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By Azin Zangooi, Cesar Gomez, James Finch

Frother concentration is a variable which significantly affects the flotation performance by decreasing bubble size and helping froth stabilization. Variations in frother concentration, which mostly go unnoticed in industrial operations, may affect these functions. Some factors that can cause variations include the fact that frothers are normally dosed based on feed tonnage and not solution concentration, unstable frother delivery, incomplete dissolution for low solubility frothers, addition of frother-free wash water, remnant frother in recycle waters and frother partitioning to the froth. A colorimetric technique developed for determining frother concentration on site makes it possible to detect the occurrence of these problems and to establish their magnitude, allowing conditions to be adjusted to reduce frother concentration variations. By sampling and analysis, frother distribution throughout a circuit can be established, referred to as ‘frother distribution mapping’. Experiences at several concentrators processing sulphide ores are used to illustrate time restrictions for sample analysis, and to demonstrate temporal and spatial frother concentration changes as a consequence of variations in the grinding stage, recycled waters containing frother, and frother partitioning.

Jan 1, 2014

By M. Pelser, C Aldrich

"The presence of calcium and magnesium in the hydrometallurgical processing of base metals, results in a number of process difficulties. These problems range from the contamination of the final product (where the final product is a precipitate) to high energy consumptions and large bleed streams during electrowinning. Calcium poses an additional problem in sulphate solutions owing to the low solubility of its sulphate salts. This can easily lead to a process stream that is supersaturated with calcium sulphate, resulting in unwanted solids formation within the process equipment.Several processes are reviewed for the control of calcium and magnesium. Of these, fluoride precipitation was selected for experimental investigation. This method involves the addition of a soluble fluoride to precipitate CaF2 and MgF2. The experiments showed high selectivity for calcium and magnesium over the base metals. The experiments also showed magnesium precipitation to dominate for calcium to magnesium molar ratios greater than 1:3.To avoid the domination of magnesium precipitation, a flow sheet is proposed whereby only a portion of the base metal stream is subjected to fluoride precipitation. For the precipitation, a 10% excess of ammonium fluoride is used to remove the maximum amount of calcium and magnesium. After precipitation and solid-liquid separation the split-stream is returned to reduce the overall calcium and magnesium concentration of the base metal stream."

Jan 1, 2003

By J. Yianatos, C. Matamoros, F. Díaz

The non-selective entrainment of fine solids in flotation equipment has a detrimental effect on the concentrate grade. Reduction of solids entrainment (upgrading) is typically related with a loss in recovery of valuable minerals. For improving the froth transport characteristics and flotation cells design, a better understanding and quantification of the actual solids drainage and entrainment processes are required. In this work, the study of solids transport in the froth of a two-dimensional flotation cell was performed. The prototype cell represents a radial section of an industrial flotation cell (130m3) and was operated at steady state. Experimental tests consisted of adding a small amount of radioactive solid tracer (0.3g) near the top-of-froth or near the bottom of froth (close to the interface). The solid was selected as a non-floatable mineral (gangue) in order to evaluate both the solid entrainment into the concentrate as well as the solid drainage into the collection zone. Solid tracer consisted of fine or coarse gangue particles, P80 of 35 and 120 µm, respectively. Twelve collimated sensors located along the froth and collection zones allowed the evaluation of the solid transport in the froth, and the solid drainage from the froth to the collection zone, after tracer addition at different distances from the discharge lip. Results showed that longer distances to the froth discharge lip, as well as higher particle sizes, promotes higher solid drainage from the froth to the pulp zone, while decreasing the solids entrainment into the concentrate. The same result was observed for the solid located near the top-of-froth as well as near the bottom of froth. This information was complemented by the froth surface velocity measurements, using the Visiofroth system, showing a good agreement between the froth bubbles velocity and the solid transport velocity, measured near the discharge lip.

