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By D Cotnoir, Q Liu, D Richard, M Ourriban

The difficulty in fine particle flotation has been attributed, among other things, to a low bubble-particle collision efficiency. Many technologies have been developed which aim at increasing bubble-particle collision efficiency, either by generating micro bubbles or by enlarging particle sizes. However, commercial applications of these technologies are limited. Over the last five years COREM has been actively testing fine particle froth flotation technologies with the objective of commercialisation. Several fine particle flotation technologies, such as dissolved air flotation, electro-flotation, floc flotation, selective flocculation-flotation and carrier flotation, were tested on both single minerals and ore samples in order to identify the reasons that prevented these technologies from being used on a commercial scale. It was found that the two most noticeable factors that prevented the successful application of these technologies were: Mechanical entrainment of fine gangue minerals. This was a general problem in fine particle flotation, but was aggravated by these technologies that either generated micro bubbles or enlarged the sizes of hydrophobic particles. Oxidation of (sulfide) minerals that resulted in hydrophilic oxidation product coatings. The oxidised fine particles could not be recovered by these fine particle flotation technologies effectively. Solutions to the two problems, ie gangue entrainment and fine particle oxidation, were proposed and tested. It seems that polymeric depressants with both depression and flocculation functions could significantly reduce gangue entrainment, and hydrophilic surfaces of oxidised fine particles could be modified by high intensity conditioning or controlled sulfidisation, thus increasing the recoveries of fine valuable minerals. The improved fine valuable particle flotation and reduced fine gangue entrainment along with fine particle flotation technologies resulted in much improved flotation separation of fine particles.

Jan 1, 2005

By B C Tanda, E A. Oraby, J J. Eksteen

"Base metal and precious metal deposits are well known for their significant geometallurgical variation throughout the volume of the proven resource. At the metallurgical level, the plant normally processes an upper oxidised layer, a transition zone and a sulfide zone, often leading to different processing techniques for the different zones. A novel processing approach is presented whereby alkaline leaching with glycine is used to leach base and precious metals, using a copper-gold ore deposit as a case study. Glycine is a cheap, non-toxic, non-volatile, highly water-soluble crystalline solid produced industrially in bulk quantities. As a chelating ligand it forms a number of stable glycinate complexes with Ni, Co, Cu, platinum group metals (PGMs), Au, Ag, Zn, Pb, Hg and Cd, with broad stability regions over an extended temperature-pH-Eh range, allowing dissolution of these metals in the neutral and alkaline regions (pH 7–13). It has been shown that this lixiviant system can leach the metals from their oxide, oxy-halide, basic sulfate, carbonate, native and various sulfide forms, including refractory sulfides such as chalcopyrite. Extraction of the metals from their soluble glycinates is easily achieved using a range of solvent extraction and precipitation processes, and the glycine remains stable in aqueous solution for recycle and reuse. Minerals bearing metals in Groups 1 to 8 of the periodic table are normally unaltered. This technology therefore provides a highly selective leaching environment for the extraction of numerous scarce metals of economic interest, with minimal interaction with gangue minerals, whilst using environmentally benign reagents. Problematic leach residues such as jarosites, elemental sulfur and silica gels are averted through this processing approach. This technology allows hydrometallurgical processing that is much less domain-sensitive in the geometallurgical sense, and utilises essentially the same key reagents for the whole deposit.CITATION:Eksteen, J J, Oraby, E A and Tanda, B C, 2016. Developing Robust Hydrometallurgical Processes to Recover Metals from Deposits with Large Geometallurgical Variation, in Proceedings The Third AusIMM International Geometallurgy Conference (GeoMet) 2016, pp 15–20 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 15, 2016

By R Castroviejo, F Segundo, C Brea, J-C Catalina, H-J Bernhardt

Optical microscopy is a basic but still indispensable tool for examining mineral parageneses in ores. The design and concepts behind the reflected light ore microscope have obviously not been subject to spectacular technical evolutions in the last decades. However, digital imaging capabilities have opened new and stimulating perspectives for automated mineral identification. Recent works in developing multispectral image analysis (Pirard, 2004) have demonstrated its superior potential with respect to conventional colour imaging, but at the same time reconciliation with spectroscopic databases such as the Quantitative Data File III (Criddle and Stanley, 1993) still needs a more in-depth investigation as well as the possibility to extend both imaging and spectroscopy into the near infrared domain. In this paper, the authors present results gained from multispectral imaging in the range between 400 and 1000 nm together with spectrophotometric data from the QDFIII database, with an emphasis on minerals that cannot be easily distinguished in the visible spectrum.

