Search Documents

By Pingchao Ke, Zhihong Liu

"To overcome the problem that scoroditeis not stable in neutral and alkaline solutions, we proposed and investigated a synthesis method of scorodite coated in-situ with hydrated ferric oxide in the Fe(II)-As(V)-H2O system at the initial Fe(III)/As(V) molar ratios larger than 1.0.The synthesis was carried out at 90?,pH 1.5 under atmospheric pressure. During the synthesis, oxygen gas was conducted and bubbled into the system to oxidize Fe(II) ions into Fe(III)ions, and Na2CO3aqueous solution as neutralizing agent was added controllably into the system for keeping the pH constant at 1.5. In this study, three samples of scorodite were synthesized at the controlled initial Fe(II)/As(V) molar ratios of 1.0, 2.0 and 3.0, respectively. The characterizations of the samples by HRTEM, TEM/EDX, and chemical composition indicated that the particle surfaces of scorodite synthesized at the initial Fe(II)/As(V) molar ratio of 2.0 and 3.0 were coated in situ by a film of hydrated ferric oxide with the thickness of several nanometers, while the sample synthesized at the initial Fe(II)/As(V) molar ratio of 1.0 was uncoated scorodite. The TCLP and long-term leaching for the toxicity characteristic of the samples showed that scorodite coated in situ with hydrated ferric oxide was stable in a wide pH range from 3.0 to 10.0, with the arsenic concentrations in the leaching solutions less than 1.0mg/L. Nevertheless, uncoated scorodite was unstable under the conditions from weak acidity to alkalinity, with the arsenic concentrations in the leaching solutions larger than 5.0 mg/L.INTRODUCTIONArsenic pollution is a challenge for environment and health and has been an important issue for scientists (Hopkin, 1989).Arsenicis commonly associated with ores or concentrates of nonferrous metals, mainly as independent arsenic bearing minerals such as arsenopyrite (FeAsS), tennantite(Cu12As4S13), enargite (Cu3AsS4), cobaltite (CoAsS), and gersdorffite (NiAsS), realgar (As2S2), orpiment(As2S3), etc.(Matschullat, 2000; Mandal & Suzuki, 2002; Long & Peng, 2012). In the nonferrous metallurgical processes, arsenic is enriched mainly in such arsenic bearing materials as various flue dusts, residues, and anode slimes, which results in the accumulation of arsenic in the system owing to the circulation of those arsenic-bearing materials back to the system and the pollution to the environment (Harris, et al, 2003).In addition, the utilization of arsenic is limited and has been decreasing owing to its toxicity and carcinogenicity. Therefore, arsenic has to be removed from those arsenic-bearing materials and discarded safely (Dutrizac & Jambor, 1988; Monhemius & Swash, 1999; Drahota & Fillippi, 2009).In this case, how to immobilize arsenic has become a difficult problem which must be solved. Among the methods of immobilizing arsenic which have been proposed and investigated, immobilizing arsenic into a stable mineral to fix it, has been realized as a promising method and becomes a research focus(Dutrizac et al, 1987; Dutrizac & Jambor, 1988; Demopoulos et al, 1995; Fujita et al, 2008a; 2008b).Scorodite has been known as one of the best minerals for immobilizing arsenic, owing to its high stability under weak acidic condition, the arsenic content as high as 32wt%,and good crystallinity benefiting the separation of solid to liquid(Daivid et al, 1999; Zhu & Merkel, 2001). Scorodite can be synthesized from arsenic containing solutions under both hydrothermal and atmospheric conditions, and a lot of work has been done on the synthesis of scorodite and its leaching stability characterization (Filippou & Demopoulos, 1999; Gomez et al, 2011).Two plants for the immobilization of arsenic as scorodite have been putin to operation in Chile and Japan, respectively (Filippou & Demopoulos, 1999; Amir et al, 2016)."