Jan 1, 2018

By Tom Leistner, Urs A. Peuker, Martin Rudolph

"It is well known, that for conventional froth flotation techniques the processing of ultrafine mineral particles is generally inefficient and results in rather low-grade concentrates and relatively high losses of valuable minerals. Therefore, the investigation of other possible methods, which can selectively separate such fine particle systems effectively, is of considerable interest. In this study, the application of two-liquid flotation, a flotation-related process using oil droplets instead of air bubbles, is investigated as a possible processing strategy for the separation of ultrafine particle systems. The investigation involves the testing of the two-liquid flotation technique as simple laboratory-scale batch trials and moreover, the up-scaling to a semi-continuous process by using a modified lab scale flotation column. Magnetite and quartz particles, with particle sizes below 10 µm respectively, as academic mineral mixture and iso-octane and water as the two immiscible liquid phases are chosen for the experiments. To manipulate the wettability of the magnetite particles as well as the interfacial tension of the oil/water interfaces, surface active reagents of fatty acid basis are introduced in the system. The selectivity of the process is characterized by determining the removal of magnetite particles from the aqueous suspension through selective accumulation at the oil/water interface or extraction into the oil phase, respectively. Operational parameters including pH of the aqueous suspension, additional electrolyte addition and surfactant type as well as dosage are varied in order to maximize the efficiency and stability of the process."

Jan 1, 2014

By Janusz S. Laskowski

The flotation-related properties of hexanol derivatives and mono-alkyl ethers of propylene oxide, which include many important flotation frothers (e.g. MIBC, DF-200, DF-250, DF-1012, etc.) have been studied. The obtained results show that the DFI (Dynamic Foamability Index) - CCC (Critical Coalescence Concentration) plot can be used to classify flotation frothers. The frothers characterized by low CCC and high DFI values have properties of strong flotation frothers, while those with high CCC and low DFI values are more selective. The proposed frother classification system, based on simple CCC and DFI measurements, provides, for the first time, a solid ground-work for characterization of the flotation frothers.

Jan 1, 2003

By M. H. Moys, M. M. Bwalya

The use of the Discrete Element Method (DEM) to simulate the interaction of particles in dynamic environments is growing rapidly. This technique is also being applied in the study of milling extensively. However, to date more focus has been on the validation of the model. In spite of the advantages of the detailed information that is available from the simulator, appropriate application of this information remains a daunting task. In this paper a technique that combines particle breakage probability data with the energy spectra generated from the DEM is discussed.

Jan 1, 2003

By N. Panteleeva, E. Konoplev, I. Michailova, S. Titkov, S. Aliferova, T. Gurkova, T. Chumakova

Cationic flotation using alkylamines and their derivatives as collectors, and characterized by high selectivity of mineral particle separation, is finding ever growing industrial application. In recent years the industrial application has been initiated of new cationic collectors - alkylmorpholines. Efficiency of cationic surfactants operation as collectors is dependent upon their colloid and sorption properties and the availability of silicate .carbonate rock-forming mineral impurities in the ore, which sorb the cationic collector. Investigations have been carried out on the influence of frothers and organic depressors with various compositions upon physical-chemical and flotation properties of alkylamines and alkylmorpholines. On the basis of these investigations requirements for organic depressor were developed and new flotation reagents were proposed (V-1 frother and KS-MF depressor). The use of new reagents enables one to decrease considerably the consumption of expensive cationic collectors and to enhance the floatability of coarse mineral particles. Data of new reagents industrial application is presented. The reagents developed can be used for flotation processing of other ores.

Jan 1, 2003

By Rainer M. Lotzien, Michael J. G. Battersby, Jan Kleefeld, Julian V. Brown, Rainer M. Imhof

"The standard method of separation using flotation is compromised in terms of kinetics and efficiency, because of the generally slow separating differentials of fine bubbles and fine particle suspensions. A new flotation system has been developed that addresses these issues and imparts other benefits. The new technology is based on established pneumatic flotation designs called Imhoflot which use intensive in-line pre-aeration to aerate the flotation pulp prior to its introduction to the separating cell. Consequently the cell is designed only for the separation of the phases and not for bubble-particle contact. In the new system this separation is speeded up dramatically by the introduction of centrifugal motivation in the separating vessel, without the use of internal moving parts. The design focuses on providing increased differential forces on buoyant mineralised bubbles and hydrophilic fines. The observed result of these differential forces is the improvement of concentrate qualities by the reduction of the amount of misplaced material found in the froth. The commercial benefit to industry is much reduced residence time, less than 30 seconds, which offers considerable cost savings in equipment and infrastructure.Prototypes of 0.65m, 1.7m and 2.2m cell diameter size have been constructed for hydrodynamic and industrial scale tests to assess the previously established computational methods for scale up of the process. The 1.7m cell has been installed and operated for cleaning of potash concentrates in Germany, at throughputs of 150 m3/hr, with extremely encouraging results. A 2.2m cell has been installed and operated in plant trials for superfine coal in South Africa. Results are presented that illustrate the effects of differential separations by comparison with conventional pneumatic and mechanical flotation techniques. Predictions of performance are provided in the contexts of the applications tested."

