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By L. Xia, B. Hart, J. Nigim, Z. Chen

"Grinding ore is an important step in the flotation process. Not only does grinding reduce particle size and liberate minerals, it also creates conditions for reactions to occur on particle surfaces that can aide or inhibit flotation. There have been numerous studies examining various grinding regiments and the effect on flotation pulp chemistry, including autogenous grinding and using media of variable composition. There have been however, few studies looking at the effect of variability in grinding media size on pulp chemistry and subsequent flotation. This study attempts to link changes in pulp chemistry in response to variations in grinding media size to flotation recovery. It uses probes mounted in the grinding chamber (pH, Eh, DO, and conductivity) to monitor pulp chemistry changes during grinding of a Cu-Zn ore. Surface chemistry analysis by ToF-SIMS was performed on sphalerite from the mill discharge. Activator and depressant species were monitored on the mineral surfaces and their presence was evaluated in the context of variability in pulp chemistry linked to differences in grinding media and its ball size.INTRODUCTIONIt has been widely recognised that not only does grinding reduce particle size and liberate minerals but the grinding environment has a large effect on the flotation of sulphide minerals. This effect is attributed to Eh change, iron hydroxide coating on surfaces, oxygen reduction, precipitation from solution and galvanic coupling (Grano, 2009). As early as 1960, it was reported that after grinding the ores in an iron mill the natural floatability of sphalerite was reduced significantly (Rey and Formanek, 1960). Kocabag and Smith (1985) studied on the industrial circuits showing that the depression of sulphides flotation in a steel mill is possibly due to the coating of iron oxidation products. Peng, Grano, Fornasiero, and Ralston (2003a, 2003b) found that iron contamination from grinding media plays a dominant role in depressing galena and chalcopyrite flotation. Huang, Grano, and Skinner (2006) reported the same observation in the flotation of arsenopyrite."

Jan 1, 2016

By Irving Wigden

The world is fast becoming information based. Mine companies migrate business infrastructures to be handled electronically. Suppliers move onto the worldwide web. In this ?e-world? successful suppliers will recognize they no longer trade in just equipment, but in knowledge. Companies can no longer just provide products and services, but instead must find ways to harness their knowledge to provide new value for customers. Mine customers will be attracted to suppliers that can help them streamline the process and use Information Technology to optimize operations, increase profit, reduce cost and enhance shareholder value. With the continued move to industry standard communications and software platforms, technology that formerly stood alone can now be integrated with other technologies. This creates more powerful systems that mine operators can use quickly, easily and cost effectively. These unified architectures improve productivity, provide higher asset optimization and allow more informed decision-making. As a leading supplier of process automation solutions for the industry, ABB provides a dynamic range of such control systems. These systems are designed for instrumentation controls, variable speed drives, electrical distribution, electrical equipment and related services for Mine Automation. Enhanced by ABB´s new family of integrated software solutions ? collectively known as Industrial IT ? ABB´s control and Scada systems place you in the best position to optimize your plant, process and enterprise operations. The paper discuss system integration and installation of High-Tec system in an underground mine. ABB has the ambition to be a System Integrator and co-operate with partners in different areas of technology. To day it is a problem to find one Supplier that can be responsible for the complete Automation System. The design of the system is also much depending of the design of the mine and also which caving procedure that is used in the current mine. Much of the work must be done in a feasibility study and during the design phase. If there is careful planning and consideration during these phases is vital in order to avoid costly changes during the commissioning phase. The paper will also include a presentation of the benefit of using Automation in an Underground Mine, and how important the integration of the Human Being is to the Automation System. The most profit gained in mining industries are received when the mines can reduce internal and external disturbances in the production flow and speed. Must of the experience and discussed in this paper is from advanced technology, that has been developed in Scandinavian and adopted of LKAB in Kiruna. The author of this paper has been responsible för the Automation projects in the Kiruna Mine during 1994 - 1999. These projects include: Broadband communication of data, audio, compressed video in one data stream. Control System for Haulage -1045m Automation of Load Haulage and Dumping machines (LHD) Control of Production Drilling Riggs from a Central Control Room.

