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By R. P. King

Flotation plant simulation, a relatively recent methodology in mineral processing, is defined and corresponding uses are discussed. Typical simulation structures are compared. Current problem areas exist although these are not insurmountable. Following a brief state of the art discussion, the N. I. M. simulation program is reviewed. In general, digital plant simulation is expected to be of substantial benefit in the near future.

Jan 1, 1976

By J. E. Flinn, E. R. Gilbert

Recently, Green reported some high-temperature, 0.60 to 0.89 T3, creep results on unalloyed tantalum. From his study he determined an activation energy of 114 kcal per mole for steady-state creep using the T, differential-temperature method25 for testing. He accounted for the difference between this value and 110 kcal per mole for self-diffusion by the temperature dependence of the elastic modulus, 4 kcal per mole. This reported activation energy is in apparent disagreement with that which can be determined from Green's isothermal data, which we have plotted as log creep rate vs 1/T in Fig. 15. From this figure, it appears that there are two activation energies of -185 kcal per mole at the higher temperatures and -75 kcal per mole at the lower temperatures. It is not obvious that the data can be fitted to a straight line corresponding to an activation energy of 114 kcal per mole. One is led to two possible conclusions regarding Green's study: there are two discrete processes controlling the creep rate from 0.60 to 0.89 Tm or the apparent activation energy is not discrete but continuously increases with increasing temperature. The former speculation would be in closer agreement with the high-temperature creep behavior of tungsten.28 The apparent disagreement between the activation energies determined by the AT and isothermal methods certainly suggests that further study on the high-temperature creep of tantalum is needed.

Jan 1, 1967

By A. W. Adamson

A model for transport processes in liquid mixtures is discussed which supposes that the elementary act involves a position exchange between two species and that the exchange is so confined by the solvent cage as to occur nearly isosterically. The rate-determining step, thus, is likened to a bi-molecular reaction and is so treated, using absolute rate theory. The cage model has been applied to diffusion, thermal diffusion, sedimentation and viscosity, but only the first and last of these phenomena are emphasized in the present paper. The model leads to semi-empirical relationships between the absolute value for a digusion coefficient and the activation energy for diffusion, between mutual and self-diffusion coefficients and for the variation of the viscosity of a binary mixture with composition. These are discussed in relation to experimental data for various systems, including hydrocarbon mixtures. It is shown that the proposed viscosity equation and seven other commonly used ones all may be regarded as special cases of a single general relationship; a brief critical analysis is made of the basis of selection of one or the other for data fitting or interpolation. INTRODUCTION AND GENERAL THEORY The present paper covers a brief discussion of a cage model for transport processes in liquid mixtures and how this model may be useful in treating the diffusional behavior and the viscosity of such systems. Since diffusion requires the more detailed treatment, it will be taken up first, and the model then applied to viscosity. There are two types of diffusion coefficients that may be measured experimentally, apart from thermal diffusion quantities. The first is the mutual or binary diffusion coefficient, D which may be defined in terms of Fick's first law. This states that the permeation, or flux P, is proportional to the concentration gradient. In the usual experiment, P is measured relative to a frame of reference fixed with respect to the medium (e.g., the diaphragm in a diffusion cell); as a consequence, the same value of D is obtained regardless of whether P and C refer to Component 1 or to Component 2; i.e., there is only one independent mutual diffusion coefficient for a binary system. In addition to D there will be various self-diffusion coefficients. defined in terms of the gradient in labelled species i and its permeation in an otherwise uniform medium. The thermodynamic approach to mutual diffusion supposes that the actual driving force is the gradient of the chemical potential, i.e., that In the case of a dilute solution of solute, Eqs. 1 and 3 lead to the Einstein equation, If the solution is ideal and the friction coefficient is taken to be then the familiar Stokes- Einstein equation results. Mutual and self-diffusion coefficients can not be related on general thermodynamic grounds; it is necessary to invoke some additional assumptions, i.e., a model; several such have been proposed. Hartley and Crank' supposed the existence of separate, intrinsic diffusion coefficients (Dl and D2) for each component, essentially corresponding to the two self-diffusion coefficients. The two flows can not be independent, however, but must be coupled through the usual restriction that there be no net volume flow. For an ideal solution. one then obtains' Glasstone, et al' treated diffusion in terms of absolute rate theory, but their approach otherwise resembled the previously mentioned one in that each species was considered to move with respect to the general medium in a manner determined by its individual jump distance and specific rate constant. For other than dilute solutions, a coupling of flows leading to an equation such as Eq. 6 would again be present. However, as required by Eq. 6, one does expect that the self-diffusion coefficient for the solute and the mutual-diffusion coefficient for the system become identical at infinite dilution. Lamm4 recognized that there should be three distinctive interactions in a two-component system-1-1, 1-2 and 2-2 — and, therefore, proposed three rather than two fundamental friction coefficients. Mutual diffusion resulted from 1-2 interactions only, and self-diffusion resulted from 1-2 plus either 1-1 or 2-2 interactions. Again, a collective coupling between all motions was imposed to meet the condition of no net volume flow. Laity' has shown how to convert the Onsager equations to a form very similar to Lamm's. Cage Model For Diffusion Work in this laboratory on diffusion in aqueous sucrose solutions made it apparent that three, rather than two, interactions were indeed needed," but considera-

The total number of applications brought before the Committee during the year 1916 was 962; the total number, of persons who were elected, and became members of the Institute during the wane period was 750. The total membership of the Institute on. Dec. 31, 1916, was. 5,781, consisting of 19 Honorary Members, 5,246 Members, 215 Associate Members, and 301 Junior Members. The changes in membership during the year are shown on the accompanying schedule:

Jan 2, 1917

By N. W. Sager, H. W. Mossman

The arrangement and general dimensions of the reverberatory furnaces and waste-heat boilers for the Nos. 2 and 3 smelting units at the McGill plant of the Nevada Consolidated Copper Corporation are shown in Fig. 1. Each of the two reverberatory furnaces has its own set of waste-heat boilers, and before February, 1932, each furnace, when it was in operation, delivered waste-heat gases to its own boilers only. In January, 1933, the idea was suggested of using some of the waste-heat boilers as economizers to operate in conjunction with the waste-heat boilers that were generating steam. The execution of this idea gave rise to the gas-flow scheme depicted in Fig. 1, the advantages of which were obvious, particularly so in view of the fact that for some months prior to the adoption of this scheme the smelting had been confined to No. 2 furnace, with No. 3 furnace and its boilers idle. The waste-heat gases from No. 2 furnace pass through the boilers serving this furnace as steam-generating units, thence through the original exit duct to a point where a bulkhead diverts the gases in a reverse direction through two of the boilers of No. 3 furnace. After the gases have traversed these two boilers, another bulkhead placed in the duct between No. 3 furnace and its boilers causes them to traverse still one more boiler, from which the gas path leads to the stack. In this scheme the last three boilers traversed by the gases, i.e., the boilers behind No. 3 furnace, function as economizers and preheat the feed water for the two steam-generating units directly serving No. 2 furnace. This discussion will give consideration to the results obtained in waste-heat recovery by the scheme shown in Fig. 1, and, further, will compare these results with those obtained before the boilers of No. 3 furnace were set up to act as economizers, but before going into the detail of heat generation, distribution and recovery, will present some additional details of the equipment. All boilers in this waste-heat plant are of the Stirling type. The two behind No. 2 furnace, acting as steam-generating units, of class 13, are 40 tubes wide and rated at 1112 boiler hp., while the three boilers behind No. 3 furnace, acting as economizers, are also of class 13, but 28 tubes

Jan 1, 1934

SEC. 1. The membership of the Institute shall comprise seven classes, namely: 1. Members; 2. Honorary Members; 3. Senior Members; 4. Associates; 5. Junior Members; 6. Rocky Mountain Members; 7. Junior Foreign Affiliates. All shall be equally entitled to the privileges of membership, excepting that no member of any class whose residence shall be outside of the United States of America, except those residing in Mexico and Canada, shall be entitled to vote. SEC. 2. Members: A person to be eligible for election or transfer into the class of Member must be at least 27 years of age and must have had at least six years' employment in the practice of engineering, mining, geology, metallurgy, or chemistry, during at least three years of which he must have held positions of responsibility in one or more of these fields. This shall not apply to Rocky Mountain Members.

Jan 1, 1946

By Richard F. Miller

The investigations of large-grained specimens carried out by Polanyi and Schmid,l Sykes,2 Goucher,3 Yamaguchi,4 Gough, Cox, and Sopwith,5 Carpenter and Elam,6 Aston,7 and others have shown qualitatively that grain boundaries restrain the deformation of adjacent crystals. But whether or not the influence of the grain boundary is confined to the glide planes intersected by the boundary has not been demonstrated in any of these investigations, nor has there been carried out any quantitative analysis of the influence of a boundary on the deformation of a crystal. Indeed, the specimens employed in the previous work contained so many complicating factors that it would have been difficult to observe any variation of the extent of the influence of the grain boundaries in relation to their sizc. The specimens were small, the grain boundaries irregular and at no particular angle to the specimen axis or the

Jan 1, 1934

By G. W. Mao, A. M. Gaudin, D. W. Fuerstenau

Activation of sphalerite with copper salts has long been thought of as a chemical reaction of the following form: ZnS + Cu++ [=] CuS + Zn++ [ 1 ] Early experimentation1-3 showed that the reaction seemed to be stopped by the coating of insoluble copper sulfide, but since the analytical methods were crude, it was only surmised that the reaction could proceed by diffusion. Probably the most conclusive evidence for reaction (Eq. 1) was obtained by Cooke,4 who found a stoichiometric replacement of Zn++ by Cu" after 50 days' reaction at about 100°C. Cooke also found the sphalerite to be covered with a rather thick coating of covellite, which in¬dicates that activation is a continuing replacement of Zn++ by Cu" rather than diffusion of Cu" throughout the sphalerite lattice. However, the occurrence of diffusion at high temperatures has been observed.5,6

Jan 4, 1959

SEC. 1. The membership of the Institute shall comprise seven classes, namely: 1. Members; 2. Honorary Members; 3. Senior Members; 4. Associates; 5. Junior Members; 6. Rocky Mountain Members; 7. Junior Foreign Affiliates. All shall be equally entitled to the privileges of membership, excepting that no member of any class whose residence shall be outside of the United States of America, except those residing in Mexico and Canada, shall be entitled to vote. SEC. 2. Members: A person to be eligible for election or transfer into the class of Member must be at least 27 years of age and must have had at least six years' employment in the practice of engineering, mining, geology, metallurgy, or chemistry, during at least three years of which he must have held positions of responsibility in one or more of these fields. This shall not apply to Rocky Mountain Members.

Jan 1, 1946

By Robert H. Richards

During tile summer of 1870, I had an opportunity to visit the laboratory of the late David Forbes, Esq., in London, and was much interested in a labor-saving device which he had attached to his agate mortar. The mortar was placed in the centre of a small table, and about ten inches to the right of the mortar, a post, perhaps two

Jan 1, 1879

By William J. Coulter

WITHIN the United States the problem of meeting maximum production by our metal mines has been solved by: (1) Conservation of man power by mechanization. (2) Increasing man-power efficiency as expressed in tons per man-shift by the adoption of new and more efficient methods. (3) Production from submarginal properties made possible by some form of government subsidy. (4) Selective mining of high-grade areas. (5) Drawing on broken ore reserves and reducing advanced development work to a minimum. (6) Making maximum use of available equipment. (7) Repairing equipment that normally would be replaced. (8) Working a seven-day week on a three-shift basis to get maximum use of equipment and man power. (9) Adoption of incentive plans to increase maximum efficiency and unit production. (10) Important advancement in metallurgy, resulting in larger recoveries. (11) Improvements in safety, health, and general working and living condi-

Jan 1, 1945

By L. D. Anderson

IN STUDYING Utah as a lead producing state one is immediately confronted by the fact that few, if any, of the ores of the state are valued for their lead contents alone. More correctly the ores from which this metal is recovered are characterized as silver lead. Even then the whole story is not told for many of these ores carry also gold, copper, zinc, bismuth, antimony, arsenic, tellurium, and other metals. It becomes apparent, therefore, that the production of lead i11 Utah is influenced by many factors. For example, i11 the early part of 1923 there was a marked increase in the production of the lead by reason of the efforts made by silver mines to produce as much silver as possible before the termination of purchases under the Pittinan Act in June, 1923. As nearly all silver ores carried more or less lead the production of that metal was increased with the increase in silver production. Very few, if any, ores of the State are mined for their lead contents alone. Important as Utah's contribution to the lead output of the country is nevertheless it is bound up to some extent with the production of gold, silver and copper.

Jan 1, 1925

By I. N. Zavarine

THE observations presented in this paper were recorded during a study of the spheroidizing process. Spheroidization of cementite in steel is either brought about to develop a set of desirable mechanical properties or is an incidental result of mechanical and heat-treating manipulations. Physical properties of steel are materially influenced by the state of the cementite. Conversion of cementite from the lamellar to the spheroidal state is usually accom-panied by a decrease of hardness and of strength and by an increase in ductility. The spheroidized structure is usually considered as an ultimate step in the process of the softening of steel. The unorthodox hardening of a 3.5 per cent Ni steel (SAE No. 2330) after a heat-treatment that previously proved entirely suitable for a complete spheroidization of cementite in carbon steels led to the observa-tions that constitute the subject of the present paper.

Jan 1, 1939

By Alexander L. Field

In the light of the experimental data on equilibrium for the reaction C + FeO = Fe + CO in molten steel recently obtained by Kinzel and Egan,l it is necessary to revise current theories regarding the nature of equilibrium between carbon and FeO in the basic open-hearth furnace. According to the measurements of these investigators the equilibrium constant m for the above reaction for a pressure of dissolved CO equal to 1 atm. is equal to 0.0005 at 1550" C., when concentrations of carbon and FeO are expressed in percentages by weight. Their work also shows that, with the pressure of CO fixed at 1 atm., not only is the product of carbon and FeO constant, but carbon and FeO are each independently constant—a circumstance which might have been predicted from theoretical considerations. At 1550" C., carbon is constant at about 0.025 per cent. and FeO at about 0.020 per cent., with the pressure of dissolved CO equal to 1 atm., the product of these two constants being equal to the originally mentioned constant of 0.0005. Available data on the dissolved FeO content of samples taken from the metal bath at practical slag-metal equilibrium prove that this FeO content is determined solely by temperature and the effective FeO content of the slag. The distribution constant r at 1550" C., as determined by Herty, Gaines, Larsen, Simkins, Geruso and Watkins2 is equal to 0.0086. A slag would have to contain 0.020 = 2.3 per cent. effective 0.0086 FeO or less in order to prevent the metal from containing more dissolved FeO than that required for equilibrium with CO at 1 atm. pressure. Such low percentages of FeO are never found in basic open-hearth slags at the completion of a heat when rate of carbon drop has become practi-

Jan 1, 1930

By Samuel B. Christy

The present paper is a continuation of a study of the reductionworks of New Almaden, the first part of which was published under the title " Quicksilver-Reduction at New Almaden," in the Transactions of this Society, vol. xiii., p. 547.* Frequent reference will be made to some of the data there given. The following is an outline of the contents of this paper: I. Condensing appliances used at New Almaden: a. Brick condensers, b. Iron condensers—flues and " water-backs," c. Glass and wood condensers, d. Friction-coudensers—filters and revolving screens, e. Flues, towers, and chimneys. II. Analysis of condensing-systems. III. Temperature of condeusers. IV. Product of condensers. V. Treatment of soot. VI. Losses of treatment: a. Nature of losses, b. Composition, weight, and volume of dry gases, c. Volume of wet gases, d. Specific weight of quicksilver vapor, e. Vapor-loss at various temperatures. VII. Comparison with New Almaden practice. VIII. Comparison with results at Idria, Austria. IX. Comparison with results at Almaden, Spain. X. Future improvements in quicksilver-condensation. I. Condensing Appliances. The complete condensation of mercurial fumes in a large way presents numerous practical difficulties, familiar to all who have had to retort amalgams. In condensing the quicksilver-fumes discharged

Jan 1, 1886

By AIME AIME

WHEN H. I. Smith joined the Institute back in 1908, he was an instructor in mining and metallurgy at Penn State the college from which he had graduated the year before with a B.S. degree. He had not gone far afield for his education, for he was born, February 15, 1984 at Finleyville, Pa., a small village some fourteen miles south of Pittsburgh and without doubt famous chiefly as H. I.'s birthplace. The summer that he graduated he took a trip to the copper mines Arizona and Mexico and en route worked for four weeks for the Portland Gold Mining Co. at Cripple Creek, Colo., as a mucker and trammer. The next summer he roamed farther afield mines and metallurgical works in Europe. Wishing to see more of Arizona, he left the Penn State faculty early in 1909 and went out to Wenden in that State to become mining engineer and assistant superintendent of something called the Corona Copper Co., with 72 mining claims and a one-mule-powered whim for a hoist. When that job folded he helped build the Santa Fe railroad from Parker. Ariza., to Danby Cialif., and then came back to Pennsylvania to enter Government services as a junior mining engineer with the Bureau of Mines.

Jan 1, 1943

By C. H. