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By G. L. Oldright

"The various districts in the United States where complex lead-zinc ores occur are too well known to require description, there being hardly a mining State with any large amount of ores of either metal that is free from this problem. This paper briefly presents developments in the volatilization process, as applied to the treatment of such ores, since the data in Bureau of Mines Bulletin 211** were published. In that bulletin, among the many types of ore treated, examples are given of the treatment of lead-zinc ores by the chloride volatilization process for the separation of lead. An outline of the general process, with views of the rotary kiln, ore feeder, firing system (these three features resemble closely those of cement-kiln practice), dust chambers, and a Cottrell precipitator to remove the fume from the gas, are also shown in that bulletin, to which the reader is referred for the results obtained, and for practical details of operation. The small initial cost of a volatilization plant, and its adaptability for use in isolated districts were emphasized.In general, it was found that when an intensely oxidizing atmosphere was maintained in the furnace, a good lead-zinc separation could be made. Therefore, a heavy sulphide ore would have to be preroasted, and enough air would have to be admitted to obtain complete combustion of whatever fuel might be used.The work done by private companies and the bureau since the data for Bulletin 211 were obtained, indicates that the ores most immediately amenable to treatment by volatilization are of two types. The first is an oxidzed lead. silrer ore whose variable lime content makes it impractical to chloridize the ore for acidulated brine leaching, and whose base metal content makes treatment by cyanidattion unfeasible, The second type is the lead-zinc ore mentioned above, and is the one on which data are available for publication at present. This article Chows what ores of this latter type are amenable to treatment by volatilization, by giving briefly some of the more important physical and chemical properties an ore should preferably possess. Several examples are given from both laboratory experimental work, and from practice in the field, showing various phases of the volatilization process."

Nov 1, 1923

By Virgil J. Stachura

The Bureau of Mines conducted a series of delayed blasting experiments at a West Virginia contour coal mine that resulted in smoother highwalls. The 17; were smoother due to reduced overbreak and inherently safer A, to reduced likelihood of rockfall. Reduced overbreak was accomplished by an increase in the highwall hole delays, which changed the effective delay pattern geometry and the direction of burden movement. The blast delays in the highwall holes were 50 to 100 ms longer than the mine's nominal design pattern (flat V, 17- by 42-ms surface delays, 200-ms in-the-hole delay). The burden movement was effectively changed from a 45* angle to 90* with respect to the highwall. The results of the blast delay changes were evaluated using terrestrial photogrammetry to generate vertical profiles at regular intervals. This evaluation showed that delay changes produced generally smoother vertical profiles.

Jan 1, 1984

By Noel N. Moebs

The coal wants at the Westland Mine in southwestern Pennsylvania consist chiefly of elongated, sandstone-filled channels with slickensided basal contacts. Tentatively identified as washouts, these channels are about 1,000 feet long and 300 feet wide, are erratic in occurrence and trend, and are difficult to delineate from the customary core drilling pattern. Roof conditions are hazardous adjacent to the washout contact, but roof stability is generally unaffected greater than 30 feet away.

Jan 1, 1981

By L. E. Schultze

The Bureau of Mines devised a technique to recover a Zn-Pb concen-trate from a geothermal brine. More than 99 pct of the Zn and Ph was precipitated by treating the brine with H2S and controlling the pH with lime. Recycle of the sulfide precipitates increased crystal size and resulted in easily filterable products. A typical sulfide precipitate contained 53 pct ZnS, 8 pet PbS, 24 pct MnS, and 15 pct FeS. Addition of sulfide as FeS or CaS was not effective in precipitating Zn and Pb, but Zn in the brine was selectively removed with a strongly basic ion-exchange resin. A proposed flowsheet for metals recovery is discussed.

