Search Documents

By R. M. Santmyers

Thorium and cerium are two of the group of elements known as "rare earth metals," and are obtained from the mineral monazite. Previous to the employment of thorium and cerium in incandescent gas mantles these elements were nothing more than laboratory curiosities, as the rest of the rare-earth metals are to-day. The most important salts of these rare earths are the nitrates. In the manufacture of gas mantles, thorium nitrate is the principal ingredient and forms prom 92 to 99 per cent of the impregnating material; the other 1 or 2 per cent is largely cerium nitrate and is quite as necessary, for without it there would be little luminosity to the mantle when in use. When the mantle is "burned off," the nitrates are changed to oxides. The monazite used as a source of thoria contains from 6 to 9 per cent of thorium oxide (Th02) and 24 to 32 per cent of cerium oxide (Ce203). As only the thoria and a very small hart of the ceria from the monazite could be used in gas-mantle manufacture, for a time the residues consisting mostly of ceria with somewhat smaller quantities of other rare earths found no commercial application. Later, however, they came to be utilized in several ways, the most important being: (1) the manufacture of cored flaming arc carbons, a great, irmprovement over the plain arc carbons used in electric lighting; (2) cerium metal used in the manufacture of pyrophoric or sparking alloys or "flints" for automatic pocket lighters and miners' lamps; and (3) the production of special kinds of optical and art glass.

Jan 1, 1930

By D. G. Kuehn

Mass spectrographic studies have been conducted on the positive ions and neutral species of glow discharges containing 1.0 pct S02 and 1.0 pct CO in helium. Measurements were conducted for gas pressures from 3.5 to 10.1 torr using both dc and 60-Hz ac excitation. The ion species that were observed included S+, SO+, SO+, 0+, O2+, C+, CO+, and CO2+ with lesser amounts of SO3+, (CO)2+, SCO+, and (SO?CO)+ or CS+2. Interpretation of the functional dependence of the various ionic and neutral species on pressure and applied power showed that CO reacted with the SO formed in the discharges to produce CO2 and sulfur. Deposition of elemental sulfur was observed in the plasma container.

Jan 1, 1973

By David A. Monaghan

This report describes the results of a 2-year investigation of extensible face ventilation techniques and systems for use at the working face in underground coal mines. The goal was to provide a safe and convenient method of maintaining the extensible system within 10 feet of the face, thereby ensuring good ventilation. A summary of approximately 20 extensible ventilation systems proposed or tried in the past is included for reference, together with a detailed description of the design, construction, and underground testing of a new extensible brattice panel and a new fiberglass duct system. The extensible brattice system utilized a special panel which could be pushed forward as the miner advanced. Brief testing in three mines revealed some conflict with the mining cycle and led to recommendations for two improved designs. The extensible duct system was designed for a Goodman borer and utilized a telescoping tube on the left side of the roof, so that it could be extended without interfering with the miner operator. For mine sections with right-hand return ventilation, a special flat tube section is used to cross over the entry. Underground testing showed substantial improvement in face ventilation without interfering with production.

Jan 1, 1976

By Richard A. Winters

There are no producing or developing mines or active mining claims in the Deschutes Canyon RARE II study area. Only two prospects were found; they have no identified potential for mineral resources. Thin diatomite deposits occur in the Pliocene Madras Formation. Development of sand and gravel deposits in the area could not favorably compete with similar deposits in the surrounding area which are closer to points of use. By mid-1982, active oil and gas lease applications covered about 25 percent of the area, a reduction from nearly 100 percent in early 1981. No holes were drilled for oil and gas exploration. INTRODUCTION Personnel of the Bureau of Mines, Western Field Operations Center conducted a mineral investigation of the Deschutes Canyon RARE II area during the summer of 1982. The area, about 10 mi (16 km) southwest of Madras, Oregon, covers 10,890 acres (4,407 ha) in the Crooked River National Grasslands (fig. 1). The Deschutes River has incised a deep canyon into the north sloping elevated lava plain near the transitional boundary of the High Lava Plains and the Deschutes-Umatilla Plateau geomorphic divisions (Baldwin, 1964, p. 20).