Jan 1, 2008

Better quality at lower cost is today's formula for remaining competitive in a world market. For an integrated steel company, high quality low cost steel production must originate before the blast furnace. In 1979, when U.S. Steel initiated a Quality Management Program throughout its steelmaking operations, efforts began at the coal, ore and flux mines. The objective was to improve the quality and reduce the variability of the critical parameters for steelmaking raw materials, to get the blast furnaces, and subsequently the melt shops, under optimum control. The general details of U.S. Steel's Quality Management Program are discussed and how it was used to promote the desired improvements in steelmaking raw materials. Some of the outstanding results obtained by the cooperative efforts between the mines and the steel plants are reported. The lessons learned by U.S. Steel were through upgrading existing operations and facilities. These principles should now be applied to new projects and the benefits of good quality management should commence from the time new projects are Commissioned.

Jan 1, 1986

By Purvis A. H, Greenwood-Smith R, Sowerby B. D

A nuclear technique for the determination of copper and nickel in bulk samples and drill core has been developed at Lucas Heights andfield-tested at Mount Isa. The technique, which is highly specific to the element being measured, utilises the gamma-ray resonance scallering process.A bulk mineral analyser was installed in mid-1976 for the routine assay of copper in bulk samples and drill cores, and remained in operation until late 1981. The operation of the analyser over this five-year period is reviewed with particular emphasis on reliability, accuracy and principal usage.The main application of this analyser was in stope planning and design whereby several thousand drill-core and Wall-chip samples were analysed. It was also used as an aid to underground grade control of stopes where ore dilution by supporting barren backfill was a problem.

Jan 1, 1984

An on-stream iron ore analyser has been developed in collaboration with Hamersley Iron Pty. Limited for determining the iron content of both lump (- 30 + 6 mm particle size) and fines (- 6 mm particle size) on conveyor belts. The analyser, which is called IRONSCAN, is based on pair production, and is now commercially available from Mineral Con- trol Instrumentation Limited (MCI) in Adelaide. It can be mounted under existing conveyor belts with minimal modifications to the conveyor struc- ture, and the presence of steel cables in the belt does not interfere once the analyser has been correctly calibrated. The analyser has been exten- sively tested on both lump and fines on the shiploading conveyor at Damp- ier, and typically the root mean square (r.m.s.) deviation between single IRONSCAN measurements and conventional chemical analyses is better than 0.5% Fe. It is currently being evaluated on - 150 mm ore from the primary crusher at Mount Tom Price, and initial results are encourag- ing. The principal advantage of IRONSCAN is that it provides rapid infor- mation on ore grades. But perhaps its greatest potential is at the primary crusher where conventional sampling and analysis is very expensive to Implement. at the University of Melbourne, and those of us who were his students had learnt of the application of physical chemistry to pyrometallurgical processing, pioneered by Chipman in the USA, Wagner in Germany, and Richardson in the UK. It was possible, by applying this theoretical insight to the equilibria between metal, speiss or Legierung, matte and slag phases, to find a practical and effective way to recover metal values in some residues which had been accumulating for many years at the NA, but which had defied all attempts to treat them to that date. There was also an opportunity to study the batch lead refining methods still in use at all lead refineries apart from Port Pirie, and to devise optimis- ing techniques which greatly improved the operations and effected considerable savings. Next the writer spent some six years alternating between the BHAS, Port Pirie, and Imperial Smelting at Avonmouth in the UK, concerned with lead or lead-zinc smelting, and the develop- ment of several further continuous lead refining processes, before returning to Australia as Section Leader, Process Development in the CSIRO Division of Chemical Engineering, Fisherman's Bend, Victoria. Metallurgical opportunities which arose during this last period included the problem of tin smelting which had developed over about a decade: the world's tin smelters had been accustomed to treating fairly high grade tin concentrates, con- sisting of almost pure cassiterite, with very little impurity-mostly quartz, limestone, iron oxides, and sundry other silicates. Most such concentrates had been produced from alluvial deposits, where nature had already done some of difficult part of the mineral processor's work-at who knows what recovery-so that he could now produce high grade concentrates at high recovery. The smelters were not really set up for the treatment of lower grade concentrates, such as could be made with reasonably high recoveries from rock mining. Thus they imposed such penalties on impurities and lower than desired tin grades, that whenever a mineral processor improved tin recovery at the expense of lower- ing grade, such an improvement entailed a lower financial return to the miner. There was clearly a need for improved understand- ing of tin smelting, (at that time shrouded in secrecy) and develop- ment of techniques better suited to the treatment of lower grade concentrates. As well as the practical development, a start was made with the computer modelling of the smelting process, with the obiect of optimising the process parameters.

