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By P. H. Jennings

Commercial tellurium commonly contains heavy basemetal impurities such as lead, copper, iron, etc., as well as selenium and oxygen. The base metals may be removed by vacuum distillation or by zone melting. Vacuum distillation is a convenient method for treating moderate quantities (~ 100 kg.) for the production of a material having a total content of heavy metals in the 10-30 ppm range. By zone melting, it is possible to lower all the heavy metal impurities tm below the limits of spectrographie detection. Neither vacuum distillation nor zone melting is effective for the removal of selenium, but treatment of molten tellurium with hydrogen converts selenium to hydrogen selenide. This procedure is too s low to be considered except as an adjunct to zone melting. In the course of air-melting, many of the more easily oxidized impurities form a dross and may thus be readily removed. Substantial refinement with respect to iron, tin, chromium, aluminum, sodium, silicon, magnesium, calcium and manganese can be achieved in this way. Although tellurium can be electrodeposited from either acid or alkaline solutions of the dioxide, various factors militate against successful electro-refining, amongst which may be mentioned the brittleness of cast tellurium anodes and the tendency for the metal to be deposited in dendritic form, even at low current densities.

Feb 1, 1966

By P. H. Jennings, J. C. T. Farge

Commercial tellurium commonly contains heavy base-metal impurities such as lead, copper, iron, etc., as well as selenium and oxygen. The base metals may be removed by vacuum distillation or by zone melting. Vacuum distillation is a convenient method for treating moderate quantities ( 100 kg.) for the production of a material having a total content of heavy metals in the 10-30 ppm range. By zone melting, it is possible to lower all the heavy metal impurities tm below the limits of spectrographie detection. Neither vacuum distillation nor zone melting is effective for the removal of selenium, but treatment of molten tellurium with hydrogen converts selenium to hydrogen selenide. This procedure is too slow to be considered except as an adjunct to zone melting. In the course of air-melting, many of the more easily oxidized impurities form a dross and may thus be readily removed. Substantial refinement with respect to iron, tin, chromium, aluminum, sodium, silicon, magnesium, calcium and manganese can be achieved in this way. Although tellurium can be electrodeposited from either acid or alkaline solutions of the dioxide, various factors militate against successful electro-refining, amongst which may be mentioned the brittleness of cast tellurium anodes and the tendency for the metal to be deposited in dendritic form, even at low current densities.

Jan 1, 1966

By L. Frost

Physical Conditions Great Britain The physical conditions in the mines investigated in Great Britain are similar to those found in the mines of the Dominion Steel and Coal Corporation, with the important difference that many of the coal seams visited were interspersed by a large number of heavy faults, making the development of a continuous face operation difficult, and in many cases the life of a unit development was exceptionally short, adding to unit cost; but in spite of these difficulties, a great deal has been accomplished in the application of mechanical loading units in a number of the mines in the areas visited. The coal-bearing measures, as in Nova Scotia, consist of shales and sandstones, and in some sections mussel bands overlie the coal seams making roof conditions difficult'. In several mines, the main roof consisted of weak shale bind, being held by a coal roof of varying thickness. This shale bind had a tendency to flow when the coal roof was broken. The floor, in some cases where cutter loaders were operated successfully, consisted of weak, flaky shales with very little resistance and a tendency to disintegrate into powder when broken. The depth of cover under which these mines were operating varied from 250 feet to 2,340 feet, with an average of 1,700 feet. The coal seams varied in height from 3 feet to 8 feet 6 inches, and the gradients from level to 33 per cent. The seams vary in hardness, but all-with the exception of one seam, the 'Morrison Busty'- presented a cutting problem similar to that found in Nova Scotia. The structure and cleavage of the coal was well defined and uniform. Some of the seams visited were gassy, ?but the temperature of the workings generally was not in excess of 70°F.