May 1, 2002

By G. P. Gu

The in-service 90/10 cupro-nickel tubes in a water-chiller system suffered from severe corrosion damage during their relatively short service life causing unexpected down time. In addition to downtime, the environmental risk associated with losing refrigerant was also a concern that initiated this investigation, Microstructural investigation using SEM and electron microprobe indicated that pitting corrosion had resulted in local nickel depletion, During the corrosion process, copper appeared to have re-deposited around the corrosion pits accelerating the local corrosion.

Jan 1, 2005

By Corby G. Anderson

"Laboratory testing using industrial electrowinning solutions was performed to determine the best Faradic cell efficiency for copper cathode recovery. The variables tested were solution flow rate, recycle ratio, reagent addition combinations of guar and thiourea, and addition amount of acid mist suppressant CAL FAX DBA-70. The ideal flow rate was determined to be 37.85 litre/min. Additionally, the ideal recycle ratio was determined to be 10:1. The reagent addition scheme from testing which showed the highest efficiency was with 680 g/tonne guar of cathode copper won and with 135 g/tonne thiourea of cathode copper won. These values for reagent addition only reflect the best efficiency and should not be assumed to be the best reagent concentration for copper purity. The amount of foaming agent that showed the best efficiency was the test with 2 ppm of foaming agent. Again this amount of reagent is based on efficiency and should not be taken as the amount of reagent that does the best acid mist suppression. Additional proprietary surface characterization work indicates these additives may have enhanced the cathodic reduction surface morphology of some noble minor impurities. Subsequently, these operating parameters were introduced into the plant operation and proved successful after their implementation.BACKGROUNDCopper electrowinning has become a dominant technology for the production of marketable high grade copper cathode products. The literature is robust with applications, optimizations, additives and developments in this field (e.g., Classens & Harris, 1990; Pfalzgraff, 1999; Tozawa, Su, & Umetsu, 2003; San Martin, Otero, & Cruz, 2005; Houlachi, Edwards, & Robinson, 2007; Romero, Avila, Fester, & Yacher, 2007; Marsden, 2008; Beukes & Badenhorst, 2009; Vainio & Weatherseed 2009; Bender, 2010; Joy, Staley, Moats, Perkins, Uhrie, & Robinson, 2010; Khouraibchia & Moats, 2010; Moats, 2010; Rutledge & Anderson, 2015).Tests of forty hours duration and at room temperature were performed for this project using samples of actual industrial electrowinning solutions. These industrial solutions were comprised of 60 g/L Cu plus 65 g/L Ni, 3 g/L Fe, and 30 g/L free sulfuric acid. Other confidential minor impurities were also present including some solubilized precious metals. The testing apparatus utilizing stainless steel anodes and cathodes is illustrated in Figures 1 and 2."

Jan 1, 2016

By P. R. A. Andrews

"The sillimanite group minerals, kyanite, sillimanite and andalusite are identified as alumino-silicate minerals with the common chemical composition AIP3.Si02' so that each possesses similar physical properties. Kyanite is the most abundant mineral and mainly occurs in Quebec, Ontario and British Columbia; sillimanite occurs in Ontario and Manitoba; and andalusite in Nova Scotia. The main use for the sillimanite-group minerals is in refractory applications for the production of refractory bricks and shapes. In refractory applications, the main performance criterion is the relative percentage of mullite formed within the material during firing. This phase gives a greater degree of resistance to creep deformation and slag attack, and improves the ability of the refractory to withstand high temperatures under load. The beneficiation of refractory silicate minerals has been the subject of many investigations at CANMET, and the former Mines Branch. Eighteen kyanite, two sillimanite, and three andalusite evaluation studies were conducted between 1933 and 1987. A review of some of the more important studies is presented, which includes information concerning mineralogy, beneficiation methods and flotation data."