Jan 1, 1988

Coal production from Coal & Allied's Hunter Valley No 1 open cut is presently hauled 10 km by road to washing and train loading facilities at Liddell. This road haul, using bottom dump trucks on a bitumen sealed road, presents some unique earthmover tyre problems. Sound tyre management has controlled one potentially serious problem, that of heat damage, implicit with such a long haul. Tread abrasion or wear is therefore the limiting tyre performance factor. Study of abrasion mechanisms and interpretation of abrasion patterns has facilitated an understanding of the wear processes involved. This understand- ing has highlighted the importance of front tyre wheel alignment. The development of irregular wear is shown to be related to the mildness of the abrasion and methods of remving irregular wear are presented. In conclusion haulage by large off highway trucks on long sealed haul roads has been eooncoically and technically successful at Hunter Valley No 1. INTRODUCTION Hunter Valley No 1 (HVl) is a major open cut coal mine, owned and operated by Coal & Allied Operations Ltd, and located in the Hunter Valley of New South Wales. Present

Jan 1, 1982

A research and testing facility has been developed at Simtars to allow the spontaneous combustion testing of coal on a large scale. In this adiabatic reactor, the coal particle sizing is closer to that which could be found in the goaf and therefore the reaction is more likely to simulate the underground situation. This allows aspects of the spontaneous combustion process and methods for detecting a heating to be investigated which cannot be done in an operational mine. Up to 18 tonnes of run of mine or crushed coal is loaded into the reactor and allowed to self-heat while the temperature and gas profiles within the coal pile are monitored. The gases evolved from the coal are analysed using a fixed gas monitor system and gas chromatography to determine which of the common mine fire indicators and ratios can be used to predict the onset and progress of coal heatings. Benchmarking of the inherent propensity of a coal to spontaneously combust at both the large- and laboratory-scale is also possible by comparing the sample against previously tested samples. It has been found that the coal particle size affects both the time it takes for the coal to react and the location of the developing heating. The heatings generate approximately one metre from the inlet but in the crushed coal case do not progress to an advanced heating stage until the æhot spotÆ migrates towards the coal surface where there is an increased oxygen supply. Physical properties such as the compressive strength of the coal also affect the heating size and the time it takes for a heating to develop. Higher strength coals appear to oxidise more slowly and therefore take longer to self-heat as oxidation of the coal is the heat-generating step in the spontaneous combustion process. The best indicators of the state of the heating were found to be CO make and GrahamÆs ratio which are independent of air flow. Investigation of a potential spontaneous combustion should begin as soon as the CO make or GrahamÆs ratio exceed the background levels. The results from the tests undertaken on a number of Queensland and NSW coals are reported here together with the implications for the mining industry.

