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By D. A. Beattie

Three novel dextrin polymers of varying functional group chemistry but similar molecular weight have been used to depress talc in single and mixed mineral studies. The mixed mineral system was a model sulphide ore consisting of talc, pentlandite, and chalcopyrite. Adsorption isotherms for the three polymers on both valuable and gangue mineral phases were determined to give initial clues as to the ability of the polymers to depress talc. Flotation testing revealed a distinct hierarchy of effectiveness of the polymers in the depression of talc in the single mineral system (MP Dextrin > CM Dextrin > Dextrin TYM), reflecting the observed adsorption affinity and adsorbed amount of the polymers on talc. However, a different order of effectiveness was observed for talc depression in the mixed mineral system (CM Dextrin > MP Dextrin > Dextrin TYM). Competition between the valuable and gangue mineral phases for uptake of MP Dextrin is responsible for its observed decrease in efficiency in mixed mineral flotation. All three polymers were found to be reasonably selective in their action, although at high dosages the polymers began to affect the flotation of the valuable minerals.

Jan 1, 2006

By V. Prodanovic, M. Militzer

Production of advanced linepipe steels with strength levels of 685MPa (100ksi) and higher requires excellent control of runout table cooling to produce the desired final fine-grained microstructures, which may include acicular ferrite. Cooling is exerted on the runout table by applying water jets onto the hot surface of the strip and heat is removed from the steel by forced convective boiling. The associated boiling mechanisms are complex and include film, transition and nucleate boiling. A pilot-scale runout table test rig has been built to systematically study boiling heat transfer from a moving steel plate by employing industrial scale headers. Experiments were conducted using test plates moving at speeds between 0.3 m/s and 1.4 m/s. The plates were cooled down from 850°C to temperatures below saturation by a single water jet supplied through an industrial size circular nozzle. Based on these experiments heat fluxes were determined and further used to develop improved runout table cooling models.

Jan 1, 2005

By J. I. Gazzarri

A model of solid oxide fuel cell AC impedance behaviour has been developed and is used to simulate the frequency response of a single cell with and without mechanical damage. The results indicate that the presence of mechanically induced damage within the components of a solid oxide fuel cell can be detected by comparing the frequency response of the undamaged cell with that of a cell in which in-plane cracking or delamination has occurred. The presence of such defects manifests itself as a new semicircle in the Nyquist impedance diagram of the full cell. A parametric study reveals the resolution capabilities of the method in terms of the geometrical characteristics of the defects.

Jan 1, 2005

By Göckmann. Klau

"IntroductionCopper has been recycled ever since its discovery. Even in Graeco-Roman times recycling of this resistant, and thus valuable material was carried out as a matter of course. Just take, as an early example, the Colossus of Rhodes: after the figure collapsed during an earthquake, the bronze parts were melted down into ingots and sold.Copper is a material which can be recycled again and again because copper produced from recycling is not different from copper originating from primary materials. This is mainly due to electrolytical copper refining whereby not only the base metals but also the precious metals can be removed. In contrast, with aluminum and iron only the more electropositive elements can be removed by refining, and the resultant scrap must, therefore, be sorted mechanically into various alloys for subsequent smelting.The recycling rate for different base metals is given in Table 1. Despite this ideal prerequisite, the generally quoted recycling rate of copper of about 40070 appears rather low. However, it must not be forgotten that the recycling rate is defined as the ratio of the annually utilized quantities of copper scrap and the annual production figures (Table 2). Moreover due to the economic growth over the last 30 years the availability of copper from scrap materials is lower than its consumption because copper is principally employed in very long-life consumer durables and only returns to the recycling circuit after many years. The average time for the copper of some goods to be recycled is detailed in Figure 1."