Jan 1, 2017

By T. Grammatikopoulos, K. Gibbs, H. De Souza, C. Gunning

The mineralogy of any ore body is a key factor in defining ore zones and predicting minerals/metals behaviour during processing. The determination of forms of gold, defined as the different chemical states in which gold is encountered in ore deposits, is critical. The most commonly known form is that of gold minerals and alloys, while other forms of gold have been collectively described in the literature as submicroscopic gold (i.e., less than 1 µm in diameter). Gold mining operations generally deal with very low-grade ores, in the order of a few g/t, in which gold displays complex mineralogy. These difficulties complicate the mineralogical studies and pose challenges for processing and recovering the gold. A comprehensive understanding of the chemical forms of gold is necessary to define gold mineralization and optimize gold metallurgy. SGS Canada Inc. has been using QEMSCANTM and a Tescan automated SEM that are automated mineralogical techniques that provide vast amounts of data for microscopic Au. The data in conjunction with other physical and chemical methods provide a comprehensive delineation of the ore composition and behaviour.

Jan 1, 2011

By Andrew Kerr

Overview of Presentation ? Introduction ? An historical context: From 1866 to the 21st century. ? Geological framework for iron ore in the region known as the ?Labrador Trough?. ? Producing iron-ore deposits of the Labrador City ? Wabush area, and near-future production from the Schefferville area. ? Exploration projects representing potential future production?.or expansion of the district. ? Some concluding remarks???

May 1, 2011

"The Crescent, DM, and Pothook zones are copper-gold porphyry deposits which formed in association with alkalic intrusions of the early Jurassic Iron Mask batholith. The characteristics of the Crescent and DM deposits are nearly identical. Both formed along the contact between the Cherry Creek monzodiorite and Pothook diorite phases of the batholith. Permeable intrusion breccias along the contact concentrated the flow of hydrothermal fluids. Early, pre-ore alteration is represented by pervasive, sulphide-barren potassium metasomatism. The precipitation of copper-gold ore occurred during subsequent fracture-controlled potassic alteration, and is most strongly developed in chlorite-sulphide veins and their alteration envelopes. A central zone of potassic alteration is surrounded by a propylitic, pyritic halo in both deposits. The DM zone is unique among alkalic porphyry deposits in its high abundance of quartz-sulphide veins.The Pothook deposit formed at the westernmost contact of the Iron Mask batholith with enclosing Nicola Group volcanic rocks. Pervasive potassium metasomatism, similar in style to that at Crescent and DM, is associated with intrusion of the Cherry Creek monzonite. Pervasive and fracture-controlled albitic alteration is associated with intrusion of the Sugarloaf diorite and introduced minor copper-gold mineralization. Most of the copper-gold mineralization was introduced during formation of veins and breccia matrices dominated by magnetite/hematite and sulphide. Late-stage chlorite veining may have remobilized or introduced additional gold mineralization.Copper and gold assays in the Crescent deposit are well-correlated and have a nearly constant Cu:Au ratio, suggesting that the metals coprecipitated during a single hydrothermal event. In the Pothook deposit, copper and gold do not correlate closely, lack spatial correspondence, and suggest that transport and/or deposition of the two metals were not identically controlled and that they may have been introduced at different times by separate hydrothermal events."

Jan 1, 1995

By P. S. Arthur

The copper I SAS MELT? process is a submerged lance bath smelting technology. In the 20 years since the process was first demonstrated on a semicommercial scale at Mount Isa in north-west Queensland, Australia, copper ISASMELT? plants have been constructed to treat concentrates or secondary raw materials around the world. The process is operating in smelters in Australia, the USA, Belgium, India, Germany, China and Zambia. ISASMELT? plants have been installed to improve the environmental performance of operating smelters and reduce costs for smelting companies. A new copper furnace is being commissioned at Southern Peru Copper Corporation in early 2007, while more furnaces are under design for installation in Kazakhstan and Peru. Copper ISASMEL T? plants are supplied as complete technology packages including engineering design services for the furnace and key ancillaries, supply of core equipment, provision of intensive training programs in operating plant environments and commissioning assistance services. The proven technology transfer process ensures successful implementation of submerged lance bath smelting into large scale plants. This paper summarises developments at recently constructed copper ISASMELT? plants.

