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By Tom Snyder, John Brulia

PART 3 – UN Identifi cation Markings for the Highway Transportation in Commerce of Bulk Explosives, Oxidizers, and Combustible Liquids

Jan 1, 2015

By Manuel Gutierrez, Roberto Gomez, Juan Aravena, Johan Gjoevad

The use of explosives in mining operations is a process that involves the search for an ideal explosive for the type of geological condition of the mineral to be extracted. For the explosives present on the market the majority are based on Ammonium Nitrate. This as it is an ideal balance of high energy efficiency achieved with low development of gas emission. The manufacturing and loading operation of the explosive requires multiple process stages and different raw materials, which, if is not correctly supervised and controlled may cause the development of harmful gases or, in the worst case, even toxic gases. The majority of mining operations are located at remote locations without the presence of communities, and hence individuals, which could be affected by emission of the harmful or even toxic gases. In these operations the protection is mainly to protect the employees of the operation. However, if the operation is located near communities, the effect of these gases becomes a serious problem. The communities' perception of post-blasting gases, according to interviews carried out in this project, describes these as smells of black gunpowder, damp soil with a volatile permanence and medium intensity, sometimes a stinking tone is added. The legislation in Chile that controls the exposure of “workers” to different gases is Supreme Decree 594, 2019 (Decreto Supremo 594). Currently the Chilean Ministry of Environment and Sernageomin (Servicio Nacional de Geología y Minería) are taking actions to reform and strengthen oversight, seeking through a short law to provide more tools to the government to decentralize decisions in case of non-compliance with the decree. This paper describes the development and implementation of a permanent and remote gas monitoring system, considering the reasons for choosing the gases to be included in the equipment, the types of sensors and their capabilities, the way to verify in the field the correct functioning of the technology throughout the project, and finally how the data collected in the field is meeting the government's expectations in terms of permanent and online reportability. Additionally, it addresses the continuity of gas monitoring in the community that will disappear in the short term due to the expansion of mining operations, thereby ensuring the protection of both workers and affected communities.

Jan 21, 2025

By D. Scott Scovira, Thomas Gustavsson

The potential of hydrogen peroxide explosives was introduced to Thomas Gustavsson and Robert Håkland by Dr Miguel Araos through his development of hydrogen peroxide gel compositions (HPG). In 2020, Thomas and Robert developed a concept project with Boliden Minerals and received Swedish government funding to evaluate HPG technology in a mine environment. The project showed HPG reacted violently with mine mineralization and concluded that HPGs did not offer a commercial solution due to safety concerns. Thomas and Robert engaged with Stefan Nilsson to develop hydrogen peroxide emulsion (HPE) compositions and the process techniques to manufacture them. In 2021, laboratory work produced a promising low carbon intensity, nitrate free, ammonia free, emulsion formulation based on industrial grade hydrogen peroxide and a fuel-emulsifier phase. Design and construction of an HPE pilot plant and underground charging unit commenced. The manufacture of hydrogen peroxide emulsion shares several similarities with the production of nitrate-based emulsions in that the plant is a facility to blend a strong oxidizer solution with a liquid fuel phase into a finished emulsion. A key differentiator between HPE and nitrate-based emulsion is that the manufacture of HPE is a cold production technology in that neither the oxidizer phase (HP) nor the fuel-emulsifier phase requires high temperature heating to prepare raw materials. A successful proof-of-concept HPE evaluation ran from April 2022 to October 2022 at Boliden’s Kankberg underground mine in Sweden. This evaluation demonstrated HPE technology's safety, performance, production, handling, and indicative environmental benefits.

Jan 21, 2025

By Ruilin Yang

The vector sum peak particle velocity (PPV) of blast vibrations describes the blast vibration intensity more completely than the PPV of a single component waveform. It is more logical to use a vector sum PPV as a vibration limit than using a single component PPV. In 1980 the USBM recommended the frequency related peak particle velocity criterion. So far this method has been only applied to single component waveforms, but not to the vector sum PPV since there is no method available to associate a frequency to the vector sum PPV. The present paper describes a method to define a principal frequency associated with vector sum PPV. The method is based on the weighted average of the principal (zero-crossing) frequencies of the three tri-axial components at the time of the PPV.

