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By R. Scheepers

"Abstract -Mineral deposits and prospects of the Pan African Saldanian orogenic belt in the south­ western Cape Province South Africa, are reviewed. Despite the entire absence of operating base or precious metal mines in the area, this study has established at !east four metal associations that offer enticing exploration potential .The poly-phase deformed, low-grade metamorphosed volcano-sedimentary Malmesbury Group constitutes a complex, poorly understood supracrustal sequence that has been loosely subdivided into the Tygerberg, Swartland and Boland tectono-stratigraphic terranes by northwesterly trending fault zones. Syn- and post-tectonic granitoids of the Cape Granite Suite selectively intruded these terranes. Early S-types preferred the Tygerberg terrane whereas the later I-types dominate the remaining areas. Anorogenic A-type granites, however, occur in all three domains. Known metallization is directly or indirectly related to the intrusives, yet syngenetic deposits are conspicuously absent from the supracrustals. Four metal associations have been identified.•,Cassiterite-wolfrarnite (± Au, Cu, Mo, Fe-sultides) in quartz and quartz/aplite veins hosted by tourmalinized and locally greissenized S-type granite. Similar exo-granitic veins occur in proximal metamorphites.•,Juxtaposed disseminated, stockwork, breccia and vein style Cu-Mo-Fe-(Au)-sultide mineralization hosted by matie to intermediate intrusives of high K calc-alkaline, 1-type affinity.•,Cu-Mo-Au-sultides hosted by hydraulic breccia pipes, stocks and veins occurring in anorogenic A-type alkali feldspar granites and amphibole quartz syenites.•,Scheelite with minor Cu-Mo-sulfides and Au-associated with endo- and exo-skarns spatially related to I-type monzogranite, granite and alkali feldspar granite .The first three associations occur along the Yzerfontein-Helderberg-Zone, a 180 km lineament in the Tygerberg terrane, a zone exploited by syn-, late- and post-tectonic intrusives and their related mineralization. The fourth association is typical of the Boland terrane. The spatial and temporal relationships between the various metal associations is interpreted as the result of sequential intrusion of relative early high level S-type, followed by intermediate level I-type and finally anorogenic A-type granitoids during the evolution of a contracting continental margin arc and its inner arc. This plate tectonic setting suggests subduction in an easterly direction underneath the Kalahari craton. The spatial configuration of the various terranes at the present erosional levels is the result of rifting and significant differential vertical displacement following cessation of subduction, a terminal tectonic event possibly synchronous with intrusion of the A-type granitoids.Near surface preserved roof zones and cupolas of both S- and I-type granitoids in the Tygerberg and Boland terranes, respectively, render these areas extremely prospective for Sn, W, Mo and Au mineralization. The presence of intermediate to mafic volcanics, a diversity of calcareous lithotypes and favorable plate tectonic setting of the Malmesbury Group suggest potential for the thus far elusive VMS, MVT and Sedex base metal and minor precious metal deposits."

Jan 1, 1994

By Abhilash

Uranium is conventionally extracted using a process that employs strong acid (H2SO4) and an oxidant (MnO2) as leaching agents. This method often creates environmental problems, requires large amounts of energy, and involves a complex operational plant. It is not, however, economically attractive to extract uranium from low-grade ores by chemical leaching. Because the content of U3O8 in the Indian ore is usually below 0.1% by weight, it is necessary to develop an alternative process to enable the efficient and economic recovery of uranium. Uranium ore from the Narwapahar mines, UCIL is a type of vein deposit found in India, which accounts for ~54% in India. The ore (0.047% U3O8), though of Singhbhum area, possess exceptionally different mineralogy due to presence of some refractory minerals and richness of apatite (5%) resulting in a maximum 78% recovery through conventional processing at UCIL, with a very high consumption of sulfuric acid and pyrolusite, besides possible loss of uranium as uranium phosphate. To avoid usage of environmentally non-benign oxidants, remediation of influence of phosphates, and improve the overall process output of uranium; an alternate extraction technology using microbial isolate(s) is worthwhile exploring and the same is presented in the paper. The microbial isolate enriched with Acidithiobacillus ferrooxidans grown from source mine water was employed for bio-leaching of uranium while varying pH, pulp density (PD), particle size, etc. On varying pH at 35oC using 20%(w/v) PD and <75µm particle size, 83.5% and 78% uranium bio-recovery were observed at 1.7 and 2.0 pH in 40 days against maximum recovery of 46% and 41% metal in control experiments respectively. Whereas, it was observed that grinding of ore to finer size actually helped dissolution of uranium. Finer size particles (<45µm) gave a maximum biorecovery of 93% in 40days at 10%(w/v) PD, 1.7 pH and 35oC. The bio-recovery of uranium fell down from 93% to 82.73% and 60% on increasing the pulp density from 10% to 20% and 30% respectively for particles of <45µm size. The higher uranium dissolution during bioleaching at 1.7pH can be correlated with increase in redox potential from 433 mV to 664mV in 40 days.