Jan 1, 1985

By J. E. Hipp

Three electrostatic field sensing proximity warning devices were tested using full-scale cranes and power line systems, a scaled model facility, environmental testing facilities, and theoretical/numerical analysis. The design objective of each device is to assist in safe crane operation near overhead power lines. Several design deficiencies (varying from device to device) were observed, including inadequate overlap in sensitivity ranges, utilization of vacuum tubes and electro-mechanical parts, temperature sensitivity and inaudible alarms. In addition, the testing showed major device limitations including sensitivity to boom orientations and length, polarization dependent responses, and unreliable operation in the presence of multiple power line circuits. The multiple power line circuit problem is intrinsic to electrostatic sensing devices. The remaining deficiencies and limitations are correctable within a state-of-the-art design. This investigation is not intended to evaluate the safety aspects or policy of utilizing proximity warning devices. Rather, the purpose is to determine the performance characteristics of such devices in relation to the criteria specified in proposed MSHA regulation 77.805-4 (i. e., the devices must alarm at a distance of 10 feet from the power line).

Jan 1, 1980

By J. D. McLenegan

The purpose of this investigation was to prepare a market survey of the refractories industry in California and Nevada (referred to in subsequent paragraphs as the region), and to determine the degree of self-sufficiency and the potential capacity for anticipated growth. The report includes estimates of the total annual refractories consumption, the quantity of refractories imported into the region, the tonnage of raw materials required for their manufacture, and the resources of fire clay and high-alumina minerals in the region.

Jan 1, 1956

By R. K. Koch

The normal spectral emissivities of liquid Ti, V, Zr, Mo, and Pt were determined at the fusion temperatures in an electron-beam furnace using a water-cooled copper hearth. The normal spectral emissivities were estimated above the melting points by using adjusted two-color temperatures as approximations of the true temperatures for substitution in Wien's equation. Simultaneous brightness temperatures were determined with a micro-optical pyrometer. The true temperature ranges covered were 1,668° to 1,885° C for Ti; 1,919° to 2,013° C for V; 1,855° to 2,367° C for Zr; 2,610° to 2,751° C for Mo, and 1,772° to 1,990° C for Pt. The spectral emissivities for titanium and zirconium decreased with increasing temperature. At an effective wavelength (?) of 658 mµ the emissivity of titanium ranged from 0.51 to 0.45 and zirconium, from 0.47 to 0.41. The emissivities of vanadium (? = 658 mµ) and molybdenum (? = 657 mµ) were constant at 0.41±0.02 and 0.33±0.01, respectively. The spectral emissivity of platinum (? = 658 mµ) was constant at 0.39±0.02 up to 1,900° C; above that temperature anomalous data were obtained. A mass spectrometric study indicated that platinum was reacting with back-streaming silicon vapors from the diffusion pump when the ambient pressure was greater than 2 X 10-5 torr.

Jan 1, 1973

By J. M. Singer

The Bureau of Mines investigated the threshold of dispersal of monolayers and piles of rock dust, anthracite, and Pittsburgh seam coal dust in a small wind tunnel that simulated a coal mine gallery, with the objective of preventing or limiting the formation of flammable dust clouds. The effect of selected variables on entrainment velocity was examined. Mode of entrainment and flow processes in the wake region of dust configurations were investigated by means of high-speed motion pictures. Significant results were as follows: 1. Local minimum air velocities required for dispersal were only slightly higher for shallow dust ridges than for dust particles. 2. Minimum velocities for entrainment of dust particles from smooth glass and coal surfaces increased in the order rock dust, anthracite, Pittsburgh seam coal. 3. The mechanism for dispersal of dust poles depended significantly on dust pile geometry, cohesiveness of dust, bulk density and compaction of dust, adhesive surface, and vibrations perturbing the supporting surface.