Jan 1, 1995

By Maureen McGuiness

"The pastefill circuit at the Bell Allard Mine in Matagami, Quebec started up in August 1999. The surface pastefill plant produces a cemented paste which is sent underground by gravity through a vertical pipeline in the mine ventilation shaft. Difficulties with paste flow during the start-up highlighted the importance of understanding paste rheology and the effect of operating procedures on line wear. By June 2000, the original circuit had been modified to include a paste pump to transport the paste to the shaft.The steps taken during the paste plant commissioning are discussed. The final flow sheet is presented, focussing on the use of instrumentation to ensure full column flow and proper distribution underground. Resistance modelling and accelerated curing of samples are examined as possible ways of predicting paste resistance to ensure compliance with the mine’s paste specifications.INTRODUCTIONCommissioning a new plant can be difficult and time consuming. The start-up of Noranda’s Bell Allard paste backfill plant was no exception. Since the first day it went into operation, the paste circuit could not meet the tonnage and paste quality requirements of the mine because the paste would not flow by gravity into the vertical pipeline in the mine’s ventilation shaft.Diagnosis of the pastefill problems proved difficult. It was only when the rheology of the Bell Allard paste was understood that the flow problems were solved. To ensure that the paste placed in the stopes meets mine requirements, two methods of paste resistance prediction are being developed."

Jan 1, 2002

By S. Feinstein, I. Reznik, Y. H. Hatzor, O. Shitrit, Y. O. Rosenberg, H. J. Vinegar, S. Nguyen

"We report the effects of porosity and total organic carbon (TOC) content on the mechanical behavior of organic-rich chalks, based on laboratory measurements. The organic-rich chalks are from the Senonian Ghareb and Mishash formations. This deposit is an immature oil-prone source rock, about 300 meters thick, situated at shallow depths (several hundreds of meters) in the Shefela basin in central Israel. The study is based on core data collected from the Zoharim borehole.Three main phases comprise the bulk volume of this rock: 1) carbonate mineralogical phase (predominantly calcite); 2) pores (mostly saturated with brine); and 3) solid organic phase (type IIS kerogen). The mechanical effects of porosity (23-45%) and TOC (4-19%) are evaluated based on bulk incompressibilities vs. volumetric fractions analysis. Volumetric fractions of mineralogical and organic phases were obtained by porosity, density and TOC measurements. Saturated rock bulk moduli were measured through ultrasonic velocity measurements. Saturated rock bulk moduli correlate best with the sum of kerogen and pore volume fractions, rather than each of them separately. The volumetric fractions were also used to define the range of bulk modulus of the organic-rich chalk, using the Hashin-Shtrikman upper and lower bounds. Based on Marion's Bounding Average Method (BAM), the normalized stiffness factor of the chalk averaged at w=0.197, indicating a soft pore geometry. Using the average normalized stiffness factor, the BAM predictions showed excellent match with the saturated rock bulk modulus and the sum of kerogen and pore volume fractions. Based on our findings, it is inferred that kerogen grains do not support the solid skeleton but are distributed between the minerals grains. We also propose here a straightforward approach for calculating the Hashin-Shtrikman bounds, based on TOC and porosity measurements. The mechanical effects of porosity and TOC indicated here are very important for the understanding of the influence of immature kerogen presence in highly porous chalks, as the Ghareb and Mishash formations."

Jan 1, 2015

By B. Burke

Magnesium and its alloys are attractive materials for use in automotive and aerospace applications because of the low density and good mechanical properties. However, difficulty in forming magnesium and the limited number of available commercial alloys limit their use. The present paper reviews the efforts to improve the attractiveness of magnesium through non-traditional processing, and presents preliminary results of current work on producing magnesium alloys via powder metallurgy P/M. P/M can be used to alleviate the formability problem through near-net-shape processing, and also allows unique chemical compositions that can lead to new alloys with novel properties. The feasibility of producing magnesium powder metallurgy products utilizing the industrially dominant process of mixed powder blending, uniaxial die compaction and controlled atmosphere sintering was investigated. An alloy composition based on the commercial Mg alloy AZ31 (3% Al, 1% Zn) was used to facilitate comparison to similar wrought products. The optimal processing conditions (compaction pressure, sintering time and temperature, and quenching temperature) were found to maximize sintered density and mechanical properties.

