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By Robert E. Barieau

General expressions for evaluating various thermodynamic properties applicable to the van der Waals equation of state have been derived. These formulas were subsequently used to evaluate various thermodynamic functions in the two-phase region. The results indicate that, for a van der Waals fluid, there is a finite discontinuity in the second derivative of the vapor pressure curve, in the second derivative of the chemical potential or Gibbs free energy at the critical point, and in the heat capacity at constant volume measured at the critical density. Numerical values are tabulated and graphs are presented for all functions calculated.

Jan 1, 1967

By Arnold M. Lansche

[Selenium and tellurium are rare elements in the earth's crust. Their scarcity and primary dependence of supply on copper and lead output are in consonance with the relatively small quantities consumed at 1964 level. Production depending on output of copper and lead creates a supply situation- which would appear to militate against development of large-scale usage of these elements. However, supplies have adequately met. demand in the past decade and can be increased substantially if warranted by new uses for either selenium or tellurium Ores of copper and lead re the principal sources of selenium and tellurium. Byproducts from the smelting and refining of copper and lead concentrates are incorporated in refinery anode slimes from which selenium and tellurium metal are recovered.]

Jan 1, 1967

By A. B. Campbell

The mines in the eastern part of the now active region of the Tri-State zinc district of Missouri, Kansas, and Oklahoma have unusually acid water, which during periods of moderate or no rainfall As used in the mills to replace losses from evaporation, seepage, and tailings disposal. Its use has caused difficulties by corrosion of equipment and by interference with flotation. The growing importance of flotation- Which requires good water, and the increasing troubles caused by the corrosion of the milling equipment have prompted the Mississippi Valley Experiment Station of the United States Bureau of Mines, in cooperation with the Missouri School of Mines and Metallurgy, Rolla, Mo., to investigate the action of the waters on flotation and to undertake to develop means of obviating their harmful effects.

Jan 1, 1932

By K. K. Kelley

The entropy values at 298.1° K. for the elements and inorganic compounds, on which sufficient data were available for calculation in 1931, were discussed in a previous publication (96).3 Since that time the specific beats at low' temperatures of many more inorganic substances have been determined, and considerable advances have been made in the realms of spectroscopy applicable to the determination of thermodynamic properties. Moreover, a critical study of the existing vapor-pressure data made by the author (98) furnishes entropy of vaporization results suitable for obtaining approximate values of the entropies of a number of gases from the entropies of the solids or liquids. Consequently, it appears worth while at the present time to supplement the former publication, giving the new values now obtainable and making such revision in the older values as the data warrant. The methods of calculating entropies were discussed in previous publications (96, 98) and will not be repeated here. ENTROPIES AT 298.1° K. FOR INORGANIC SUBSTANCES In the following pages, the same arrangement is followed as in the previous publication (96). All entropy values are expressed in 15° gram-calories per degree Kelvin per gram-formula mass of substance. The figures given for gases do not include the effect of nuclear spin, as is nearly universally customary at present. The estimates of accuracy in the case of the values obtained from heat-capacity data apply only to the existing measurements and to the necessary extrapolations as they are made. It is assumed usually that the substances are in such an energy condition at the lowest temperatures reached in the specific-heat measurements that the usual normal type of extrapolation may be made. No allowance is made for error in this assumption. The recent work on Gd2SO4. 8H2O and FeC13 illustrates the difficulties that may arise in obtaining the entropies of some paramagnetic substances. Also the data and calculations for such substances as CO, H20, and N20 show that the correct entropy is not obtained in all cases by indiscriminate application of the usual

Jan 1, 1936

By J. A. HUFF, V. V. BAKER

This circular is intended to present in brief form the statutory provisions of Pennsylvania regarding mining operations, in force at the end of the 1931 session of the legislature. lo reference is made to general laws which affect mining only incidentally in common with other subjects, such as the workmens compensation law. The statements have been condensed as far as practicable, and provisions not deemed of general interest, such as matters dealing only with administrative details, have been omitted. This circular obviously is not written with such particularity as to be of great value to the legal profession, but it is hoped that it will be beneficial to the mining industry in giving this information in a relatively compact form. At the end of each paragraph the statute from which it is derived is cited to facilitate reference to the text of the law. It is planned to publish additional circulars from time to time dealing with the mining laws of other States. Any criticisms of the form of publica- tion followed herein, or suggestions aimed at the improvement of future circulars, will be welcomed.

