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By J. A. Brothers, M. R. Foran

"AbstractThis paper reviews the progress made in the manufacture of hydraulic cement from iron blast-furnace slag by simply grinding the granulated material with other constituents. The influence of the chemical and mineralogical composition of the slag, the conditions of granulation, the manner of drying, and the fineness of grinding, on the hydraulic properties of the cement, is discussed. The effect of additions of lime, portland cement, and anhydrite, alone and in combination, on the physical and cementing qualities of the mortar and concrete made from Sydney blast furnace slag, is shown in tables of data and is reviewed in some de- tail. The work at the Nova Scotia Technical College has shown that a cement equivalent in every respect to portland cement can be made from basic blast furnace slag- by the us2 of certain quantities of portland cement as an activator.IntroductionBlast furnace slag is a potentially valuable material for the manufacture of hydraulic cement. It is a by-product of the manufacture of iron in the blast furnace, and is formed by the combination of the silica and alumina .of the iron ore with the limestone flux. The metallurgist terms a slag .acid or •basic according as the percentage of lime is less or greater than the percentage of silica plus alumina. The basic slags have the •more pronounced hydraulic properties."

Jan 1, 1950

By Charlie Graham, Helen Shang, Ashley Scott, Andrew Hall

"Approaches to Energy Recovery• Upgrading for electricity generation - steam turbines• Direct extraction- process improvement or space heating- support medium for animal or plant growth– fish or microalgae• Heat pumps- space heating/coolingWater Energy Grades• High (150+ °C) - electricity Generation• Medium (26 to 121 °C) - direct extraction• Low (5 to 18 °Celsius)- use of heat pump is required• Temperatures between zones will depend on circumstances for best use."

Jan 1, 2012

By K. Ihara, R. Akiyoshi, Y. Takaki, S. Kang, H. Shishido

"Tensile tests and scanning electron microscopy-electron backscattered diffraction (SEM-EBSD) analysis were performed in an Al-Mg-Si alloy to clarify the effect of annealing and cold-rolling reduction on the texture formation. The hot-rolled specimens were cold-rolled with the reduction of 58-75%(CR1), followed by annealing at 773 K for 5 min(IA). The secondary cold-rolling(CR2)for the IA specimens with the reduction of 33–66%, followed by the solution heat treatment(ST), were performed. Focusing on the CR1 and CR2 specimens, the average r-values increased with higher primary and lower secondary cold-rolling reduction, respectively. This was considered to be due to the increase of r-values measured in the direction of 45 degree with respect to rolling direction, caused by the formation of the ß-fiber components (Brass {011}<211>, Copper {112}<111> and S {123}<634>) with high density. Based on the texture analysis of annealed specimens it was suggested that the high density of the ß-fiber components after IA and the small amount of stored strain energy of CR2 introduced by the lower cold-rolling reduction remained the ?-fiber components even after solution treatment.INTRODUCTION Al-Mg-Si alloys have been applied to automobile body applications, due to their excellent paint-bake hardening (age-hardening) and corrosion resistance compared to other aluminum alloy. On the other hand, the mechanical properties and deep drawability of Al-Mg-Si alloys are inferior to those of steels. Thus, it is important to improve the mechanical properties and deep drawability in order to expand the application components. One of the best methods to improve the deep drawability is to increase the Lankford coefficient (r-value). Previous studies reported that the increase of the average r-value ( ) improves the deep drawability. The relationship between the r-value and texture of the alloy is also well known. Inoue et al. reported that the ß-fiber components, such as Brass ({011}<211>), Copper ({112}<111>) and S ({123}<634>), increase the r-value measured in the direction of 45o with respect to the rolling direction. r"