Jan 1, 1948

By C. Bergstrand

"Precipitation of gypsum and the formation of scale may pose a serious challenge in the leaching of several minerals. As an example, precipitated gypsum may form scale in the machines increasing the need for maintenance. Alternatively, it may encapsulate precious elements, i.e. gold and lower the recovery during subsequent leach processes. In this work we explore how different biopolymers modify the rheology of gypsum at three different pH levels at ambient and elevated temperatures. The ability to disperse gypsum vary with temperature, pH and biopolymer. It is also inversely related to the scaling potential. Measurements of the zeta potential as a function of increasing amounts of biopolymer reveals that the magnitude of the zeta potential changes in the presence of biopolymer, and so does the ability to disperse the gypsum suspension. Similar results with hematite will also be discussed. The methodology and results may aid in the selection of additives used in mineral processing applications where scale pose a problem.INTRODUCTION Processing of refractory gold ores normally involve either atmospheric or oxidation under pressure in order to convert sulfides to oxides (Weir, King, & Robinson, 1986; Weir, Robinson, & King, 1986). This conversion facilitates leaching of gold (and silver) in normal CIL processes. During oxidation, sulfides are converted to sulfates. Normally, there is an abundance of calcium ions in the process water, either released from the ore or added as lime to adjust pH for the CIL process. Precipitation of calcium sulfate, or other compounds (calcium carbonate, jarosite, hematite) is a way to remove gangue minerals from the solution entering the CIL circuit (Ji, King, Fleming, & Ferron, 2010). Precipitation may also cause challenges in the process as gold (or other valuable elements) may become encapsulated in gangue. (Beauchamp, Choung, & Xu, 2006). In addition to precipitation, the precipitated gangue minerals may solidify and form scale in the processing equipment. Recently, Lauten and Kluck (2016) found that dispersants used as scale inhibitors to prevent encapsulation of gypsum did not modify the solubility of gypsum. In the utilised model system, similar amounts of gypsum precipitated with and without dispersants. Instead, it was found that the dispersants evaluated as scale inhibitors reduced the yield stress of gypsum suspensions. The reduced yield stress was associated with a reduced tendency for gypsum particles to agglomerate and form scale."

Jan 1, 2017

By D. Yuan, L. Yan, M. J. Collins, P. Kalanchey, I. M. Masters

ABSTRACT Pressure oxidation tests have been conducted by Sherritt for a refractory gold-silver project in China. The feed contained 39 g/t Au and 970 g/t Ag; the major gold-bearing minerals were pyrite and arsenopyrite. Because the feed contained a significant amount of silver, which can be refractory to cyanide leaching after pressure oxidation due to the formation of argentojarosite, the test program included investigation of methods to enhance silver recovery. The “lime boil” process proved successful and was incorporated into the flowsheet. Gold extraction from the lime boil product solids was 95–98%; silver extraction was up to 94%.

Jan 1, 2013

By A. J. Reed, W. R. Bergey, Carr. J. M.

"The Highmont copper-molybdenum deposits are at Gnawed Mountain in the Highland Valley porphyry copper district, 125 miles northeast of Vancouver. This district is near the center of the lower Jurassic Guichon Batholith, where a north-trending swarm of porphyry dikes is crossed by west-northwesterly structural belts in which fracturing, intrusion of porphyry and breccia, and mineralization areconcentrated.The Highmont deposits are 2 miles southeast of, and in the same southernmost structural belt as, the Lornex deposit. The main deposits occur on either side of a composite dike of granodiorite, porphyry and breccia which strikes west-northwestward in fractured quartz diorite. North of the dike, the adjacent Nos. 1 (East) and 2 (West) zones together contain 150 million tons of open-pit ore mineable in two separate pits. These two zones will support a 25,000-tpd mill with a grade in the first five years of approximately 0.46 per cent copper equivalent. South of the dike, the Nos. 3 and 4 zones are partly explored and will provide large additional reserves. In these various zones, chalcopyrite, bornite and molybdenite form disseminations and fracture-fillings accompanied by quartz, K-feldspar, tourmaline, sericite, specular hematite and other minerals. Bornite extends for varying distances north of the dike, beyond which chalcopyrite is locally accompanied by pyrite. Higher-grade mineralization tends to coincide with fracture swarms, or with shear zones and faults which largely parallel these swarms. The ore zones are reflected by geochemical soil anomalies which show some glacial dispersion. LP. surveys gave weak but significant responses, expressed as per cent frequency effect. The ore zones occur within a strong magnetic gradient, but do not show a significant magnetic response."