Jan 1, 2007

Open pit production planning is a procedure consisting of multiple stages. Although all the planning stages rely on the geostatistical block models, long- to short-term plans each require their appropriate resolutions and levels of details. The main motives behind using different resolutions are the tractability of the models and the practicality of the generated schedules. The current approach in the mining industry is to use nested pits generated by Lerchs-Grossman as the basis for long-term planning and to use manually generated polygons, within those pushbacks, as the units of production control in mid- and short-term planning. However, the nested pits generated by Lerchs-Grossman algorithm and the polygons drawn by mining engineer do not provide control over the value and tonnage of ore and waste inside the planning units and therefore cannot lead to optimum solutions. In this paper, we first present a pushback determination approach which maximizes the profit of the mine with control over the tonnage of ore and waste within each pushback. We then propose a clustering approach with size and shape control that determines aggregates within those pushbacks; and finally, we introduce a mathematical programming model which uses the generated pushbacks and aggregates as the planning basis and generates production schedules that maximize the net present value of the operation and are practical from the operation?s point of view.

Aug 1, 2013

By Z. Bibak, S. Banisi, A. Ghasemi, E. Nematollahi

"The use of large AG/SAG mills in the mineral industry has been on the rise recently due to a significant reduction in the capital and operating costs for achieving significant increases in plant throughputs. The major reason for downtimes in these mills is the time taken for the replacement of broken or worn liners. This loss of “availability” of these units has a significant impact on the productivity of these plant operations. The ability to predict liner life time and its evolving shape could help to optimize these comminution operations. In the past decades, various models have been proposed to estimate liner wear rate, but because of their empirical nature they could only be used within certain limited operating conditions. In this research, a phenomenological model which could predict the liner wear rate was proposed and tested. This model considers parameters such as; operating conditions, liner hardness, pressure on the lifter, and, relative velocity of particles and mill shell. Data from industrially measured liner profiles were taken during the liner life time at the Sarcheshmeh and the Gol-E-Ghohar SAG mills to provide a solid base to calibrate and validate the model. The comparison of the model predictions with the actual measurements of the liner wear rate showed that the results were in a good agreement at both, the Sarcheshmeh (R2=0.94), and the Gol-E-Ghohar (R2=0.97) concentrators.INTRODUCTIONAG/SAG mills are one of the most important technologies in the mineral processing industry in the recent decades. The “Availability” of these units in a plant operation is one of the most important economic parameter for evaluating their performance. The major reason for the downtime of these mills affecting their “availability”, is the time required to change worn or broken liners (Yahyaei, Banisi, & Hadizadeh, 2009; Maleki-Moghaddam, Yahyaei, & Banisi, 2012). The knowledge about the magnitude and profile of liner wear not only enables more accurate liner life estimation to prevent unwanted interruptions of the SAG milling in mineral processing plants and more strategically plan the scheduled mill outages for liner changes. It also could provide key information needed to select an appropriate liner design (Yahyaei et al., 2009; Rezaeizadeh, Fooladi, Powell, & Weerasekara, 2010a)."

Jan 1, 2016

By M. Medraj, M. A. Arafin, D. P. Turner, P. Bocher

In this study, the kinetics of isothermal solidification during TLP bonding of Inconel 625 and 718 superalloys with nickel based multi-component filler alloy BNi-2 have been studied through a combination of direct experimentation and mathematical modeling in order to determine the effect of process variables and, thus, to optimize the process. The predicted isothermal solidification completion times from the boron diffusion model and migrating solid/liquid interface model were in good agreement with the experimentally determined values and, they were found to be significantly less than those of other nickel superalloys with different nickel based filler alloys. Further, significant reduction of holding time was observed with increasing bonding temperature and with decreasing joint gap. No significant grain growth in the base metals has been observed in the temperature range being investigated (1325 - 1394K).

