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By Colin Hardie, Simon Pelletier, Rakan Rhabani, Guy Comeau

"In order to improve the nickel concentrate thickener operation at Raglan Mine, two pulp deaeration cyclones were installed. These units obtained from Outotec Pty Ltd, also called the FrothBuster®, have been in continuous operation since mid-October 2006. The primary objective of the de-aeration cyclones is to lower the solids content in the thickener overflow by de-aerating the concentrate pulp before it enters the concentrate thickener. This dearated slurry should help decrease the nickel particle losses that report to the thickener overflow because of the flotation effect within the thickener.Optimizing the de-aeration cyclones has been a slow and ongoing process, however, initial testing is encouraging. The latest test results indicate a 50 % reduction (0.070 to 0.035 % solids) in nickel losses to the concentrate thickener overflow resulting in an additional $350,000 in annual revenues.This paper will present an overview of installing the de-aeration cyclones within a limited space, as well as the preliminary commissioning and testing challenges. This paper will also discuss the most recent concentrate thickener operating results since the de-aeration units were installed.INTRODUCTIONThe Xstrata Nickel Raglan Concentrator, located at the northern limit of Quebec’s Nunavik Region has been in production since 1997. In early 2002, the concentrator implemented the Zero Process Water Discharge (ZPWD) project to recycle the process water to decrease fresh water consumption and reduce discharges to the environment. Due to this initiative, the chemistry of the process water changed significantly resulting in flotation concentrate streams, which were very frothy and difficult to manage. This phenomenon has resulted in operational challenges in many areas of the concentrator including slurry pumping, flow measurement and concentrate thickening.In October 2005, the Raglan Mine underwent a conversion from an AG mill to a SAG mill operation in order to increase throughput and to optimize key process areas. As part of this project, the first two North American pulp de-aeration (FrothBuster®) units from Outotec were installed to improve the operation of the concentrate thickener. The primary objective of the deaeration technology was to lower the solids content in the thickener overflow by de-aerating the concentrate thickener feed pulp. This in turn was to reduce the froth, which accumulates on the thickener surface, and more importantly reduce valuable nickel losses to the thickener overflow because of the flotation effect within the thickener."

Jan 1, 2008

By L. Parthasarathy, S. K. Pan, M. P. Srivastava

"Total iron ore reserves in India, as reported by the Indian Bureau of mines, are 23.6 billion tons. Hematite iron ore reserves constitute about 45 % of the total reserve. If we go by the National Steel Policy-2005 projections, India’s supply of hematite iron ore would not last more than 40 years. Laboratory investigations were carried out for the development of a process flow sheet for treating low grade as well as Banded Hematite Quartzite (BHQ) iron ore. The purpose of these investigations was to aim for better resource utilization.Beneficiation studies were conducted on samples of low grade and siliceous iron ore from the Dalli mines, a captive mine of the Bhilai Steel Plant and BHQ ore from Southern states of India. The process flowsheet, developed for upgrading of low grade iron ore, incorporates wet screening of the ore at 0.5 mm, followed by grinding of the +0.5 mm fraction to below 0.5 mm. The whole –0.5 mm fraction, after grinding, was treated in a conventional hydro-cyclone and stub cyclone followed by treatment in Wet High Intensity Magnetic Separator (WHIMS). This resulted in a concentrate product having >66% Fe content from a feed containing 55.5% Fe with an iron recovery of 48 %. The process flowsheet developed for treating BHQ ore in the laboratory resulted in an increase in iron grade in the concentrate from 43.4 to 61.3 Fe % with a yield of 51.7 % .INTRODUCTIONThe classification of Indian iron ore resources have been made compatible with United Nations Framework Classification (UNFC), which is more scientific and has been adopted in most countries in the world. Iron ore reserves and resources estimated using the UNFC classification system, as of April 01,2000 are about 12,906 million tons of hematite ore and 10,628 million tons of magnetite ore. The Indian Bureau of Mines (IBM) has given a breakdown of these reserves by designation as either lumps or fines of hematite iron ore (Table 1). The percentage of the reserves reported lumps and fines are 42 and 34% of the total reserves respectively. High grade iron ore is less than 10% of the total reserve."

