Search Documents

By R. I. Grauch, Michael D. Glascock, Chen Nansheng, Jr Coveney, James B. Murowchick

"Unusually rich molybdenum ores (cutoff grade = 4.10/0 Mo) hosted by Lower Cambrian black shales have been mined since 1985 near Zunyi in the province of Guizhou in China. Similar ores were once worked for Mo and Ni near Dayong in the province of Hunan. In both mining areas, mineralization occurs in Lower Cambrian black shale (Niutitang Formation and stratigraphic equivalents) as a single sulfide bed or lens with exposed thicknesses up to 15 cm and reported thicknesses up to 35 cm. In addition to high Mo values (4% to 7%), ore samples contain up to 7% Ni, 2% Zn, 2.5% As, and several hundred ppb Au and Pt-group elements, but the precious metals have never been recovered from the ores. Sporadic occurrences of Mo-Ni sulfide ore beds are found in at least five provinces stretching approximately 1600 Ian from Yunnan to Zhejiang. None of the Mo-Ni ore-bed occurrences has any obvious connection with mafic or ultramafic source rocks. Similar occurrences containing elevated values for Ni, Mo, and PGE exist in Devonian black shale in the Yukon. Future exploration for Pt, Au, Mo, and Ni deposits should consider this previously unknown type of sediment-hosted mineral deposit.Sommaire - Des minerais anormalement riches en molybdène (teneur-limite = 4.1% Mo) provenant de schistes argileux noirs du Cambrien Inferieur ont été exploites depuis 1985 près de Zunyi dans la province de Guizhou en Chine. Des minerais semblables ont déjà été traire pour Mo et Ni près de Dayong dans la province de Hunan. Dans ces deux régions minières, la minéralisation se présente dans le schiste argileux noir du Cambrien Inferieur (Formation Niutitang et équivalents stratigraphiques) sous forme de couche ou lentille unique de sulfures avec des épaisseurs exposées de plus de 15 cm et des épaisseurs rapport6es de plus de 35 cm. En plus des fortes teneurs en Mo (4%-7%), des échantillons du minerai contiennent jusqu’ à 7% de Ni, 2% de Zn, 2.5% d'As, et plusieurs centaines de ppb d'or et d'éléments du groupe du platine; toutefois, les métaux précieux n'ont jamais été récupérés des minerais. Des présences sporadiques sous forme de couches de minerai sulfure de Mo-Ni se retrouvent dans pas moins de cinq provinces s'etendant sur 1600 km de Yunnan a Zhijiang. Aucune de ces présences de minerais, sous forme de couches, ne semble associée a des roches du type mafique ou ultramafique. Des présences similaires contenant des teneurs élevées en Ni, Mo et EOP se retrouvent dans le schiste argileux noir Devonien du Yukon. L'exploration future pour des gisements de Pt, Au, Mo et Ni doit prendre en considération ce type de gisement encore inconnu précédemment."

Jan 1, 1992

By D. Milne, P. Germain, G. Sauriol

"The practical determination of optimum stope geometry has, until recently, been an art relying primarily on experience at a given operation. Due to the complex and variable nature of rock masses in situ, stopes are often designed either very conservatively, resulting in excess development, or non-conservative resulting in excessive dilution and, in some cases, in loss of ore reserves.The Geomechanics group of the Mining Technology Division, Centre de Recherche Noranda, uses a combination numerical modelling and empirical design techniques to optimize allowable stope geometries. The above methodology allows the optim ization of stope geometry for varying rockmass classifications within an operation or between different operations. Such techniques require the development of a thorough geotechnical database at each operation and are best used when calibrated to the specific operation through back analysis.This paper discusses the above optimization techniques in light of specific examples from the Noranda Group. The design methods, limitations and results are discussed.INTRODUCTIONMine design has traditionally referred to production planning, general facility layout, (i.e. ore passes, crusher stations, main haulage drifts, etc.) and ventilation design. The dimensioning and sequencing of the stopes and pillars, however, has been almost solely based on trial and error and precedent practice.More recently, numerical stress analysis has received much more attention as part of the design process. It is common now at many operations to look at the effect of proposed stope layouts and sequences on stress redistribution through the surrounding mine workings. Through calibration of actual stope and pillar behaviour in situ, one can then relate the model predictions to support requirements, safety problems, etc."