Aug 1, 2010

By M. E. Charles

The use of water flowing as a lower layer to reduce pressure gradients in petroleum pipelines was investigated using 17.5 deg. A.P.I. Lloydminster crude oil in a 1-inch laboratory pipe-line and a 21h-inch field pipeline. The method was found to be very effective in reducing the pressure gradient below that for the oil flowing alone. The factor by which the pres-sure gradient was reduced varied with the percentage of water added, and in general exceeded 10 for water contents ranging from 40 to 60 per cent. Within this range of water content the pressure gradient reduction factor was independent of the oil flow rate.

Jan 1, 1960

By L. Wolofsky

"The Candego property is in Boisbuisson and Christie Townships, Quebec, about 13 miles south of Marsoui, a village on the north coast of the Gaspe peninsula, 80 miles east of the railhead at Matane. It was the first producing mine in the peninsula. Production to October 1954, when operations were suspended, totalled 68,497 tons of ore, which yielded concentrates containing 8,706,535 lb. lead, 5,870,272 lb. zinc, 355,526 oz. silver, and about 1,000 oz. gold. The property was acquired by the present company in the summer of 1955.The mine has been developed by seven adits, driven into the west slope of the valley of the Marsoui River. The river here is at an elevation of about 1,600 feet, and is roughly 1,500 feet below the level of the adjacent upland. Adit elevations range from 1,760 to 2,330 feet. Five of them are in one vertical zone, on what was originally believed to be a single vein. Past production has come from Nos. l to 5; the chief present high-grade ore reserves are in No. 7.The author's observations were made in adits Nos. 3 to 6, in several of the old pits, in the surface trenches, and on drill core, at various times between December 1952 and September 1953. Much of the surrounding area has been mapped by Jones (I) and McGerrigle (2) for the Quebec Department of Mines. H. M. Kingsbury served as consulting geologist to the mining company for several years.General GeologyThe Candego veins occur in Lower ( ?) Ordovician sedimentary rocks which form a strip about 15 miles wide along the north coast of the Gaspé peninsula. The series includes limestones, shales, and sandstones, mildly metamorphosed in places. Three miles south of the mine is the north contact of the granitic intrusive, regarded as Lower or Middle Devonian, which underlies the Tabletop Mountains area. This batholith is about 10 miles long, in a north-south direction, and about 4 miles wide. At Mount Albert, about 5 miles west of the Tabletop intrusion, is a group of basic rocks, amphibolites and serpentinized peridotites, thought to have been intruded at the close of the Ordovician."

Jan 1, 1949

By Lou Covello

Bow Valley Industries Limited i conducting an on-going exploration program for gold in Archean, turbidite-hosted iron formations near the Lupin mine on Contwoyto Lake, orthwe t Territorie . Exploration philosophy and practice are modelled on the Lupin deposit where 70% of the gold occurs within laminated pyrrhotitechert. sulphide facie iron formation. Thi i intimately associated with barren to low-grade silicate facie iron formation which i enclosed by predominantly argillaceou meta ediment . This type of mineralization i amenable to exploration through an integrated program of geological and geophy ical surveying, consisting of the following: i) Geological urvey both regional and local to outline area of turbidites and a ociated iron formation. Structural and tratigraphic trends documented during this phase are useful in determining eventual grid configurations. Grids are then mapped and ampled at 1:2000 cale. ii) Magnetometer and gradiometer urvey at the ame scale define strongly magnetic diabase dyke and erratically magnetic portions of iron formation. iii) VLF-EM survey are u eful in outlining conductive trend invariably as ociated with sulphidic or graphitic phase of iron formation. iv) Geological updating and ampling of iron fom1ation based on the geophysical su rveys. This is necessary for the production of a final geologic map and a an adjunct to drill target election. In problematic instances self-potential urveys have documented the pre ence of non-conductive sulphide accumulations, and horizontal loop EM surveys have been used to determine conductor geometry and quality. Target selection is based on a synthesis of the information from all of the above surveys with the results of no single survey being critical to drill decisions. The program is designed to provide first-pass, detailed , cost-effective ground coverage of large areas of highly prospective geology.