Jan 1, 2007

By Gaoming Wang

Outline 1. The Gangdese porphyry Cu-Mo belt 1.1 Regional geological background 1.2 Cu-Mo-bearing porphyries 1.3 Mineralization and alteration 2. Dating methods and results 2.1 Qulong porphyry 2.2 other porphyries 3. Geodynamic implications 4. Conclusions 5. Acknowledgements

May 1, 2004

Discovery of an economic diamond deposit produces considerable wealth in terms of jobs, royalties, mining investment, and economic spinoffs for residents, including Aboriginal peoples. Diamond mines contribute to the GDP, increased personal income per person and reduced unemployment rates. Is it possible in Alberta?

May 1, 2008

By C. S. Touchard, F. Bourgeois, L. Cassayre, Julcour-Lebigue C.

Developing a hydrometallurgical process that can overcome the refractory nature of chalcopyrite (CuFeS2) to leaching still eludes the minerals industry, despite major research efforts spanning decades. The several leaching experiments of this ore in sulfuric acid tend toward the same conclusion that the precipitation of elemental sulfur or iron containing species are the main dissolution inhibitors. Describing both the electrolyte composition and the various solid phases in equilibrium for the Fe-H2SO4-H2O system is essential to overcome this issue and to find an operating window. According to the thermodynamic models and to the thermodynamic data, we demonstrate, in this study, the need to use the Specific ion Interactive Theory (SIT) model to describe complex electrolytic systems through a limited number of parameters. Hence, the binary interactions for our case study have to be defined and estimated. This work develops a methodology to determine these parameters of the SIT model up to 90°C and an acid concentration of 1 mol/kg from published data for H2SO4-H2O and Fe(II)-H2SO4-H2O sub-systems or from new experimental data for the Fe(III)-H2SO4-H2O one. This method will eventually be applied to copper systems to lead to a thermodynamic description of the complete CuFeS2-H2SO4-H2O system. INTRODUCTION A leaching process consists in the dissolution of a solid phase into an aqueous medium in order to extract compounds of interest. It is a key step in the hydrometallurgical processes used in the primary production and recycling of metal components. One of the main leaching issues is the formation of passivating layers on the surface of solid particles, whose consequence is a partial or total hindrance of the dissolution. The leaching of chalcopyrite (CuFeS2) in sulfuric acid is a prime example. No industrial solution for the atmospheric pressure leaching of this ore has been developed to date because of passivation phenomena caused by the formation of elemental sulfur or iron-containing precipitates on the surface of the particles (Li, Kawashima, Li, Chandra, & Gerson, 2013). In the 1970s, the Pourbaix diagrams established for the Cu-Fe-S-H2O system at 25°C for low concentrated solutions (Garrels & Christ, 1965; Peters, 1976) agreed that copper and iron are fully dissolved at high potential and in acidic medium (pH < 4). However, they neglected the many stable solid phases that can form in these conditions. In addition, the Pourbaix diagrams of chalcopyrite in water, calculated with two recent databases (FactPS and Thermoddem 2017) associated to FactSage and PhreeqC softwares respectively, show large discrepancies at 75°C (Figure 1). Indeed, at high potential, FactSage predicts the formation of goethite FeOOH at a pH value of 1, while PhreeqC predicts the formation of jarosite (H3O)[Fe3(SO4)2(OH)6] for pH greater than 2.5.

