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By M. M. Barr

Rapid expansion of the titanium-metal industry focused attention upon ilmenite as a possible substitute for the more expensive and less abundant rutile in producing titanium tetrachloride. Most of the rutile available for this use is imported. Preliminary studies were undertaken to determine the chlorination characteristics of high-titanium slags produced by electric-arc furnace smelting of alluvial Idaho ilmenite at the Federal Bureau of Mines Northwest Electrodevelopment Experiment Station, Albany, Oreg. Low silicon, calcium, and aluminum contents of the slags enhanced their potential value for chlorination.

Jan 1, 1958

By R. E. Lindstrom

Effective separation of rare-earth mixtures is obtained using hydrogen as a retaining ion at 200° F with ethylenediaminetetraacetic acid (EDTA) eluant. Results obtained in Bureau of Mines bench-scale apparatus and large columns with hydrogen as a retaining ion closely parallel those obtained with copper as a retaining ion. The use of hydrogen as a retaining ion permits EDTA and water, collected before rare-earth breakthrough, to be recovered in a form that allows the material to be recycled without extensive processing. With the exception of yttrium and dysprosium, separation of rare-earth mixtures is improved and throughput is increased by elevated temperatures. Separation with 1,2-diaminocyclohexanetetraacetic acid (DCTA) eluant increases markedly on increasing temperature from ambient to 250° F; however, on the basis of separation efficiency, DCTA does not compare favorably with EDTA.

Jan 1, 1962

By Andrew Cecala, John Organiscak, William Heitbrink

Many types of heavy equipment used in the mining and construction industries use enclosed cabs to protect equipment operators from dust and noise exposure. Normally, when the equip- [ ] ment is new, manufacturers' deigned controls are effective at keeping the operator's exposure at acceptable level. However, as equipment becomes older and many components of the enclosure deteriorate, such as gaskets and seals, the effectiveness of the enclosed cab can be greatly reduced. This can cause excessive and dangerous exposures to respirable dust, especially when the ore or overburden contains crystalline silica.

By L. A. Neumeier

Sound experimental ingots of zinc alloys for use as rolling slabs were cast with a specially constructed, semicontinuous casting machine. Nominal alloy compositions of Zn-1.0 percent Cu, Zn-0.12 and 0.36 percent Ti, and Zn-1.0 percent Cu-0.03 to 0.36 percent Ti were cast. This Bureau of Mines study was conducted to evaluate the suitability of the casting procedure for providing stock for rolling into sheet. Microscopic examination of ingot sections revealed structures in which grain size varied from the outer to center ingot zones. Columnar grains present in the center zone of the Zn-1.0 percent Cu ingot were absent in the titanium-containing ingots. The ingots with titanium displayed a finer grain size and eutectic structure in the center ingot zone than in the outer zone; the transition in grain size between the two zones was quite abrupt in some ingots. The overall grain size of the titanium-containing ingots was finer than that of alloys cast by more conventional methods. Chemical analysis revealed that compositional segregation is not a significant factor in the formation of the ingot structure. Microstructural studies of small ingots of similar alloys solidified at slow, fast, and intermediate rates confirmed that the ingot structure in the semicontinuous-cast ingots is related to cooling rate, which is, in turn, related to the particular casting machine design and the influx of cooling water on the withdrawing ingots. Microstructures of thin sheet hot-rolled from slabs of the semicontinuous-cast ingots demonstrated that the ingot structure does not preclude the rolling of sheet having a uniform microstructure. Results of hardness surveys of the semicontinuous-cast ingots demonstrated that copper and titanium exert essentially additive hardening effects in these cast alloys.