Jan 1, 2006

Operating CIP/CIL gold recovery plants in the arid regions of Western Australia face unique challenges due to water and ore quality issues. The presence of cations of Mg, Fe and Cu metals in water supplies and leached sulphide ores can have considerable effect on plant consumption of lime and cyanide, due to pH buffering and complexation effects. Reagent costs are critical to many of these operations. In this paper, computational modelling is used to analyse a number of process options to mitigate such issues. This requires careful consideration of the chemistry of the process system, and the ability to predict accurately the response of speciation and precipitation reactions to changing process conditions. The Mg-Fe-Cu-CN-H20 system is specifically modelled in this application. The Gibbs Free Energy Minimisation thermodynamic framework has been selected to model equilibrium phenomena. Furthermore, this approach has been extended to the process flowsheet level, incorporating multiple unit operations and recycle streams in a steady-state mass balance model. The Gibbs equilibrium composition module of HSC Chemistry software has been successfully integrated into the commercial flowsheeting package SysCAD. Consideration of the Gibbs Energy Minimisation capabilities of other flowsheeting packages has also been given. This approach has been successful in simulating the aqueous process chemistry typical of such plants. It has resulted in a predictive capability where equilibrium states respond appropriately to process changes. Potential cost savings may be identified by examining alternative process conditions to minimise overall reagent consumption.This methodology may be extended to other hydrometallurgical plants where issues of solution ideality, temperature and other equilibrium processes are sufficiently understood.

Jan 1, 2005

By M. Mai Manga, M. Renaud, A. Faucher, C. Bazin

ABSTRACT Grinding circuits are operated in the presence of disturbances resulting from ore changes and equipment malfunctions, such as hydrocyclone overloading, worn or partly plugged apexes, surging, and internal liner detachment that may cause a loss of classification performance. Metal recovery losses in downstream leaching or flotation circuits justify the development of methods for rapid detection of hydrocyclone malfunction. Two methods are presented in this paper. The first method uses measurements from sensors available in a grinding circuit and the second uses vibration sensors installed on the individual hydrocyclones of a nest.

Jan 1, 2011

A study was made to determine the effect of increasing concentrations of dissolved oxygen on the floatability of galena pyrite and chalcopyrite. Adsorption, flotation and contact-angle tests were done in deoxygenated, in air-saturated and in oxygen-saturated solutions. The results showed that the adsorption of collector increased as the concentration of oxygen increased. Adsorption followed the exponential law r = kC'/"• Discontinuities in the curves were observed after the adsorption of several monolayers of collector. Although adsorption increased with increasing oxygen concentration, the floatability of the pyrite minerals did not increase, because oxidation had adverse effects on the floatability of these minerals. The floatability of galena was maximum in oxygen-saturated solutions, pyrite was depressed and chalcopyrite was also slightly depressed. Contact-angle tests proved that a bubble could not be attached to large flat surfaces in deoxygenated solutions, because sufficient surface free energy was not available for adhesion after the deformation of the bubble. In the presene of air, all the minerals yielded the same maximum angle of 72 degrees, characteristic of isopropyl xanthate.