Jan 1, 1992

By F. Habashi

The pioneer work on pressure hydrometallurgy was conducted in Russia at the end of the nineteenth, and the beginning of the twentieth centuries, by Karl Josef Bayer (1847-1904) and Vladimir Nikolyevitch Ipatieff (1867-1952), both working independently in Saint Petersburg. Bayer was studying pressure leaching while Ipatieff was studying the precipitation of metals and their compounds by hydrogen under pressure. Gradually, industrial applications took place first in the aluminium and later in the nickel industry. Today, the technology is well established in a large number of industries, such as uranium, gold, zinc, titanium, tungsten, and more recently copper.

Jan 1, 2004

By B. Das

"Computers have been used extensively in the mineral industry in exploration, reserves calculation, mining technology, mineral processing, etc. With respect to coal mining, there are also various applications for evaluating rock slope stability of open pits, design of open pits, underground operations, mine ventilation, ground control, data processing and management information, operations control and certain technological applications. Mine ventilation appears to be the field in underground coal mining touched on most; on the other hand, underground coal mining methods evaluation is represented only sparingly.It is therefore essential to review the status of the computer in underground coal mining methods evaluation in order to define its scope for further application. The paper discusses the roles of the mining engineer, programmer, computer operator and analyst as well as that of the computer. The important parameters will be identified and discussed along with their application for different underground coal mining methods, with their individual unit processes. Mainly, longwall face operations have been covered. Although many models have been of academic interest, they can be considered as important steps in a transition stage which will be followed by more practical applications for computers for underground coal mining method evaluations in the future. This calls for a coordinated effort from all concerned."

Jan 1, 1981

By W. Curlook, V. G. Papangelakis, M. Baghalha

A pressure acid leaching process has been developed for the extraction of metal values, nickel, copper, cobalt and zinc, from base metal smelter slags. The basic concept contemplates cooling the smelter slags through solidification sufficiently slowly to induce a good measure of crystallization; and subsequently, after fine grinding, to pressure leach such slags at around 250°C while applying oxygen overpressure, utilizing smelter byproduct sulphuric acid. High levels of extraction of the slags' metal values are thereby achieved. It has been shown that if the same slags are quenched thereby producing an amorphous structure, the resulting metal extractions are very low. The process is applicable to smelting furnace throwaway/discard/dump slags, as well as to in-process converter slags. By extracting the bulk of the residual base metal values in the throwaway/discard/dump slags, the resulting leached residues are rendered virtually benign vis-à-vis the external environment.

Jan 1, 2004

By J. A. Finch, G. Labonté

"A long-standing objective has been to obtain interpretable measurements of the oxidation-reduction potential in mineral slurries. For this purpose several sensing electrodes (black platinum wire, platinum foil and spiral, gold foil and spiral, and sulphide minerals such as chalcopyrite and galena) were investigated to determine their response to the presence of sulphide minerals in the pulp, and to the addition of reagents commonly used in flotation. The observed discrepancies between the electrodes may be explained using a combination of the classical mixed potential model for complex solutions and the probability of contact between the mineral particles and the sensing electrode. It is shown from laboratory testwork that gold spirals are preferred over platinum electrodes. Finally, some of the practical aspects of using the electrochemical measurements in a plant environment are discussed.IntroductonThe interpretation of flotation of sulphide minerals in terms of electrochemical (electron transfer) processes has brought new possibilities for process control of selective flotation. Investigations on massive and compacted particulate bed electrodes have shown that the flotation of a given mineral in the presence of a collector can be controlled by the potential induced on the mineral surface. Also, phenomena such as collector less (self-induced) flotation, activation by heavy metal ions, and natural selectivity sustained by galvanic coupling during flotation might also be controlled by electrochemical means.The technique for measuring electrochemical potential in slurries is an adaptation of that used for solutions. The measurement of the oxidation-reduction potential of a solution (ORP , Redox, Eh) is usually carried out by immersing a noble metal electrode (platinum, gold or silver) and a non-polarizable reference electrode: Standard Hydrogen Electrode (SHE), Standard Calomel Electrode (SCE), or silver/silver chloride (Ag/AgCl) in the solution. (The abbreviation Eh implies the SHE is the reference electrode.) The potential difference between the two electrodes is measured using a high impedance electrometer. ASTM standard D 1498-76 (revised 1981)(1) covers the practical details of such measurements; however, it does not deal with their meaning either in complex solutions or in mineral slurries ."