Jan 1, 2018

By H. Stocker, C. E. Makepeace

"This paper presents the statistical analyses of several sets of data acquired in several programs of sampling of radon daughters in uranium mines. The measurements were taken over periods of days or weeks for given locations or location occupations within these mines. Because the sampling applies to specific intervals of time and specific locations, a method is suggested f or the eventual application of a monitoring program which would be suitable on an annual basis for these locations. The present data and analyses thereof are not justifiably applicable to a monitoring regimen on an annualbasis, without a number of additional assumptions.The aim of the present analyses of concentration measurements is the determination of the minimum number of measurements required to achieve an annual radon daughter exposure estimate, for individual workers, having an error no greater than 50% at the 95% confidence level. The criterion of accuracy is taken from a statement in the American National Standard, Radiation Protection in Uranium Mines (ANSI NI3.8-I973), and is currently used, in somewhat modified form, as a guide to uranium mining licensees in Canada. Uncertainties associated with occupancy time are ignored in the present analysis. IntroductionOne of the principal aims of any scheme of radiation protection is that of improving the accuracy of exposure estimation for workers. The example presented here is from the area of radon daughter exposure estimation for uranium miners. The conventional means of estimating workers&apos; exposures is grab sampling of radon daughter concentrations combined with occupancy time weighting in the various work and travel locations. Uncertainties exist in each of these components, and in an environment of highly variable radon daughter concentrations (such as an active uranium mine) one is always uncertain as to the representativeness of the grab sample (compared to the average concentration) unless a sophisticated monitoring scheme has been implemented based on previous experience in such an environment.Improvements in the accuracy and precision of employee radon daughter exposure records depend, primarily, on three factors;"

Jan 1, 1980

By Hoeve. J.

"In the unconformity-type uranium deposit at Midwest Lake, mineralization is associated with extensive host rock alteration, which affects the metamorphic basement as well as the overlying Athabasca Group sandstones. Host rock alteration is manifested by (I) transformation of clay minerals [kaolinite into illite and chlorite (sudoile)]; (2) bleaching due to removal of hematite from the lateritic paleoweathering profile and the overlying red bed, Athabasca Group sandstones; (3) loss of coherence of the sandstone resulting from corrosion of quartz cement; and (4) in the immediate vicinity of high-grade ore, development of a clay envelope due to residual enrichment of clay minerals caused by massive dissolution of quartz. Clay mineral transformation and bleaching are the most prominent and the most widespread alteration effects, forming haloes that extend for several kilometres along the strike of the mineralized structure and also constitute distinct alteration pipes that rise f or several hundred metres above the unconformity to be truncated at the present top of the bedrock.Although the two haloes are largely congruent features, cross-culling relationship s indicate that clay mineral alteration represents an earlier phase in the history of the deposit than the large-scale bleaching that gave rise to the superimposed bleaching halo.Because clay mineral alteration and bleaching are intimately tied to the mineralization and extend well beyond the limits of the actual orebodies, host rock alteration may be used as an ore guide in exploration and drill-hole evaluation. In this application a third hydrothermal discharge centre was identified, as yet untested for are, which is located between the hydrothermal centres associated with the two known orebodies of the deposit.It is estimated that host rock alteration may enlarge a potential drill-target by a factor 10 - 20X. Information on the configuration of bleaching haloes can be obtained from systematic core logging, whereas diagnostic clay mineral alteration is readily identified by means of automated, quantitative XRD techniques."

Jan 1, 1984

By F. D. Aaring

"IntroductionTHE PINCHER CREEK gas condensate field, in Township 3, Range 28, and Townships 3 and 4, Range 29, West of the Fourth Meridian, was discovered in 1947 by the Canadian Gulf Oil Company with the completion of Pincher Creek No. 1 well in the Madison lime-stone of Mississippian age.This discovery was the result of a great deal of detailed seismic work in the area and is a credit to the geophysical personnel of the Company. The depth of the reservoir varies from 7,400 feet to 8,200 feet subsea, with the established water level at -8,200 feet. The predicted depth was but a scant 100 feet from that found in the discovery well, at 11, 705 feet. Since the discovery of the reservoir, three additional wells have penetrated the Madison limestone and have further verified the original •seismic interpretation of the limits of this reservoir.To date, •only a very small amount of gas has been produced from this field. Consequently, the reservoir studies that have been made so far are predominantly based on investigations of the phase behaviour of the fluid and physical characteristics of the reservoir rock. In view of the above limitations, it has been necessary to set up and perform model reservoir studies with the fluids and to recover as much core from the productive Madison limestone as possible in order that it might be analysed by conventional laboratory technique and be subjected to detailed microscopic geological examination."