Jan 1, 1989

By C. M. Diaz, S. W. Marcuson

In the late 19th century, the discovery of rich nickel-copper sulfide ore bodies in Sudbury and the need for tonnage quantities of the metal to be used in nickel steel armor provided the foundation for establishing the Canadian nickel industry. For almost 50 years, International Nickel was the key player. In 1930, Falconbridge Nickel entered the field. These two companies remain the key Canadian nickel producers. This paper discusses the factors that have influenced the evolution of nickel smelting processes. The initial Sudbury ore smelting and nickel copper separation technologies were imported from abroad. It was only in 1937 that International Nickel established a process research laboratory in Copper Cliff The explosive post WW II industrial development created a strong demand for a broader variety of nickel products. For both International Nickel and Falconbridge, R&D became an essential business tool to succeed in the new market scenery. In the last few decades, new technologies were developed and commercialized to respond to the raising cost of energy, society pressing environmental concerns, the advent of nickel laterites as an important source of new metal, the incorporation of new nickel producers to the market, and, therefore, the need to increase productivity. Canada thus became an important exporter of technology. In this paper, the authors review this history with the objective of highlighting the forces that have triggered the most important changes in Canadian nickel smelting.

Jan 1, 2005

By F. McCarthy, R. McDonald, G. Woodbridge, G. Brock, D. Robinson

"The Direct Nickel process is a hydrometallurgical technology being developed to treat nickel laterite ores by leaching at atmospheric pressure. The leaching process uses nitric acid in a relatively large excess, is thus non-selective, and much of the soluble iron goes into solution. The first stage of solution purification is iron hydrolysis and the Direct Nickel process utilises the colligative properties of the pregnant leach solution (PLS) to enable the removal nitric acid of varying concentrations via distillation. Once sufficient acid has been removed, the boiling point of the solution is increased allowing high temperatures (up to ~170°C) to be achieved under atmospheric pressure. The higher temperatures initiate the precipitation of the iron primarily as hematite and allow the removal of the acid generated by the hydrolysis reaction. The rejection of the iron is near complete with solution tenors typically falling from 65 g/L Fe, or more, to less than 50 mg/L Fe. The separation of clean nitric acid from the PLS at this stage allows for relatively simple acid recycling. A hematite product with iron content above 60% could also provide an extra revenue stream.INTRODUCTION The Direct Nickel (DNi) Process is a novel hydrometallurgical processing route designed to treat all types of nickel laterite ores in a single flow sheet using nitric acid under atmospheric conditions. A simplified flow sheet is shown in Figure 1.Between 2007 and 2012 the process was developed and refined at Direct Nickel’s laboratory within the CSIRO Minerals’ facilities in Perth, Australia, and in 2013 a series of pilot plant trials were run under continuous operating conditions. The process is designed to treat both limonite and saprolite in the same flow sheet, and after comminution, the blended ore is mixed with nitric acid and leached just below boiling point in agitated atmospheric leach tanks. The acid is added in excess, so typically for a blend of limonite and saprolite the acid addition can be in the order of 1.8-2.0 t acid/t dry ore. After a residence time of between 4-6 hours the majority of the soluble metals have leached into solution and the insoluble leach residue is separated from the pregnant leach solution (PLS) via counter-current decantation."

Jan 1, 2016

By Claudia Gasparrini

"Factors affecting the extraction of gold are of a mineralogical nature. Knowledge of the mineralogy of the ore or metallurgical product to be treated, if appropriately combined with the metallurgical test work, may improve gold recoveries. .This paper outlines the mineralogical techniques f or the study of gold ores and metallurgical products and describes the gold mineralogy in relation to its metallurgy. An effective plan for studying refractory and other difficult ores, combining metallurgical test work, chemical analysis and mineralogy and capable of giving positive results over relatively short periods of time, is suggested.IntroductionFactors affecting gold recoveries are of a mineralogical nature and include (i) the gold-bearing minerals, (ii) their grain size and, particularly where the grain size is very fine (10 microns in diameter and less), (iii) their host minerals and (iv) the association these form with the gold-bearing minerals.Mineralogical studies of gold ores and metallurgical products containing gold in economic amounts (today down to 1/10 of one ounce per tonne or 2.84 ppm) are difficult and time consuming. Mostly because of such reason, metallurgical testing (test work) is usually done simply by trial and error without understanding the causes for failure or success.Mineralogical studies, if appropriately conducted and combined with the test work, provide an efficient mean s of improving recoveries through the understanding of gold losses derived from the use of the wrong technique for separation. The information they provide is therefore the first step in the development of recovery techniques, for those ores where the test work alone failed to produce positive results."

Jan 1, 1983

By D. M. Ward

"The uranium deposits upon which the Rabbit Lake project story is based are located at the eastern margin of the Athabasca Basin just west of Wollaston Lake in northern Saskatchewan. This paper provides a general review of the exploration history for the major deposits and the influence of an expanding geological data base, which served to guide the continuing exploration programs.A brief description of each of the deposits is provided in order of their discovery and with emphasis upon their relative geological and mineralogical characteristics.The Rabbit Lake and Eagle Point orebodies are monometallic uranium deposits localized by thrust faults within the Aphebian Wollaston Group. The Cof/ins Bay A-zone, B-zone, and D-zone are polymetaflic U, Ni, As, Co (Au , Ag) deposits located within the Helikian Athabasca Group at its unconformable contact with the underlying Wollaston Group. INTRODUCTIONThis paper demonstrates the importance of applying the accumulated geological knowledge, gained through the exploration, mining, and development process, to the ongoing success of exploration programs. To emphasize this point, the basic geology of each of the major Rabbit Lake area deposits will be presented in chronological order of their discovery and subsequent development. These depos its include Rabbit Lake, Collins Bay A-zone, B-zone, D-zone and Eagle Point. The geological descriptions are based primarily upon the detailed observations of many current and former geologist s employed by both Gulf Minerals Canada Limited and Eldorado Resources Limited. Much of the early historical data was obtained from Dr. E.E.N. Smith, formerly with Eldorado Resources Limited. Regional GeologyThe Rabbit Lake area which includes the Rabbit Lake, Collins Bay A-zone, B-zone, D-zone and Eagle Point deposit s, is located on the eastern edge of the Athabasca Basin close to the western shores of Wollaston Lake (Fig. I). The area is in the Churchill Province of the Canadian Shield within the Wollaston lithostructural domain, at the eastern edge of the Athabasca Group. The uranium deposits occur within both the Wollaston Group metasedimentary assemblage of probable early Aphebian age, and the diagenetic ally altered quartz sandstones and conglomerates of the Athabasca Group of Paleohelikian age. Both units unconformably overlie granitoid gneisses interlayered with metasediments and a graphitic iron formation all believed to be of Archean age. All uranium depo sits in the Rabbit Lake area occur in close proximity to the Paleohelikian - Aphebian or Paleohelikian - Archean unconformity."

Jan 1, 1989

By D. A. Stokes

"In October of 1980, Fording's 15 000-ton capacity clean coal silo was put into operation. The silo was unique in that it was designed to allow the mass flow of material, coupled with a sophisticated computer-controlled dynamic loadout/weighing system.On May 1, 1982, an explosion, attributed to a methane buildup, devastated the top of the silo. .As a contingent plan to minimize the effect of the production loss the conveyance to the silo top was reconstructed and the silo' was back in operation by mid-June 1982, although the silo top was left open to prevent further methane buildup. As dust emissions occurred during loading ofthe silo, an extensive study was undertaken to establish dust control for the silo, while at the same time providing methane detection and control.The study, conducted for Fording by the Cambrian Engineering Group of Calgary, involved an extensive search and investigation of existing coal silos. The study concluded that there IS no universally accepted method of controlling methane emissions in coal silos.The study also produced a unique conceptual design for handling methane, while at the same time, protecting the environment . Fording's Clean Coal SiloThe silo, located at Fording Coal's Fording River metallurgical coal operation, is utilized for the storage and load out of cleaned thermally-dried metallurgical coal.The silo was constructed in 1979 and 1980 to reduce unit train loadout times and to facilitate the handling of “special shipments"" of coal. The silo went into operation in October 1980, under manual control and utilized computerized, automated loading by February 198I.The silo is 21 m in diameter and 76 m high, with a nominal capacity of IS 000 live tonnes. The coal storage portion of the silo is 21 m in diameter and 48 m high, utilizing 2 steep-angled hopper outlets allowing mass flow of the stored coal during train loading. Each hopper has a control gate and a discharge chute, one chute for bulk loading, the other for trim loading of coal into the rail cars."

Jan 1, 1986

By D. R. Boyle

"The Murray Brook precious metal (Au, Ag) gossan deposit is one of nine supergene mineral deposits that have developed over polymetallic massive sulfide deposits in the Bathurst Camp of New Brunswick. Reserves consist of 1.9 Mt of gossan containing 1.53 g/t Au and 65.9 g/t Ag. The supergene zone at Murray Brook consists of six distinct units: a) altered massive sulfide, b) pyrite-quartz sand, c) massive sulfide gossan, d) disseminated sulfide gossan, e) ferruginized wallrock, and f) leached bedrock. The massive sulfide gossan constitutes the main body of economic mineralization and consists of goethite, primary quartz, secondary amorphous silica, K-Fe-Pb-As- Sb-Ag hydrated sulfate and oxide minerals (beudantite, plumbojarosite, jarosite, bindheimite, scorodite), trace cinnabar, and cassiterite of primary origin. The order of stability of sulfide minerals during oxidation was pyrite _ arsenopyrite _ galena _ Bi-Sb sulfosalts _ chalcopyrite _ tetrahedrite group _ sphalerite.Two mass balance techniques (isovolumetric and conservative element) indicate elemental depletion in gossan relative to primary ore in the order: S>Cd=Zn>Cu=Mn>Na=Ca>Fe=Al=V> Mg= K=Se=Hg>Pb>Ti>Ag>Mo=P>Ba; and enrichment in the order Au>As>Sb>Si>Bi. Tin, as cassiterite, is conservative.Mineralogic and paleomagnetic data suggest that the gossan deposit formed under a warm temperate climate throughout the Pliocene. The rate of oxidation and the compositional nature of the ore was significantly influenced by: a) the position of the primary sulfide zone in a downward moving hydrological system, b) primary sulfide composition and zonation that promoted the development of a strong electrochemical oxidation system, and c) pronounced intercalation of carbonate and sphalerite mineralization in sulfide zones, which promoted rapid development of secondary porosity, permeability and downward flow of oxygenated groundwater.During progressive oxidation and physico-chemical erosion of the gossan zone, Au was transported downward in groundwaters, probably as a Auo colloid complex, to be concentrated in the lower horizons of the gossan profile. The precipitation of Au was greatly increased in the pyrite/arsenopyrite zones. Gold concentration was multi-cyclic with continual dissolution and nucleation of the metal until final concentration in the void structures of the gossan. Leaching experiments and microprobe analyses indicate that Au is present in the gossan as submicron composite sols of Au-Ag-silica."

Jan 1, 1995

By Amyn S. Dahya, David J. King

"The object of the paper is to discuss the developments in Carbon-In-Pulp (C.I.P.) technology for gold recovery. The CIP process is comprised of four major operations:(a) adsorption of precious metals onto activated carbon;(b) elution (stripping) of precious metals from the loaded carbon;(c) electrowinning of the precious metals from the concentrated eluate;(d) regeneration of the eluted carbon before recycle to the adsorption process.A detailed review of the technological developments in each of the above operations is presented together with a brief theoretical background of the underlying processes. The advantages and disadvantages of the CIP process are discussed in comparison with conventional zinc precipitation. IntroductionThe carbon-in-pulp (CIP) process involves the use of activated carbon for treatment of pulps containing dissolved precious metals, and provide s an alternative to the conventional gold recover y processes using filtration or counter-current decantation in conjunction with the Merrill-Crowe zinc precipitation process. The commercial application o f the CIP process in gold processing technology is a fairly recent development and it is of growing importance around the world.The fact that activated carbon ha s the property of adsorbing precious metals from solution was first published in 1847. In the following years , a great deal of work was carried out to develop an over-all recover y process using carbon, but all attempts were uneconomical because the loaded carbon had to be smelted to recover the gold.It was not until 1950 that Zadra, at the United States Bureau of Mines Research Centre in Reno, Nevada, developed a technique for stripping the loaded carbon using sodium sulphite-sodium hydroxide mixtures and then recovering the gold from the stripping solution by electrolysis. However, this process was not effective for stripping silver and further testwork was carried out on alternative stripping techniques. In 1952, Zadra published a paper describing the use of a hot sodium hydroxide- sodium cyanide stripping technique, which was effective in stripping both gold and silver. This paper included a description and flowsheet for the CIP process which is essentially the same as we know it today. This technique was used in the first major CIP plant, constructed and commissioned in 1973 by Hornestake Gold Mining Company. Since then there have been numerous CIP plants built in the U.S A., South Africa and Australia."

Jan 1, 1983

By H. C. Gunning

Introduction The invitation to contribute a discussion on some of the broader features of the mineral deposits of our Cordillera seemed acceptable enough when presented several months ago. More mature consideration has impressed upon me the difficulty of making any constructive or very helpful contribution in the short time available and with my limited inspiration. Dr. Lang deserves our real gratitude for his general paper of nineteen pages at the beginning of the Volume. Into it, with the help of two diagrams and seven tabular summaries, he has packed a lot of useful information and has analyzed along several lines the data of the Volume's twenty-eight detailed papers on our mines and camps. He has added additional facts from his own knowledge of the region. I am sure that, like myself and the whole fraternity, he feels especially grateful to the eleven company geologists who found time to contribute detailed descriptions of mines they have studied. The Regional Situation With the Jubilee Volume and two recent publications of great value from the Geological Survey, we are more up-to-date on Cordilleran geology than we have ever been. But I would like to emphasize that we still have but fragmentary information. Brief study of G.S.C. Map 932A will illustrate this. Our knowledge of the Rocky mountains is limited to two narrow sections along the main railway lines, a somewhat larger area from the border north along the Mesozoic coal-bearing basins, and some reconnaissance along Peace river and the Alaska highway. There is some additional information on old maps, particularly those by G. M. Dawson, but it is very much of the 'exploratory' type. The other mapped areas are chiefly in the accessible region south of 'fifty-one', in the central part adjacent to and spreading north, recently, from the Canadian National railway, and along the edges of the Coast Range.

Jan 1, 1950

By G. N. Nnadi, R. J. Mitchell

"The response of cemented backfills subjected to simulated blast loadings is studied using centrifugal modelling techniques. Scaling requirements for centrifugal modelling are developed and the results of the similitude analysis show that an acceleration field is required to capture the true dynamic response of backfill models. Experiments have been conducted at various centrifugal accelerations. The effects of ring blasting were simulated by an impact loading on the exposed fill face. The behaviour of the cemented backfill was monitored with accelerometers as well as dynamic stress gauges.Cemented backfill response to impact loadings was found to depend strongly on simulated gravitational stress level. Results also show that the characteristics of the response changes with distance from the impact. Finally, the results of the models were used to predict prototype peak accelerations, velocities and displacements. The results reported in this study indicate that centrifuge modelling may be a useful tool for dynamic studies of blast damage to backfills. Centrifuge modelling can be carried out at low costs and can be used to design prototype instrumentation systems. IntroductionThe response of cemented mine backfills to blast loadings is of concern to the mining industry because these backfills provide local and regional support during ore pillar extraction. Considerable research has been reported on the static stability (Smith et al., 1983) and on effects of reinforcements on cemented backfills (Mitchell, 1989). However, information regarding dynamic aspects of cemented backfill is limited. O'Hearn and Swan (1989) reported on the response of cemented backfill to blast loading, but these blasts were not very dose to the backfill . A schematic representation of a rock-backfill system is shown in Figure I.The mechanics of transfer of explosive energy to rock and subsequently to the backfill, and the resulting responses, are complex. Achison (1968) listed more than twenty factor s affecting the blast fragmentation of rock and grouped these into the categories of explosive parameters, charge parameters and rock parameters. Although significant advances have been made, during the past two decades, in understanding the mechanics of blasting, the degree of uncertainty associated with predicting the behaviour of backfills subjected to dynamic loadings makes the application of simple design safety factors insufficient. Comprehensive testing programs or prototype instrumentation is required to evaluate the risks associated with blast or earthquake loadings on backfill."

Jan 1, 1991

By A. E. Hilder

Introductory The following pages present the results of field investigations, laboratory and commercial tests, drilling, surveying, and preliminary development of the refractory clays which have been discovered recently in the township of Kipling, at the foot of Long rapids on the west side of the Mattagami river about 57 miles north of Kapuskasing and approximately 7 miles north of Smoky Falls, the terminus of the privately owned railway operated by the Spruce Falls Power and Paper Company, Kapuskasing (see Figure 1). Investigations on the clays of northern Ontario have been carried on over a period of seven years by officers of the Ontario Department of Mines, and I am indebted to the information published by that Department in reports by W. S. Dyer and A. R. Crozier, as well as?by Professor R. J. Montgomery, of the Ceramic Department, University of Toronto. It was, in large measure, the data given in the 37th, 38th, and 42nd Annual Reports of the Ontario Department of Mines that led me to make a personal investigation of the Mattagami River clays, with the result that we now have a commercial undertaking that will develop eventually into an industry of considerable importance in supplying the central manufacturing districts of Canada with refractories that heretofore have been largely imported from the United States. An extract from the 42nd Annual Report of the Department, Part III, 1933, page 75, reads as follows: "As for the refractory clay, the deposits are undoubtedly very large, but what is urgently needed is a deposit near the railway under sufficiently shallow overburden for recovery by stripping'. Having previously made an investigation of the clays adjacent to the Temiskaming and Northern Ontario railway, and these clays proving unsuitable, I turned my attention to the outcrops of refractory clays on the Mattagami river, first reported by Keele in 1919. This area offered possibilities within the economically permissible distance from rail transportation.

Jan 1, 1935

By M. G. Rylatt, G. M. Popplewell

"Production from Canada's first diamond mine is planned for the last quarter of 1998. The climatic conditions and the variation in kimberlite types to be treated have lead to the development of a compact and flexible processing plant.High kimberlite moisture contents and winter temperatures below -40°C have dictated a process flowsheet with limited in-circuit storage to reduce materials handling difficulties. The latest developments in High Pressure Grinding Roll technology will be used to liberate the valuable diamond, reduce diamond breakage, and increase fines production to reduce the amount of material for down stream processing in the Heavy Medium Separation section.A varying heavy mineral concentrate yield has lead to the development of a final Recovery section that will incorporate Attrition Milling and Wet High Intensity Magnetic Separation for concentrate reduction. The latest developments in diamond X-ray sorting will be used to produce a final diamond concentrate for mechanical sizing, weighing and packing.Fine tailings thickening will utilise Deep Bed Compression type thickeners. This relatively new technology can produce;i) high underflow densities at low flocculant dosage rates, andii) clear overflowswith a smaller thickening area than conventional high-rate thickeners."

Jan 1, 1998

By James A. Finch, Yue Hua Tan, Wei Zhang

"The paper is part of our study of the frother structure-property relationship using bubble rise velocity. Single bubble rise velocity profiles were determined in a 350 cm column for surfactants from the polypropylene glycol (PPG) family. Using velocity at 300 cm, the concentration to reach minimum velocity (CMV) is determined. The CMV is shown to decrease as alkyl chain length (n, number of carbons) increases and as the number of propylene oxide groups (m) increases. Linear correlations log CMV vs. n and m were observed. Taking literature data for critical coalescence concentration (CCC), linear log CMV vs. log CCC correlations were also noted. Mechanisms are briefly discussed, and prediction of CCC made for a commercial polypropylene glycol.INTRODUCTIONAs one of the great enabling technologies of the 20th century, froth flotation is a highly versatile method for physically separating minerals by exploiting differences in wettability (hydrophobicity). Over the last century, flotation reagents have undergone significant developments (Khoshdast and Sam, 2011). One important group of reagents is frothers which are used to reduce bubble size, slow bubble rise velocity and help stabilize froth (Klimpel and Isherwood, 1991).Frothers, originally derived from natural sources (e.g., pine oil and cresylic acid), are largely replaced today by synthetic products which provide more consistent properties. Polyglycols, based on PEO (polyethylene oxide), PPO (polypropylene oxide), or PBO (polybutylene oxide) groups, were first described by Leja and Nixon (1957) and have attracted wide use since then (Farrokhpay 2011). The chemical structure of polyglycols can be represented by a general formula: R(X)mOH, where R = H, or CnH2n+1 and X stands for EO (-C2H4O-), PO (-C3H6O-), or BO (-C4H8O-). The polypropylene glycol ethers (CnH2n+1(PO)mOH) are the most common of these reagents (Pugh, 2007) and the focus of this study.In general, the chemical structure of frother molecules comprises two parts, a non-polar hydrophobic hydrocarbon (alkyl: CnH2n+1) chain and a polar hydrophilic head. By introducing the ether -Olinkage, which acts as another polar site, the propoxy group (-OC3H6-) in the structure makes the frother readily soluble in water (Somasundaran and Wang, 2006), facilitating the industrial use of these frothers. Available as by-products, Dow Chemicals introduced as series of polyglycols, e.g., Dowfroth (DF) 200, 250, 263, and 1012, the most familiar being DF250 (CH3(PO)4OH), a polypropylene glycol methyl ether. While no longer available from Dow, these and other polyglycols are still widely used."

Jan 1, 2016

By John Kostuik

AT the Sladen-Malartic mine, a number of orebodies have been mined, some by shrinkage and others by open sub-level scopes, from which the ore is handled either through a grizzly system or by mechanical loaders. This paper deals with the comparative costs and relative merits of the two handling arrangements. The facts brought out in this comparison have a bearing on the selection of a proper handling method. The mine is in Fourniere township, northwestern Quebec, about forty miles east of the town of Rouyn. It is served by the Rouyn-Senneterre branch of the Canadian National railways. Two vertical three-compartment shafts give access to the present workings. No. 1 shaft, at which the plant is centralized, is the main hoisting shaft, with five levels to 950 feet. No. 2 shaft, 2,400 feet east of No. 1, is under development, with four levels to 725 feet. At the main shaft, the ore is hand-trammed in 1 1/2 tons cars from the scopes to the stations o:i each level and hoisted in cages to surface at a rope speed of 900 feet per minute. Air-operated tipples are used to dump the ore through grizzlies of 14-inch openings into a surface bin of 150 tons capacity. The ore hoisted at No. 2 shaft is trucked from the headframe bin to the mill. Milling commenced in January, 1938, ar a daily rate of 250 tons. Within two months this rate was increased to the unit's maximum capacity of 325 tons. A second unit to treat a further 325 tons daily was installed in April, 1939. The orebodies mined at No. 1 shaft are parts of a silicified zone at the contact between syenite porphyry and greywacke. The zone is ten co sixty feet wide, strikes easterly, and dips to the south at 55 to 85 degrees. The hanging-wall of the zone is marked, though not precisely, by a strong gouge fault. Locally, the boundary of silicification may be as much as twenty feet either above or below the fault, but for practical mining purposes the fault is the hanging-wall of the ore-zone. The footwall roughly parallels the fault, but as an assay wall it is usually irregular in detail. The ore is dense and hard, a siliceous replacement of both porphyry and greywacke, mineralized with fine disseminated pyrite.