Jan 1, 1971

By D. M. Baird

ABSTRACT A revised stratigraphic section of Carboniferous rocks which occupy about 700 square miles in southwestern Newfoundland is presented. Gypsum, which outcrops at thirty-five different localities, is found to belong to four principal zones in the section. The newly mapped structure of the region makes the otherwise random occurrences of gypsum appear as systematic outcroppings of the four zones which follow the regional structure. Details of several occurrences are given and those most advantageous for exploitation are pointed out. INTRODUCTION ROCKS of Carboniferous age occupy an area of about 700 square miles in southwestern Newfoundland. They occur in a belt, from 5 to 15 miles wide, which extends from the head of St. Georges bay southwestward for 65 miles to the mouth of Little Codroy river (see Figure 1). Several hundred feet of Pennsylvanian rocks overlie rocks of Mississippian age, which are at least 12,000 feet thick. The rocks of the Carboniferous section of Newfoundland are very similar to those of Nova Scotia and represent a northeastward continuation of the same palaeophysiographic conditions. Mississippian measures of Windsor equivalence include thick gypsum deposits which outcrop at many places and which extend under large areas as indicated by sink-holes and by structural considerations.

Jan 1, 1951

By K. N. Subramanian

Previously reported work on total oxidative leaching of chalcopyrite concentrates ha s shown that high copper extractions are obtained at 210°C and 0.4 MPa oxygen pressure. A simple integrated flow sheet using pressure leaching, solution treatment involving precipitation with a calcium base, and electrowinning to produce wire-bar-quality copper is described. Reagent and energy requirements developed from this work indicate that the process could be attractive for small operations where a smelting-refining complex cannot be justified.

Jan 1, 1978

By Tassos Grammatikopoulos

The St. Lawrence deposit is a large wollastonite skarn (ca. 9 Mt @ 41.3% wollastonite) adjoining the gabbroic-to-syenitic Leo Lake pluton in the granulite facies of the Frontenac Terrane of the Grenvillian Central Metasedimentary Belt. It occurs within a horseshoe-shaped horizon of quartzite, open to the east. The skarn extends over 1.2 km2, and comprises wollastonite-dominant, wollastonite-clinopyroxene, and diverse quartz-feldspar-sulphide (-titanite) layers, interbanded with, and strongly folded within, the quartzite. As in the world-class wollastonite deposits of the Willsboro district, New York State, no carbonate protolith is preserved and calcite is a negligible constituent of the mineralized zones. Wollastonite development is nonetheless ascribed to metasomatism of a metacarbonate unit by magmatogene, silica-rich, CO2-poor (XCO2 < 0.05) fluids, at P = 350 MPa and ca. 560 oC, or, alternatively, 550 MPa and ca. 630 oC. Several high grade zones, averaging >40%, but locally exceeding 80%, of translucent, white, tabular wollastonite grains, with lengths of 0.2 - 2 cm, have been delimited by drilling. Preliminary beneficiation studies yield high aspect-ratio and high-purity (low Fe and Mn) concentrates. St. Lawrence compares favourably to other known prospects and operating wollastonite deposits; having good chemical and physical properties, low iron content, and high aspect ratios (>20:1). In addition, the deposit has a favourable size and location, and will benefit from a low Canadian dollar. Canada currently has no wollastonite production.

May 1, 2002

By P. Cheung, J. Gulyas, R. Clary

Over the past 50 years, the use of autoclaves in the metallurgical industry has evolved from final metal recovery (hydrogen reduction) and purification (sulphide precipitate oxidation) to treating whole ores and concentrates. Recent process developments, such as the use of autoclaves for laterite leaching, have necessitated higher temperature and pressure operations, which in turn have seen marked advancements in technology and manufacturing capabilities to keep in step with process demands. This paper will discuss the advances in technology in terms of design, materials and construction of autoclaves and liners, typical dip tube design and geometric layout. This paper will also address specific auxiliary equipment, such as acid and steam injection systems, and components, such as agitator seal systems.