Jan 1, 1969

By John F. Papp

International and U.S. chromium material flow, losses, and environmental releases and transfers from mining through industrial processing, end use, and recycling are identified and quantified. Average (1983-92) U.S. consumption has been: metallurgical industry, 87 pct; chemical industry, 10 pet; and refractory industry, 3 pct. Average chromium content of aluminum, cobalt, copper, nickel, and titanium alloys and alloy, carbon, and stainless steel alloys was estimated. Anthropogenic chromium consumption was estimated for the cement and copper industries. N on-commodity cycle anthropogenic chromium mobilization resulting from U.S. fuel and fertilizer use was estimated. Commodity cycle anthropogenic world chromium loss from mining and primary consumer industry was estimated to be equivalent to about 56 pct of chromium contained in chromite ore production and represented a loss rate of 181 kt-Cr/Mt-CrOre. Chromium released to the atmosphere from natural and from anthropogenic sources were comparable in magnitude. Chromium released to soil was mostly from anthropogenic sources, and aquatic releases were all anthropogenic. Domestic product chromium losses exceed process losses by more than a factor of 10 showing the importance and potential environmental impact of post-consumer recycling. The location of historical and current domestic chromium industry processing sites in 23 States were reported. Chromium releases and transfers to the environment were estimated from 1973 through 2002 by primary consumer industry. A decrease in chromium releases and transfers to the environment was anticipated.

Jan 1, 1995

By J. M. Kuchta

Concentrated hydrogen peroxide (H202) is a highly reactive oxidizing agent that liberates heat when it decomposes. The heat liberated may be sufficient to ignite combustibles with which the peroxide comes in contact. For this reason, concentrated hydrogen peroxide should be handled only by personnel familiar with its many unique properties.6 Hydrogen peroxide is used as a bleaching agent in the manufacture of textiles; this is its major single use in the United States. It is also employed as a reagent in chemical synthesis, as a source of free radicals to start polymerization, as a foaming agent in the manufacture of porous substances, and for its effect on biological processes. Moreover, highly concentrated hydrogen peroxide is a compact source of energy that can be utilized both as a monopropellant and as the oxidizer in a bipropellant system, During World War II, large quantities of highly concentrated hydro- gen peroxide were used as propellants, particularly in Germany. Since then, production of the peroxide has increased rapidly; in the United States alone it has more than doubled since 1950.7 Because of its widespread use, increasing interest has been shown in the hazards of handling the high- strength peroxide.

Jan 1, 1961

By R. C. Diehl

Coal, fly ash, and flue gas samples were analyzed for mercury (Hg) by double gold amalgamation-flameless atomic absorption spectrophotometry. The purpose of the study was to elucidate the fate of the trace mercury in the coal when the coal is burned. Samples were collected from a bench-scale 100-g/hr combustor, a 500-lb/hr combustor, and three coal-burning powerplants. In all cases mercury was found in the fly ash. The amounts ranged from about 9 to about 70 percent of the mercury in the coal that was burned.

Jan 1, 1972

By A. B. Pederson, G. E. Bartlett

As a part of our study of how coal mine dusts injure the lung we have studied the effects of dusts and dust-exposed pulmonary alveolar macrophages (PAMs) on the growth of lung fibroblasts (LF). Fibroblasts were cultured near confluence in low-serum medium, either alone or in the presence of dusts, dusts plus PAMs, dust leachates or superriatants of dust-exposed PAM cultures. We report here provisional conclusions, based on initial observations. Rat LF were relatively unresponsive to direct effects of dusts, showing weak stimulation in only a few cultures, and there was no evidence that dust-exposed rat PAMs had released any growth-regulatory products. In contrast, guinea pig cells were more responsive to the dusts. The pattern of responses was quite complex. Three of the dusts stimulated LF directly (with no mediation by PAMs). Two dusts were essentially inert when added directly to fibroblast cultures, either with or without PAMs, but their leachates were active: 867 leachate was inhibitory and RF leachate was stimulatory. Dust 1361, either directly in the cultures or as an aqueous leachate, was stimulatory, and it activated cocultured PAMs to stimulate LF growth; however, supernatant products of 1361-stimulated PAMs were inhibitory. Direct exposure to 1192 stimulated LF, but its leachate was inert; cocultured PAMs exposed to 1192 had weak stimulatory effects, but supernatants of 1192-exposed PAMs were mildly inhibitory. MP3-3 had effects similar to 1192, except that the cocultured, dust-exposed PAMs had no effect on growth. We conclude 1) that guinea pig lung cells are more responsive to dusts than are rat lung cells, 2) that dusts can influence growth of LF by four kinds of interaction (by direct dust-cell interaction, by release of soluble dust components into the culture medium, by activating P AMs to exert direct cell-cell interactions, and by activating P AMs to release growth regulatory products into the culture medium), 3) that each kind of interaction may be neutral, inhibitory or stimulatory, depending on the dust tested, 4) that four of the dusts tested were neutral, inhibitory or stimulatory, depending on the assay (the fifth <lust was either neutral or stimulatory), and 5) that the effects of soluble mediators (leachates or products of activated PAMs) frequently did not correspond with the direct dust-cell or PAM-fibroblast effects. These results suggest that the nature of the dust-lung interaction at the level of cells and molecules is exceedingly complex. These observations need to be confirmed and extended to determine what characteristics of the dusts determine the nature of the cellular responses, and to determine which patterns of responses are detrimental and which are beneficial in the overall health of the dust-exposed lung.