Jan 1, 1983

By Branch of Editorial Services

"The Bureau of Mines was established in the public interest to conduct inquiries and scientific and technologic investigations concerning mining and the preparation, treatment, and utilization of mineral substances; to promote health and safety in the mineral industries; to conserve material resources and prevent their waste; to further economic development; to increase efficiency in the mining, metallurgical, quarrying, and other mineral industries; and to inquire into the economic conditions affecting those industries. The organic act of the Bureau, as amended by Congress and approved February 25, 1913, made it the province and duty of the Bureau of Mines to ""disseminate information concerning these subjects in such manner as will best carry out the purposes of this Act.""In accordance with this directive, the Bureau reports the findings of its research and investigations in its own series of publications and also in articles that appear in scientific, technical, and trade journals; in proceedings of conventions and seminars; in reference books; and in other non-Bureau publications. The number of these reports, the wide range of subjects they cover, and the variety of mediums in which they appear make the kind of list and index presented in this special publication both necessary and valuable. This issue of the Bureau of Mines List of Publications and Articles describes reports and articles published during the period January 1, 1980, to December 31, 1984. It supplements the 50-year list of Bureau publications issued from July 1, 1910, to January 1, 1960;1 the 50-year list of articles by Bureau authors published outside the Bureau from July 1, 1910, to January 1, 1960;2 the 5-year lists of publications and articles from January 1, 1960, to December 31, 1964,3 from January 1, 1965, to December 31, 1969,4 from January 1, 1970, to December 31, 1974,5 and from January 1, 1975, to December 31, 1979;6 and the annual lists of Bureau publications and articles from January 1 to December 31, 1980,7 from January 1 to December 31, 1981,8 from January 1 to December 31, 1982,9 and from January 1 to December 31, 1983. 10"

Jan 1, 1985

By Thomas E. Green

A gas volumetric method was developed for determining metallic aluminum at the 0.01-to 0.3-percent level in 100-gram samples of recycled glass. The method is based on the measurement of the change in gas volume produced by the reaction 2 Al + 2 NaOH + 2 H2O ? 2 NaAl02 + 3 H2 using a simple apparatus assembled from readily available glassware. Apart from sampling errors, the precision of the method is within ±5 percent. A minor modification of the apparatus would extend the method to larger samples or samples of higher metallic aluminum content. Metallic iron and metallic zinc do not interfere at the concentrations found in recycled glass recovered from incinerator residues.

Jan 1, 1971

By William H. Pomroy

The Bureau of Mines, through a 4-year program of combined in-house and contract research, has developed the necessary hardware and software technology to provide rugged, reliable automatic fire protection for surface mining mobile equipment. One element of this program was a continuing effort to help foster rapid mining industry acceptance of the technology by keeping end user costs reasonable. This report is an analysis of the economic impact of surface mining mobile equipment fires and the cost benefit of utilizing automatic fire protection systems to abate these losses.

Jan 1, 1982

By A. S. Griffiths, J. E. Evans

Noise processing experiments with ELF (3 to 300 Hz) atmospheric noise and signals in the 40 to 80 Hz range are described. The primary purpose of the experiments was to record and analyze wideband ELF noise in order to design the noise processing portion of a receiver which minimizes the required transmitter power. The application of appropriate theory and extensive simulations led to a noise processor which consists of the following functions: (1) a compensating (or whitening) filter, (2) a prenotch filter clipper, (3) notch filters at frequencies of manmade interference (e. g., power lines), (4) a post-notch filter clipper, and (5) a phase-coherent linear matched filter. The nonlinear processing provides considerable gain relative to a linear receiver (i. e. , a receiver consisting only of a matched filter and appropriate whitening filters). It is convenient to measure sys tem performance in terms of an "effective noise level" which is equal to twice the received signal energy divided by the signal to noise ratio at the matched filter output. For example, the highest effective noise levels observed at 45 Hz with the nonlinear processor were about -134, -131 and -137 dB wrt 1 amp/m [Hz] using Saipan, Malta and Norway data, respectively, compared to 1 percent exceedance levels of effective noise for the linear receiver of about -115, 115 and -130 dB wrt 1 amp/m [Hz] respectively.