Jan 1, 1986

By J. Ambrose, R. W. Zimmerman

"Shales are highly anisotropic in their mechanical behavior. The strength ( ??1) of anisotropic shales depends not only on the magnitude of the other two principal stresses ( ??2, ??3), but also on the bedding plane orientations (?) relative to the principal stresses. In this study, the role of the intermediate stress ( ??2) on the strength of shale is evaluated using new data from triaxial compression and extension tests. To understand the failure behavior of shales, we have carried out triaxial compression tests ( ??1 > ??2 = ??3) on two organic rich mudstones, at different confining stresses and loading angles. We first fit the triaxial compression data with Jaeger’s plane-of-weakness model, and find that the model is able to represent the strength behavior of anisotropic shales reasonably well. We then carried out five triaxial extension tests ( ??1 = ??2 > ??3) for a high strength-anisotropy shale, and two extension tests for a low strength-anisotropy shale. Results from the compression and extension tests for failure along the weak plane shows that the role of ??2 is not significant for weak plane failure. However, for the low strength-anisotropy shale, the failure strength of the intact rock (i.e., at ??= 0o and 90o) for compression and extension tests were significantly different. This indicates that for intact rock failure, the role of ??2 is important and cannot be ignored.INTRODUCTIONFor many years, various researchers have studied the roles of ??2 for failure of isotropic rocks. (Mogi, 1967 and 2007; Colmenares and Zoback, 2002; Al-Ajmi and Zimmerman, 2005 and 2006; Haimson, 2009; Ma and Haimson, 2012). The findings from these studies show that the effect of ??2 on the strength of isotropic rocks is generally significant, and cannot be ignored.Since the role of ??2 in the failure of isotropic rocks was recognized, other researchers attempted to extend some of these isotropic failure criteria to anisotropic rocks, but with limited success (e.g., Tiwari & Rao, 2007; Singh et al., 1998; Zhang and Zhu, 2007; Pei, 2008). Smith and Cheatham (1980), on the other hand, conducted true-triaxial experiments on the Green River Shale and used a J2-I1 type relationship to predict the strength behavior, but without considering the effect of the three-dimensional orientation of the weak plane on strength. Therefore, unlike for the case of isotropic rocks, additional studies need to be done to determine the role of 2 on the failure of anisotropic rocks."

Jan 1, 2015

By A. K. Debnath

Coal is the mainstay of Indian energy supplies. The many-fold increase in demand for coal puts a huge pressure on augmenting production, primarily from opencast mines. The increase in production necessitates heavy blasting in overburden and coal benches of opencast mines, which poses numerous challenges in carrying out blasting operations techno-economically. Presently, the consumption of industrial explosives and accessories in Coal India Limited (CIL) has touched a whopping figure of $350 million USD per annum and CIL will be spending approximately $1 billion USD between 2012?2013 to 2014?2015 for procuring explosives and accessories. This paper discusses some of key challenges faced in various mines of CIL during blasting, where blast instrumentation at the mine level will prove to a harbinger for practicing blasting engineers. Presently, the problem of scattering in surface detonators and down-the-hole detonators affects the blast performance significantly by increased blast induced ground vibration and reduced fragmentation. The paper discusses a case study carried out at Umrer opencast project of CIL to investigate the effect of scattering by using blast simulation techniques (i.e., JKSimblast) and observing the actual blast results with the help of a high-speed camera and multi-channel high frequency data acquisition systems. The fragmentation assessment was carried out by adopting Digital Image Analysis techniques and using the granularity software viz. Wipfrag. The blast instrumentation in the case study mine resulted in improvement in fragmentation of 12.76% and a direct savings in explosives cost of 28%. Geophysical techniques such as the seismic survey method have been used at Umrer Project, CIL to characterize the rock mass using the Multi Channel Analysis of Surface Waves system for selecting the explosives technoeconomically. The minimum deck thickness for mines of CIL using drill cuttings as decking materials should be 10 D, where D is the drill diameter. The estimation of blast performance on the basis of prescribed Powder Factor (i.e., kg of explosives per m3 of rock) is technically unscientific as the criterion of a good blast depends on many factors (i.e., good heave, loose muck, muck profile angle, ease of digging, uniform fragmentation). The present paper proposes a new methodology for techno-economic evaluation of blast performance. The new methodology involves four significant factors viz. specific energy consumed by the loading equipment, charge factor, productive yield and diggability index for assessing blast performance. The use of user-friendly, accurate, reliable, rugged and handy instruments in blasting will significantly improve mine productivity, equipment efficiency and economics. The improvement in blast performance, even by 1%, will provide a significant savings of $3.5 million USD per annum to CIL. It may be concluded with high degree of confidence that blast instrumentation at the mine level will influence the mine productivity and economics.