Jan 1, 2008

By N. I. Basuki, E. T. C. Spooner

"Abstract - More than 2800 published fluid inclusion data (primary inclusions) from eighteen typical Mississippi Valley-type (MVT) Zn-Pb deposits and districts were examined to study possible relationships between MVT fluid properties and metal tonnages and ore grades. The mean Th and salinity values for fifteen MVT deposits and districts are 122°C ± 21°C and 20.7 ± 2.6 wt% CaCl2 equivalent, respectively. In general, temperatures increase from pre-ore to ore stages, and salinities decrease from ore to post-ore stages. From post-ore to late calcite stages, salinity and temperature decrease with various trends within specific districts.Several conclusions are drawn: first, results show that Hanor’s (1996) salinity threshold for metalrich basinal fluids applies to typical MVT ore fluids (~16 wt% CaCl2 equivalent). Second, the lower limit of mean Th values of measured MVT deposits and districts (n = 15) of ~75°C is similar to Hanor’s (1996) observed temperature threshold for metal-rich basinal brines of ~60°C (n = 224). Third, there is no statistically significant relationship between fluid inclusion homogenization temperatures (Th) and metal tonnages or ore grades. Fourth, there seems to be a tendency for large tonnage districts/deposits to be associated with mean fluid salinities that are relatively low (~16 to 21 wt% CaCl2 equivalent) within the overall range of salinity means (~16 to 26 wt% CaCl2 equivalent). There is also a correlation between higher ore grades and higher salinities. Finally, comparison with other sedimentary rock-hosted Zn-Pb deposit types shows a trend of salinity decrease and temperature increase from MVT, sandstone-hosted and diapir-related Pb-Zn deposits, to vein-type and Irishtype Pb-Zn deposits, and then to sedex deposits. However, more data are needed for sedex deposits. The salinity threshold for significant Zn-Pb transport decreases to =~10 wt% CaCl2 equivalent at ~250°C. This study suggests that fluid inclusion analysis during exploration may be useful in assessing ore-forming potential (threshold salinity) and possible ore grades (salinity)."

Jan 1, 2002

By H. E. Pawson

"COMMON METHODS OF ELIMINATION: The four methods most frequently used to dispose of cyanide wastes are:1. Oxidation2. Dilution with water or with cyanide free wastes3. Acidification and dilution of resulting gas with air4. Alkaline ChlorinationMost operators practice a combination of the first two methods, allowing oxidation and dilution of cyanide waste in tailings ponds. Then, pond effluent is introduced to a stream for further dilution andoxidation which is expected to take care of the cyanide. This method oftreatment does work to a certain degree. Atmospheric oxidation in tailings ponds and in receiving streams chemically breaks down the cyanide radical to form carbon dioxide and nitrogen.2(CN) + 202 2 CO2 + N2The monetary advantage to this method is obvious to the operator but too frequently though, climatic conditions are ignored. Length of winter, and reduced flow of the receiving stream in summer, adversely restricts the result of this combined method. For those of us who rely mainly on dilution it would be wise to remember that 70 million pounds of water are required to dispose of one pound of sodium cyanide (1).The third method outlined involves addition of acid in a closed vessel and venting resulting gas to atmosphere with or without air dilution by mechanical means. Cost, safety and some form of secondary treatment to complete destruction of cyanide remaining in the solution usually make this method prohibitive.The alkaline chlorination method is the one most commonly accepted for treating cyanide bearing wastes since it is felt that cyanide is completely eliminated in this manner."