Jan 1, 1968

By John Henderson

If you missed this year?s Texas State Holmes Safety Association meeting, you missed a great one. On January 23 & 24, 2009, we held the meeting that was rescheduled when Hurricane Ike threatened Corpus Christi in September 2008. Sixty-five persons from across the state attended the meeting held at the Holiday Inn Emerald Beach. The weather was 82 degrees, and the sky was clear and perfect for a safety meeting. Evaluations submitted by the attendees gave the presentations, the networking, and even the food top marks. There were eight councils represented; Big Country, Central Texas, Costal Bend, Heart of Texas, Hill Country, North Texas and North Central. Presentations included Workplace Examinations, Emergency Preparedness, Screen Safety, Contractor Responsibilities, Powered Haulage, Supervising for Safety, and Basic Inspections of Slings and Rigging. Mr. Edward Lopez, SC MSHA District Manager, gave the State of the District Address.

Jan 1, 2009

By Potter G. M.

Ore-dressing tests were conducted on a sample of ore submitted by the Richmond Hill Mining Co. of Lead, S. Dak. as a part of the Bureau of Mines program for investigating potential domestic sources of manganese. Half of the sample was taken from the 300-foot level and half from surface cuts. The problems involved were liberation and rejection of silica and iron and removal of lead, Silver, and gold from the manganese concentrates. Although a portion of the silica and iron oxides was too intimately associated with manganese minerals for rejection by ore-dressing methods, thus limiting recovery of high-grade concentrates, the Richmond Hill ore was found amenable to simple gravity methods of concentration for producing intermediate-grade products. By jigging and tabling, 73.8 percent of the total manganese was recovered in a product that, when sintered, assayed plus 40 percent Mn. Lead, silver, and gold were successfully removed from gravity concentrates by a chloridizing roasting treatment.

Jan 1, 1948

By A. Gene Collins

The Bureau of Mines conducted a research study of the geochemistry of the Smackover Formation to determine what geochemical relationships are useful in exploration for and production of oil and gas. Samples of oil, gas, brine, and rock were collected and analyzed. The oilfied brines were analyzed by methods recommended by the American Petroleum Institute and by tentative methods of the American Society for Testing and Materials. The crude oils were analyzed by Bureau of Mines methods; the gas, by Bureau of Mines methods; and the rocks, by wet-chemical, atomic absorption, and neutron activation methods. The results were correlated and interpreted, and several geochemical relationships useful in exploration and production were found. These include the type and class of brine, organic constituents in the brine, redox potential, in situ temperature and pressure of brine, degree of sulfate and carbonate saturation of brine, and halide concentrations in the brine.

Jan 1, 1974

By Daryl R. Tweeton

The Bureau of Mines compared the effects of surface-active chemicals with those of pure water on core-drilling rock and quartz and on fracturing quartz. The objectives were to determine if these chemicals assist drilling and fracturing rock and if zeta potential control was worth pursuing as an aid to full-scale drilling. All tests were performed in the laboratory. No significant increases in drilling rates were observed for 1 to 10,000 ppm Al (as AlC13) in flushing water when drilling microcline or serpentine, nor for 1 to 10,000 ppm Mg (as MgC12) when drilling microcline or marble. Concentrations near those giving a zero zeta potential were used with microcline and marble. A 50-pct rate increase was observed for drilling quartz in 0.7 ppm oleylammonium acetate, which gave a zero zeta potential. No other concentrations were used. No effect on the tensile strength of quartz thread in 0.05 ppm Al (as AlC13), which gave a zero zeta potential, was observed. Heptanol, reported to give a zero zeta potential on quartz, did not reduce the bending strength of small quartz bars below that in water. These generally negative findings raise doubt about the usefulness of zeta potential control in full-scale drilling. The results, combined with previous studies, suggest that controlling physical properties of drilling fluids, such as viscosity, is more useful than altering chemical properties.

Jan 1, 1976

By Jon C. Volkwein

Dust concentrations inside and outside enclosed cabs on several types of mining machinery were measured by the Bureau of Mines. Results indicated that properly enclosed cabs can offer significant dust protection for machine operators. Recommendations for improvements in cab technologies were discussed.