Jan 1, 2004

By DONALD E. BARNETT

Since the days of early settlement ew Brunswick has produced a variety of industrial minerals but it is perhaps only the recent discoveries of significant reserves of potash that have elevated the meaning of industrial minerals in their contribution to the provincial economy. With potash production commencing in July 1983, the role of industrial minerals will increase significantly to the value of mineral production in the province.

Jan 1, 1984

By E. R. Lea

The B. M. & S. orebodies, consisting of the No. 6 (Brunswick) and the No. 12 (Anacn Leadridgz, have the distinction of being the first major 1base metal ore deposits to be found in the Province of New Brunswick. They are massive sulphide de-posits consisting of pyrite (pre-dominantly) and base metal sulphides, and they carry values in lead, zinc, copper, and silver. These orebodies are localized within favourable drag fold structures believed to be related in their origin to external forces set up in the area subsequent to the primary regional folding. Both orebodies are characterized by the presence of magnetite &apos;iron formation&apos; which, in certain &apos;Portions of each orebody, may be found as relics within the massive sulphides. Studies show the magnetite to be the first metallic mineral within the ore ?zones, followed by pyrite, Sphalerite, galena, and finally chakopyrite. The shape of these massive pyritk orebod:es as well as the distribution of values within them is controlled to a large degree by the ore-ore drag fold structures. A possible relationship is discussed between the basic intrusives in the area ?and the magnetite deposits. It is suggested that a large portion of ?the iron content of the massive suplhedes has been derived from the earlier magnetite. Intermittent movements in the area during the sulphide mineralization are believed to belong to the last stages of deformation in the area. These late movements may have been caused by the intrusion of the granite into the area. The granite may have a genetic relationship to the B. M. & S. orebodies.

Jan 1, 1958

By Newell G. Alford

COAL companies are definitely becoming conscious of the need for better organization. Mechanized mining and the intricate preparation of coal have brought with them the demand for better trained and more highly skilled mining personnel. Refinement in coal mine management is increasing the demand for young graduate engineers to start in the lower grades of the reorganization and prepare themselves to meet rapidly increasing coal mining responsibilities. The interest is wide in scope and extends from self-helps, extension work, and management study at the mines to stimulation of interest in coal mining amongst undergraduate mining students, leading to their permanent employment after graduation. Data by the United States Bureau of Mines show the total annual value of coal production (bituminous and anthracite in the U.S.) through the past 22 years as being more than 38 per cent of the combined value of all ocher mineral industry products. Natural-gas production has gained rapidly on coal since 1916; petroleum exceeded coal beginning with 1934 (see Figure 1). For this 22-year period, the Committee on Student Interest in Coal Mining, in the A.I.M.E., made a survey of the mining schools in Canada and the United States to show the approximate absorption of young graduate mining engineers by the coal industry. In 1938, 232 mining engineers were graduated as compared with 42 in 1918 (a war year) and 180 in 1923. From 1923 to 1929 the graduates declined to another low of 90, but from there on there was a rapid annual increase in the graduating output, reaching a total of 232 in 1938 and continuing upward to a maximum of over 325 graduating this present month.

Jan 1, 1940

By A. J. Miller

Estimates of interstitial water saturation derived from capillary pres-sure data are compared with residual water saturations found by the analysis of cores out in oil-base drilling fluid. A theoretical explanation for the high-rate of water production from the Bellshill Lake Field is proposed, based on the interpretation of the capillary pressure data.