Nov 1, 1932

In 2005, a total of 7,111 sand and gravel mining operations reported employment to the Mine Safety and Health Administration (MSHA). ? Sand and gravel mines were the largest mining sector, comprising 48.5% of all mining operations. ? Sand and gravel mines were found throughout all 50 states and Puerto Rico.

Sep 1, 2008

By Gilbert L. Forst

The objective of this program is to identify and evaluate superior, lightweight substitutes for selected coal mine roof support concepts such as crossbars, posts, and crib blocks. Engineering analysis and concept design identified, through tradeoff studies, that some materials are promising, from a technical standpoint, as support substitutes: E-glass reinforced polyester resin, high strength low alloy steel, aluminum, and very high early strength (VHE) cement. An economic analysis indicates that none of the lightweight substitutes are economically competitive with wood on an initial cost basis; however, in terms of life cycle costs based on current dollars, the high strength low alloy steel appears competitive for crossbars, and the VHE cement and E-glass/resin appear competitive for posts.

Jan 1, 1978

By D. A. Elkins

Design plans and detailed cost estimates of mining and treating ore from Maggie Canyon deposit by two alternative methods which can be used in the event of a sudden need to exploit this resource are given . Lower costs are estimated for the operation employing oil - emulsion flotation . The total capital investment required for this operation is estimated at $ 11,750,000 . Assuming an 85 percent recovery in mining , 55.6 pct of the manganese in the ore reserve would report in 153,333 tons of ferromanganese containing 75 pct manganese . The production cost for the 5 - year operation would be about $ 245 per ton of ferromanganese . The total annual operating cost would be approximately $ 7.5 million , distributed , in pct , as follows : Mining 11.9 , milling 24.4 , sintering 9.9 , smelting 47.2 , hauling ore and sinter 2.8 , and general offices 3.8 . Recovery and costs are both higher for the operation employing dithionate leaching . In this operation the required investment is about $ 17,220,000 . Manganese recovery would be 67.6 pct in 186,160 tons of ferromanganese . Production cost would be about $ 284 per ton of ferromanganese . The total annual operating cost would be about $ 10,575,000 , distributed , in pct , as follows : Mining 8.4 , milling 44.4 , sintering 7.4 , smelting 34.7 , hauling ore and sinter 1.3 , and general offices 3.8 . Potential process modifications might reduce the operating cost of the first operation by as much as 7 pct and that of the second operation by as much as 9.5 pct , but exploitation of the deposit by the techniques studied is not economical today .

Jan 1, 1964

1. Domestic Production and Use: In 1982, 13 companies operated 30 primary aluminum reduction plants, with 3 firms accounting for 55% of production. Washington, Oregon, and Montana accounted for 34% of the production; Texas, Louisiana, Missouri, and Arkansas 18%; Tennessee, Alabama, South Carolina, and North Carolina 14%; other central and eastern States 34%. Based on published producer prices, output of primary metal in 1982 was valued at over $5.5 billion. Aluminum consumption by 25,000 firms was centered in the East Central United States. Packaging accounted for an estimated 39% of domestic consumption in 1982, transportation 20%, building 14%, electrical 8%, consumer durables 8%, and other uses 11%.

Jan 1, 1983

By K. J. Liles

The U.S. Bureau of Mines evaluated the physical properties of ceramic particulate composites made from titanium nitride (TiN), alumina (AI203), and aluminum nitride (AlN) as part of a program to meet the high-performance demands on structural materials for new and emerging technologies. Samples containing from 20 to 80 wt pct TiN were pressed and fired, and their composition, Vickers hardness, modulus of rupture (MOR), and fracture toughness were determined. X-ray diffraction and scanning electron microscope (SEM) analyses showed that, depending on the amount of TiN added, the microstructure of the samples consisted of either a titanium-aluminum-oxynitride (TiAlON) particulate in a spinel matrix or a spinel particulate in a TiAlON matrix. The best results of the physical tests were achieved on a mixture of 40 wt pct TiN, 30 wt pct A1203, and 30 wt pct AIN. Sintering aids were added in 1-and 3-mol-pct increments to the 40-30-30 mixture to determine their effect on microstructure and physical properties. Results of an analysis of variancf' on a 4 by 4 factorial analysis showed significant effects on density, MOR, and Vickers hardness.