Jan 1, 1952

By H. Fujiwara, T. Ito, T. Mizuguchi, K. Kawasaki

"In this study, we characterize the high-temperature deformation of typical “Class I” solid solution Al-Mg alloys as a superplastic elongation attributable to the solute drag creep of dislocations. The second-phase particles formed by adding Fe or Si as impurity atoms to the Al-Mg alloys impeded the gliding motion of dislocations, thereby decreasing their hot ductility and resulting in cavity formation. High-temperature tensile tests were performed with initial strain rates in the range of 1×10–3 to 1×10–1 s–1 at air temperatures 673–723 K. The dominant high-temperature deformation mechanism in these alloys was the solute drag creep controlled by the interdiffusion of Mg in Al. In this study, the calculation of critical length, defined by the diffusion-based relaxation of the stress concentration region around second-phase particles, is reported using the Needleman–Rice parameter. An analysis of the impact of cavity formation based on a comparison of the Needleman–Rice parameter and second-phase particle size is also reported.INTRODUCTION Aluminum alloys with high specific strengths are utilized as structural materials for transportation machines to minimize their weight, which consequently maximizes fuel efficiency, environment preservation, and so on (Miller et al., 2000; Heinz et al., 2000; Starke & Staley, 1996; Polmear, 1996; Immarigeon et al., 1995; Burger, Gupta, Jeffrey, & Lloyd, 1995; Ye, 2003). Microstructure refinement by severe plastic deformation (SPD) has been performed on a laboratory scale to achieve a higher strength of crystalline materials (Valiev et al., 2006; Song, Ponge, Raabe, Speer, & Matlock, 2006; Beyerlein & Toth, 2009; Sabirov, Murashkin, & Valiev, 2013; Sauvage, Wilde, Divinski, Horita, & Valiev, 2012). At room temperature, grain refinement strengthens the material, as given by the Hall-Petch relationship (Hall, 1951; Petch, 1953); at higher temperatures, superplasticity can be expected (Sherby & Wadsworth, 1989; Edington, Melton, & Cutler, 1979; Furukawa, Horita, Nemoto, & Langdon, 2001; Langdon, 2006). However, the synthesis of large-size materials by SPD processes is not yet feasible."

Jan 1, 2018

By A. Navarra, C. Arrancibia, R. Yañez, C. Acuña, F. Valenzuela

"Discrete event simulation (DES) is a suitable framework to evaluate and optimize the dynamics of sulphide smelters. In particular, iron-nickel-copper-cobalt sulphides undergo continual oxidation within a roasting or smelting operation, followed by batch oxidation within the converting operation, thus producing iron-free Bessemer matte (or blister copper, in the case of copper smelters); this semi-finished product undergoes further processing to produce nickel, copper and cobalt products, and to recover precious metals. The juncture between continuous smelting and batch converting is often an appropriate focus for the earliest phases of DES development, since it is typically a major bottleneck within nickel and copper smelters; later phases may include increasing levels of detail for auxiliary unit operations, as well as plant logistics. Moreover, DES can support matte-slag chemistry, including Gibbs free energy balances to determine the iron speciation within the slag. DES is therefore capable of linking the fundamentals of oxidation reactions to the intricacies of plant dynamics.INTRODUCTION Discrete event simulation (DES) is gaining acceptance within the extractive metallurgy community, as a technique that quantifies the system-wide performance of metallurgical plants under conditions of uncertainty (Wheeler & McGinty, 2015). In particular, over 90% of smelters that process nickel-copper-cobalt sulphides and copper sulphides exhibit similar semi-continuous dynamics (Crundwell et al., 2011b; Schlesinger et al., 2011b), in which the converting aisle produces batches of material that are sent for further processing (Figure 1). Thus the tools and practices that are developed for a specific sulphide smelter are often relevant to numerous other smelters.The juncture between continuous smelting and batch converting has long been a focus for discrete event simulation (Welgama et al., 1996). Nonetheless, the broad acceptance of DES in nonferrous smelters has been hindered by interdisciplinary barriers that divide industrial and metallurgical engineers (Navarra et al., 2016; Noorossana et al., 2012); this divide has been less severe in steel plants (Hollocks, 2006). In recent years, DES has been used in copper smelters to analyze crane-and-ladle motions (Coursol et al., 2009a), reverts production and consumption (Noorossana et al., 2012), and innovative control systems (Herrera et al., 2016); additionally, DES models have accounted for shutdowns and random breakdowns to provide realistic assessments of copper smelter capacities, thus guiding equipment upgrades (Campbell et al., 2013; Coursol et al., 2009a). All of these studies feature a Peirce-Smith converting aisle similar to Figure 1 that, under normal operations, constrain the smelter throughput, and are thus a bottleneck (Campbell et al., 2013; Navarra et al., 2016)."