Jan 1, 2019

By Steven R. McCutcheon

"The Bathurst-Newcastle district, a subcircular area approximately 50 km in diameter, contains 37 massive-sulfide Zn-Pb-Cu deposits that have defined tonnages, and has 58 additional significant occurrences. The largest deposit is Brunswick No. 12, with total reserves (including past production) of 148 million tonnes grading about 12.5% combined Pb-Zn. The deposits/ occurrences are spatially associated with a felsic volcanic pile that contains a significant sedimentary component. In the vicinity of the Brunswick deposits the pile is divisible into lower and upper sequences. The lower is characterized by megacrystic rhyolite (QFAS) and coarse- to fine-grained quartz (± feldspar) wackes and/or tuffites (QAS); the upper sequence is characterized by aphyric to sparsely porphyritic rhyolites (HWR), micro-breccias, and acid hyaloclastites with interbedded dark gray sedimentary rocks. A greenish gray to dark gray siltstone (GGS) separates the two sequences and hosts the sulfide deposits. Lithogeo chemistry of least altered samples shows that the QFAS and HWR have an igneous character, whereas the QAS and GGS have a sedimentary signature. The two types can be distinguished on the basis of total alkalies (Na2 + K2O) versus SiO2/Al2O3 and Ti02 versus Fe/(Fe +Mg). Some trace elements, such as Sr and Y, also help differentiate the two types. The QFAS differs from HWR by having higher La/Yb ratios but lower Zr and Th. The Bathurst deposits do not show a close spatial association with rhyolites but rather are stratiform bodies Oacking clastic textures) within fine-grained sedimentary rocks. The scarcity of barite and other sulfates indicates that there was little mixing between the metal bearing fluids and cold seawater. High Fe/(Fe+Mg) ratios in chlorites also indicate the fluids did not contain a significant seawater component. These features and the large size of many deposits suggest that the deposits formed from metal-rich pore waters that were released catastrophicallyfrom an acquifer in the footwall stratigraphy."

Jan 1, 1992

By Jean-Jacques Bouillon, Michel Jébrak, Stephane Faure

"Le gisement polymétallique (Cu-Zn-Au-Ag) des Mines Selbaie est forme par un réseau de filons encaisses dans une séquence de pyroclastites felsiques du sill on Harricana-Turgeon. Les minéralisations sont encaissées dans le tuf de Selbaie, situe sous une épaisse séquence d'ignimbrites Iitées. Ce gisement se distingue des autres gites archéens par une chronologie atypique des minéralisations: les veines de chalcopyrite, de sphalérite et de galène recoupent un amas exhalatifpyriteux stérile. Un vaste halo d'altération hydrothermale a chlorite et mica blanc est associe à cette minéralisation.La mise en place des veines minéralisées est associée à une phase d'extension NNW-SSE. Le complexe volcanique subit, par la suite, trois phases de déformation. Une compression, orienté N-S, développe une schistosité à peine pénétrative et un réseau de fentes de tension. Une réorientation des contraintes locales selon une direction WNW-ESE conduit au chevauchement de I' écaille d'andésite et de tonalite de Brouillan. Un réseau conjugue de failles normales cassantes est associe au relâchement des contraintes."

Jan 1, 1990

By P. J. Dunlop

THE object of this paper is to present a brief survey of the work done and the results obtained in controlling dust at the Hollinger Consolidated Gold Mines milling plant. The plant includes all primary and secondary crushing, grinding, and treatment operations. The major items of equipment are: (1) Underground Crusher Plant 1 48 in. by 60 in. jaw crusher, crushing run-of-mine ore to minus-6-in. Rate: 420 tons per hour (2) Surface Crusher Plant 3 No. 772 gyratory crushers 3 4 ft. by 16 ft. trommel screens 4 No. S gyratory crushers Reducing ore to rninus-172-in. Rate: 420 tons per hour (3) Roll Plant 5 sets of 62 in. bJ: 24 in. rolls 7 5 ft. by 10 ft. v1bratrng screens Delivering a minus-3/16-in. finished product Rate: 420 tons per hour (4) Grinding Plant 4 7 ft. by 15 ft. low discharge grate ball-mills 4 12 ft. reciprocating rake classifiers Rate: 4,800 tons per 24 hours Maximum capacity: S,800 tons per 24 hours