Jan 1, 1973

By L. D. Smith

"This paper examines the impact of the various assumptions that go into an economic evaluation, and shows how these can be combined to show an exciting result that may not really exist. An example of an embellished case (the kind that one frequently sees when projects are being promoted) is developed and the cumulative impact is analyzed to show the actual project underneath. The paper also points out some areas to watch for overly optimistic assumptions such as prices, inflation, and debt. The concept of a “bare bones” base case is proposed (constant metal prices, constant dollars, no inflation, no debt, no interest, on a project basis, after tax) as a common reference point.As well, the discount rate is examined as one of the fundamental means of reflecting risk in discounted cash flow evaluations. Current industry practice is discussed, and a methodology for the analysis of risk levels is proposed that assesses the constituent components of the discount rate: real interest, mineral project risks, and country risk."

Jan 1, 2002

By Cecilia Arrue, Dominic Fragomeni, N. O. Lotter

"A statistically designed benchmark mill survey was carried out in July 2005 at the Kidd Creek Concentrator, D Division circuit, which processes Ni/Cu ore from the Montcalm deposit. A structured statistical survey approach was followed, together with defined quality controls, which would assign a 95 percent level of confidence in the result.A set of six surveys were completed over a limited time; the corresponding stream samples of the surveys found acceptable were combined to obtain high confidence composite samples. The head grade of each survey is compared to two distributions to test its acceptability; surveys that fail to conform to these trials are rejected. The accepted set of surveys, which is a robust representation of the process, is prepared into a composite for QEM-SEM analysis and mass balance purposes.Where the above practice is a standard procedure in Falconbridge for QEM*SEM purposes, in this case each individual two-hour survey unit was measured and analysed for a mass and value balance. It is shown that none of the individual mass and value balances close as well as the composite set of accepted two-hour survey units. This founding is in keeping with the averaging properties of the Central Limit Theorem.INTRODUCTIONMontcalm OperationsNi/Cu bearing ore from the Montcalm deposit is being processed at the Falconbridge, Kidd Creek Concentrator in a modified D Division circuit. The circuit was commissioned in the fall of 2004. Ore is crushed at the minesite to –19 mm and trucked to Kidd for delivey into the 4 parallel fine ore bins.Ore is milled in a rod mill followed by cyclones and 2 parallel ball mills. The grinding circuit treats Montcalm ore at an average feed rate of 100 wet tonnes/hour (750,000 tonnes/annum) and produces a flotation feed particle size of 83% -53 um. A simple flowsheet including bulk Cu/Ni roughing and 2 bulk cleaning stages followed by Cu/Ni separation in 2 stages is practiced. Soda ash is used as a pH modifier in bulk flotation. SIBX is the collector. Lime and Dextrin are added into Cu/Ni separation for the depression of pentlandite."

Jan 1, 2007

By P. Bousquet

Acid mine drainage (AMD) is a serious environmental problem that preoccupies the Canadian mining industry. Considerable amounts of money are spent every year in an effort to prevent or reduce the acid mine drainage phenomenon. AMD occurs when sulphide minerals (e.g., pyrite) contained in rock are exposed to air and water and subsequently oxidize to produce low pH water. This acid effluent has the potential to mobilize any heavy metals contained in the rock. Coating the sulphide minerals with silicates is a new promising technology to reduce AMD. Pyrite is treated with a solution containing H2O2, sodium silicate and a buffering agent. H2O2 oxidizes a small part of pyrite producing ferric iron (Fe3+) ions. These ions subsequently react with the silicate ions to produce ferric hydroxide-silica that precipitates on the pyrite surface producing a passive coating. This silicate coating can protect the grains of pyrite from oxidation. This paper presents a series of experiments that confirm that silicate coating can considerably reduce AMD.