Jan 1, 2015

By Walter Voglauer

On May 14, 2011 a chimney blast took place in Vienna, Austria. The blasting operation was part of the demolition works at a former railway fabrication. The demolition works on this ground were done under the leadership of the Austrian construction and demolition company PORR. In agreement with the civil organizations which were involved, the commander of the Regional Military Command of Vienna, Brigadier general Dr. Karl SCHMIDSEDER ordered a reserve force engineer company to demolish the chimney. The concrete planning of the chimney blasting was done by specialist Markus SEWALD who belongs to the HEERESTRUPPENSCHULE (combined armed force school) of the Austrian armed forces.

Jan 1, 2013

By Carlos Alvarado, Hernan Narea, Jhon Silva, Bryan Townsend, Katherine Gil, Brayan Caceres, Felipe Pontanilla

With the promising development of new technologies, automation in Drill and Blasting (D&B) is on the horizon. The data generated in all D&B activities, which is currently segregated, can be linked to become information and carry a logical meaning. This information can be used to identify critical activities and make decisions regarding corrective measures to accomplish the goals of D&B. Minera Caserones, supporting Alert2Gain (A2G), and Dyno Nobel, has been working on the development of a quality assurance and quality control (QAQC), system for the mine involving all D&B activities. The main variables in the model for D&B include data from the geology of the deposit, drilling, explosive products, and material loading, among others. To create the model, the mine is divided into blasting polygons. Those polygons are part of a block model. The block model is assembled following different rules, such as: • Block sizes of 4m x 4m x 15m, • Classification of the blocks to a particular blasting polygon using a geospatial intersection algorithm, • Algorithms connect all the pieces of data automatically with the minimum of human intervention and populate the block model, Because measuring data for each block is impossible, another set of rules and algorithms completes the model. Dyno Nobel generates an essential set of data for the QAQC system. Explosive truck loading rates and explosive products, among other data, are also included in the system. The system autogenerates reports every hour, and a summary of the results of each mining day (a mining shift of 12 hours) is distributed by email to all responsible persons to identify the critical tasks and then to make the proper adjustments to accomplish the goals of D&B. The information is updated every hour and available through a dashboard for easy and straightforward interpretation. This paper explains the conceptual details of the QAQC system implemented in Minera Caserones, how the data is aggregated automatically from the different sources, shows examples of the type of information in the dashboard, and presents a successful case where a deviation was detected, and the corrective measures that were implemented to keep the performance of the D&B activity. The paper finally discusses the next steps toward an autonomous D&B system based on new AI technologies, with minimum human intervention.

Jan 21, 2025

By Dirk Voogt, Quentin Steyl, D. Scott Scovira

A South Africa iron ore mine reported a decline in blast performance and ore and waste fragmentation. Preliminary investigation by the explosives services company found that the straight gassed bulk emulsion was breaking down and collapsing inside of some loaded slept blastholes. The bulk emulsion loaded at the subject site was manufactured in country and shipped to various clients throughout the region, with normal function in blasts at other sites. Historically, the bulk formulation emulsion being used at the subject mine site also performed well and without issue. This raised the question, “why is this bulk emulsion now breaking down and not firing in blastholes?”. Iron ore mines are not typically associated with reactive or acidic ground, and ground sample reactivity testing against the emulsion confirmed this. So, if not reactive ground or acidic water, then what is causing the emulsion to breakdown?

Feb 6, 2023

By Larry Mirabelli, David Lilly

In 1777, the French naturalist, Georges Louis Leclerc, Compte de Buffon developed a statistical technique to estimate the width between two parallel lines by randomly throwing a needle at the two lines and counting the number of times the needle intersected one of the two lines. By knowing the length of the needle, the distance between the parallel lines could be estimated. This analysis was named the “Buffon’s Needle Problem”.