Jan 1, 2003

By Patricio Berrios, David Barriga, Peter Amelunxen, Gerson Sandoval, Roger Amelunxen

Laboratory test equipment and methods have undergone relatively little change since their introduction in the 1950’s. The Denver sub-A cell is still by far the most commonly used laboratory batch cell, but bottom-driven and instrumented cells are beginning to appear. Test procedures have also changed little over the past 60 years, and most engineers continue to rely on empirical models for predicted plant scale performance from laboratory scale tests. This approach is problematic, because changes in the froth phase characteristics in the lab hamper the reliability and reproducibility of the empirical extrapolation to plant scale. In a previous work, the authors reported on the impact of froth recovery at the laboratory cell, showing that variability in the froth recovery can lead to significant error in the modeled kinetic rate constant unless it is properly accounted for in the scale-up model. In this work, we review the role of hydraulic entrainment in the lab cell, and how variability in particle specific gravity, shape factor, and froth residence time can impact the entrainment recovery.

Jan 1, 2014

By Sunil Tripathy, Y. Rama, Srinivasulu. A., Amit Ranjan

Process improvements in an operating plant are always challenging. Mineral beneficiation plants based on gravity concentration techniques need continuous evaluation and monitoring of its processes for getting maximum recovery and better grades. But, in an operating plant it is very difficult to control all the parameters due to numerous reasons such as unsteady operation, fluctuation in the quality of run-off-mine ore, overall flow rate etc. For better understanding of the beneficiation circuit, it is necessary to evaluate the critical operating parameters which affect the performance in terms of grade, recovery and throughput including losses of valuable materials into tailing. Accurate data collection and proper data interpretation followed by making necessary change which is implementable in an operating plant play very critical role in performance of the circuit. In case of gravity operated beneficiation circuits of chrome ores where the quality of the feed and physical parameters varies continuously, the operators are required to modify the critical operating process parameters on continuous basis which is very difficult and tiresome. There are many causes of the data variability, including both error (sampling and assay), and real variation in performance due to changes in ore mineralogy, operating conditions and other factors. In this article, attempts made to evaluate the performance of ultra-fine beneficiation circuit in terms of silica reduction in the concentrate of chrome ore beneficiation plant (COB), India are discussed. The approach adopted and practical problems encountered during the study were also discussed. Results obtained from plant audit based on the above methodology has shown that SiO2 content in the concentrate can be reduced to <4%.

Jan 1, 2014

By Luís Marcelo Tavares, Juliana Segura

Comminution is one of the most energy consuming stages in a mineral processing plant. This consumption is not only related to the power supplied to equipment, but also to the indirect or embodied energy, mainly associated to materials that are worn during operation, including grinding media and liners. Until recently, preparation of iron ores in Brazil did not use comminution intensively, given that plants mainly produced sinter feed, natural pellet fines, besides lump ore. However, with decreasing ore grades, size reduction now occupies a centre stage in nearly all new plants. Technologies used up to date for processing low-grade iron ores in Brazil, in particular itabirites, have consisted of three or four stages of crushing followed by ball milling. A number of new plants are either being built or are currently being designed that will process the same type of ore, so that engineers are investigating alternative comminution routes. The paper analyses comparatively four comminution routes for processing a particular itabirite ore, many of which using technologies and layouts that have not yet been used in such application. Using data from bench scale and/or pilot-plant tests, the different routes are compared on the basis of sustainability principles in accordance to the Brazilian energy matrix, which is quite particular. It is concluded that if the sustainability criterion is used, then the optimal route would correspond to a circuit that uses HPGR technology with truncated feed followed by ball milling. Given the particular case of itabirite iron ores and specially to the one in the present work and the source of Brazilian energy, it is evident that indirect energy expenditure in comminution plays a significant role in greenhouse gas emissions when compared to direct energy, being the reason for the great attractiveness of HPGR technology. Evidently that these will have to be balanced against CAPEX, OPEX, NPV and other qualitative criteria, which can certainly lead to a different optimal circuit.

Jan 1, 2014

By Tamara Matveyeva, Tatiana Ivanova, Nadezhda Gromova

"The paper presents the results of study of the sorption and flotation properties of the reagents of plant origin - tannin and natural extracts of the oak bark and stems of plants, with a view to their application as a low-cost environmentally friendly modifiers of iron sulfide flotation for the recovery of minerals containing precious metals. The technique of preparation of plant extracts with a fixed content of extractable tannins has been developed.The mechanism of flotation reaction of tannin extracts has been identified as based on their adsorption on the surface of pyrrhotite and arsenopyrite to form strong complexes with iron (III) at concentrations below micelle concentration. It has been found that adsorption of plant extracts occurs without displacement of primarily adsorbed xanthate, and preliminary adsorption of xanthate did not preclude fixation of tannin on the mineral surface.It has been shown that plant extracts having hydrophilizing properties at low concentrations could be applied as selective depressants for pyrite, pyrrhotite and arsenopyrite in a weakly acidic, neutral or weakly alkaline medium. The use of plant modifiers could help to increase the quality of gold- and platinumcontaining concentrates and reduce the ecological impact on the environment."

Jan 1, 2014

By T. Leißner

This contribution deals with the mineral processing of Li-silicate greisen-type ores comprising of quartz, topaz and zinnwaldite (lithium-rich mica). The origin of the greisen-type ores processed is the Ore Mountains(Germany) where it is explored as a potential resource for the production of lithium carbonate. The goal is to develop a process chain for the enrichment of zinnwaldite using dry techniques only. As basis for the investigation the process chain, which historically was used to process the greisen focused on cassiterite and wolframite, is taken and modified towards the zinnwaldite. Starting with crushed material with particle sizes smaller than 35 millimeters, investigations on different approaches to grinding to liberate mica from gangue are carried out. Concentrates of zinnwaldite are then produced by magnetic separation of size fractions. To assess the success of grinding, classification and separation, mineral liberation analysis and atomic absorption spectroscopy are used. The amount of lithium measured in the sample with atomic absorption spectroscopy was used to calculate the content of zinnwaldite based on its known mineral chemistry. Combined with the particle size distributions, product qualities are determined. Altogether, this allows the thorough evaluation of the success of comminution with focus on following steps of concentration. Keywords: lithium, zinnwaldite, magnetic separation, mineral liberation analysis

Sep 1, 2012

By Hajime Miki, Mutia Dewi Yuniati, Tsuyoshi Hirajima, Keiko Sasaki

Acid mine drainage is mainly due to pyrite/arsenopyrite oxidation processes, and suppressing such processes is important issue. As a promising process it is reported that silicate ion can complex with catechol (1,2-dihydroxybenzene) and this complex is oxidized to a solid silica layer on the surface of those sulphide minerals. Detailed behavior was investigated from the result of electrochemical experiments. Results of polarization potential showed that oxidation peak can be seen only in the presence of both silicate ion and catechol addition at this peak potential and this peak can be identified as silicate-catechol complex oxidation to silica. Potentiostatic experiments indicated the dissolution kinetics of pyrite. Untreated pyrite dissolution rates were higher than pyrite treated with catechol and silica solution. To enhance the silica layer reaction on pyrite, the pyrite potential was held at 550 mV vs. SHE in catechol silica solution. This pyrite dissolution kinetics was almost the same as untreated pyrite. Potential hold followed by drying for 30 min process resulted in much lower pyrite dissolution rates. Drying is important for development of the silica layer. Analysis of this potentiostatic curve provided a way to estimate the thickness of the produced silica layer and kinetic information of treated/untreated pyrite. Untreated pyrite showed thinner initial layer thickness on the surface of pyrite (oxidized passive layer, not silica) and higher oxidative kinetics of pyrite compared with silica-coated pyrite.

Jan 1, 2014

By Stoyan Groudev

Two experimental plots consisting of a slightly acidic soil heavily contaminated with radionuclides (mainly uranium and radium) and non-ferrous metals (mainly copper, zinc, and cadmium) were treated in situ under real field conditions using the activity of some representatives of the indigenous soil microflora. This activity was enhanced by suitable changes in the levels of some essential environmental factors such as pH and water, oxygen and nutrient contents of the soil. The treatment was connected with solubilization and removal of the contaminants from the top soil layer (horizon A) due to the joint action of the soil microorganisms (mainly acidophilic chemolithotrophic bacteria) and leach solutions (diluted sulphuric acid) used to irrigate the soil. In one of the plots, the dissolved contaminants were removed from the soil profile through the drainage soil effluents and were subjected to cleaning by a constructed wetland located near this plot. In the other plot, the dissolved contaminants were transferred to the deeply located soil subhorizon B2 where they were precipitated as the relevant insoluble forms (uranium as uraninite, and the non-ferrous metals as the relevant sulphides) as a result of the activity of the sulphate-reducing bacteria inhabiting this soil subhorizon. This activity was enhanced by injecting water solutions of acetate, lactate, ammonium, and phosphate ions to this soil subhorizon.

Sep 1, 2012

By P. Thareja, V. Prasad, S. P. Mehrotra

In recent times, the transportation of minerals and their tailings has become a major concern across the world. There exists a huge demand of efficient and cost effective transportation system which poses minimum environmental damage. One of the economically and environmentally viable techniques which potentially offer a solution to the above problem includes transportation of minerals and their tailings in the slurry form through pipelines. Slurry transportation through pipelines is reported to be more beneficial in terms of cost, environmental impact, maintenance and safety when compared with other conventional modes of bulk transportation such as train, truck, barge and conveyors. The main challange associated with hydraulic transportation of slurries is to obtain a non-settled slurry and to design a pipeline system which results in the optimum energy requirement for transporting a large throughput to longer distances at a lower cost. The feasibility of hydraulic transportation of slurries through pipes mainly depends upon slurry properties and flow conditions in the pipe. Results from rheological studies exhibit the presence of shear thinning flow behaviour of minerals and their tailings in water. The flow behaviour index (n) and consistency coefficient (k) obtained from the rheological analysis are further used for the specific energy consumption and energy losses during transportation. The cost of transportation in USD per ton per 100 km and transport capacity in tons per day are calculated from the specific energy consumption to transport these slurries. The results demonstrate that the slurries can be transported to long distances (say, 100 km or more) corresponding to optimum energy consumption and dissipation rate at a substantially cheaper cost than the existing rail and road transport in India. Although we have carried out transportation studies with coal fly ash (CFA), lignite & bauxite slurries, for paucity of space, the results reported here are essentially for CFA slurries. Details of our investigations with lignite coal & bauxite will be reported seperately.

Jan 1, 2018

By Gabriel Barrios, Juan Pérez-Prim, Marcelo Tavares

"The application of High Pressure grinding Rolls (HPGR) has been growing in the mining industry for the last 10 to 15 years. The major benefits generally supporting this trend are better energy efficiency, improved grinding capacity, less sensitivity to ore grindability variations and higher metal recovery in downstream processes such as heap leaching and flotation. The HPGR machine comprises a pair of counter-rotating rolls mounted in a sturdy frame. One roll is fixed in the frame, while the other is allowed to float on rails and is positioned using pneumohydraulic springs. The feed material is introduced in the gap between the rolls and is crushed by the mechanism of interparticle breakage. Comminution performance is largely determined by the pressure exerted on the bed of particles by the floating roll hydraulic system. The operating bed pressure depends on the hydraulic system start-up parameters and the loading response of the feed material. The work describes how the coupling of the multi-body dynamic simulation with Discrete Element Method in which particle breakage is described using the particle replacement method, can be effectively used to predict the performance of the HPGR. The model considers important variables as the HPGR rolls geometry and design, the hydraulic spring system start-up parameters and the material loading response, to describe operational key outputs as material throughput, operating gap and roller pressure distribution. The preliminary version of the model has been used to predict the effect of material properties on the operating gap and the load distribution on the surface of the rolls, demonstrating that it can describe qualitatively the HPGR operation, indicating that the model will be a power full tool for the simulation and selection of industrial HPGR units."