Jan 1, 2017

By Peter Hayes, Evgueni Jak, Taufiq Hidayat, David Grimsey, Denis Shishin

"An integrated nickel flash smelter is operated with Peirce-Smith converters at the Kalgoorlie Nickel Smelter. To improve the partitioning of arsenic between slag waste and matte product, an option to modify the slag–matte chemistry by addition of CaO was analysed. A combination of plant sample analysis, high-temperature laboratory experiments and thermodynamic modeling was carried out to evaluate the process options. The high-temperature experiments involved the re-equilibration of industrial matte-slag samples at 1225 °C and P(SO2) = 0.12 atm, rapid quenching in water, and direct measurement of phase compositions using electron probe X-ray microanalysis (EPMA) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LAICPMS). A private thermodynamic database for nickel sulfide smelting and converting was used together with the FactSage thermochemical software package to assist in the analysis of the distribution of elements between slag and matte as a function of CaO addition. The thermodynamic predictions combined with experimental data obtained in this study can be used to characterise the effect of CaO fluxing on the slag–matte thermochemistry during the nickel sulfide converting.INTRODUCTION At the Kalgoorlie Nickel Smelter (KNS), nickel sulfide concentrate is processed in an Outotec-type flash furnace to produce nickel matte containing +47 wt% Ni. Separation of nickel matte and waste slag from the flash smelting is enhanced through settling in the electric arc -heated zone attached to the flash furnace. The flash furnace matte is further processed in a Peirce-Smith converter to produce Ni-rich matte containing +66 wt% Ni (Crundwell, Moats, Ramachandran, Robinson, & Davenport, 2011). Iron silicate-based slag is used in the converting process at KNS. Most of the arsenic is contained in the final matte and very little of the arsenic partitions into the slag. Previous work by Font et al (Font, Hino, & Itagaki, 2003) shows that the distribution ratio of arsenic between calcium ferrite slag and nickel-matte (LAsslag/matte) is significantly higher than that between iron silicate slag and nickel-matte, where LAsslag/matte = (wt pct As in slag)/{wt pct As in matte} (1)"

Jan 1, 2017

By W. C. Ferguson

"This paper could be more appropriately titled ""The Application of Vacuum Filters to Underground Minewater Treatment. in a previous paper co-authored by the writer (1) the history and development of minewater treatment at the Sudbury District Operations of the International Nickel Company was outlined. It is the intention of this paper to dwell more specifically WIth the the application of the vacuum filter to a problem found in most, if not all, underground mining operations. In the preparation of this paper the writer has made liberal use of the illustrations and text of the paper previously noted.Last year we heard Mr. Nemeth discuss the basic mechanisms involved in vacuum filtration (2), and today Yr. Cunliff has exposed us to the selection of the filter media (3). I will now briefly review the various vacuum filter designs that generally lend themselves to metallurgical dewatering applications.DRUM FILTERSThe revolving drum-type which filters on its outside periphery is illustrated in Fig. 1. This is the Oliver or Drum filter and represents the first commercially available continuous vacuum filter. The original design dates back more than 50 years, but with the exception of the method of discharge, is identical to the units being marketed today. This filter is generally applied to slow filtering slurries. The cake may be discharged in several ways; strings, scraper blades, rolls or by passing the filter cloth over a small diameter discharge roller (belt discharge).THE DORRCO FILTERThe revolving drum type which filters on its inside periphery is illustrated in Fig. 2. Here the slurry lies in the drum and the cake discharges through a chute or conveyor. This type of filter is most often applied to fast-filtering slurries.THE DISC FILTERThe revolving filter which filters on the vertical plane of the disc is referred to as the Disc or American-type filter. This represents the most inexpensive design in terms of cost per square foot of filter area. This filter is widely applied, but is probably more suitable for slower draining pulps."