Jan 1, 2008

By Hernan Escalante, Jonathan Alvis, Paulo Alcazar

Constancia Mine, operated by Hudbay Perú and located in the district of Velille, Chumbivilcas province, Cusco, is an open-pit operation characterized by low-grade ore. In this context, operational efficiency and process optimization are essential to ensure long-term profitability. This paper presents an innovative strategy based on the processing of large volumes of data (Big Data), primarily from the drilling and blasting stages. By consolidating approximately 9 million records per month into a georeferenced block model, an analytical platform was developed to directly correlate material fragmentation quality with plant mill throughput. The implemented methodology integrates multiple operational and geometallurgical data sources, enabling dynamic visualization of blasting conditions and their impact on material behavior during crushing and grinding. Through this correlation, operational patterns that maximize plant throughput while minimizing energy consumption and processing costs were identified. Beyond the direct benefits in the plant, this approach significantly improved mine planning by enabling more informed decisions regarding drill pattern design, explosive loading, and blast sequencing. Improved coordination between mine and plant departments was also observed, contributing to better alignment of operational goals and an integrated business perspective. The application of Big Data in this context represents a step toward digital transformation in mining, demonstrating that advanced analytics can be effectively implemented in large-scale, complex operational environments. This solution was validated under real operating conditions and shows high scalability potential for other operations facing similar challenges. In conclusion, this study demonstrates that systematic analysis of drilling and blasting data, when integrated with geological and operational models, can lead to substantial improvements in plant performance. This contributes directly to the competitiveness and sustainability of low-grade mining operations.

Jan 26, 2026

By Martin Langenderfer, Catherine Johnson, Phillip Mulligan, Kelly Williams

The physical geometry of a charge has a direct correlation to the geometry of the shock wave. This relationship appears strongest within the boundaries of the visible fireball. As the shock wave propagates outward past the limits of the fireball, the theory states that the geometry of the shock wave should even out and become more spherical. This paper investigates pressure vs. time at two distances, one ‘Near Field’ at the extent of the fireball and one ‘Far Field.' The two Fields were instrumented with three free-Field pressure probes from PCB oriented at 0, 45, and 90 degrees to the front face of the charge, in the same horizontal plane as the charge. This orientation allows for the comparison of the shock wave from the face and vertices of the charge. All the pressure sensors were connected to a Data Acquisition System (DAS) recording at 2 million samples per second (2MS/s). Two high-speed cameras, a Phantom and an MREL Ranger II, recorded the detonations for qualitative examination of the fireball, and the shock wave. Three charge geometries were used and compared to the shock propagation of a sphere. The other geometries tested are cylinders, cubes, and tetrahedrons. Charges were made from a PETN based sheet explosive. In the Near Field, a lower pressure is observed along charge vertices with highest pressures from each face. In the Far Field, vertices record a higher pressure, possibly due to the shock waves from the adjacent faces intersecting, indicating that shock pressures do not always even out in the Far Field. This paper will describe the methodology and findings of this experiment and attempt to determine causality for trends in the data gathered.

Jan 1, 2018

By Tristan Worsey, Jhon Silva

The paper discusses a limestone quarry case study that looks at change in fragmentation due to using different charge sequences when using the regular rhythmic timing method.

Feb 1, 2020

By Jeffrey W. Lin, Larry B. Weston, Jonathan D. Abbott, Jordan L. Arthur

Hydrocarbon fuel oils are one of the main components of ammonium nitrate-based explosives, including ANFO (Ammonium Nitrate-Fuel Oil) and emulsions. While a wide variety of fuels can, and have, been used in the manufacture of ANFO and emulsion products, No. 2 diesel, particularly dyed, off-road diesel, is widely used due to its ready availability and use in fueling mining equipment. However, a number of alternatives to standard diesel have been introduced over recent years, namely, biofuels, ‘high-performance’ diesels, and renewable diesels. The pressure to adopt these alternative fuels come from a variety of sources, such as initiatives to reduce carbon footprints, increased lifetime of equipment, and cost-advantages from tax credits. While these factors may provide a very real benefit to the mine site, a consideration that is often missed is how the use of these fuels can impact the formulation and characteristics of the ammonium nitrate-based explosives. Herein will be presented a discussion of these alternative fuels from a chemical perspective as well as the results of several studies focused on how the inclusion of various alternative diesels influences the production and performance of ammonium nitrate explosives. ANFO and emulsion were manufactured using representative fuel sources and studying in terms of the manufacturing parameters, shelf-life, interaction with other chemicals using in mining explosives. Detonation data was then collected for these products and compared to the behavior of products made with standard diesel fuels.