Jan 1, 1939

By Alan Rice

Abstract-The mechanism by which stratiform ore deposits of PGE (platinum-group elements) are laid down in ultramafic igneous complexes is not completely clear. Early studies by the author and coworkers on numerical analyses of the convective cooling of low-Rayleigh-number magma chambers examined the effect of suspended crystal load on fluid density, and raised the possibility that the growth of the suspended crystal load during cooling could split a magma chamber into several convecting layers. The lower layers would have a higher content of refractory phases than the upper layers, which would consist of more evolved melt. This paper considers numerical modelling, as well as theoretical and experimental work in other fields dealing with suspended loads in fluids. The calculations, which are based on the physics of convecting magmas, yield quantitative relationships consistent with the observation that economically interesting stratiform PGE deposits are restricted to large magma bodies, and also yield estimation of the depth in a magma chamber at which certain grades of mineralization may occur.

Jan 1, 1997

By Alan Rice

The mechanism by which stratiform ore deposits of PGE (platinum-group elements) are laid down in ultrama?c igneous complexes is not completely clear. Early studies by the author and coworkers on numerical analyses of the convective cooling of low-Rayleigh-number magma chambers examined the effect of suspended crystal load on ?uid density, and raised the possibility that the growth of the suspended crystal load during cooling could split a magma chamber into several convecting layers. The lower layers would have a higher content of refractory phases than the upper layers, which would consist of more evolved melt. This paper considers numerical modelling, as well as theoretical and experimental work in other ?elds dealing with suspended loads in ?uids. The calculations, which are based on the physics of convecting magmas, yield quantitative relationships consistent with the observation that economically interesting stratiform PGE deposits are restricted to large magma bodies, and also yield estimation of the depth in a magma chamber at which certain grades of mineralization may occur.

Jan 1, 1997

By K. Adham, C. Lee

The demand for nickel is continuing to exceed inventories, and producers are working vigorously to increase capacity. Many nickel processes utilize the fluidized bed technology for its fast heat and mass transfer, excellent temperature control and low maintenance. The following four nickel applications of the fluidized bed technology have been commercialized: I) Sulfide ore roasting; II) Nickel sulfide (matte) roasting; III) Nickel oxide reduction; IV) Nickel chloride pyrohydrolysis. This paper examines the issues surrounding the application of fluidization technology to the above processes, from the stand point of the engineer modeling the process and designing the key equipment, based on the historical success stories and the fundamental principles of flow sheet synthesis. Using the available data in open literature, typical flow diagrams (with convenient bases of 1 t/h feed or product) are developed to illustrate the relative flow rates and to highlight the key features of each application. In addition, some historical background information is provided for each process with supplemental notes with regards to our company&apos;s involvements.

Jan 1, 2005

By W. J. Bennett

"I AM very happy to have this opportunity of speaking to the Montreal Branch of the Canadian Institute of Mining and Metallurgy.I have selected as the subject of my remarks transportation in that area which is at present our only source of uranium -Northwest Canada. Considering the widespread interest in atomic energy, the end-product of uranium, it may be wondered why I have not chosen to speak of a more spectacular aspect of the development. I hope it will be evident from what I have to say that transportation plays a very dominant role in our effort to maintain a continuing supply from Eldorado's producing property at Port Radium on Great Bear lake and from its coming producer at Beaver lodge Lake in Northwest Saskatchewan. Moreover, transportation has such a bearing on the entire mineral development of the Northwest that it cannot help but be of concern to an organization of this kind. Finally, the transportation problem, of which I shall try to tell you something, is quite unique and the story of its solution or partial solution is, I believe, an interesting one.Transportation experience on this continent indicates that the cheapest method of moving freight is still by water -with •rail, highway, and air transportation following, and in that order •of economic significance. Excluding rail transportation, since the area has as yet no railway lines, this order also applies in the Northwest. I shall direct my remarks to the two kinds of transportation which serve our uranium producers -water and air."