Aug 1, 2013

By Davood Moradkhani, Maryam Rasouli

"The present study reports solvent extraction and separation of zinc from concentrated nickel sulfate solution. In our previous study, Zn and Cd in cold filter cake (CFC, 45-55% Zn, 11-16% Cd, and 2.5-4% Ni) were extracted by alkaline leaching followed by electrowinning processes respectively. The strip solution from electrowinning process, was a pregnant liquor solution (PLS) containing 16.8 g/l Ni and 4.2 g/l Zn. In this work, PLS is subjected to the solvent extraction process for separation of traces of Zn from high grade nickel. The zinc free raffinate containing 16.6 g/l Ni sulfate solution will flow to nickel electrowinning plant for cathode production. Di-(2-ethylhexyl) phosphoric acid (D2EHPA) is the organic phase used in this study. The effects of various parameters such as organic phase concentration (10- 40 % v/v), pH (1.5-3), and temperature (25 and 45°) are investigated. Zinc over nickel separation factor increases by increasing pH from1.5 to 3. The results show that 98.7% of Zn was loaded at25°C O/A ratio of 1, pH 3, and 10% vol. D2EHPA. A 10 M NaOH is used for pH control. However, replacement of pH controlling agent with ammonia solution (25%. v/v) results in interesting observations. Ammonia addition, reduces the solubility of Ni2+ cations in solution. Nickel starts to precipitate from raffinate in a crystalline bluish-green form. The obtained crystals are characterized by XRF and identified to be nickel-bearing analog of boussingaultite, a rare sulfate mineral of nickel with chemical formula of Ni (NH4)2(SO4)2.6H2O. The crystallization rate of crystals is studied. It is a slow precipitation process with 75% in 4 days.INTRODUCTION Annually, many hydrometallurgical processes such as electrowinning, solvent extraction and leaching are applied to waste filter cakes in Zanjan, Iran. These additional processes on filter cakes are critical from both environmental and economic points of view. CFC (cold filter cake) is a toxic but valuable filter cake (45-55% Zn, 11-16% Cd, 2.5-4% Ni, and 0.2-1.5% Cu) produced in many zinc production plants. Our research group at Research and Engineering Company for Non-ferrous Metals (ReCo.), developed a series of hydrometallurgical methods for extraction of zinc, cadmium and nickel from CFC (Moradkhani, & Rasouli 2012). The recovery of zinc and cadmium with alkaline leaching and electrowinning was successfully studied. The strip sulfate solution from cadmium electrowinning unit, contains high concentration of nickel with some traces of zinc impurity. This pregnant liquor solution (PLS) was analyzed and reported to contain 16.8 g/l Ni and 4.2 g/l Zn. In this work, PLS is subjected to the solvent extraction process to separate Zn from nickel (Fig. 1). The organic phase stripping solution containing 4.2 g/l zinc and 200 ppm nickel can be circulated and used in the acidic leaching step. This generates nickel solution with high purity suitable for nickel cathode production."

Jan 1, 2017

By B. P. Simser, R. K. Brummer, A. Mortazavi, P. P. Andrieux

"A large-scale panel destress blast was fired at Brunswick mine in the fall of 1999 in order to reduce the ground stresses in a critically important neighbouring mining region. This work, sponsored by the Mining Division of CAMIRO and Brunswick mine, consisted in heavily choke-blasting — and subsequently leaving in place — a massive waste sulphide pillar in the southwest end of the 1000 m level. This paper describes the approach and design methodology used to try to maximize breakage in the rock mass in the area to destress, while minimizing damage to critical infrastructures in the vicinity. The loading operations, as well as the results of the blast — in terms of its field performances, as recorded by near-field blast vibration monitoring equipment, visual postblast assessments and measured impact on the regional stress field — are discussed as well. A brief comparison between the measured stress changes and inelastic numerical modelling of the test site is also presented.Un tir à grande échelle de relâchement des contraintes dans un pilier a été effectué à la mine Brunswick à la fin de l’automne 1999 dans le but de diminuer les contraintes de terrain dans une très importante zone de production adjascente. Ces travaux, financés par la division minière de CAMIRO et la mine Brunswick, consistaient à tirer violemment sans aucune face libre, et à laisser en place, un pilier de sulphures massifs au sud-ouest du niveau 1000 m. Cet article décrit l’approche et la démarche conceptuelle utilisées pour tenter de maximiser les fractures dans le pilier visé, tout en minimisant les dommages collatéraux à des infrastructures critiques se trouvant dans les environs immédiats. Les opérations de chargement des explosifs et les résultats du tir — en termes de ses performances, telles qu’évaluées par de l’équipement de monitoring rapproché des vibrations de tir, d’observations visuelles, et de son impact sur les contraintes de terrain locales — sont également discutés."

Jan 1, 2003

By Walter Koellner

Today?s large electric mining shovels are significant users of power and represent peak loads of more than 3.5 MW to a mine?s distribution system. The power swings during normal operation can influence the line voltage at the Point of Common Coupling (PCC). The static converters for the shovel?s motions also create voltage and current harmonics which are fed back into the mine?s power grid. In addition, shovels themselves are affected by the power quality of the mine?s distribution system. This paper introduces the use of active IGBT rectifiers, also called Active Front Ends (AFE), as alternative to conventional, line commutated SCR thyristor rectifiers. The AFEs convert the AC line input into a controlled DC-link voltage. This DC voltage is then used as input to IGBT inverters, which power the AC motors of the shovel?s Hoist, Propel, Crowd, and Swing motions. The introduction of AFEs creates the following operational improvements: i) reduction of the Harmonic Current Distortion THDi from more than 40% to less than 4%; ii) full regenerative operation; iii) the potential for line voltage stabilization at the PCC; iv) high tolerance for line voltage fluctuations; v) improved dynamic performance, and, as result vi) higher availability and productivity of the shovel.

May 1, 2001

By P. E. Weidmark

Allard, M., Hucka, V.J., Das, B., and Borchtch-Komponietz, V.I., "Investigation of seismic vibration due to large blasts in Gaspe Copper Mines"; (in Russ); The Industry of Chemical Raw Materials; Referativnyi sbornik; 5:18-20: 1978. Askew, J., McCarthy, P.L. , and Fitzgerald, D.J ., "Backfill research for pillar extraction at ZC/NBHC"; Mining with Backfill; Proc 12th Cdn Rock Mech Symp; May 23-25, 1978; Sudbury; CIM Spec Vol 19:100-lJO; 1978. Barrett, J.R., Coulthard, M.A., and Dight, P.M., "Determination of fill stability" ; Mining with Backfill; Proc 12th Cdn Rock Symp; May 23-25, 1978; Sudbury; CIM Spec Vol 19:85-91; 1978.

Jan 1, 1979

By G. F. Raymond, W. P. Armstrong

"At the time of this study, the Valley mine was producing 23 000 tonnes of ore per day from a large, low-grade porphyry copper orebody. Sulphide mineralization, principally bornite and chalcopyrite, occurs in a stock work of quartz veins in one phase of the Guichon Creek batholith. The property was explored from 1967 to 1982, and was placed in production in 1983.Using a three-parameter lognormal approximation developed by G.F. Raymond at Similkam een and Mount Isa Mines, a geo- statistical conditional probability ore reserve was estimated prior to mining. Comparisons with blasthole kriging and milled ore for the first 17 months of production showed close agreements at all cut-offs between conditional probability estimates and mineable ore. This was not true of either kriging or polygon estimates. An important part of this work was identifying and correcting for bias in both exploration and blasthole samples.IntroductionCominco&apos;s Valley lake deposit is a large, low-grade, porphyry copper orebody in the Highland Valley of British Columbia. Total indicated plus inferred ore reserves are 700 M tonnes at ore grade of 0.47070 Cu. At the time of writing, ore milling is at a rate of 23 000 tI d through the old Bethlehem mill. Mining is in 10m horizontal benches using 9.8 m3 shovels and 90 tonne trucks. Since this paper was written, Valley and nearby Lomex have been combined into Highland Valley Copper with a combined oreproduction of about 120 000 tI d.Copper mineralization, principally bornite and chalcopyrite, is regularly distributed throughout the deposit as disseminated low-grade within a granodiorite host rock, and as higher grade veinlets within a stock work of near-vertical quartz veins generally 10 cm or less in width. It is likely that problems with sample variability and sample bias are mainly related to mineralization within quartz veining. Valley geology has been described in detail by Allen and Richardson and by Osatenko and Jones (2). The exploration sampling program and identification of diamond-drill sample bias have been discussed by Armstrong and Newman&apos;»."