Jan 1, 2002

By Camilo I. Morales

At present, many open pit mines are designed to operate and feed a processing plant with ore characteristics that were defined in the design of the mining business, which are not necessarily the same as those found during the operation. This is the case of Spence Mine, whose design was conceived considering the extraction of primary iron sulphides, however, with the extraction of such minerals, it was necessary to mine and process minerals with secondary enrichment. Then it is necessary to work with a greater selectivity degree in the operation, however the capacities of the mine and operational resources were not designed for this. Thus, the changes in the general conditions of the operation should be considered as a series of geometallurgical restrictions to achieve production schedules. The above facts impacts directly in the short-term planning, whose task is to achieve the goals proposed in productive long-term planning because the company does not have the tools necessary to plan with the degree of selectivity required, so it should be done by hand, discretizating and scheduling the production polygons. Naturally, this manual process in the short term planning deviate sharply from the areas in operation, opening new fronts and benches that result in a significant increase in costs and a loss of the value of the mineral resource to miss the exploitation sequence. The research presented in this paper is related to the development of a mathematical programming model to support the short-term planning, so as to integrate the challenge of selective mining with geometallurgy restrictions, to provide the planner a guide to construction of the polygon of exploitation, guiding the fines production to achieve the goals of the proposed production plan.

Oct 1, 2009

By Anand Raman, Steve Dixon

"Industry practice for defining acid consumption is based on column tests. Freeport-McMoRan (FCX) has adopted a practice of leach operation using a defined pH or gpl acid in the raffinate based on the column test program. The acid consumption can be easily calculated using the leach operating parameters of SX-EW efficiency, lift height, bulk density, irrigation rate, primary leach cycle time, acid cure dose and acid concentration in the raffinate. The column leach test results and a column to heap efficiency factor are used to define the copper extraction. The maximum acid consumption will occur when zero acid is contained in the raffinate. The term Net Extracted Value (NEV) is to define the maximum extracted value relative to acid consumed.This paper presents the operating logic and method used to calculate acid consumption based on column tests and operating parameters.INTRODUCTIONIndustry practice for defining acid consumption is based on column tests. This may result in lower economic value if the tests are not designed to account for operating variables. A test program is described to assist in defining lift height and the influence of gangue on solution chemistry. A simple spreadsheet is presented that will use the leach operating parameters of SXEW efficiency, lift height, bulk density, irrigation rate, primary leach cycle time, acid cure dose and acid concentration in the raffinate to calculate the acid consumption for a proposed operation.A review of current leach operations solution chemistry will help to define acid consumption. This is recommended for all current leach operations.DISCUSSIONThe current practice at Freeport-McMoRan (FCX) is the use of column test results to define operating parameters. The monitoring of operational solution chemistry and copper production addresses any changes needed in operational parameters. This practice maximizes the value extracted from each tonne of ore leached."

Jan 1, 2008

By Dara L. Hrytzak-Lieffers

Canada has long since been a place that has led the world in mining development, in a safe, clean, and sustainable manner. This has led to the integration of corporate social responsibility (CSR) philosophy in corporate governance, policy, and programming. The paper will identify the basis of CSR practise in Canada?s mining industry and provide a Canadian example of CSR implementation. Biography Dara Hrytzak-Lieffers is the manager, corporate social responsibility at Cameco Corporation. She oversees corporate CSR initiatives including the Sustainable Development report and public engagement programs. Dara received her BA in International Studies from the University of Saskatchewan and an MA in International Conflict Analysis from the Brussels School of International Studies. She is a recent graduate of the World Nuclear University summer institute.

May 1, 2011

By V. Murugaiyan

The Geotechnical Engineer is faced to view problems emerging from the task of protecting the environment and also the problems related to prevention of natural hazarders. Geo-Environmental Engineering, based on the development of geotechnical engineering, addresses the problems for the industrial world and the impact on health and welfare in relation to pollution of the ground. In the recent years, acute land pollution due to indiscriminate discharge of industrial effluents especially Organic acid based effluents has become one of the major concern due to erosion in the privatization of sustainable development under Indian Scenario. To study the effect of chemical changes on soil properties due to amino acid effluent contamination on soil and erosion behavoiur. The changes in the soil properties of effluent contaminated clay and silty soil were experimentally observed to be due to the interaction of organic and inorganic constituents of effluent on index properties of soil. The surface reactivity of soil mass is experimentally reported to be varying proportionately with respect to clay (%) in the soil. Also higher surface reactivity of clay increases the Solid Retension Time (SRT) with increase in rate of chemical transformation of organic and inorganic solids within soil. Hence soil S1 (high clay content 54.5%) showed increased SRT and soil S3 (low clay content, high silt and clay content 94.9%) showed decreased SRT and long transformation stage.