Jan 1, 1971

By I. Ruiz Bustinza, L. F. Verdeja, Daniel Sbarbaro, R. Parra, J. Mochón

The oxidation of sulfides is a complex process involving gaseous products and intermediate species given rise to emission and absorption spectra which carry out important information about the reaction process. This information could be used for on line monitoring of pyrometallurgical reactor if the appropriate sensors were available. We present in this paper an analysis of the concept that has been successfully applied in iron and steel making industry, as well on fuel combustion control, where the spectra measurement gives the possibility for online monitoring and automatic control of high temperature processes. This concept has not been widely applied in the nonferrous pyrometallurgical primary production. The design of new sensors is discussed from the analysis of spectra measurements during flash combustion of copper concentrates at laboratory scale.

Jan 1, 2015

By E. A. Collins

I TAKE it that the papers presented tonight on the subject of Reconstruction, as regards both gold and base-metals, are intended primarily to stimulate discussion of this important subject and, in regard to base-metals in particular, cannot in any manner be considered as a policy or plan to be followed as a panacea for all the ills which are bound to beset the industry when peace is declared. A famous cook-book written by a Mrs. Beeton contained a recipe for jugged hare which began with the instruction, "First catch your hare". To date, we have not caught the hare of victory and it may seem to many that any thought, energy, or effort devoted to the problem of reconstruction which will in any way impede the acceleration of the chase after victory will leave us open to the charge of being derelict in our duty as citizens. Much of our present trouble is due, however, to our lack of preparation for war in time of peace, and it follows that it is of equal importance in our national economy to prepare for peace in time of war. Most of us here tonight have vivid and sad memories of the chaos in the metal mining industry following the Great War of 1914-1918. In our own industry, mining, smelting and refining of nickel and copper, it was not a problem of absorbing the men who returned. There were only some three hundred who came back to the Mining and Smelting Division, and these men were all given their former jobs without any apparent difficulty. They were rehabilitated gradually due to the fact: that some of these men did not return for a year after the Armistice was signed. The numbers of men involved in the present conflict are much greater. We have to date in the armed forces upwards of 3,000 men enlisted from our employ.

Jan 1, 1943

By T. R. Skerry, H. P. Hudson, T. E. Warren

"ALTHOUGH coal is generally the cheapest fuel on the basis of heating value it has been at a disadvantage in competition with other fuels because means have not been available for efficient •Conversion of its thermal energy to mechanical work. Taking the •railway application •as an example, the cost of Diesel oil is about three times that of its thermal equivalent in coal, but the overall efficiency of a Diesel locomotive is about five times that of a coal-fired steam locomotive. Accordingly, the Canadian railways are replacing all coal-fired steam Locomotives, as they are retired from service, with Diesel units. This conversion in itself represents a major loss to the coal industry because the value of railway fuel is approximately 130 million dollars per year, and there are other applications in the medium power range where oil is displacing coal. There is, therefore, a strong incentive to attempt development of an efficient coal-burning engine.Coal has never been a promising fuel for reciprocating internal combustion engines because of the time required for its combustion in pulverized form . This is not less than one-tenth of a second so that the speed of such an engine would have to be very slow. There are also serious difficulties of a mechanical nature arising from the necessity for intermittent combustion and the use of close-fitting pistons."

Jan 1, 1952

By F. A. McLean

The past decade has witnessed a rapid increase in the number and variety of uses found for internal combustion engines in mining operations. Gasoline engines are now widely used for operating core drills, pumps, compressors, small hoists, switching locomotives, tractors, boats, and other equipment. The heavy-oil engine is employed for operating compressors, generators, shovels, ore-milling machinery, and- in the iron, copper, and coal districts- in connection with that&apos; latest newcomer in modern railroading, the oil-electric locomotive. Each of these applications could well form a subject for a lengthy treatise in itself. This paper, however, will be confined to a discussion of some of the features of internal combustion engines as applied to mine compressing plants and mill drive. Perhaps at no time in the history of mining in Canada has the search for new mines been more vigorously carried on, more old properties rejuvenated, or more remote districts exploited than during the past three years. The mine operator of today has a far wider range of equipment and facilities at his disposal than had the pioneers of Rossland, Cobalt, or Porcupine. Each year now witnesses the hinterland driven farther and farther back as improved forms of transportation, machinery, and methods make possible the exploration of properties once considered too inaccessible to warrant serious attention. Howey, Sherritt-Gordon, Callinan-Flin Flon, Jackson-Manion, Picard Gold Mines, and a number of properties in British Columbia, afford excellent examples of work carried out on an extensive scale miles from a railway, or in comparatively inaccessible mountain regions.