Jan 1, 1952

By E. Busse

"Heath Steele Mines Ltd. operates a lead-zinc-copper mining and milling complex in New Brunswick.• During the past seven years, as ore reserves increased, the mill capacity was first expanded to 1,600 tpd and then to 3,000 tpd. In the last expansion, instead of building a completely new 3,000-tpd mill, or adding to existing installations, Heath Steele retained service facilities, buildings, ore bins, Jab, etc., and removed and replaced almost all existing process facilities. Requiring a complete mill shutdown, the expansion had to be carried out in minimum time. Also, new equipment had to fit into existing space. Critical path networks of the project were prepared, a tight schedule for construction was mapped out and progress charted daily to detect problems before they could interrupt the schedule. Heath Steele supervised the purchasing, handling and storage of new equipment, maintained liaison with the engineering contractor and became a sub-contractor, using its own staff to install all flotation equipment and process piping. The 1,600-tpd installation was dismantled and a 3,000- tpd unit was successfully put onstream in 5 months - on time and within budget. One benefit stemming from the expansion: production increased 87 per cent while operating and maintenance labour rose only 8 per cent."

Jan 1, 1972

By N. M. Steven, J. M. Moore, J. L. Kuyper

Abstract - Mineral exploration and research has led to the identification of four types of tungsten mineralization in the NE-trending, largely ensialic, inland branch of the late Proterozoic/early Paleozoic Pan-African Damara Orogen. The mineralization (mainly scheelite) occurs in a terrane (the Central Zone) that is characterized by multiple deformation, greenschist/amphibolite-facies metamorphism and numerous peraluminous S-type granitic and pegmatitic intrusions. The four major types of scheelite mineralization are (in ascending stratigraphie order of host rock): (1) thin (5 cm to 2 meter) quartz+ plagioclase+ diopside ± scapolite cale-silicate granofels with finely disseminated scheelite (scheelite-bearing granofels; SBG) developed as discontinuous intercalations within the cale-silicate rocks of the Khan, Spes Bona, Oberwasser and Kuiseb Formations (Nosib and Swakop Groups); garnet+ pyroxene ± vesuvianite + scheelite ± fluorite replacement skarns hosted by Okawayo, Karibib and lower Kuiseb Formation marbles in the aureoles of late tectonic, unmineralized leucogranites; metaturbidite-hosted scheelite- (and possibly wolfrarnite-) bearing tourmalinites, both stratiform and crosscutting, in the Kuiseb Formation located in the &apos;cleavage fronts&apos; of late tectonic granitoids; scheelite-bearing vesuvianite +quartz+ garnet skarnoid rocks (several hundred meters in length) in the calcareous metaturbidites of the upper Kuiseb Formation. These scheelite occurrences were discovered by the follow-up of a large number of tungsten anomalies located during a regional stream sediment sampling program. Detailed mapping, ultra-violet surveys and rock sampling proved to be the most effective surface exploration techniques for locating mineralization; soil sampling and geophysics were of almost no use. The largest, continuous scheelite-bearing skarn of economic interest, Otjua, has a drill-indicated reserve of 250 000 tonnes at 0.53 wt% W03 and 8 wt% CaF2.