Jan 1, 1988

By Donald Strickland, Peter Kresin, Dave Hall

"Have your parents or grandparents ever tried to share with you their wisdom and you ignored it because it did not relate to you‘? I have been ignorant and inevitably grew older and wished I had listened. The result: learning the hard way. As British Astronomer Fred Hoyle once said. “It is the true nature of mankind to learn from mistakes not from example.“ Hopefully we will continue to learn from the examples shared by our fellow mineral processors in these conference proceedings. It is the intent of this paper to share wisdom from the Musselwhite Mine that you may apply to your own operation.This paper is divided into three sections:1. Feasibility3. Operation3 . DesignKey points of the Feasibility and Design stages are summarized. followed by an analysis of actual operating statistics. An attempt is made to relate these statistics back to the feasibility and design with emphasis on areas of success and those with potential for improvement."

Jan 1, 1999

By A. Eslami

When producing high grade mattes in smelter plants, copper losses in the slag are inevitable. Hence, the recovery of copper from slag has been the focus of many research projects, copper flotation being a widely used process. In the Khatoonabad converter, 200 t/d of slag are presently produced with a grade of 2.3% Cu. Assuming a 85% recovery by flotation, about 3.9 t/d copper could be produced, which is of prime importance economically. In the present work, a sample of this slag was crushed and ground in the laboratory to liberate the copper-bearing minerals. Following mineralogical studies, optimum laboratory flotation parameters were obtained, resulting in 90.27 % recovery and 9.42% of copper grade for the rougher stage. At pilot scale, a pulp of 28% solids was floated at ph 10.5 using 40 git of Z6, 25 git of R407 and 20 git of MIBC and A65. A recovery of 83.52% was obtained for a concentrate grade of 28.36% Cu. In the rougher cells, the feed consisted of particles 94% finer than 74 microns whereas in the cleaning stage, particles were 95% finer than 44 microns. Based on the obtained results, the Sarcheshmeh Khatoonabad converter slag is presently being fed to the Chargonbad flotation plant, where a concentrate of 32% copper at 86% recovery is being produced.

Jan 1, 2007

By J. Fournier

A novel sol ? gel (SG) synthesis procedure utilizing varying ratios of glycine and ethylene glycol to total metal cations has been developed to create high purity nanometer sized La0.65Sr3.5MnO3 powders. X-ray powder diffraction (XRD), transmission and scanning electron microscopy (TEM, SEM), and dynamic light scattering (DLS) have confirmed that the crystallite sizes of such powders are ~ 20 nm, and the aggregate particle sizes vary between 100 to 300 nm. Mixing varying weight percents of SG LSM powders with commercially available Praxair LSM in a composite LSM/YSZ functionally graded cathode has been shown, through the use of electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV), to exhibit enhanced oxygen reduction kinetics vs. at conventional cathode materials.

Jan 1, 2005

By J. Fournier

A novel sol ? gel (SG) synthesis procedure utilizing varying ratios of glycine and ethylene glycol to total metal cations has been developed to create high purity nanometer sized La0.65Sr3.5MnO3 powders. X-ray powder diffraction (XRD), transmission and scanning electron microscopy (TEM, SEM), and dynamic light scattering (DLS) have confirmed that the crystallite sizes of such powders are ~ 20 nm, and the aggregate particle sizes vary between 100 to 300 nm. Mixing varying weight percents of SG LSM powders with commercially available Praxair LSM in a composite LSM/YSZ functionally graded cathode has been shown, through the use of electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV), to exhibit enhanced oxygen reduction kinetics vs. at conventional cathode materials.