Jan 21, 2025

By Brian Stump, D. Craig Pearson

This work quantifies seismic coupling as a function of charge weight for single-fired (simultaneously detonated) explosions observed in the mine and at regional distances. These single-fired explosions are contrasted to standard production shots from the same mine. Production shots include cast blasts to remove overburden and coal shots for fragmentation. The blasts were conducted in a mine in NE Wyoming. The data sets consist of measurements in the mine (100-10,000 m) and at regional distance (360 km) using a seismic array near Pinedale, Wyoming (PDAR). The single-fired explosions ranged in designed size from 5,500 to 50,000 lbs. Peak amplitudes measured at a single element of the regional array are modeled by a power law relation dependent on explosive weight. Scaling constants were determined for each of the dominant regional phases: b(Pn) = 0.84±0.14; b(Pg) = 0.84±0.09; b(Lg) = 0.91±.08. Spectral ratios of observations from different explosions observed at the same station illustrate the frequency dependnce of the source scaling relations. Spectral ratios of in-mine observations are consistent with those of regional data. The observed single-fired ratios are well replicated by Mueller-Murphy source model ratios. The data and model illustrate both the increase in long-period spectral level and the accompanying decrease in source corner frequency with increasing charge weight. The coal and cast blasts that make up the production shots ranged in size from 77,000 to 4,738,230 lbs. The peak amplitude (1-20 Hz) for the largest delay-fired production shot (4,738,230 lbs.) is comparable to that of the largest single-fired explosion (50,000 lbs.). This comparison can be explained in terms of destructive interference between waveforms from individual boreholes introduced by delay firing. Shot specific models of delay firing suggest that peak amplitudes in this same frequency band for the production shots are insensitive to the total amount of explosives in the blast. Peak amplitude data at regional distances supports his modeling result.

Jan 1, 2002

By Terri Jordan, Gregory Hempen, Thomas Keevin

Water-borne blast pressures from confined blasts were recorded as part of a submerged blasting program in Florida for channel deepening. The blasting was confined within the rock floor by stemming. Shot patterns of stemmed borings were recorded, as were two open-water shots. One hole of one shot was not confined properly, which allowed comparison of confined and a poorly confined larger charge weights per delay. The pressure data were intended to gain information on typical pressure measures from the rock removal program relative to impacts on marine organisms. Water-borne pressures from actual confined, rock-removal shots validate the hypothesis of lessened impacts to aquatic and marine biota.

Jan 1, 2007

By Orica Peru, Pedro Lozada

Proper management of exclusion zones in blasting operations is essential to ensure safety without compromising operational efficiency. In Peru, mining regulations establish minimum exclusion distances specifically for personnel (500-meter radius / 1,640 feet), but do not define clear technical criteria for equipment. As a result, conservative distances such as 200 meters (656 feet) are often applied, negatively impacting productivity. This study proposes a technical-scientific methodology to reduce equipment exclusion zones, based on the use of advanced technologies such as drones, high-resolution cameras, and specialized software tools. The solutions used allow video recordings of blasts to be transformed into dynamic data through artificial intelligence and computer vision, as well as execute probabilistic simulations of the flyrock phenomenon using Monte Carlo algorithms and physical models calibrated to real operating conditions. Technological integration enabled the simulation of real operational scenarios, considering variations in critical blasting parameters that directly affect flyrock generation, such as drill diameter, explosive density, linear charge, and stemming height. Additionally, the Terrock methodology was incorporated, allowing the behavior of the rock mass to be included as a variable in risk assessment, improving analysis accuracy under different rock hardness conditions. The methodology was applied in four phases: diagnosis of the current design (15 blasts), modeling, validation of the calibrated model (6 blasts), and subsequent operational implementation. As a result, it was determined that the exclusion radius can be safely reduced from 656 to 492 feet (200 to 150 meters), maintaining as the main restriction the use of stemming lengths greater than 5.0 m. This optimization has the potential to generate tangible benefits, with estimated monthly savings exceeding USD 50,000, associated with reduced evacuation times, lower fuel consumption, less equipment wear, and increased productivity in drilling and hauling activities. The comprehensive approach presented here highlights the transformative potential of digital technologies applied to blast management, contributing to safer and more efficient mining operations.