Jan 1, 2014

By Masakazu Niinae, Tasuma Suzuki, Mai Moribe, Yohhei Okabe

Bench-scale electrokinetic experiments were performed to elucidate the electrokinetic remediation mechanisms of arsenate from artificially contaminated kaolinite. The electrokinetic experiments in which a constant voltage was applied demonstrated that high soil pH favored arsenate remediation with respect to both the remediation time and electricity consumption. It was also demonstrated that applying a pulse voltage (1 hour ON, 1 hour OFF) significantly improved the electricity consumption efficiency when the soil pH was maintained at the initial value during the experiments; this trend was not observed when the soil pH was gradually increased from the cathode side. These electrokinetic experimental results indicate that the remediation rate-limiting step varied with soil pH. When the soil pH was maintained at the initial value of 7.2 during the experiments, arsenate desorption was the remediation rate-limiting step rather than the migration of dissolved arsenate toward the anode. Conversely, when the cathode pH was not controlled and the soil pH was correspondingly increased gradually from the cathode side, the migration of hydroxyl and desorbed arsenate ions toward the anode played a more important role in the control of the overall remediation efficiency.

Jan 1, 2014

By Thenepalli Thriveni, Seong-Young Nam, Nam-Il Um, Joobeom Seo

In the present work, we report a novel microstructure of synthesized scalenohedral PCC (precipitated calcium carbonate) without any additives by a simple and ecofriendly carbonation process carried out in a liquid-gas system on the crystal growth of the scalenohedral calcite phase. Especially, the process parameters of Ca(OH)2 concentration and CO2 flow rates were investigated to enhance the sensitivity of the process. The highest average length of the scalenohedral calcite was obtained at pH 6.0, temperature 450C, Ca(OH)2 concentration 0.2M, CO2 flow rate 80mL/min, and total volume 1L. The utilization of flue gas-derived CO2 from coal fired power plants could be a form of carbon capture and storage using carbonation reaction with scalenohedral PCC. Finally, the synthesized scalenohedral PCC was used as a filer for ONP recycling. We demonstrated all these experiemnts at semi pilot plant scale.

Jan 1, 2014

By I. N. Babich

"Complex technological problems associated with the processing of mineral raw materials require the search and development of new means and ways of thinking. At present, computer cognitive graphics (CCG) are one of the most actively developing areas of new information technologies. The aim of the study was to optimize the cycle of technological evaluation of ores at all stages of geological exploration of deposits on the basis of analysis of geological sampling data using CCG. A new approach has been developed that facilitates optimization of the whole cycle of subsoil exploration. At the gold ore deposit, the results of the geological sampling data were processed by the method of constructing the CCG in the form of a histogram showing the frequency of gold extraction and the average amount of its content. Significant peaks of the metal content in the ore, exceeding the level of the average content in the ore by tens of times, have been revealed. Graphical interpretation of the parameters of mineralization reflects the uneven nature of its variability, which indicates the presence of large, rarely occurs of gold in the ore and the need to conduct studies on a sample of ore of greater mass than for ores with tiny gold. On a sample of 50 kg gold-quartz ore studies were carried out on gravity enrichment. The maximum size found in the gold concentrate was 0.07 mm. In the course of integrated tests in a gravity concentrate, gold particles up to 3 mm in size were found, which predetermined the need to include the operation of gravity before flotation. A new approach to subsoil research is protected by a patent (RU 2620823).The technological problems that arise before the researcher associated with the processing of resistant ores require the exploration and development of new means and ways of thinking. New problematic situations on complex mineral and raw materials objects are practically not amenable to resolution by existing methods. Integration of industrial and information technologies is necessary. At present, computer graphics (CG) is one of the most rapidly developing areas of new information technologies. For example, in scientific research, including in fundamental research, the accent from the illustrative function of CG (the visualization of what is already known) is increasingly shifting towards the use of computer cognitive graphics (CCG) tools (Bashlykov, 2016). The function of the CCG is to obtain a new knowledge with the help of a graphic representation - a cognitive image or at least to promote the intellectual process of the logical acquisition of this knowledge. In this study, cognitive images are used to graphically represent the distribution of valuable components in the bowels of the deposit, characterizing the state of mineral-raw materials."

Jan 1, 2018