shearer-clearer system was most effective, and surmised that this would be especially useful in thicker seams. However, underground testing revealed that the shearer-clearer system alone was 35 pct more effective in reducing dust contamination than when used with the gobside passive barriers, and far more effective than using passive barriers with a conventional water spray system. For such an effective system as the shearer-clearer; the reduction in avail-able space over the top of the machine actually impeded system performance; this was shom1 in both eastern and western mines. But when used with comparatively inefficient water spray systems, the passive barriers, used in combination with a headgate splitter arm, provide consider-able help in reducing dust levels in the walkway.

Jan 1, 1986

By S. H. Katz

"At the annual meeting of the International Association of Fire Engineers at Kansas City, Mo., in June, 1919, the Bureau of Mines offered to cooperate with municipal fire departments for the purpose of obtaining information regarding composition of the air in burning buildings. (Katz, S. H., Statement made at Convention of International Assoc. of Fire Engineers: Fire and Water Eng., vol. 66, July 16, 1919, pp. 129-30, also Fireman's Herald, vol. 78, July 12, 1919, pp. 48.) The gas-mask laboratory of the Bureau's experiment station at Pittsburgh sent vacuum bottles for taking samples to fire chiefs in twenty-five cities, who had signified their intention to aid in this work. It was hoped to obtain one hundred or more samples, because statistics in quantity are necessary for drawing reliable conclusions concern-in the likelihoods of encountering irrespirable as in burning buildings. This far, eleven samples have been received by the laboratory. Results of analyses and pertinent data regarding these samples are given in the accompanyingEight of the eleven samples contained, no carbon monoxide; seven of the eight were taken above the ground level and one below ground. One sample taken above ground contained 0.03 per cent carbon monoxide, and this quantity is not dangerous to breathe for a limited time. Of the three samples taken below ground, one contained no carbon monoxide; the other two contained 0.10 and, 0.35 per cent, respectively. This indicates that in a burning building, the hazard from carbon monoxide is much greater below the ground level. The cause undoubtedly lies in the poorer ventilation that is usually found in cellars or basements. Abundance of ventilation provides the necessary air for complete combustion, or if incomplete combustion does occur, the carbon monoxide generated by the fire is greatly diluted with fresh air and swept away by the current. It may be noted that the highest proportion of carbon monoxide was found in a cellar where a fire as burning among piled cases. The difficult access of air to the burning parts facilitated the formation and lib ration of carbon monoxide. The smoke here was very light and no difficulty was experienced in breathing. Some of the air containing dense smoke showed little change from normal air by analysis. Thus the density of smoke or the irritation and difficulty it causes in breathing are no indication of the presence of poisonous gas. None of the samples shows important oxygen."

Nov 1, 1920

By Wilson Blake

The Bureau of Mines used a mathematical model based on the finite element method of stress analysis to calculate stresses and displacements surrounding an open pit mine in a gravity-loaded rock mass. Comparison of the finite element solution for a semicircular notch in a gravity-loaded plate with the theoretical solution for a semicircular notch in a plate under uniform compression parallel to the free boundary demonstrates the inapplicability of the latter method to openings at the free surface of a gravity-loaded medium. High stress concentrations are formed at irregularities along the boundary of an open pit in a gravity-loaded continuous competent rock; however, for this type of rock the magnitudes of the stresses are too low to be considered a major factor in open pit slope stability. High stress magnitudes will occur if, in addition to the gravity stress field, a large horizontal stress field exists.

Jan 1, 1967

By L. C. IlsLey

A list of permissible mine equipment approved by the Bureau of Mines before January 1, 1940, was published in Bureau of Mines Information Circu- lar 71103. Information Circular 71584, published as a supplement thereto, listed equipment approved during the calendar year 1940. The present list contains the information given in those two circulars, as well as approvals issued during the calendar year 1941. It embraces electrically operated air compressors, coal drills, conveyors and loading machines, electrical equipment for mine fans, mining machines and trucks, mine pumps, rock- dust distributors, room hoists, storage-battery gathering and haulage locomotives, storage-battery power trucks and shuttle cars, mine telephones, junction and distribution boxes, electric cap lamps, flame safety lamps, electric hand and trip lamps, electric flood lamps, flashlights, methane detectors, and single- and multiple-shot blasting units. The equipment listed is not approved by the Bureau of Mines until found by inspection and test to comply with minimum standards of safety as outlined in "schedules" prepared upon the basis of many years of ex- perience in dealing with safety problems confronting the coal-mining in- dustry. The use of such equipment in mines that are known to be gassy,. as well as in those that may become so, is earnestly recommended in the interests of safety. This circular is published so that the industry may be kept informed as to the many types of machines, devices, and lamps that are available for reducing explosion and other hazards incidental to coal mining.

Apr 1, 1942

By Ronald A. Munson

Samples of the naturally occurring zeolites phillipsite, clinoptilolite, erionite, and chabazite have been surveyed for their gas adsorption, ion exchange, and other characteristics. Chabazite and erionite, which are generally more stable, also have higher methane adsorption capacities than do the other natural zeolites. Both natural erionite and natural chabazite are classified as small-port zeolites on the basis of their inability to adsorb chlorotrifluoromethane. In the range of 8 to 100 mesh, the adsorptive capac-ity of natural zeolites is improved only slightly by a decrease in particle size. The capacity of natural clinoptilolite to adsorb methane is increased by cation replacement by the hydrogen ion and decreased by exchange with calcium ion. Natural phillipsite, which is easily decomposed by heat, adsorbed methane to a limited extent.

Jan 1, 1973

By W. E. Miller, G. S. Scott, G. W. Jones

"An important activity of the Bureau of Mines is the promotion of safety in mining and industry. In connection with these activities, the Bureau determines the explosion hazards of combustible gases, liquids, and solids and investigates means by which explosions may be eliminated or reduced in violence.The limits of inflammability and ignition temperature of combustible gases, vapors, and solids are of practical importance because such materials can be manufactured, transported, and used with greater safety, provided the range of concentrations and temperatures that cause explosions are known.Many organic compounds, which until a few year ago were merely laboratory curiosities, are now being manufactured in large quantities owing to the national emergency, particularly those chemicals entering into the manufacture of synthetic rubber, a product that is playing a major role in the Government program of national defense. This re Jolt gives results relative to the limits of inflammability of styrene and its ignition temperature in air and oxygen. This combustible liquid is now used extensively in the manufacture of synthetic rubber."

Mar 1, 1942