Jan 1, 1994

By D. Y. Li, C. D. Ma, T. Zhou, T. J. Cheng

In this paper, a number of experimental tests are carried out to study the strength difference on rectangular prismatic marble specimens with different height-to-width (H/W) rations. The specimens have a nominal size of 45×15 mm in the compressive cross-section (W×T) and different heights (H = 22.5 mm, 45 mm, 60 mm and 90 mm). It is to say that the height-to-width ratios are equal to 0.5, 1.0, 1.33 and 2.0, respectively. The quasi-static uniaxial compressive tests are finished by a servo-controlled INSTRON machine (the strain rate at about 10-5/s), and the dynamic compressive tests are finished by a diameter of 50 mm cylindrical SHPB apparatus (the strain rate reaching about 101/s). The rock failure process of marble specimens is captured by a high speed camera in order to distinguish the fracture propagation behaviour. It is found that the compressive strengths increase when the H/W ratio of marble specimen changes from 2.0 to 1.0 due to the end clamping effect both for quasi-static and dynamic loads. However, when the H/W ratio changes from 1.0 to 0.5, the apparent compressive strengths decrease both for the two loading conditions. The strength decrease of short marble specimens may be attributed to the change of failure mode from shear to slabbing, which can be identified by the fracture patterns of the specimens. Based on the uniaxial compressive tests, the slabbing strength of the marble was found to be about 40% of its UCS for the specimens with a nominal height-to-width ratio of 2.0. In addition, it is found that the dynamic increase factors (DIF) are affected by the specimen’s aspect ratios. It implies that the same aspect ratios should be used to compare the dynamic and static compressive strength of rocks. Meanwhile, both the static and dynamic tensile strengths of the marble are obtained by the Brazilian disc tests. The ratio of the dynamic tensile strength to the static tensile strength of the marble is about 2.68.

Jan 1, 2015

By R. S. Forgan

The synthesis and study of a systematic series of phenolic oximes have shown that substitution in the 3-position can greatly affect extractive efficacy. Solid state, solution and gas phase analytical techniques, including X-ray crystallography, EPR and IR spectroscopy and collision induced dissociation mass spectrometry have been assessed for their applicability in interpreting the origins of differences in extractant strength. The dominant substituent effect on pH0.5 is the change in ligand pKa, with the more acidic ligands being stronger extractants. The influence of the 3-substituent on the stabilising intracomplex H-bonding of their copper(II) complexes also affects extractant strength. The 3-NO2 substituted ligand shows the lowest pH0.5 value, due to a combination of its low pKa and a stabilising bifurcated H-bond assembly around the copper(II) centre. Appending an aminomethyl group to the 3-position gives a ligand capable of binding a metal and its attendant anion. These metal salt reagents show potential to open up new flowsheets for the processing of high tenor copper feeds.

Jan 1, 2007

By H. Bouzahzah

Sulfidic tailings, subjected to atmospheric water and oxygen action, can generate acid mine drainage (AMD); which is the most important environmental problem facing the mining industry. AMD generating potential can be assessed by the static tests which consist of a screening method where the neutralization potential (NP) and the acid-generating potential (AP) of a given rock sample are determined. The AP and NP are determined separately in the different static test existing procedures which can be divided into two distinct classes: chemical and the mineralogical methods. For some chemical method, the AP is calculated on the basis of total sulfide sulfur content in the sample which may overestimate its AP if significant quantities of non-sulfide sulfur species are present (e.g. organic S in coals, some sulfate as gypsum, barite, etc.). However, the mineralogical method evaluates the AP by the sum of the individual sulfides participation on acid generation based on their concentration within the sample and can be more accurate than the chemical method. For AP calculation, the Paktunc (1999a) mineralogical static test takes into consideration all sulfide minerals occurring in the sample. However, it does not take into account the rates of acidity production of these sulfides submitted to weathering conditions. So, the present study focusses on the modification of Paktunc AP calculation by considering the acidity production rates of these minerals. To reach this objective, five base-metal sulfides (pyrite as reference, chalcopyrite, sphalerite, arsenopyrite, galena), diluted within quartz (25?75 wt.%) simulating mill tailings were subjected to a kinetic test to evaluate their AP. The results show that all the studied sulfides minerals generate acidity at different rates, so the Paktunc?s equation for AP calculation has been adapted accordingly.

Aug 1, 2013