Jan 1, 1979

By W. E. Miller, Kennedy. R. E., G. W. Jones

"INTRODUCTION Ethyl mercaptan (CH3,CH2SH), a combustible organic liquid of the thioalcohol type, is employed at an odorant in many types of fuel gases and dangerous atmospheres, which in themselves are devoid of characteristic odors, to give warring against leakage of such gases or atmospheres into places where they might constitute health or explosion hazards.Ethyl mercaptan has a penetrating disagreeable odor resembling that of onions, garlic, hydrogen sulfide, or rotting cabbage, that exceedingly low concentrations of it can be detected. The of odorants as a beans of detecting leakage of gases and atmospheres has been investigated extensively by chemists and engineers of the Bureau of Mines, and numerous reports as to its value have been published."

Jun 1, 1942

By Daryl E. Radcliffe

The Bureau of Mines studied the displacement of the roof in a portion of the Bear coal mine near Somerset, Colo, Horizontal-and vertical-displacement gages were installed in a five-entry section during normal room-and-pillar mining procedures. Monitoring of the roof continued until this section was mined out. Displacement measurements in combination with known time lapses between mining and bolting operations indicate that once support is achieved, the length of unsupported time does not appear to affect long-term roof stability in the mine under investigation.

Jan 1, 1978

By M. H. Kline

The Chestatee mine is one of several well known pyrite deposits in Georgia that are reputed to carry appreciable quantities of copper with the ore. The deposit is? in Lumpkin County on the Chestatee River, 6 miles northeast of Dahlonega (fig. 1). Old records and reports indicated the probable existence of an extensive unmined ore body, but the mine is inaccessible at present. The Bureau of Mines, after studying old maps and records, decided to cor8-drill along the strike of the lense beyond the limits of the indicated old workings in an attempt to extend the possible reserves. The advantageous location of the property indicates that it could become an economic source of pyrite to be used for the manufacture of sulfuric acid. Iron sinter resulting from the roasting of the ores could be sold at a premium in the Birmingham, Ala., area, and the copper content could be extracted to help replace the nation's depleted resources of this metal.

Jan 1, 1949

By Carlton E. Brown

Brown and Yant6/ recently described a microprojection method for determining the particle-size distribution and number concentration of samples of dust collected from the air by such samplers as the Owens jet dust counter7/ and the thermal precipitator8/. This method was developed to obviate or reduce the eyestrain consequent to the regular filar-micrometer method9/ and to save time and work. The article stated that work was in progress on a microprojection method for courting impinger dust samples; this article describes the method developed. ACKNOWLEDGMENTS The assistance of the personnel of the Ventilation Department of the Anaconda Copper Mining Co., Butte, Mont., in developing this method and particularly in suggesting a suitable material to use for the microprojector screen is sincerely appreciated. Much of the work was done in the laboratory of the Anaconda Copper Mining Co. on samples collected in Butte mines during a cooperative study with this Bureau.

Jan 1, 1938

By J. E. Pahlman

The Bureau of Mines performed research on a fluid-bed magnetic roasting process for nonmagnetic taconites that utilizes low-rank coals and lignites as reductants and fuels. Roasting tests on a Michigan nonmagnetic taconite were conducted at 600° to 725° C with lignite or subbituminous coal as reductants. Partial combustion of the reductant reduced the amount of heat externally applied to the reactor to maintain the desired reactor temperature. Cleaned, dried reactor top gases were recycled to recover a portion of the reducing potential in these gases without adversely affecting concentrate grade and iron recovery. Highest iron recoveries for magnetic concentrates were obtained at a roast temperature of 650° C with lignite and at a roast temperature of 725° C with subbituminous coal. Magnetic concentrates were obtained that were comparable with commercial concentrates.

Jan 1, 1976

By G. L. Gates

Five possible sources of water for waterflooding of petroleum reservoirs in the arid San Joaquin Valley of California were considered. Three of them (water produced with petroleum, water from a shallow saline aquifer, and waste irrigation water) were analyzed chemically; laboratory information for one (sea water) had been developed during a previous study. A series of laboratory tests made on the fifth source (fresh water) determined the solubility of calcium sulfate dihydrate in water. Laboratory analyses included the following: Chemical analyses of water produced with petroleum and waste irrigation water; solubility of calcium sulfate dihydrate in water and brines; the effect of excess sulfate on the solubility of calcium sulfate in brines; the presence of sulfate-reducing bacteria; and the permeability of cores from a petroleum reservoir to air, to water from other petroleum reservoirs, and to waste irrigation water. The results showed that most of the waters and mixtures of waters are compatible with petroleum reservoir waters and are generally suitable for injection. The calcium content of some of the formation waters is quite high, and care must be taken to prevent precipitation of calcium sulfate dihydrate. The permeability of the few cores tested was about the same to water and brines as to air, indicating that formation damage due to clay swelling will not be serious. The waters most likely to be available for injection are water produced with petroleum, water from shallow saline aquifers, and waste irrigation water.