Mar 1, 1989

By R. J. Leary

Oxidation testing of copper-clad steel strip was performed in a muffle furnace to determine whether copper in contact with steel scrap could be removed by oxidation in an airstream at high temperatures. Substantially all of the copper was oxidized before any significant iron oxidation occurred. The rate of copper oxidation was not affected by contact with iron. Copper oxide scale separated spontaneously from the underlying metal during cooling. Results indicate the possibility of removing light-gage copper coatings and components from ferrous scrap by oxidation in an incineration process.

Jan 1, 1965

By A. B. Hooker

[Permissible electric cap lamps represent a workable balance between the amount of light needed and the various limiting conditions, such as the weight the miner can carry conveniently, cost of the lamp, including upkeep, and adequacy or practicability of the lamp as regards safety, mechanical strength, and general performance. Other things being equal, the coot desirable lamp is one that gives the greatest amount of useful light. Conversely, with a given amount of light the most desirable lamp is one that its the most efficient respecting weight, cost, and performance.]

Jan 1, 1935

By D. H. Platt

Gypsum and gypsite, used in the manufacture of plaster and plaster products, have been mined from deposits near Acme, Hardeman County, Tex., for more than 30 years. The Certain-toed Products Corp., 120 East Lancaster St., Ardmore, Pa., operates the Acme, Tex., mine. Underground hauling was done with storage-battery and Diesel-electric-powered shuttle cars. Many mining companies and individuals have manifested interest in all types of equipment powered by Diesel or Diesel-electric units, as attested by the recent increase in use of Diesel-powered equipment in underground metal and nonmetal mines. The purpose of this paper is to describe the manner in which a storage battery-powered Joy Model 60D2 shuttle car was converted to Diesel-electric power. The conversion was made, at the instance of the operating company, by Stewart & Stevens on Services, 4801 Lemon Ave., Dallas, Tex. This is believed to be the only such converted shuttle car in use.

Jan 1, 1950

The panic bars (and associated linkages and electrical circuitry) that are defined in this document are a machine operator-actuated control for the emergency deenergization of the tram motors on self-propelled, electric and diesel face equipment; including haulage equipment such as shuttle cars. There are nine basic types of panic bars (and several variations) that are recommended in this document, but all of the panic bars arc characteristically of the &apos;fire door" type that is frequently encountered on outside exit doors of many public, and some commercial buildings. It is also the intent of the following panic bar designs that, when emergency brakes arc added to the face equipment machinery for which they arty required, that they be designed and hooked up so that actuation of the panic bar will result in automatic application of the emergency brakes (immediately following the deenergization of the tram motors). The following panic bar design requirements are a restatement of the proposed requirements defined in the Federal Register, requirements cited in "Guidelines for the Design and Installation of Devices for Deenergization of Self-Propelled Electric Face Equipment/Automatic Emergency Brakes" by C. E. Lester and J. D. Greenhalgh of MESA, and Bendix recommendations that were formulated as a result of discussions with personnel at the various machine manufacturers and underground coal mines that we surveyed, discussions with G. I. Judy (our consultant), etc:

Jan 1, 1974

By S. H. Lorain

This paper is one of a series on mining and milling method and costs being published by the United States Bureau of Mines. The Golden Messenger mine, operated by the United Gold Mines Corporation, is in the York-Confederate Gulch mining region in Luis and Clark County, Mont., 22 miles northeast of the city limits of Helena and about 1 mile north of the town of York. It is the first operation to exploit successfully the low-grade ores of the York-Confederate Gulch area. The unusual vein structure presents some mining problems that have been solved in ail interesting manner.

Jan 1, 1937

By R. R. Sayers, W. J. McConnell

"The health, comfort, and efficiency of men engaged in the mining industry may be impaired, in some instances very seriously, by abnormal physical conditions of the mine air or by variations in its composition. This is true in some of sheet metal mines of the West where high temperatures with varying humidities are encountered. Physiological studies have been made in some of these mines showing the effects of various temperatures end humidities. As it is difficult to carry out studies on many controlled temperatures, it was thought best to make the experiments in a laboratory and apply the results to the industry insofar as practicableThe effects of moderately high temperatures and humidities are more difficult to measure perhaps than the extreme conditions, but may be predisposing causes of fatigue, discomfort and disease, A cooperative study of the physioloical effects of heat and humidity is being conducted by the Bureau of Mines and the U. S. Public Health Service cooperative with the American Society of Heating and Ventilating Engineers, in the Research Laboratory of the Bureau of Mines at Pittsburgh, Pa."

Mar 1, 1924

By Edwin M. Murphy

Methods are described for filling underground cavities remotely with dry material pneumatically injected through a borehole to seal openings, prevent air movement, and reduce subsidence; this often brings underground fires under control by limiting the access of air. Large-scale tests were made in the Bureau of Mines Experimental Coal Mine, Bruceton, Pa., in an operating mine, and in an abandoned Pennsylvania mine. Supplemental trials were made aboveground in galleries and in the laboratory. The parameters studied include horizontal and inclined passageways, obstructions in the entry, water leakage into the borehole, dry material, and grout and slurry mixes. The materials studied were fly ash, crushed and pulverized limestone, and sand. Best results were obtained with dry fly ash, though satisfactory seals were obtained with the other materials. When a borehole is dry and ends at an open void, casing is not necessary. If more than 5 gpm of water flows in the borehole, if the void contains loose debris, or if coarse material is injected, a material feedpipe should be inserted through the borehole. Fly ash was most suitable for remote filling because of its low angle of repose (8°) and its good flow characteristics. The depth of borehole through which the fly ash is injected has no appreciable effect on the filling operation.

Jan 1, 1968

By Jon K. Ahlness

The Bureau of Mines investigated technologies for testing the integrity of in situ leach mining wells, as required by environmental regulations. To test for leaks, inflatable packers were used to seal the well casing. Laboratory testing determined that the packers could contain a casing pressure up to 50 to 60 psi (345 to 414 kPa) less than the packer inflation pressure. Single-and double-packer configurations were successfully field-tested in 32 wells ranging from 500 to 530 ft (153 to 162 m) in depth. A rigid pipeline and a hoist truck were used to run the packers in and out of the wells for the double-packer tests, which averaged 2-1/4 h each. In an effort to decrease the time of the rigid-pipe double-packer test. a self-contained trailer-mounted test system was designed and built. It utilizes a winch and steel cable to run the packers in and out of the well and high-pressure nylon tubing for packer inflation. This system was successfully field-tested in eight wells averaging 650 ft (198 m) in depth and resulted in a time savings of 13 pct and an operator-hour reduction of 42 pct.

Jan 1, 1985