Jan 1, 1970

By A. M. Bell

"The property of Gaspe Copper Mines, Limited, is in the Gaspe Peninsula some 60 miles west of the town of Gaspe and 20 miles in from the north coast. The Copper Mountain deposit was first discovered in 1921 and first optioned and drilled by Noranda in 1938. The Upper Needle Mountain showings a mile south were found in 1938, but it was not until after a delay of 10 years that the more important deep ore at Needle Mountain was located by drilling. Production started in 1955, and the smelter commenced operation in December. Mining is by open stope methods with first production coming from the Lower Needle Mountain orebody, of which only a small portion has been exposed in underground openings.Stratigraphy and AlterationThe country rock is composed of limy siltstones of Devonian age. Away from alteration these are dark and generally carbonaceous. Throughout the drilled area numerous narrow layers of tuffaceous fragmental material occur, and such beds are found to provide excellent horizon markers by virtue of their uniform thickness and wide lateral distribution. These markers are valuable for stope control in mining the bedded replacement deposits.Intruding the sediments at Copper Mountain are porphyry dykes, and one drill hole encountered granite 1,400 feet below the valley. Solutions responsible for the rock alteration and ore deposits seem to have emanated from this intrusive centre.On the mine claims strong hydrothermal alteration has completely obscured the original character of the sediments. The unaltered formations are all very similar in appearance, but following alteration rocks that are very dissimilar in physical characteristics are produced, and such differences have an important influence on ore deposition. The alteration effects are known to extend over a vertical range in excess of 3,000 feet and have a surface area of two square miles. All known ore bodies are within the zone of alteration. In this, rocks are strikingly bleached to a white colour in contrast to the normal dark-coloured sediments, and are much harder and more abrasive, with bedding often obscured. The first effect of alteration is driving off of carbonaceous matter, followed progressively by silicification in the acid rocks and by the formation of lime silicates in the lime rocks, with an accompanying gain in silica and a corresponding loss in lime. Extensive analysis has shown that there is an actual addition of silica involved in the alteration."

Jan 1, 1949

By F. Parada L

Two copper concentrate with medium and high enargite content were leached in a 3 L autoclave reactor under conditions based on the CESL process. Copper, arsenic, sulfur and iron were checked in all the experiments and antimony, zinc and molybdenum were evaluated in selected tests. The 98% of the obtained copper extraction is agree with others authors, but the behavior of arsenic, iron an sulfur have some differences. The solid residue was characterized by chemical analysis, DRX and QEMSCAN®. Finally a comparative analysis with neutral roasting as an option for the treatment of this concentrate is done.

Jan 1, 2014

By O. S. Perry, G. H. Charlewood, K. Griffin, S Ogryzlo, H. Hopkins, G. MacIntosh

"The gold mines of Kirkland Lake are in Teck township, Timiskaming district, Ontario, latitude 48°9'N. and longitude 80°3'W., at an elevation of 1,038 feet above sea-level.There are seven contiguous producing mines in a length of 3;1/2 miles along the general east-west strike of the deposits. The seven mines are, in order from west to east, Macassa, Kirkland Lake, Teck-Hughes, Lake Shore, Wright-Hargreaves, Sylvanite, and Toburn.The first discovery of gold in the zone was made by W. H. Wright in 1911 on the east claim of the Wright-Hargreaves property, and the following year the Tough brothers and H. Oakes found gold in what is now the No. 1 vein_ at the Toburn. Production began at the Toburn in 1915, followed by Teck-Hughes in 1917, Lake Shore in 1918, Kirkland Lake Gold in 1919, Wright-Hargreaves in 1921, Sylvanite in 1927, and Macassa in 1933.To the end of 1946, 31,938,350 tons of ore had been milled at the Kirkland Lake mines, from which 16,132,700 oz. gold, having a value of $498,517,600, were recovered. The bullion varies from mine to mine between 800 and 900 fine, the average for all the mines being 853. The average fineness of the native gold is 941.The workings of some of the mines are more than 6,000 feet deep and sinking to depths below 7,000 feet is now in progress.GENERAL GEOLOGYThe regional structural geology of the area in which the mines of Kirkland Lake occur is described in a preceding paper in this volume by J. E. Thomson."