Jan 1, 1970

By Charles L. Kimbell

Comprehensive data on market prices for crude minerals and mineral products for the world as a whole do not exist, and even the data that are available are not necessarily compatible between countries, particularly between the market economy countries and the centrally planned economy countries. Further, it should be evident that the actual delivered price for a small quantity of any specific commodity at some point substantially removed from a production facility or a seacoast port will differ appreciably from that for a large volume of the same product at or near its production source or a major import center. Nevertheless, the regularly published prices of selected major mineral commodities in key market areas can be regarded as indicative of general world price trends.

Jan 1, 1992

By J. C. Franklin

The Spokane Mining Research Center of the Federal Bureau of Mines is placing major emphasis on chemical stabilization as part of the ground support program. Development of polymeric material suitable for bonding rock fractures around the mine opening is one phase of the program. Some of the problems that must be considered are viscosity, applicability, adhesion, cure times, strength, toxicity, and flammability. Epoxies and polyesters were investigated, but shrinkage in polyesters caused redirected effort toward epoxies. Test results with the latter showed that bonded fractures in mine-roof strata were stronger than the virgin rock. Further tests showed that polymeric materials have good potential for bonding, and in conjunction with polymer roof bolts, are expected to result in an economic and useful new support concept.

Jan 1, 1974

By W. M. McKewan

This U.S. Bureau of Mines report discusses wire ropes used for hoisting in U.S. mines. The in-formation presented was extracted from a large body of data compiled by the U.S. Mine Safety and Health Administration (MSHA) using a data base management system (DMS). Further, these extracted data were then manipulated to provide tables of data that show the types and amount of wire rope used for hoisting. This report describes the different types of wire ropes and how a DMS can be used to manipulate MSHA's wire rope inventory data. The data indicate that more 1-1/4-in-diam ropes, 6x27 construction ropes, and right lang lay ropes are used in U.S. mines than ropes of any other diameter, construction, or lay type.

Jan 1, 1991

By William C. McLaughlin

In the deep vein mines of the Coeur d'Alene mining district, rock bursts are a potential hazard to the mine structure and underground personnel. Damage repair costs are estimated by one company to exceed $1 per ton of ore mined. The Bureau of Mines, in cooperation with the mining companies, has conducted research intermittently over the past 10 years to help reduce bursts. Onsite inspections of major rock bursts were conducted, and reports were submitted to mine management; these included the geology and geometry of the affected area. The paper discusses the development and improvement of microseismic and surface monitoring equipment. The underground microseismic network, when operated on a regular basis and the results plotted daily, is capable of detecting stress concentration in certain areas. The surface seismographs record rock bursts, blasts, earthquakes, etc., throughout the district and show approximate location, time, and relative intensity of the event.

Jan 1, 1976

By William J. Campbell

These investigations were undertaken as part of a program to determine the optimum X-ray spectral lines to use for analyzing the wide variety of samples received by the X-ray Laboratory. Theoretical calculations and experimental data derived from these investigations show that longer wavelength spectral lines, > 2A, are very useful for many analytical problems. Because of the low fluorescence yield of the elements of atomic numbers 13-22 and the small depth of penetration of their X-ray spectral lines, these elements were originally considered to be insensitive; however, these studies show that the wide dispersion of their spectral lines, coupled with their weak beta lines, permits the use of wide collimation, thus increasing the line intensity. More importantly, the background due to scattered primary radiation is very low in the long-wavelength region.

Jan 1, 1959