Jan 1, 2005

By A. D. Pittuck

Refractory minerals .containing uranium and columbium have been successfully treated at Queen&apos;s University, Kingston, to produce high-grade concentrates. Recoveries of over 90 per cent of the uranium and columbium have been obtained when treating concentrates containing euxenite, fergusonite, betafite, and pyrochlore. The processes ?consisted -of leaching the columbium with hydrofluoric acid, and the uranium with nitric acid, sulphuric acid, or sodium carbonate solutions. The leach liquors were extracted with organic solvents from which the values were stripped and precipitated, producing final products assaying 45 to 55 per cent Ob2O5 and 60 to 70 per cent U3Os.

Jan 1, 1958

By Christian Bourcier

La méthode d?exploitation traditionnelle de la mine est le chantier chambre-magasin. Cependant, lors de l?exploitation d?un chantier, nous avons été confrontés à un problème de soutirage. Le minerai abattu est resté accroché à l?intérieur du chantier ce qui nous obligea à soutirer environ 200 wagons, représentant 700 tonnes. Suite à l?ampleur de la situation, nous avons décidé de finir l?exploitation du chantier par la méthode sous-niveau long trou retraité. Cette première expérience de récupération de piliers ayant été réalisée avec succès, nous avons décidé de continuer avec deux autres récupérations de piliers afin de pouvoir augmenter notre expertise autant au niveau technique qu?au niveau économique.

Oct 1, 2001

By Chris M. Healey

"The Jasper Gold mine in northern Saskatchewan produced a total mill feed of 140 127 tonnes at an average grade of 19.0 g/t Au. Both diamond drilling and chip samples from underground workings returned extremely high values, up to 12851 g/t (375 oz/T) Au over 0.10 meter from a chip sample. In the presence of such extremely high grades, the accurate estimation of reserves is a major problem.In the first part of this study, production data from the mine were used to evaluate the results of a variety of reserve estimation techniques in this environment. In two out of three cases studied, indicator kriging with assays cut to 342.9 g/t (10 oz/T) gave extremely good results. In the third case, however, indicator kriging gave unacceptable results. Instead, lognormal kriging of uncut data gave the best results.Secondly, from the same database, a number of drill-hole spacings were simulated, and reserves estimated from the simulations. As may be expected, the results of this analysis show increasingly better results with tighter drill-hole spacing. However, even with a 5 m by 5 m spacing the variation from actual grade was quite large. This is not a systematic under- or over-estimation of grade, rather a random scatter of results.The results of this study show very clearly the problems of deriving good estimates of reserves when extremely high-grade samples are encountered. There is a high degree of randomness to this data base, so reserve estimation in this situation will remain a high-risk operation."

Jan 1, 1993

By A. L. Mackie

Arsenic is a highly toxic element and a known human carcinogen. It is often a contaminant in mine water discharges, particularly from gold mining and roasting operations, and has been found at concentrations as high as 4 g/L. Increasingly stringent controls on the concentration of arsenic allowed to be discharged into the environment cannot always be met by current treatment processes and thus enhanced technologies are required to achieve low treated effluent concentrations at reasonable costs. A novel two-step physicochemical treatment process was developed and tested at the bench-scale using synthetic mine water solutions (SMWs) in order to reduce arsenic concentrations in treated effluent to exceed current discharge regulations. The process includes chemical coagulation with ferric sulphate and ballasted flocculation for enhanced solid-liquid separation. The SMW contained 59 ± 2 mg/L arsenic with a slightly alkaline pH. The effect of arsenic speciation on the process was tested by using either arsenite, As(III), or arsenate, As(V), in the SMW solutions. Tests were performed at cold temperature (3 ± 1 °C) to ensure the process? efficacy year-round in northern climates. Arsenic in As(V) SMW solutions was removed to a final total concentration of 0.0054 ± 0.002 mg/L, almost half the current recommended allowable drinking water concentration of 0.010 mg/L. As(III) was removed to a concentration below the Metal Mining Effluent Regulations? (MMER) current limit of 0.50 mg/L, to 0.32 ± 0.06 mg/L, with double the coagulant dose used in Stage 1 for As(V) removal. Oxidant addition at a concentration of 5 mg KMnO4/L in Stage 2 resulted in final total arsenic concentrations of 0.017 ± 0.002 mg/L and pH adjustment with lime in Stage 2 resulted in 0.0415 ± 0.0007 mg As/L in treated As(III) SMW. Both of these modifications to the process reduced arsenic concentrations to below proposed new MMER limits (i.e., 0.10 mg/L). This two-stage treatment process was shown to reduce arsenic concentrations to well below current treatment guidelines while reducing or eliminating chemical oxidant demand.

Aug 1, 2013