Jan 1, 1954

By S. Konetschnik, Lux Degel, R. Degel, T. Haslinger

UrbanGold and its partners from Mettop and SMS group have developed a novel technology for the recovery of valuables from all non-ferrous metals’ fractions of WEEE (Waste Electrical and Electronic Equipment), with a special focus on low qualities which are commonly landfilled or incinerated. The technology is marketed under the brand name “UrbanGold Flex” to illustrate the high flexibility in respect of plant design and raw material portfolio, allowing also the processing of low grade material and materials with high caloric values. The process of the technology’s centrepiece, a modified and enhanced bath smelting furnace called “HENRI”, was investigated in numerous pyrometallurgical trials as basis for a scale-up towards a capacity of up to 100,000 tons of WEEE-concentrates per year. All relevant facility components have been evaluated in respect of references, fall-back options, as well as exit strategies (alternatives) to minimize risks when establishing a novel technology. A spin-off within the development is the “UrbanGold Compact” technology which can be seen as optimization of state-of-the-art smelters by using an optimized TBRC as primary processing unit. As an UrbanGold Compact plant will be the first industrial scale reference of UrbanGold’s technologies, it is also explained in the publication. As precious metals recovery is of major (economical) importance when recycling WEEE, major attention has been given to minimize the losses of these valuables. These measures, as well as a sophisticated way of utilizing waste heat as far as possible, result in interesting business cases with gross profits of up to 20% or even more. INTRODUCTION Over the past years, the demand of electrical and electronic equipment has increased dramatically with technological progress. Innovations on the technology of electronic devices led to a shorter usage and lifespan and thus boosted the generation of Waste Electrical and Electronic Equipment (WEEE). WEEE is one of the fastest growing waste streams, growing at 3 to 4% per year worldwide and is expected to reach more than 52 million tons per year by 2021. Currently, about 45 Mt of these wastes are estimated to arise worldwide, and the trend is rising (Baldé et al., 2017).

Jan 1, 2019

By Fathi Habashi, Ahmet Deniz Bas

"The mechanism of leaching of semiconducting minerals such as PbS, ZnS, UO2, etc., has been the subject of intensive speculation by hydrometallurgy researchers in the early 1950s who assumed the formation of intermediate surface complexes that could be neither separated nor identified by physicochemical techniques. The electrochemical theory of leaching introduced in the late 1960s resolved this problem by comparing the leaching process to a corrosion phenomenon similar to the corrosion of metals. Few years later, experimental evidence showed that anodic and cathodic zones are formed on the dissolving mineral although no electric current is imposed on the mineral during dissolution. A discussion of these findings is outlined.INTRODUCTIONIn the early 1950s researchers realized that kinetic studies for leaching ores are as important as thermodynamic calculations. It was also during this period that the concept of species adsorption on mineral surfaces has dominated the interpretation of the mechanisms of most reactions. This may have been due to the fact that many researchers of this period came from the mineral dressing sector and were influenced by flotation theories. However, when the knowledge of lattice defects and the semiconductivity of minerals became known and their importance in extractive metallurgy was realized, there was a need to explain the leaching reactions in light of these modern theories (Habashi, 1969, 1970). Semiconducting minerals of importance in metallurgy are two categories: the sulfides such as those of copper, lead, zinc, and the oxides such as those of uranium."

Jan 1, 2016

By W. F. James

Introduction The season of 1927, from the point of view of mining development in the area west of Rouyn, was quite satisfactory. Serious prospecting and development' were undertaken over quite a large area, though the results in the matter of discovering new deposits of economic importance were rather disappointing. A large amount of systematic prospecting and geological mapping was carried out in the course of the work, and a considerable body of information collected. A widespread occurrence of sulphide mineralization was noted, chiefly near bodies of older gabbro. The frequent occurrence of pyrrhotite in or near which local concentrations of chalcopyrite were localized, lends support to the idea that such older sulphides as pyrite and pyrrhotite are relatively easy of replacement by chalcopyrite. From the prospector's viewpoint, areas near the contacts of masses of older gabbro are favourable prospecting ground, and pyrite and pyrrhotite mineralization are favourable indications that massive chalcopyrite may be found where it has completely replaced such sulphides. Pyrrhotite being magnetic is easily located, even where drift covered, by the use of such convenient instruments as the dip-needle and the magnetometer. It is suggested that pyrrhotite bodies, when located, be thoroughly prospected because of the fairly strong probability that they may show replacement by the more valuable chalcopyrite.

Jan 1, 1928