Jan 1, 2005

Diamonds have been known in Australia for many years, especially in association with alluvial gold and tin occurrences. Exploration for primary sources in the Kimberely area of Western Australia has been carried out since 1968, culminating in the discovery, in 1979, of the Argyle Kimberlite No 1 (AK1) kimberlite pipe. Various techniques have been used in the search for diamonds such as geologic interpretation, aerial photography and Landsat, soil geochenical techniques, geophysics, and stream sediment sampling. Stream sediment sampling, a method developed in South Africa, using the detection of indicator minerals derived from kimberlites in gravel samples, has had wide application and success in Australia. Nevertheless, although Australian diamond bearing kimberlite and lamproite rocks contain some of the classic indicator minerals, their concentrations are generally much lower than in South Africa and Russia. Despite this paucity of indicators, stream sediment sampling is still the best known and most commonly used method of diamond prospecting in Australia. Small samples are treated by hand but larger samples require the use of diamond pans, jigs or heavy media separation plants. Each of these methods has advantages and disadvantages. The final concentrate is passed over a grease table or subjected to x-ray sorting.

Jan 1, 1984

By X S. Li

The modern mechanical excavation machines have enough power for cutting hard rock. The ‘bottle neck’ which limits the use of machines for hard rock excavation is ‘cutting tool’. To cut hard and abrasive rock, CSIRO has been developing Super Material Abrasive Resistant Tools (SMART*CUT). SMART*CUT technology replaces the tungsten carbide (WC) tip of conventional pick with thermally stable diamond composite (TSDC) and attaches the TSDC tip to steel tool body with CSIRO worldwide patented bonding technology. This paper introduces the key features of SMART*CUT, compares its performance with conventional WC tipped tools, discusses the challenges faced by SMART*CUT and the further developments needed for successful application of SMART*CUT to mining industries.

Nov 22, 2011

A mineral exploration manager's prime function is to provide a frame- work within which new mine production can be achieved. As part of this framework, the manager should know his employerb future requirements, and should direct exploration towards those particular mineral commodities which indicate satisfactory growth in consumption and price. Selection of these commodities can be assisted by studies of world reserves, and long term trends in price and consumption. Exploration planning is most efficient with an assured and reasonably uniform supply of funds.

Jan 1, 1980

By S Nie, I Bergqvist, F Ouchterlony

In blasting, a few or many cracks are driven from the borehole into the rock. But what causes the cracks? The most common theory of breakage consists of two stages; first the shock wave causes radial cracks to form around the hole then the gases penetrate into the cracks, and widen them and make them longer. Another theory presented by Brinkmann suggests that the back damage is primarily controlled by shock and that the gas penetration is the mechanism controlling breakout of the burden. He did his experimental work using blasthole liners. Recent research at SveBeFo has examined this matter further. In a quarry a number of benching holes have been blasted simultaneously. In some of these holes tubular Swellex bolts were inflated and decoupled charges put inside the tubes without stemming. Other holes were identically charged but without the lining. Finally some holes were also stemmed. After blasting the cracks in the remaining rock were studied. There was no difference in crack lengths between holes charged normally (no stemming) and holes where the charges were inside the bolts. On the other hand when stemming was used, the crack lengths increased for some explosives but remained the same for an emulsion explosive. In another set up blasted granite blocks were charged in the same way as above. Then we could also measure the bore hole pressure. The pressure gauge consists of a small carbon resistor inside a steel cylinder. It is called LHM (Location-fixed Hydrodynamic Measuring Cup) and is placed at the bottom of the hole. A smaller exit hole from the bottom is drilled for the cables. The paper presents the technique and the results obtained from both the quarry blasting and the blasting of the blocks.

Jan 1, 2001

The geology of an area in north-western New South Wales, bounded by the South Australian and Queensland borders, latitude 32° S. and longitude 14° E. is discussed.The area involved includes sixteen 1:250,000 standard military sheets and covers approximately 96,000 sq. miles.The geology of the Willyama Complex is not dealt with but a small area of metasediments previously included in this unit is separated and a possible correlation with Precambrian to the east is suggested. Torrowangee Group sediments are described and the problem of nomenclature using a glacial implication is raised.Nine areas of proven Lower Palaeozoic sediments are considered and their relationship to the boundaries of the Bancannia Trough outlined. It is possible that some exposures not yet substantiated by fossil evidence may prove to be Lower Palaeozoic rather than Precambrian in age.The sediments of the Lachlan Geosyncline in the area of the Cobar massif are described and new concepts on the age and distribution of some of the established stratigraphic units are introduced. The absence of rocks of Middle Silurian age probably indicates the time of a major orogeny in this area.Lithology, thickness, and distribution of the Upper Devonian sediments is considered and some of the more recently found fish plate localities are listed.Mesozoic sediments occur in isolated areas of Lower Jurassic age and in the Great Australian (Artesian) Basin. A four-fold subdivision of sediments of the basin has been possible in some areas but lack of sub-surface information at present, precludes the possibility of correlation with the type sections in Queensland.Units in the Cainozoic are subdivided and a five fold subdivision of the Quaternary, at present being used throughout western New South Wales, is described.