May 1, 2004

By C. Feng, D. W. M. Arrigan

Arsenic is often associated with gold mining operations and poses a significant health and environmental hazard. While a number of technologies are available for removing arsenic, none of them is effective under all conditions. Although adsorption is a promising approach, most methods focus on the purification of water under neutral or acidic conditions and tend to be less effective in gold mining process waters, operating under alkaline conditions. In this study, the removal of As (III) and As (V) from both arsenic-only solutions and simulated process waters using composite magnetic nanoparticles was investigated. The nanoparticles consisted of magnetite (Fe3O4) or maghemite (?-Fe2O3) cores covered by various metal oxides with Langmuir adsorption capacities of As (III) and As (V) ranging from 31.4 to 79.1 mg/g and 10.2 to 25.5 mg/g, respectively, in arsenic-only solutions at pH 9. Their adsorption capacities were further recognised by the adsorption tests conducted in simulated process waters. The ability to remove As (III) is of particular importance as it is harder to remove it from alkaline solutions. The magnetic cores allow simple and efficient magnetic recovery of the As-loaded nanoparticles.

Jan 1, 2017

By H. Wyslouzil

"The Kelsey Centrifugal Jig is a gravity separation device which utilizes the principles of the conventional mineral jigs but with the additional feature of being able to vary the apparent gravitational field. This is accomplished by utilizing the specific induced movements of the conventional jig within a centrifuge.Pilot plant trials have been underway since July 1988 to evaluate the potential applicability of this technology to various process streams at Rio Kemptville Tin.The grade/recovery relationships for samples treated in the jig were consistently better than results obtained from tables. Recoveries of more than 90% were attained at concentrating factors ranging up to 20. When compared with electrostatic separators, the jig achieved equivalent metallurgical results in a two stage process, without the expensive requirement of filtration and drying. Recoveries exceeding 96% were achieved with final concentrate grades averaging higher than 60% tin.INTRODUCTIONMineral jigs have been used for hundreds of years. Many different types have been developed, and each one has numerous variations. In recent years, the idea of applying centrifugal forces to conventional jigs has been put to practical tests and today a number of units are in commercial production. In principle, by enhancing the apparent gravitational field, it should be possible to recover finer particles by overcoming viscosity and surface effects which tend to limit existing gravity devices. In addition, it may be possible to use gravity to separate minerals with much smaller specific gravity differences."

Jan 1, 1990

By Brad E. Melanson

Because mine haul trucks consume considerable quantities of fuel, they are ideal candidates for the adoption of cleaner and cheaper fuels like natural gas. Impressive fuel cost savings will be realized in regions where liquefied natural gas (LNG) has cost advantage to diesel fuel, while also providing significant reductions of air contaminants and greenhouse gases. High Pressure Direct Injection (HPDI) of natural gas utilizes the diesel cycle combustion process and therefore retains the diesel engine?s high performance and efficiency characteristics. HPDI has been demonstrated in on-road Class 8 trucks since 2001 accumulating almost 10 million kilometres to date. The supply of LNG fuel will be an essential parallel aspect in the introduction of HPDI to mining. LNG can be transported to site as diesel is today, or may be produced on or near mine operations that have access to methane sources or pipelines.

May 1, 2006

By T. T. Chen, J. E. Dutrizac, G. Poirier

In the Waelz kiln process, EAF dust is converted to an Fe-rich slag, a (Zn, Fe)-rich dust that is recycled to the kiln and the Zn-rich Waelz oxide which is subsequently up-graded for the recovery of zinc. To clarify the reactions occurring, the Waelz kiln products from a European Waelz plant were characterized mineralogically to determine the mineral species present, their micro-textures and the metal carriers. The EAF dust contains 27 % Zn, and consists mainly of ZnFe2O4 and ZnO, together with minor to trace amounts of NaCl, PbCl2, KCl, CaO, Ca2Fe2O5, Fe203, FRO, Pb oxide and various Ca-Fe-Al-Mn silicates. The KCI and NaCI sometimes agglomerate the other particles. The slag consists of nodules which often exhibit colloform structures. The slag contains of variable amounts of Fe, FeO(OH), FeO, gypsum, Ca(OH)2, Ca2SiO4 and various Ca-Fe¬Al-Mg-Mn silicates as well as minor to trace amounts of ZnFe2O4, Cr-Fe oxide, Mn-Fe oxide and other species. The Waelz oxide contains 57-61 % Zn, and consists predominantly of ZnO, with minor to trace amounts of KCI NaCl, Pb(OH)Cl, Pb20(SO4), Pb chloride, ZnSO4, ZnFe2O4, Ca2SiO4, Ca2Fe2O5, Ca-Fe silicate and NaZn4(SO4)(OH)6Cl.6H2O. The KCI agglomerates the other particles in the Waelz oxide. The recycled dust appears to be a mixture of EAF dust and Waelz oxide, but it contains relatively more coarser-grained metallic Pb and Pb oxide particles.

Jan 1, 2004

By Jie Zhou

Mining mobile equipment is becoming larger in order to lower operation cost and increase productivity; however, their performance characteristics are often limited by the tire capabilities. Although considerable progress has been made in the field of tire research, the lack of comprehensive knowledge on tire performance characteristics impedes the advancement of off-the-road tires. Longer haul roads, and a severe operating environment make tires more vulnerable than other components of a vehicle. Furthermore, due to a limited availability of large tires, mines are facing shortages. Thus mines and tire service companies are keen to improve tire performance, extend tire life and hence lower operating costs. This paper reviews the relevant tire performance research, analyzes tire interactions with the surrounding environment, tire maintenance practices and operational issues using a case study based on data collected during an ongoing project with Fountain Tire.

May 1, 2006

By M. L. Smith

"In the Phosporia formation of SE Idaho, ore quality varies by depth, seam and distance along strike; phosphorus recovery is sensitive to these variations. Plant ore feed can be blended over time to minimize this fluctuation by using a combination of mine production and inventory stockpile scheduling. Mixed-integer and goal programming has been used to optimize short-term mine production, but the seasonal nature of mine haulage requires the use of stockpiles both at the mill and the mine. The contents of the stockpiles can also be optimized as part of the production scheduling problem, but introducing inventory control introduces a nonlinear term into the formulation. A solution using a piecewise linear formulation is modelled and solved using AMPL/Cplex, and solution strategies are discussed for similar large-scale problems. IntroductionIdaho’s minable deposits of phosphate rock are found in the Meade Peak member of the Phosphoria Formation; two separate zones of this formation are mined with a combined thickness of 30 ft to 60 ft. A generalized stratigraphic section of the Phosphoria section is shown in Figure 1, illustrating the degree of complexity encountered when scheduling mine production. Alteration of the formation results in higher grade ore zones near the surface and variable in P2O5 levels between seams and along strike. This variability is seen as well in other quality characteristics critical to the production of acid and elemental phosphorus. Further, plant recovery and nodule quality are sensitive to variations in ore feed; variability in SiO2, carbonates, moisture, organics (carbon), P2O5 and other constituents of the ore can strongly affect plant recovery. Because ore quality characteristics can vary as a function of the alteration zone (or seam) being mined as well as the depth and distance along the strike of the formation, scheduling of mine production can have a highly significant effect on recovery in the plant. As illustrated in Figure 1, there are nine seams containing 20% to 35% P2O5. Phosphoric acid and elemental phosphorus production requires an ore content of 30% and 25% P2O5, respectively. Variability between numerous beds that are mined and quality variation within a seam due to alteration greatly complicates production scheduling with the result that erratic mill feed characteristics greatly decrease recovery."