Jan 1, 1973

By C. M. Flynn

The solubilities of sideronatrite [Na2Fe(OH)(SO4)2?3H20] and ferrinatrite [Na3Fe(SO4),&apos;3H2O] were determined by the Bureau of Mines in the Na2SO4-Fe2O3-H2SO4-H20 system at 25°, 40°, 60°, and 90° C. The solution compositions investigated ranged from Na+-Fe&apos;+ mol ratios of 0.5 to >100 (Na2SO4 saturation) and H+ -SO4 2-mol ratios of 0 to 1. O. The results are presented in the form of contour plots. The solubilities were determined by seeding supersaturated solutions of known composition with the specified solid phase to precipitate a substantial amount of solid. Water was then added in small portions to the solution until the last portion of the solid dissolved. Equilibration times at 25°, 40°, 60°, and 90° C were 2 days, 1 day, 8 to 16 h, and 2 to 4 h, respectively. The accuracy of the solubility data is estimated to be 1 to 2 pet. Low iron solubilities of <0.36 pct Fe2(SO4)&apos;, or 1 g Fe/kg solution, were obtained in solutions containing at least 8 pet Na2SO4 in the absence of H2SO4 or a total of at least 36 to 38 pet Na2SO4 + H2SO4 at high acidity. The filterability and density of sideronatrite and ferrinatrite in comparison with other iron compounds are reported. These compounds are suitable vehicles for iron removal in Na2SO4-rieh solutions. Additional solubility data on the Na2SO4-H2SO4-H20 system were also obtained.

Jan 1, 1987

By Linneas W. Laage

The purpose of this report is to document the fire experiments conducted at the Waldo Mine, NM during March 1990. The U.S. Bureau of Mines is concerned with improving and validating the predictive capability of the mine ventilation and fire simulator, MFJRE. To accomplish this, fire experiments were conducted at the Waldo Mine and temperature profiles were developed as functions of time and distance from the fire. These tests then provided data for verifying the heat transfer model in the MFIRE mine ventilation and fire simulator. An initial analysis of this data indicates that it will serve this purpose well. This report summarizes the data obtained during six fire tests at the Waldo Mine.

Jan 1, 1994

By Nabil A. Bibawy

An improved method for preparing gravimetric standard gas mixtures of helium-4 in nitrogen has been developed by the U.S. Bureau of Mines. A single-pan 12-kg analytical balance that has a sensitivity of 3 mg is used to prepare the mixture. The balance will accommodate a cylinder having a volume of approximately 4 L that weighs approximately 5 kg. The method has been improved to a precision of ±O.04 pct by performing four successive dilutions, by improved handling of gases in the manifold, and by using an improved analytical method to select high-purity gases.

Jan 1, 1990

By J. A. Baicker

A prototype borehole probe for ore grade determinations by means of in-situ neutron activation analysis was designed, built, and tested in a two-phase program. Phase I dealt with the design and fabrication of a borehole logging system for operation in 7.6 cm (3 in.) diameter or larger boreholes. It consisted of a 5.06 cm (2 in.) diameter borehole probe containing an intrinsic germanium detector, a canister-type solid cryogen cooling system, cooled FET preamplifier, linear amplifier, high voltage supply, analog-to-digital converter, microprocessor-based multichannel analyzer, buffer memory, bi-directional cable link, power supplies, and a Californium-252 neutron source. A surface support vehicle was designed and outfitted. A minicomputer system was constructed and software developed and tested. In Phase II the system was field tested at several mine sites. The system was calibrated, tested, improved, and demonstrated in a variety of applications. Tests were performed at sites pertinent to uranium, iron, coal, copper, silver and gold. Technical feasibility was demonstrated for all these applications except gold; the gold results were inconclusive. In-situ neutron activation analysis using high resolution gamma ray spectrometry was found to be a potentially viable logging method for are grade analysis under certain conditions.

Jan 1, 1984

By Pedro Lilienfeld

This report describes a program whose objective was to develop, design, fabricate and laboratory-test two prototype instruments capable of real-time selective detection and measurement of airborne fibrous-shaped particles. The operation of this fibrous aerosol monitor (FAM) is based on the rotation imparted to the acicular particles by means of a rotating quadrupole electric field of the order of 3000 V/cm. This field induces a dipole charge separation on the fibers and aligns them with the applied field. The selective detection of the fibers is effected by synchronous detection of the resulting modulation of the light scattered from a continuous-wave helium-neon laser beam by the rotating particles. The theory of operation, design of the electric-optical detection configuration and the electronic signal processing method are discussed. By means of a scattering pulse sharpness discrimination technique, fibers whose length exceed a selectable value are detected and their number concentration digitally displayed. Counting times of 1 to 1000 minutes permit the measurement of fiber concentrations between 0.001 and about 30 cm-3. A concentration of the order of one fiber per cubic centimeter can be assessed within a relative standard deviation of 10 percent with a counting period of 10 minutes. The FAM is a portable, battery-powered instrument capable of operating continuously for about 4 hours between battery charges. Preliminary tests with crocidolite and crysotile asbestos as well as with glass fibers were performed in the laboratory and the results indicate good correlation with the standard NIOSH phase contrast microscopy filter counting method.

Jan 1, 1977

By P. L. Placek

Correlations were made on experimental data for four New Mexico ore series to determine relationships between ore grade and uranium extraction during leaching operations. Such relationships provide information needed to predict the long-range supply of minerals to meet national economic and strategic needs. Results show that other ore constituents and gangue materials in addition to uranium grade influence uranium extraction. In general, tailing grades decrease and uranium extraction increases as both H2S04 and NaCl03 concentrations increase. Terminal emf and terminal pH also were studied. Similar trends appeared for all ores; however, specific combinations of results also were observed for individual ores and ore series. Experimental results indicate that uranium extractions are higher for lower uranium feed grades than predicted by other estimates. Three factors--uranium feed grade, H2SO4 concentration, and NaC103 concentration--were used to design factorial experiments for each ore series. Four additional feed assay factors--V205, Fe, C02, and CaO--were included in regression equations to account for some of the variation in data. The three factorial factors are represented in the regression equations by linear and exponential terms of the form D i&apos;1*G i + Di,2 *e Di, 3*Gi. The four additional assay factors are represented by linear and squared terms of the form Di,*Gi + Di,2*eDi3*Gi. where the Di, ,J are coefficients, the Gi are factors, and the symbol * represents multiplication in computer notation. The interactions of the factors are represented by products of the nonlinear terms for all pairs of the factors.

Jan 1, 1981

By D. Bienstock

The Fischer-Tropsch synthesis is practicable in a reactor where the exothermic heat of reaction is removed by circulating large quantities of recycle gas through a catalyst bed of high-voids content. At an hourly space velocity of 1100, the feed gas, a mixture of 1.5 parts hydrogen to 1 of carbon monoxide, was converted 90 percent, producing hydrocarbons predominantly in the gasoline range. At these conditions a recycle-to-fresh gas ratio of 40:1 was enough to give excellent temperature control with a pressure drop of 1.5 p.s.i. per foot of bed using a steel catalyst in the form of lathe turnings. Steel parallel plates, although offering lower resistance to gasflow, were less reactive and less durable. INTRODUCTION The Federal Bureau of Mines has been engaged in a research and development program since 1944 on the synthesis of gasoline from coal. Gasification of coal with steam and oxygen to yield a synthesis gas--a mixture of carbon monoxide and hydrogen--is being investigated at Morgantown, W. Va.; and the synthesis of gasoline by catalytically reacting the carbon monoxide and hydrogen over iron by the Fischer-Tropsch reaction is being investigated at Bruceton, Pa.

Jan 1, 1960

Case 1: A driller raised a drill rig mast into a 7200-volt overhead power line. Both he and his helper were killed. Case 2: A driller-helper was pulling a winch cable toward a stack of drill steel when the cable contacted a 12,000-volt power line. The helper was killed, and the driller at the rig controls was severely injured. [ ]

Jan 1, 2006

By Llewellyn A. Rubin

ROUTINES AND SUBROUTINES A- 1 Wait Loop (Wait) A- 2 Receiver Processing (RCVP) A- 3 Control Panel Sequence (CPNL) A-4 Interrupt Routine (INTRP) A- 5 Math Processing Routine (PROC) A-6 Input Constants for Math Routine (CONI) A-7 Angle Conversion Routines (LVERT) A- 8 Display Routine (DSPY) A- 9 Message Print Auxillary Routine (MESSO) A-10 Auxillary Subroutines (AFUTC and AGETC)

Jan 1, 1973

By Robert J. Shanley

The computer program, HYBMODE, has been developed to meet the need for a fast and economical method for clustering data points on the sphere. The algorithm used in this development is an extension of D. Wishart&apos;s one-level mode analysis. The program can be used to cluster either vectorial or axial data; it is currently being used by the Bureau of Mines to cluster fracture orientations.

Jan 1, 1974

By C. B. Davison

One goal of the Bureau of Mines is to conserve the Nation&apos;s mineral resources by developing improved performance materials. Consistent with this goal, the Bureau conducted studies on the formation of undesirable cristobalite in seven different fire clays used as refractories. The studies employed scanning electron micrography, chemical and X-ray analyses, and pyrometric cone equivalent determinations to examine the sample clays and determine the effect of thermal history and stablilizing additives on the amount of cristobalite in various calcines. This research has indicated that as fire clay calcining temperatures increased from 1390° to 1,490° C there was a gradual decrease in the percent of cristobalite present in the calcines and a progressive development of mullite crystallization. No cristobalite was found in fire clays calcined above 1,550° C, but cristobalite reappeared when the calcines were reheated to temperatures between 1,400° and 1,500° C. The research also revealed that additions of lithium fluoride (LiF) prevented formation of cristobalite in fire clay calcines.

Jan 1, 1979

By Charles P. Lazzara, Alex C. Smith, Richard W. Pro, Mark W. Ryan

The U.S. Bureau of Mines conducted a study to determine if commercially available automatic sprinklers could withstand the high static pressures in deep underground coal mines without leaking and if exposure to the mine environment affected their leak pressures. New sprinklers and sprinklers exposed to the mine environment were subjected to increasing pressures until leakage occurred. The average leak pressures of the new sprinklers ranged from 640 to 2,300 psig and were significantly different for sprinklers from different manufacturers and for different types of sprinklers. Different for sprinklers from different manufacturers and for different types of sprinklers. Generally, standard-response sprinklers withstood higher pressures than fast-response sprinklers. The results indicated that most commercially available sprinklers would withstand the high static pressures in deep underground coal mines; however, they would not provide the same reliability and safety factor as sprinklers used aboveground at or below their rated pressure of 175 psig. The average leak pressures of the sprinklers exposed to the mine environment ranged from 740 to 1,180 psig. The mine environment affected the ability of 66% of the sprinklers to withstand high static pressure New sprinklers were also evaluated at pressures of at least 500 psig for 30 days to determine their ability to withstand long-term exposure to high static pressures; no leakage was observed.

Jan 1, 1993