Jan 1, 1969

By C Philander

The West Coast of South Africa is well known for its placer gem quality diamond deposits and also associated with these hosts of Cenozoic unconsolidated marine and aeolian sand and gravel are significant concentrations of heavy minerals. Exploration for economic concentrations of zircon, ilmenite and rutile along the coast started in the mid-1980s. This resulted in the discovery of an inferred 1.6 billion tonne resource with a grade of ten per cent total heavy minerals (THM), which developed into the Namakwa Sands Mine, a world-class producer of heavy minerals. Several other resources, including satellite deposits proximal and distal to the mine area, extensive diamond mine dumps and present day beach placers, demonstrate the vast heavy mineral potential along the West Coast. The favourable gangue to economic mineral ratio, a higher zircon content compared to other similar deposits, relatively lower U+TH content of zircon, low slimes content and effectively pristine low chromium-manganese ilmenite of these deposits, render them attractive exploration targets. Negative factors that will affect conventional mineral beneficiation and liberation include secondary mineral coatings and the regional coastal development of several layers of superimposed duricrust. The economically attractive heavy mineral assemblage along the West Coast is the result of erosion of the proximal, gneissic Namaqualand Metamorphic Province and mature Table Mountain Group sandstone, concentration by marine and aeolian processes and preservation under arid climatological conditions over a period of more than 100 Ma.

Jan 1, 2008

By R-H Yoon

The thin film pressure balance (TFPB) technique was used to measure the kinetics of thinning of single foam films and disjoining pressures in the presence of sodium dodecyl sulfate (SDS) and electrolyte (NaCl). The results were analysed in view of the Reynolds equation to determine the role of surface forces in film thinning. It was found that film thinning is controlled by surface forces at thicknesses below approximately 200 nm. It was also found that hydrophobic force plays an important role particularly at low SDS and NaCl concentrations. The values of the hydrophobic force constant (K232) estimated from the film thinning experiments were used to predict the disjoining pressure isotherm using the extended DLVO theory, which were found to be in excellent agreement with experiment. The TFPB technique was also used to measure the equilibrium thicknesses (He) of the foam films stabilised by a non-ionic surfactant, n-octanol, in the presence of NaCl. At a given ionic strength, He increased noticeably with increasing octanol concentration at very low concentrations. This observation suggests that hydrophobic force is at its maximum level in the absence of surfactant and decreases with increasing surfactant concentration. The results obtained with the single foam films were used to explain the stability of the three-dimensional foams.

Jan 1, 2005

By Eyers G. C

Long Shaft was initially developed using a rail haulage system on every working level comprising battery electric locomotives and granby trucks loaded by rail mounted rocker shovels. Production was commenced using conventional hand held cut and fill mining methods. In an effort to improve productivity and reduce operating costs a mechanised cut and fill stoping method evolved to suit the wider sections of the orebody. To further improve productivity and reduce costs the mechanised levels of the mine are progressively being redeveloped to enable the use of trackless diesel haulage equipment. An added benefit of trackless haulage equipment will be the ability to place development mullock into stopes as Fill.