Jan 26, 2026

By Qi Jinduo, Gong Min

On the basis of actual parameter of wall control blast in Nanfeng mine, China, the process of dynamic stress changing between two column charges was studied recently for a presplit-cushion blast by holographic photoelasticity. In the experimental model, two holes were simultaneously detonated from both ends (four ignition points). The bottom of the holes were loaded more than other parts (heavy charge). Under these conditions, four consecutive isochromatic fringe patterns at different times were acquired in one loading run, and the characteristics of the stress distributions were compared at different places and times in the holes. It was found that interaction types of stress waves vary along the holes. The theory is posed that the stress wave which is formed by the interaction of earlier producing P wave and later S wave along a distributed line charge is the most important part in all stress waves. Research indicates that a heavy charge in the bottom of the holes is crucial to producing a presplit-cushion effect at the bottom. "End Effect" doesn't affect the magnitude of stress along linking lines between the bottoms. The chief fields of the "End Effect" are also explained in the paper.

Jan 1, 1998

By Kirlk Yeager

"Ammonium nitrate (AN) is commonly mixed with a wide variety of additives to produce specialty formulations. Two additives commonly utilized are sodium nitrate (SN) and sodium nitrite (SNi). Application of the nitrite is primarily limited to gassing of emulsions. The nitrate, however, is incorporated in a wide variety of formulations. The effect of both these materials on the thermal stability of AN was examined. Experiments initially utilized lab-scale testing methods (sub-milligram sample size), such as differential scanning calorimetry (DSC), with scale-up to cook-off analyses (16 g) eventually applied. Labscale testing indicated that the presence of SN and SNi (both at 5 wt%) produced no harmful effects on the thermal stability of AN. The cook-off results did not agree with those from the lab-scale analyses, with both SN and SNi creating tremendous thermal destabilization of AN. These effects were seen at additive levels as low as 0.1 wt%. When SNi was employed as the additive, cook-offs became violent enough to create explosions in the testing apparatus. Although SN did not create as spectacular a destabilization, it did lower cook-off temperatures to approximately the same level as SNi. The dangerous situation created by SN andSNi seemed to be limited to cook-offs conducted in sealed vessels. If the SN/AN or SNi/AN formulations were allowed to cook-off in vented vessels, the thermal destabilization of AN did not occur. These results seemed to indicate that even “trace” amounts of what might ordinarily be viewed as benign additives could create significant destabilization of AN-based explosives under proper circumstances. Conditions created by blocked pumps, or deep boreholes could well overlap those produced in sealed cook-off vessels. In addition to showing the hazards potentially created by “benign” additives, the study also stressed that experiments designed to evaluate thermal hazards must include duplication of field variables to the fullest extent possible. "

Jan 1, 1999

By John Horgan, Ethan Marcoux

Explosives have been used to demolish many unsafe structures around the world. However, it is unlikely any demolition job has ever involved destroying buildings already buried 40 feet (12 meters) into the world’s largest ice sheet. That is what happened to the original research station at the geographic South Pole, built back in the 1950s, following a series of discrete explosions between 2011 and 2013.

Jan 1, 2015

By Christoph Muller, Geoffrey Liggins, Mohan Hensman

Modern commercial blasting is as much a technical process as it is a business one. As with most processes both aspects of blasting are driven by and generate new data. The time-critical nature of commercial blasting in mining and construction projects, dictate the timely exchange of information so as not to impede production or commerce. Up-to-date information about the blast to be undertaken can help suppliers: meet customers’ expectations to address challenging ground conditions; react to a market where quickly changing orders occur regularly; and address as-drilled blast patterns as opposed to baseline plans. “Real-time” data exchange into and out of the blasting process supports the whole-of-mine data management that the industry is migrating to.

Jan 1, 2010

By Mario Alvarez

Drilling with tricone drill bits is widely used in the mining industry with a direct impact on drilling safety and costs, however it can be challenging to implement a new supplier of tricone drill bits, choosing a new model of this accessory due to the normal variations of the rock mass or even due to the acquisition of new and modern drilling equipment for open pit blasting operations. This article identifies the most common mechanisms of failure in productive drill holes of tricone drill bits, both in open-pit coal and metal mines, in two South American countries. It also emphasizes the important issues that must be addressed for the optimization of the performance of these accessories, such as the correct identification of the rock mass, the drilling parameters, and the impact of autonomous drilling on new equipment with this technology. The article presents some of the successful actions to economically improve the performance of drill bits considering the close relationship in the field with the supplier's technical representatives and factory designers, as well as the commercial interrelationship between their respective business areas. The article concludes by discussing the future of tricone drill bit design development, its environmental management, and possible new advances in its manufacture.

Jan 21, 2025