Jan 1, 1928

By D. C. McDonald

"IntroductionTHE GIANT YELLOWKNIFE property is on the west side of Yellowknife bay, Great Slave lake, N.W.T., some 600 air miles north of Edmonton. This paper deals with the underground development and mining of the complex system of orebodies which have produced, in the first fifty-six months of operation (May, 1948, to December, 1952), 652,464 tons of ore with an average grade of 0.80 ounces of •gold per ton (1).The mine has been developed from three vertical shafts designated A, B, and C. Figure l shows the positions of these openings with respect to the known ore-bearing zones and the surface plant.A shaft was sunk to a depth of 522 feet in 1945-46, primarily as a prospect shaft for investigation and development of the East Zone orebody. Drifting was carried out on the 200-and 325-foot levels. Before this development had been completed it was clear that the funds immediately available made it imperative to get revenue from production as soon as possible. By the beginning of 1946, the remarkably high-grade character of the ore in the present B Shaft area had been established by surface drilling, and the decision was made to obtain initial production from this source. Since known orebodies at shallow horizons were to be developed quickly, the choice of a suitable rock outcrop for the shaft was something of a problem."

Jan 1, 1953

By L. Larson

Rock samples were taken, away from zones of mineralization , from seven sections of five rhyolitic zones as define d by Spence (l967) in the Noranda area. The purpose of the investigation was to test whether there were intrinsic differences between the zones which would differentiate between non-productive zones and productive zones. For the elements sought (major elements, Cu , Pb , Zn and S) , no clear chemical difference between the zones was found. Thus, identification of a favour able zone from the over -all composition of the zone does not appear promising. Within sampled sections, there is no clear gradual compositional change up through the sections. A capping of highly siliceous massive rhyolite is present in five of the sections sampled. A layer of relatively basic material occurs near the base of individual units. The third (mine zone) and later zones contain abundant pyroclastic material, where as the non-productive zones do not.

Jan 1, 1977

By D. J. Bowen

"The Great Dyke extends for 540 krn along strike, to unknown depth, and varies in width from 3 krn to 11 krn. Rb/Sr age determinations gives values of approximately 2470 Ma.The Dyke consists of a variety of mafic and ultramafic rocks, many altered to serpentinites. These include, from top to bottom, successions of gabbro/norites, pyroxenites, peridotiteslharzburgites, and dunites/picrites.The layers dip in from either margin, steepest at the edges (20°) and flattening toward the central sections. Four separate complexes are present. From north to south these are termed the Musengezi, Hartley, Selukwe and Wedza Complexes, and are described as &apos;boat-shaped&apos; or &apos;pig-troughed&apos;. All are similar in petrological sequences. Physiographically, the Dyke is spectacular in the north, where as a mountain range it meets the Zarnbezi Escarpment. Elsewhere in the central parts there is little surface expression and wide open treeless vleis. Dyke rocks cut through granite and schist belt terrain and are termed &apos;The Magnesia Belt&apos;.Vast mineral resources exist. These include chrome, asbestos, platinoids, nickel, copper and gold. Up to eleven chrome seams numbered from top to bottom occur in the lower ultramafic sequences. Seams are narrow at 10 em to 30 em but of high grade. The platinum occurs 10 m to 40 m below the norite/pyroxenite contact.A 60 m wide zone of Light Sulfide Mineralization (LSM) of less than 1070 sulfides extends from the lower gabbronorites into the upper pyroxenites. In this LSM, four enriched zones carry up to 5% sulfides. The most widespread is termed the Main Sulfide Zone (MSZ), below which is No. 2, No.3 and No.4 Sulfide Zones. The MSZ carrying pyrite, pyrrhotite and chalcopyrite is a multielement ore with components of PGE (pt-Pd-Rh), nickel, copper and cobalt, and gold and silver.Extensive exploration programs have been carried out and the intention is to begin large-scale mining. However, with Russia supplying metals to the western markets, South Africa&apos;s cutback on production, and an end to the Cold War, delays have arisen."