Jan 1, 1988

This paper reviews the role of fill in mining including consolidated fill both histor- ically and currently as determined by a recent survey of the Fill Subcommittee of the Canadian Advisory Committee on Rock Mechanics (CACRM). It covers the application of fill in modern min- ing methods including mechanized cut and fill, undercut and fill, post pillar cut and fill and longhole pillar recovery between stabilized fill. An automated fill preparation plant and recent developments in rotary drilling of hydraulic fill conducting holes are described briefly. The paper also summarizes the findings of some of the important laboratory and field work carried out on the behaviour of fill in Canada, the United States and Australia and again draws on current information obtained from the Fill Subcommittee of the CACRM. Space limitations and unavailability of suitable material prohi- bit the summary of similar information from other countries.

Jan 1, 1973

The Fiji islands are the world's most ac- cessible Cenozoic remnant arc. They provide occasional subaerial exposures of an arc frag- ment some 750 km long and 80 km wide, or about the size of the NE Japan volcanic arc. The fragment is one part of the former Vitiaz Arc which once connected Fiji to Vanuatu and Tonga. The Fijian portion has the most completely stu- died Tertiary section which contains a history of arc volcanism from the late Eocene to late Miocene (the Early and Mature Arc stages), a rich diversity of subsequent magmatic responses to the most recent episode of arc rifting (Ear- ly Rifting stage), and an example of transition from arc to intraplate volcanism as this rift- ing proceeded (Late Rifting stage). The arc fragment is surrounded by younger backarc ba- sins. The chemical composition of magmas in both the arc and backarc changed with time, but in opposite directions. In the arc, magmas be- came enriched in sialic components from the Early Arc to Early Rifting stages, whereas in the basins the magmas became more similar to mid-ocean ridge basalts (MORBs) with time. In southwest Fiji, the oldest backarc basin has subducted obliquely beneath the remnant arc du- ring the last 3 Ma, resulting in chemically ex- otic calcalkaline volcanism. During the last decade over 150 radiome- tric age measurements and 650 rock analyses, many with trace element and isotopic measure- ments, have been obtained for samples from Fi- ji, Tonga, and the surrounding seafloor (Figs. 1 and 2). These data are summarized, drawing from the publications of Colley and Hindle (1984), Gill et al. (1984), Hawkins and Melchi- or (1985), Kroencke (1984), Malahoff et al. (1984), Scholl et al. (1985) and Whelan et al. (1985), from the specific research papers refe- renced therein, and from the half dozen or so manuscripts currently in preparation by these people and others.

Jan 1, 1987

Electrochemical investigations of the flotation of sulphide minerals are re- viewed. Flotation with thiol collectors is interpreted in terms of a "mixed poten- tial" model in which the process leading to hydrophobicity is the anodic oxidation of the collector at the mineral surface and this is driven by the cathodic reduc- tion of oxygen. Electrochemical studies have identified the products of anodic oxidation as chemisorbed collector, metal collector compounds, and dithiolates; the products formed in each situation depend on the collector used, the mineral under study, and the pretreatment of the mineral surface. Investigations on galena, pyrite, and chalcocite are discussed. Electrochemical and x-ray photoelectron spectroscopic studies have been used to determine the products of surface oxi- dation of sulphide minerals in order to elucidate the mechanism of collectorless flotation. The mixed potential mechanism allows consideration to be made of the ways in which flotation of sulphides with thiols can be inhibited. Examples of depressant action are presented. The relevance of electrochemical investi- gations to practical flotation is Discussed.

Jan 1, 1984

By M Stephens, T A. Sutra

Currently, there are several open pit mines with production rates of about 200 000 tpd of ore that are reaching the end of their economic lives. In most cases, the remaining orebody extends to depths greater than 300 m below the pit limit, leaving hundreds of millions of tons of reserves that can only be recovered by means of an underground mining method. One such method used for mass production is block caving. This paper presents a ventilation system for a four-zone block cave mine operation developed on a footprint 1000 m wide and 1200 m long. The system is designed for a mine with a nominal production rate of 120 000 tpd of ore using diesel powered units on the production and reduction levels. It discusses the air quantity requirements for the worst case scenario, which is anticipated to occur five years after the mine has reached its full production capacity. Finally, it summarises the results of computer modelling exercises that were carried out to determine an economic ventilation infrastructure that includes shafts, drifts, main fans, and ventilation control devices.

Jan 1, 2005