Jan 1, 1999

By R. M. Oliver

THE Falconbridge property is almost completely covered with over-burden to a depth varying from 60 to over 200 feet. This overburden consists of grave], sand, and boulder, with bands of very fine silt, and there is usually a layer of water-bearing quicksand adjoining the r:ock surface. In previous shafts sunk at Falconbridge, this water-bearing quicksand had given considerable trouble, and further difficulties were expected in sinking No. 5 shaft, due to its greater size. The method described in this paper is the one adopted in sinking this shaft, after the matter had been carefully considered. No. 5 shaft is located 2,400 feet east of the old main No. l shaft, and is sunk in norite in the hanging-wall of the ore-body, which is, however, ? practically vertical to the deepest known intersection. The greatest depths of overburden prevail on the south side, or footwall, of the ore-body, and this, together.. with the fact that the footwall is wet and more badly fractured, swayed the final decision to sink in the hanging-wall. After the shaft site had been chosen and cleared, a diamond drill was set up a few feet away and a hole bored to a depth of 405 feet to test the over-burden and character of the norite bedrock. The depth of overbudren indicated by the hole was Ill feet, with the last 10 feet water-bearing. The norite was rusted and broken up for only a few feet below bedrock. A steel sinking shield (Figure l) was assembled at the shaft location, and consisted of 5/8-inch plate, 5 feet deep, built around a frame of 6 inch by 6 inch angle-iron, and braced at the corners with the same material. Twelve-inch I-beams held the shield as rigid as possible. In order to reduce binding against pebbles to a minimum, the shield was constructed with a 1-inch batter on all sides.

Jan 1, 1938

By M. S. Moats, F. Elnathan

"The effect of current reversal on two commercially manufactured electrodes (RuO2-TiO2 and IrO2-Ta2O5 coated Ti) in a chloride bearing electrolyte was evaluated. Accelerated lifetimes were found to decrease with increasing current density and increasing reversal frequency. Ru: Ti coated electrodes exhibited longer lifetimes than Ir: Ta coated electrodes even though they had one-third as much precious metal content. Chloride concentration did not affect lifetime in the range examined. Using energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS), the failure mode of the electrodes was determined to be coating dissolution leading ultimately to passivation by the presumed growth of a highly resistive oxide at the coating/substrate interface.INTRODUCTIONCatalytic titanium anodes (CTAs) were developed in the 1960’s to replace graphite anodes in chlor-alkali cells. CTAs exhibited much better dimensional stability than graphite leading to lower operating potentials by promoting smaller electrode gaps and better operational efficiencies as they had to be replaced less often. CTAs are simply Ti substrates coated with precious metal oxides (such as IrO2 and RuO2) mixed with other components (such as TiO2 and TasO5) (Trasatti, 2000).CTAs are used in many other electrochemical industries, including water disinfection, wastewater treatment, cathodic protection and metal plating. RuO2 based coatings are typically used for chlorine evolution. IrO2 based coatings are for the most part utilized for oxygen evolution (Comninellis & Nerini, 1991; Forti, Olive, & De Andrade, 2001; Kotz, Stucki & Carcer, 1991; Trasatti & Lodi, 1981)"

Jan 1, 2016

By Euler De Souza

Backfilling in Canadian mines has been practised for close to 100 years and evidence anticipates the application of mine fill technology at an increasing rate during the foreseeable future. The evolution of backfill technology is closely related to the advancement of modern mining methods and the development of new backfill technology continues to evolve. The authors, after conducting extensive surveys of backfill practices in underground mines across Canada, have concluded that, because backfill operations employ large quantities of cement and experience large costs associated both with backfilling practice and cement use, opportunities exist for reducing backfill energy costs and enhancing the application of alternative cementing agents in backfill. Consequently, the authors have developed an alternate, equally effective and lower cost binder agent replacement for cement, and incorporated waste glass into the development of a lower cost backfill (glassfill). This paper presents the results of two design stages associated with the development of glassfill: strength development and flow performance. The advancement of this technology has reached a stage that should promote industrial implementation within the Canadian mining industry. A number of Canadian mining operations exhibit potential for plant optimization through possible binder source replacement, and might thus realize associated reductions in backfill and energy costs.

Apr 1, 2005