Jan 1, 1960

By Arthur Brant

STEEPROCK LAKE (Figure 1) lies about two miles north of Atikokan, a village approximately one hundred and forty miles west of Fort William and one hundred miles east of Fort Frances on the Canadian National railway. The possible presence of hematite beneath the waters of Middle arm was inferred by early geological investigators (1890-1903) from the dense hematite float found on the southerly shores of this portion of the lake (1). A dip-needle survey of Middle arm, undertaken in the winter of 1930-31 by J. G. Cross, indicated two areas of high magnetic attraction which Mr. Cross thought might be due to magnetic iron oxides associated with possible hematite bodies. Bedrock could not be reached by the ineffectual hand-drilling so courageously attempted, and further work was abandoned. It was not until 1937 that Mr. Jos. Errington, of Toronto, convinced of the possibilities, determined to support Mr. Cross to the extent of several thousand feet of drilling. During the winter of 1937-38, holes Nos. 1, 3, 4, 5, and 13 were put down (see Figure 1). The first four of these holes demonstrated that the areas of magnetic attraction outlined by the dip-needle survey east of the Narrows and southwest of Elbow point were due to ash rock (2). As a result, Mr. Cross decided to investigate the bordering areas of low magnetic attraction and selected a location near the high ferruginous lime (3) point in the northeast of Middle arm. Dense, hard hematite beneath approximately 350 feet of water and clay was struck in the first hole, and, before the end of the winter&apos;s drilling, hematite had been encountered in holes Nos. 6 to 13 along a straight line 700 feet in length (see Figure 1). In the meantime, the Steerola ( 4) Exploration Company had been formed to continue development and already, in the spring of 1938, W. D. Neeland, the Company geologist, had come to the conclusion that the most probable location for possible hematite was at the ash-lime contact. Accordingly, during the summer, drilling was continued off-shore in holes Nos. 15, 25, and 27 (see Figure 2) toward possible hematite bodies inferred by Mr. Neeland.

Jan 1, 1940

"In response to needs created by intensive exploration and accelerating expansion of coal mining in the Western provinces, Canadian R & D on coal is progressively widening its scope. Principal interests continue to lie in coal geology, preparation and processing, carbonization, combustion and transportation, but much active work is also in progress with respect to mine environments, mined-land reclamation, and environmental consequences of coal mining, processing and use. Long-range 'basic' research, which characterized much of the R & D pattern in the fifties and early sixties and which was often no more than an attempt to prevent total extinction of a dying industry, has been somewhat de-emphasized, except insofar as it relates to 'safe' coal storage and to coal-based carbons (which are beginning to command attention as pollution control media).In this review, recent exploration, mine development and new preparation facilities are noted, and current R & D in transportation, processing, handling, carbonization and combustion is summarized. Reference is also made to investigations bearing on non-fuel uses of coal (notably as source-materials for carbons and agrobiological products)."

Jan 1, 1970

By J. S. Redpath, W. R. Dengler

"A description of the equipment used and the electrical-mechanical problems encountered in sinking a deep shaft is given. This shaft is currently being sunk to a depth of 7,115 feet. Some of the features of the sinking plant are a 6,500-hp double-drum hoist, a Blair stage hoist, special high-capacity mucking gear, a Galloway stage, high-tensile stage suspension ropes and 12-ton sinking buckets.INTRODUCTIONIN THE EARLY FALL OF 1965, a contract was let, by The International Nickel Company of Canada, Limited, to Shaft Sinkers (Canada) Limited -J. S. Redpath Limited -Joint Venture, • to sink and equip the Creighton No. 9 shaft at their Creighton Mine proper-ty in Ontario. This paper describes the electrical and mechanical equipment used by the contractor on this project, and details various problems that were en-countered.The shaft itself is circular in section and is lined with monolithic concrete. Upon completion, it will feature twin skip compartments, a cage compartment, counterweight compartment, manway and pipe compartment. The finished diameter of this opening will be 21 feet and the shaft will bottom 7,115 feet below the collar. The present depth of the shaft (April, 1968) is 5,400 feet. The opening is concrete lined as excavation takes place and the steel will be placed in the shaft upon completion of sinking. Hoisting is done on rope guides which are part of the stage suspension system."