Jan 1, 1941

By D. F. Hambley

"In designing are passes f or underground mines specific consideration should be given to unimpaired flow of broken rock, the dump point, and typical practices f or overcoming operational difficulties. Design features such as branches, bends, and knuckles should also be considered. This paper pro vides engineering information and various criteria for designing are passes, draw points. feeders, and support systems, together with several illustrative examples.IntroductionOre passes are the primary mean s o f vertical transfer of mined ore to the ore bins and loading pocket from which the o re is hoisted to the surface (Fig. 1) . While the words "" ore"" and ""ore pass"" are used here, such transfer systems ca n be used for any broken rock.The most extensive ore pass systems are found in caving and sublevel stoping mines. Extensive ore pass systems are also found in multilevel mines having steeply dipping orebodies. In more flat-lying orebodies , ore pass systems are sometimes used in conjunction with conveyor systems .Two decades have passed since the principles of the flow of bulk solids were formulated (Jenike, 1961, 1964; Johanson and Colijn, 1964; Kvapil , 1965). However, few published papers are available that discuss the design criteria for ore pass systems. Therefore, the aim of this paper is to provide the information necessary for good o re pass design .Rock Flow in Ore Pass SystemsIf an ore pass system is to fulfill its function, the transfer o f material must occur in an orderly fashion and in such a way that the full size of the opening is employed effectively. Apart from un controlled flow at the drawpoint, or outlet , whose design will be considered later in this paper, two occurrences may impede flow in an ore pass, namely:• Hangups due to interlocking arches.• Hangups due to cohesive arches.Prevention of each of these problems will be discussed in succeeding sections of this paper. A third problem piping, is related to the ratio of the drawpoint size to the o re pass size and will be discussed under drawpoint de sign."

Jan 1, 1987

By D. Mraz

"Under high pressure in a deep potash mine, the salt rock behaves in accordance with the concept of a generalized, perfectly plastic substance. The paper presents the evidence of this behaviour and engineering concepts f or room-and-pillar design. IntroductionThe mining and refining facilities at International Minerals &. Chemical Corporation (Canada) Limited are located near Esterhaz y at the southeastern edge of the Saskatchewan evaporites. Ore extraction began in 1962 and at the present time the annual mining capacity is in excess of eleven million tons of potash ore.A generalized geological section is shown in Figure I. The mining horizon is overlay in by 100 feet of rock salt followed by a thin bed of competent dry shale. The strata in the next 1,500 feet are generally competent and locally water bearing. The Blairmore formation contains strata of water-bearing unconsolidated sand. Below the mining horizon, rock salt is interbedded with anhydrite bands.The 8-foot mining bed is distinguished mainly by grade and clay content, as there is no definite bed boundary. The chief mineral s are halite, sylvite and, in some cases, carnallite, with up to 2 per cent disseminated clay. The ore is coarse grained, with crystals averaging one-half to three-quarters inch across.The major mining problem is related to the fact that the Dawson Bay formation, overlying the evaporites, contains areas and channels that are highly porous and permeable and are filled with unsaturated brine under high pressure. Consequently, all mining areas, with no exception, must be so designed that the overburden salt stratum remain s competently supported for the duration of the mine .This paper outlines a successful engineering method of determining the stability of the pillar s and designing a stable room -and-pillar mining system."