Jan 1, 1988

By P. A. Studemeister

"A trondhjemite stock intrudes a volcanic sequence that has massive sulphide lenses and that is metamorphosed to the greenschist facies at Gutcher Lake, 25 km north of Wawa, Ontario. The stock is 4 km2 in plan and is partly enveloped by an aureole of chlorite-epidote-amphibolehornfels up to 1 km wide. Within this contact aureole, biotite is partly pseudomorphosed by chlorite;epidote and hornblende are mottled by chlorite, calcite, plus quartz; albite has 0% An to 8% An; and hornblende porphyroblasts have actinolite rims. The stock has chlorite pseudomorphous after biotite; and feldspar is mottled by white mica plus calcite and has a clear rim of albite. Fractures filled with quartz, calcite, ankerite, chlorite, white mica, pyrite, and native gold cross-cut the stock and its hornfels aureole. These gold-bearing veins are enveloped by foliated rocks with quartz, calcite, white mica, and chlorite that grade outward from the veins into trondhjemite or hornfels.The stock, emplaced into a submarine volcanic series, emanated heat that caused seawater to convect and formed a contact aureole of hornblende hornfels. The stock eventually intruded its aureole and this culminated with regional metamorphism to the greenschist facies. Regional metamorphism hydrated the stock and its hornfels aureole. Native gold precipitated with quartz along fractures from metamorphic flu ids in response to cooling and wallrock hydration. exploration for this type of gold deposits should focus around felsic intrusions that have albite and that have contact aureoles retrograded by regional metamorphism."

Jan 1, 1985

By Dalton. J. L., H. P. Dibbs

An account is given of investigations into the application of two neutron methods to the on-line analysis of slurries. One deals with the application of the neutron moisture gauge principle to the determination of the water content of iron oxide slurries, and the other with the application of gamma radiation from thermal-neutron-capture to the determination of the composition of aqueous slurries of iron oxide, copper oxide, zinc oxide and sulphur. Linear relationships were found between the composition of the slurry and the neutron count-rate in the first study, and between the slurry composition and the prompt-gamma-ray count-rate in the second study. A mathematical relationship has also been developed which relates changes in the prompt-gamma-ray counts from hydrogen to changes in slurry composition.

Jan 1, 1973

By R. A. Rabnett, G. Paget, Patrick Walsh

"Tumbler Ridge, Canada's newest resource community, has been developed differently than have been other resource communities.Since its conceptualization, emphasis has been placed on the establishment of a traditional municipal government at early a stage as possible.Planning f or the community goes back to 1977. By then, extensive study by provincial agencies had shown a new resource town would be required to exploit north east coal. The Ministry of Municipal Affairs, in conjunction with a consultant named R.A. Rabnett began the extensive Tumbler Ridge conceptual plan.The results of the conceptual plan are evident in the organizational and planning goals of Tumbler Ridge. In every aspect from the election of officials to some financial matters, the town functions as a normal municipality. With the resource companies of the North East Coal Development within its municipal boundaries. Tumbler Ridge has been able to debenture its capital projects against its municipal tax base.The town's ability to function as a normal municipality is enhanced by its control over Crown land it has purchased from the province. This gives it further control over the development of the community and helps in establishing agreements with the resource companies and the provincial government to ensure that housing and service needs are met. While resource company representatives sit on certain municipal committees, their roles are advisory in nature.The community continues to move toward full municipal status and will have a fully elected Council by 1986.BackgroundPlanning for the development of northeast British Columbia coal resources began in 1976 under the aegis of the provincial Cabinet Committee on Coal Development. A series of subcommittees were established including a Townsite/Community Development subcommittee. The Ministry of Municipal Affairs chaired this subcommittee and continued as the lead agency for the provincial settlement planning effort over the period 1976 to 1981."