Jan 1, 1994

By W. J. Taylor, T. D. Parris

"Over 90,000 feet of raise have been bored at International Nickel underground mining operations throughout the Sudbury District since the advent of raise boring in the early part of July, 1964. With a total of 10 raise borers on hand at this time, techniques have improved steadily since introduction at INCO mines. The first unit, designed for use in rock of low compressive strength, had to be modified and redesigned to cope with Sudbury Area Precambrian rock. As equipment and boring techniques improved, a specially designed machine for larger holes was developed and is now in use. More powerful units, with a thrust capacity of up to 750,000 pounds, are under investigation. Raises have been bored up to 84-inch diameter, and the changeover to 5- and 6-foot flat reaming heads with improved cutter design has increased performance substantially. As a result, 5-foot-diameter raises have been completed to a length of 750 feet and 6- and 7-foot raises to over 500 feet. Reference is also made to the drilling of over 23,000 feet of drainage and sand-fill holes, ranging up to 7% inches in diameter, with smaller underground rotary drill equipment.Finally, a look into the future indicates the need for further improvements in equipment design to permit economic boring of 7- to 8-foot-diameter raises in Sudbury Area ground types."

Jan 1, 1972

By R. B. Ellestad

Introduction Lithium has been known since 1817, when it was discovered by the Swedish chemist, Arfvedson, while working in the laboratory of Berzelius on the chemical analysis of the mineral petalite, LiAl(Si205)2. Development of the chemistry of lithium proceeded slowly, following the early work of Davy, Gmelin, Bunsen, and Matthiessen. Approximately seventy years elapsed before lithium products assumed any commercial importance, and for a considerable period it was a&apos; very minor industry. Their chief early use seems to have been in medicine, and in the production of lithiated water. Other more important uses were gradually discovered, and the industry has had a slow but steady growth. Chemistry Lithium is classified as an alkali metal, along with sodium, potassium, rubidium, and cæsium. Like these, it is a silvery-white metal, which can be cut with a knife; it is harder than sodium, but softer than lead" It is remarkable in having a density of only 0.53 gram per cubic centimeter, which makes it the lightest metal. On ignition in air, it burns intensely to form chiefly lithium monoxide, Li2O. Like the other alkali metals, lithium reacts vigorously with water to form hydrogen and lithium hydroxide. The later is a strong base, and reacts with acids to form salts. The salts of lithium are in general analogous to those of the -other alkalies, but many of them have unique properties. For example, lithium chloride and bromide are extremely hygroscopic, and have a very high water solubility. Lithium fluoride, phosphate, and carbonate, on the other hand, are all relatively insoluble, unlike the corresponding sodium and potassium compounds. In this instance, lithium exhibits its frequent tendency to resemble the alkaline-earth group of elements (calcium, strontium, and barium). Many of the special and valuable properties of lithium are related to the extremely small size of the lithium ion.

Jan 1, 1948

By F. Baczek, S. S. Rocks, D. Chaiko, T. Walters

The atmospheric leaching of chalcopyrite concentrates using acidic ferric sulfate lixiviants is well known to suffer from slow leach kinetics and poor copper recoveries. A number of approaches have been proposed for improving both leach kinetics and recoveries in this system. Many of these, while effective, suffer from high CAPEX and/or OPEX. As many mine sites begin transitioning from heap leaching of copper oxides to processing of primary copper sulfides, cost-efficient leach processes that are compatible with existing SX/EW processes will be needed to maintain existing cathode production. To this end, FLSmidth is exploring process options and reactor technology for the hydrometallurgical processing of primary sulfides. One approach that appears to be highly effective at increasing copper recoveries takes advantage of the enhanced reactivity of transitory, surface-defect structures generated during particle fracture. Significant process efficiencies are gained by matching the rate of grinding to the rate of electrochemical leaching in Mechano-Chemical leach processes. The patent-pending FLSmidth® ROL process uses a Stirred Media Reactor (SMRt reactor) to achieve copper recoveries of 97+% in 6 hours or less. This approach overcomes many of the surface passivation problems that have hindered other atmospheric leach processes. New insights to leach mechanisms are presented.

Jan 1, 2015