Jan 1, 1989

By G. R. Hopkins

A fifth successive record in fuel efficiency was established by the petroleum-refining industry in 1937, when the average heat requirement per barrel of crude oil run to stills was 554,000 3. t. u. compared with 597,000 3. t. u. in 1936. These amounts represent roughly the heat ob¬tainable from a tenth of a barrel of fuel oil (see fig. 1). Innumerable factors can influence heat consumption at rep aeries, but only a few are important enough to be subject to statistical measurement. Foremost of these is the ratio of runs to capacity, it being generally recognized that because the fuel demands for other than stills are comparatively inelastic, total heat requirements do not increase in direct proportion to crude runs. Thus, in 1937, crude runs of 1,183,440,000 barrels wore 11 percent higher than in 1930; the average operating ratio was 93 percent compared with 79 percent in 1936; but the total heat requirement increased only 4 percent, or from 639,149 billion 3. t. u. in 1936 to 663,966 billion 3. t. u. in 1937.

Jan 1, 1938

By David C. Grant

A laboratory technique for simulating in-situ uranium mining was developed and used to determine the effects of leaching variables on permeability, uranium recovery, leach solution interaction with the ore-aquifer environment, and post-leach chemical leakage. In particular, ammonium bicarbonate, the commonly-used leach solution, was examined in great detail. Agitation leach tests were conducted to examine the effect on ammonium sorption and desorption of clay content, solution and clay ammonium levels, pH, and the type and concentration of other anions and cations in solution. Initial column tests were performed to determine the degree of ore-aquifer interaction that could be expected for various leach solutions; sulfuric acid, and ammonium, sodium, and potassium bi-carbonates. Subsequent tests examined various methods to restore the ores by lowering the post-leach chemical leakage. The restoration tests examined the use of reducing agents (e.g., ammonium bisulfite, sodium bisulfite; and sodium sulfite), ore blocking and stabilizing agents (e.g., sodium silicate, aluminum chloride, and magnesium-calcium salt).and ammonium displacement agents (e.g., aluminum chloride and lanthanum chloride-sulfate)

Jan 1, 1980

By C. Daniel Kealy

Finite-element,, mathematical models that solve LaPlace's and Richard's equations numerically were used to locate the phreatic surface within tailings pond embankments and to define the subsurface flow of water from the pond. Both must be known to design structurally and environmentally safe tailings dams. The permeability distribution within and beneath the embankment, the fluid potential values upgradient and downgradient from the embankment, and the geometry and elevation of an approximately impermeable layer at some depth beneath the embankment were used as computer inputs in analyzing over a dozen finite-element models of tailings dams varying structurally from simple to complex. Results predicted with the finite-element model were confirmed with measurements in a laboratory model of a tailings pond and in the field. Of particular importance to the design of safe slopes, all data indicated that the phreatic surface within a tailings dam is concave upward, a configuration opposite that in most earth dams. The close correlation between predicted and experimental values confirmed the practicability of using the finite-element technique to design safe tailings dams.

Jan 1, 1971

By A. F. Robertson

"INTRODUCTION This report is supplemental to R.I. 4178 and deals with the work accomplished between June 15, 1945, and September 7, 1945, on the Mitchell-Hodge mine, Grady mine, Albea and York property, and Cuzzort property.ACKNOWLEDGMENTSIn its program or exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurigcal Branch, O. C. Ralston, chief, analyzes samples and performs benefication tests.Acknowledgment is due Mitchell H. Kline, chief, Raleigh Division, Mining Branch; Abraham L. Fox, acting chief, Raleigh Division, Metallurgical Branch; and Rowe McCrae, district engineers, U.S. Bureau of Mines, Gainesville,"

Jan 1, 1946

This report is a compilation of all information obtained in accordance with the requirements of contracts SO122076 and H0232056. A series of eight coal mines were visited to determine their communications usage and requirements. Presently available equipment was surveyed and evaluated to determine its applicability to the needs of the mines. The equipment studied includes that made by the following companies : Anaconda Telecommunications Division Andrew Antenna Bendix Communications Division Collins Radio Group of Rockwell International Executone Communication and Sound Systems Gau-tronics Mine Safety Appliances Company Motorola Communications and Electronics, Inc National Mine Service Company Plessey Communications Systems Corp Pye Electronics Limited Reach Electronics Set Com Corporation Sonex Incorporated Mine visits and in-depth interviews were made alt the following sites: Robena No. 4, Pennsylvania Greenwich Colliery Mines, Pennsylvania Somerset Coal Mine, Colorado Keystone No. 1, West Virginia Harris Mine No. 1, West Virginia Baldwin Underground No. 1 Mine, Illinois Lovilia No. 4 Coal Mine, Iowa Orient No. 3 Coal Mine, Illinois