Jan 1, 1983

By P. West-Sells, B. Wassink, N. Fisher

Gold leaching from a commercial cyanide-amenable gold ore was studied at 25°C using sodium bisulfide-hydrogen sulfide solutions containing elemental sulfur. Gold extraction from the ore using 0.55 M NaSH, 4.1 atm (60 PSI) H2S, 1 g/L S8 and 26% solids by weight was about as good as the best extraction obtained by cyanidation. Maximum extraction was achieved in roughly 48 hours. Sulfur dissolves in the bisulfide solutions to form a mixture of polysulfides. Simple speciation calculations indicate that gold solubility as bisulfide complexes should be roughly ten times higher than in the absence of added zerovalent sulfur. The principal bisulfide complex is believed to be [Au(HS)2]-. Gold dissolution is favoured by increasing HS- concentration and by increasing H25 pressure. Polysulfide complexes of gold are also likely to be formed, and may contribute substantially to gold leaching. Two experiments using pure gold were also performed. Up to 100 mg/L gold was dissolved in 140 hours using 0.55 M NaSH, 1 g/L added elemental sulfur and 6.2 atm H2S.

Jan 1, 2005

By G. R. Baiden

"An Automatic Haulage Truck (AHT) has been developed for manless tramming of run-of-mine material in an operating mine. The AHT has a 70-ton capacity and uses an electric trolley system in combination with a computer control system to operate the vehicle. The purpose of the AHT was to provide a high capacity, high productivity material transfer system where conveyor belt applications are not immediately practical.The AHT project was started in 1983 at Inco Limited, Ontario Division as a result of the need for rapid material transport to match increased extraction rates resulting from bulk mining methods. The original concept was to use a continuous loader with the truck. However, in order to minimize development problems the truck project was considered a stand-alone project.The AHT project consisted of concept development, preliminaryand detailed design, manufacture, surf ace testing and mine implementation.The AHT was manufactured and ready for testing in 1988. At this point the truck was first moved onto the test track for debugging. This proved successful and in 1989the decision was made to install the AHT at Little Stobie mine on 2000 level. Commissioning of the system was started in 1990and at present a fully functional automated haulage system is in place at Little Stobie mine producing 3000 tons/day.This paper describes the project presenting results achieved to date."

Jan 1, 1992

By L. C. S. Dharmasiri, S. M. Shin, A. Senaputra, J. S. Sohn, K. H. Park, J. Avraamides

Reducing agents can be applied to leach metal values from natural and secondary resources such as laterite ores and deep sea manganese nodules and recycled materials such as spent batteries / catalysts which contain high-valent metal oxides of manganese, cobalt and iron. Selective leaching of some metals can be achieved by selecting conditions to control the saturated solubility and dissolution rates of metals from oxides or mixed metal/oxide matrices. The leaching results are rationalized on the basis of chemical species, Eh-pH diagrams and heterogeneous kinetic models. The role of reducing agents such as hydrogen peroxide, sulfur dioxide and iron(II) sulphate, in acid, alkali and in the presence of complexing ligands such as ammonia for the improvement of the leaching of metal oxides and metals is discussed. Previous studies on acid leaching of metals from nickel laterites, manganese nodules and spent catalysts/batteries in the absence or presence of reducing agents show that the rate controlling step involves the diffusion of protons through a thickening product layer on the particle being leached. It is shown that the leaching of nickel and cobalt from manganese nodules and zinc-carbon batteries in ammoniacal sulphur dioxide solutions also obey shrinking core kinetics.

Jan 1, 2014

By G. B. Hobbs, S. Saimoto, L. Collins

"Plastic yielding and flow in metals is dependent on the microscopic process of simple shear along crystallographic planes and directions known as slip. Thus, by altering the crystallographic direction of the stress axis or placing constraints in the direction of plastic flow, anisotropy of yield strength for the same material is observed. This phenomenon is called texture strengthening. The application of this concept to highly anisotropic crystal structures such as the hexagonal group of titanium and zirconium alloys, the former in missile casing and the latter in nuclear reactor fuel tubing, seems obvious. The outstanding example in cubic structures is the case of deep-drawing steel. The R value, the width strain over the thickness strain during a tensile test, is taken as a measure of texture strengthening. In face-centred cubic structures, texture strengthening has been completely ignored on the basis that materials with R less than one are not amenable to this beneficiation. This study will review two aspects of texture which will lead to strengthening, first the thermal stability of the deformed microstructure, which is dependent on the stress axis, and second, the texture strengthening aspect of fcc metals.A review of recovery and recrystallization in textured aluminum wires, copper and cupro-nickel sheet will be presented with the view of extending these concepts to the manufacture of heat-exchanger tubing. The superior creep properties of specially processed commercial products such as TD-Ni, TD-NiCr and MAR-M200 will be shown to be a manifestation of the same physical phenomena."

Jan 1, 1981

By J. R. Pronovost, P. M. Tiley, D. W. Watts

"In 1980, J.S. Redpath Limited were retained by Dickenson Mines Limited to increase hoisting capacity from 700 to 1000 tons per day. The hoisting capacity of the present skip-over-cage system could not be increased significantly through design modifications. The other constraint was a minimum of disruption to the current production. The Dickenson shaft was a three-compartment shaft from surface to the 8th level and four compartments before the 8th to the 23rd level. The solution to the problem was to remove the services from the shaft man-way compartment from the 8th level to surf ace by drilling a borehole close to the shaft and rerouting those services through the borehole to the 8th level. A service compartment would then be available from surf ace to the 23rd level.By providing a service hoist in this compartment, the skip hoist would then be free to produce the 1000-tons/day required production. This paper will describe the search for the required hoist and the friction hoist selected for the project, and trace the design modifications required to modify the hoist to suit the Dickenson application and satisfy the Department of Labour safety requirements.The paper has been co-authored by J.S. Redpath Limited and C.L. Tiley Associates, who participated in the design changes and eventual commissioning of the hoist.IntroductionIn the earl y part of 1980, J.S. Redpath Limited conducted an engineering study on the Dickenson Mines Limited No. 1 Shaft materials handling system. The object of the engineering study was to investigate the possibility of increasing the tonnage hoisted from the No. 1 Shaft complex by adding a service cage compartment and service hoist. This would permit utilization of the existing hoisting plant solely for production hoi sting. A further consideration of the engineering study was that any alterations had to be accomplished with little, or no, interruption to production."

Jan 1, 1982

By J. R. Pronovost, P. M. Tiley, D. W. Watts

"In 1980, J.S. Redpath Limited were retained by Dickenson Mines Limited to increase hoisting capacity from 700 to 1000 tons per day. The hoisting capacity of the present skip-over-cage system could not be increased significantly through design modifications. The other constraint was a minimum of disruption to the current production. The Dickenson shaft was a three-compartment shaft from surface to the 8th level and four compartments before the 8th to the 23rd level. The solution to the problem was to remove the services from the shaft man-way compartment from the 8th level to surf ace by drilling a borehole close to the shaft and rerouting those services through the borehole to the 8th level. A service compartment would then be available from surf ace to the 23rd level.By providing a service hoist in this compartment, the skip hoist would then be free to produce the 1000-tons/day required production. This paper will describe the search for the required hoist and the friction hoist selected for the project, and trace the design modifications required to modify the hoist to suit the Dickenson application and satisfy the Department of Labour safety requirements.The paper has been co-authored by J.S. Redpath Limited and C.L. Tiley Associates, who participated in the design changes and eventual commissioning of the hoist.IntroductionIn the earl y part of 1980, J.S. Redpath Limited conducted an engineering study on the Dickenson Mines Limited No. 1 Shaft materials handling system. The object of the engineering study was to investigate the possibility of increasing the tonnage hoisted from the No. 1 Shaft complex by adding a service cage compartment and service hoist. This would permit utilization of the existing hoisting plant solely for production hoi sting. A further consideration of the engineering study was that any alterations had to be accomplished with little, or no, interruption to production."

Jan 1, 1982

By G. R. Larocque

"The Loss Prevention Program and management style applied at Kidd Creek enabled them to maintain a 1.02/200 000 man-hours accident frequency over a 20-year period. Falconbridge Limited, Kidd Creek Division operates a major zinc, copper, silver mine, two gold mines and a metallurgical facility in Timmins, Ontario. The metallurgical site and the base metal mine are 17 miles apart and joined by their own railroad. The minesite consists of two shafts, one 3000 feet deep and the other to 5200 feet deep, as well as the necessary maintenance and service shops. The metallurgical site consists of a 14 000 STPD concentrator, a zinc refining plant, copper smelter, copper refinery, and the necessary maintenance shops. The two gold mining operations are adjacent to the metallurgical site.At the time of writing this paper the workforce consisted of some 2500 people divided between the two sites. Nine hundred and ninety-two employees are stationed at the minesite, with the remainder at the metallurgical site and gold mines. The workforce in the Timmins operation is non-unionized and reflects the belief that employee interests are well served.Beside providing competitive wages and an excellent benefit package, Kidd Creek takes special pride in its employee relations practices and continued efforts in communication.In each of the programs referred to, there have been equal involvement by both management and the employees. Each crew, under the direction of a supervisor, makes up its own health and safety committee. To maintain a successful Loss Prevention Program, it is essential that management and the employees work closely together and provide meaningful input and effort to succeed.At this point, refer to the lost time injury frequency as a measure of failure and refer to the opposite end of the scale as the measure of success. The ultimate goal of every operating company is to have a zero frequency, therefore denoting 100070 success. The company uses most of the tangible safety aids found in other mining operations, such as safety posters, safety reminders, check lists, and the use of the Neil George Safety System. The difference is the manner and style of management at the Kidd Creek Division. Their ""open door"" policy and the close association, between management and the employees, has always served them well. Also, at Kidd Creek they believe they have a well-trained and dedicated workforce."

Jan 1, 1989

By G. Wilson

"Satisfactory hydraulic performance of a centrifugal slurry pump is not the only design criterion. If abrasive wear exists the severity of any damage can be reduced and the life of the wearing parts prolonged by selecting the correct pump to suit the conditions of service. This paper is concerned with the design and construction of centrifugal pumps for handling abrasive solids. The wear phenomena due to the slurry being pumped and the materials used to combat abrasive, wear are outlined. The hydraulic design of the impeller and casing and their relationship to wear and the hydraulic radial and axial unbalance are discussed. The prediction of abrasive wear in pumps can not be precise, as many factors are involved - and this is the object of current research."

Jan 1, 1973

The mixer that is commonly encountered in hydro metallurgical operations consists of a single turbine and tank combination. However, it would be advantageous to examine some common solvent extraction mixing systems in the light of the fundamentals of chemical reactor design. The basic concepts of reactor design are commonly used in the chemical industry, and it should not be too difficult to apply them to solvent extraction. The factors that affect the engineering design of a reactor are: the reacting system; the type of reaction; and the configuration of the reactor. The reaction system in solvent extraction consists of a heterogeneous liquid phase, involving two immiscible liquids. It is essential f or the process that the reactor product can be separated efficiently in the subsequent settler. The type of reaction in solvent extraction system may be quite complex, and the picture is complicated by the presence of competing and side reactions. The reactors themselves have been generally continuous stirred tanks, and the nature of the mixer-settler makes it unlikely that the pumping mixer can be dispensed with. However, it appears that there should be some definite advantages to a system of stirred reactors in series. The kinetic experiments which are carried out should have the definition of optimum reaction conditions as one of their goals. The data obtained from these experiments must also be applicable to the design of reaction equipment. Reactor selection and design is often a unique problem for each chemical process, and does not lend itself to a systematic general approach. However, the application of chemical and physical principles to mixer design in solvent extraction should result in practical, more efficient plants.

Jan 1, 1979