Jan 1, 1980

By Fathi Habashi, Michel Pagé, Farouk T. Awadalla

"Chrysotile asbestos can be dyed with certain dyestuffs to form stable coloured products whose hemolytic and cytotoxicity are greatly reduced. Examples of these dyes are Thiazol Yellow G (a monazo dye) and Trypan Blue (a diazo dye). Other dye stuffs, for example, basic dyes with triphenyl methane structure, Brilliant Yellow (a diazo dye), and Methylene Blue (a thiazine dye) colour asbestos but do not reduce its toxicity. Similarly alizarin, 8-hydroxyquinoline, and representative members of the phthalein group Bromocresol Purple and Phenolphthalein.IntroductionThere is, at present, a controversy regarding the dangers of asbestos fibres, and attempts are being made to render it less toxic. One of these attempts consisted of treating chrysotile asbestos with gaseous phosphorus oxychloride, POCI], at ambient temperature and in absence of moisture. The product had to be heated at 300°C to 500°C to expel exess entrained reagent to get a material containing 0.5070 to 5% phosphate groups and known as Chrysophosphate (Lalancette and Dunnigan, 1982). This product showed decreased toxicity as measured by its hemolytic effect on red blood cells (fable 1). In another approach, Flowers (1983) showed that when chrysotile asbestos was thoroughly mixed with a solution of ferric ammonium sulphate and the slurry was then filtered and dried, the product showed a marked decrease in cytotoxicity.In the present investigation the problem of toxicity was considered from a different point-of-view. Chrysotile asbestos is a hydrated magnesium silicate that can be represented by the structural model shown in Figure 1 from which it can be seen that magnesium hydroxide groups, Mg(OH)2, form a part of the silicate structure. Certain organic reagents that are known to react with magnesium ion in solution to form chelates were reacted with asbestos to find out whether a chelate was also formed on the fibres, and if so , what will be the hemolytic action and cytotoxicity of the product."

Jan 1, 1991

By Fan Delian, Ye Jie, Lui Tiebing

The lower and the upper parts of the Doushantuo Fonnation, Hubei Province, China, contain silicate-type K-rich beds (illite and feldspar), and intraclastic phosphorites, as well as Ag-V and V deposits in a "Black Shale Series". The K-rich beds fonned in an anoxic basin whereas the phosphorites fonned in a more oxic and higher energy depositional environment. The Black Shale Series occurs in the lower and upper parts of the Doushantuo Fonnation; that in the upper part consists of black illite shale and dark gray dolostone, and contains Se-rich Ag and V deposits. These deposits are of more industrial significance than the previously discovered Ni-Mo polyelement sulfide deposits which occur in the Lower Cambrian Black Shales Series of South China. Studies of lithotype, sedimentary sequence, and geochemistry of the Doushantuo Fonnation have led to more attention being focused on the uppennost Black Shale Series and its Ag-V and V deposits. There are three ore types: black, Ag-V-rich, illite shale; black, V-rich, illite shale; and dark gray, Ag-Vrich, fmely crystalline dolostone. The first two ore types contain 3070 to 5% Corg and the last, 1.25%. The Ag-bearing minerals are naumannite, argyrodite, aguilarite, acanthite, and native silver that occur as inclusions in pyrite associated with barite. Vanadium substitutes for AI in illite and is also related to organic-matter contents. Because (1) the pre-Sinian Kongling Group contains one to three times greater than the Clark Ag value; (2) black, illite shale has a negative Ce anomaly; and (3) there are large occurrences of black, K-rich, tuffaceous, fme siltstone, the sources of Ag are thought to include subaerial and submarine volcanic materials. It is proposed that Ag, V, and Se were absorbed by clay particles and organic matter during syngenetic deposition in an anoxic environment; Ag subsequently was reconcentrated into sulfides and selenides, whereas V was incorporated structurally into illite during early and late diagenesis. These types of Black Shale Series-hosted Ag-V and V deposits are, therefore, considered to be sedimentary-diagenetic in origin.

Jan 1, 1992

By Abhinav Karanam, Lukas Bichler

Yttria Stabilized Zirconia (YSZ) is a promising thermal insulator for high temperature environments due to its thermal stability and chemical inertness. As was demonstrated with other technical ceramics (e.g., Alumina), addition of Single-Wall Carbon Nanotubes (CNTs) to a ceramic matrix may significantly enhance the mechanical properties of the composite ceramic. In this work, 8 mol% YSZ with 0.2, 0.5 and 1wt% CNTs composites were prepared via Spark Plasma Sintering process. The densification, Vicker’s microhardness, specific gravity and microstructure evolution of the composites were investigated. The results suggest that the addition of up to 1wt% CNTs to YSZ yielded optimal combination of the studied properties. At higher addition levels, the specific gravity decreased and clustering of CNTs occurred, leading to poor densification and a relative loss of performance.

Jan 1, 2014