Nov 15, 1974

By W. W. Roepke

The Bureau of Mines has developed an interactive computer program that enables mine operators and others to identify the effect of cut-ting system changes on relative dustiness at the face. The program, which simultaneously evaluates machine parameters, coal seam parame-ters, and operator-controllable parameters, was developed for use on any microcomputer using BASIC programming language. The program allows the user to change one or more of the cutting system parameters at a time to see how these changes affect relative dustiness. A complete program listing and flowchart are included along with operating in-structions and sample outputs. An example showing how to use the program is also included.

Jan 1, 1985

By A. N. Baldwin

This report documents work performed under Bureau of Mines Contract J0265029 to study and develop two innovative mining systems: ? An underground auger capable of augering into the right and left ribs without repositioning the machine ? A conventional mining system employing recently developed innovative machinery. The report is separated into two volumes to document the two studies separately. Volume I describes work performed and the recommended concept for a bidirectional auger. Volume II describes the studies of mining equipment performance and mining plane developed to determine a conventional mining plan offering improved productivity.

Jan 1, 1977

Since early July, domestic producer listings in primary aluminum ingot have been at 53¢ per pound. Dealers, however, lowered their August quotes by 1.8¢-2¢ to 47.5¢-48¢ per pound. BITUMINOUS COAL AND LIGNITE -The wildcat strike of UMWA coal miners which began on June 23 in protest of cutbacks in medical benefits appears to have ended. According to the West Virginia Coal Association on September 7, 1977, all mines in West Virginia were back in operation on September 6 and again on September 7. The Kentucky Coal Association reported approximately 2,500 miners were on strike in eastern Kentucky on September 6, but there was full employment on September 7.

Jan 1, 1977

By Charles E. McCarthy

Part 1 of this report is concerned with the electric-furnace production of calcium aluminate and iron alloy from a variety of siliceous ferruginous ores of aluminum. The furnacing research was directed, first, to determine the extent of the field in the CaO-Al2O3-SiO2 system, in which calcium aluminates with the optimum leaching characteristics are obtained; second, to produce suitable quantities of these aluminate mixtures for pilot-plant leaching tests; third, to investigate the physical chemistry of the reduction reactions during furnacing; and, fourth, to study the economics of the process. The third and fourth steps were not completed. Part 2 comprises another phase of the work and will appear as a second Report of Investigations. It deals with the extraction of metallurgical-grade alumina from the calcium aluminate slag produced in the electric furnace and includes the following steps: leaching, desilicating, precipitating, dewatering, filtering, and washing of the aluminum hydrate. No claim is made that the data are complete, nor has the chronological order of obtaining data been followed. Rather, it is emphasized that additional work is necessary if the full possibilities of the process are to be evaluated. and made available.

Jan 1, 1949

By Jr. Sayre

Results of studies of reservoir and wax-precipitation temperatures relating to wax deposition in the reservoir of the Bradford oil field are presented in this report. During 1949 and 1950 Bureau of Mines engineers made temperature measurements in 42 wells, which indicate that the Bradford Third-sand temperatures range from 59.7° F., at 1,150 feet, to 71.9° F., at 2,040 feet. Reservoir temperatures measured at the same depths in newly drilled wells and oil-producing wells differed as much as 4.5u F. Injection-well temperatures measured during water injection showed that the temperature of the water entering the sand was 11.5° F. lower than reservoir temperatures before injection. The cooling in the formation resulting froth the injection of low-temperature water was 11.5° F. in the vicinity of the injection-well bore, and a maximum of 2.1° F. 200 feet from the injection well. Sand temperature, after 5 months of water injection, was reduced 1.5° F. 90 feet from water-injection wells. The temperature at which wax begins to precipitate from solution in crude oil was determined at atmospheric pressure for 26 samples and ranged from 51° to 67° F. Oil samples from wells producing no water had wax-precipitation temperatures ranging from 51° to 58° F. and wax contents from 2.20 to 2.97 weight percent, whereas the samples from wells producing water and oil had wax precipitation temperatures ranging from 580 to 67° F. and wax contents from 2.57 to 3.42 weight percent .

Jan 1, 1952