Jan 1, 1968

By M. A. Mahtab, A. S. Burgess, R. G. Charlwood, P. O. Sandstrom, J. L. Ratigan

"Addressing a current operating and environmental concern, this paper first presents an overview of the design program for an underground radioactive waste storage vault. It then reviews the construction, operational and thermal-mechanical aspects of such a project. The relevant experience from major underground construction projects is reviewed and the paper concludes with brief comments on the design-oriented research and development requirements . 1. IntroductionA program to develop techniques for the ultimate disposal of high-level radioactive waste into geologic formations was announced by AECL in 1975 (Tamrnernagi, 1976), and is discussed more fully in a later document (Boulton, 1978). Our paper summarizes the studies caried out, as part of the AECL waste management program, by the authors and associates on the development of design concepts for a vault situated in crystalline rocks of the type present in the Canadian Shield.The design studies have been carried out in three phases, the elements of which are described in Section 2.1 (also see Fig. 1). The general vault designs are presented in Section 2.2. These provide for emplacement of either immobilized fuel or solidified reprocessing wastes in a room-and-pillar facility at a depth of 1,000 m.Section 3 reviews the principal design considerations from the construction, operation and thermal-mechanical response aspects. The concepts have been studied in both temporal and spatial domains, and the requirements and responses assessed in each as appropriate.Section 4 briefly reviews the availability of relevant experience from previous major underground construction projects. Finally, in Section 5, brief comments are given regarding design-oriented research and development requirements."

Jan 1, 1980

By M. P. Brameld, G. Archambault, R. H. McCorkell

"The rates. J. at which materials emit radon are of interest in studies of the sources of radon in mines. buildings. soils overburden and other places where it may indicate the location of ore or be a health hazard. Here J values were determined by measuring the radon concentrations by means of scintillation counters or alpha-particle track detectors in chambers in which specimens were sealed. Errors in the measurements due to leakage from the chambers. lack of secular equilibrium in the decay series of the radon measured, or the limited rate of diffusion of radon from powders or within the chambers were shown to be insignificant or could be corrected. Scintillation counter measurements are highly reproducible; track detector measurements also appear useable and may be made on many small samples using small, simple chambers. J measurements were made for uranium ores, drill cores, standard CANMET pulps. concrete and gypsum board. Powdering of ores had little effect on their J values.IntroductionIn the mining and mineral sciences, radon (222Rn) is of interest chiefly for two reasons: in geochemical exploration for mineral deposits its presence in soil. overburden and water in more than background concentrations may indicate the existence and locations of uranium deposits and, if present in sufficient concentrations, it is a possible health hazard in mines, mills and other places where people live and work. The latter aspect of radon&apos;s role has received considerable attention recently(1,2,3,4,5), and surveys of soil-gas radon concentrations have been used for some time in searches for uranium deposits(6,7,8,9,)."

Jan 1, 1981

By A. Scheltema Beduin, H. Oterdoom, A. Haaks, C. Kempe, A. Liedtke

"For the Kazchrome DC Ferrochrome plant, SMS-group specifically designed an electrode column that would minimize downtime. Special features include the possibility for on load electrode jointing, on load slipping, and back-slipping. Electrode consumption is strongly related to furnace load and impedance, and is very low at high loads, which makes the graphite electrode an alternative to consider even in AC applications. The electrode could also be applied in other DC applications, as for example TiO2 slag, the novel Conroast process, or (twin) DC FeNi furnaces, and could possibly be installed during bigger shut downs. This paper will describe some of the design considerations and operational performance data on this novel column in the FeCr industry that could also be of interest for the FeNi or PGM industry if these would continue to develop towards DC technology.INTRODUCTION Every DC furnace has a cathode and an anode. The anode applied is commonly known as the Concast design, though the original design was by ABB who handed it over to Concast, subsidiary of the SMS-group. Some well-known DC furnaces outside the steel industry where the Concast bottom has been installed are listed in Table 1 as well as a few other key design features.Sidewall cooling and some other data have been left out for reasons of space, and being a lesser relevant design feature to this paper. HES stands for Hollow Electrode System, in which feed is charged through an electrode. Table 1 is built up chronologically according to first start-up date. Below comments are given to briefly explain some of the columns in Table 1: •,“Arm” in the “Cathode” column means that the design of the cathode holding and regulating mechanism consists of an electrode arm as depicted in Figure 1. •,Charging is relevant as some operations started with HES charging, whereas recently most new operations have started without HES but only charging chutes, of which at least some are close to the electrode and possibly others installed closer to the sidewall. •,“Dome” in the “Roof” column means that the design of the roof involves a center piece that can be exchanged if worn. •,The optimal roof design still seems to be a topic of debate, where no design is without problems."

Jan 1, 2017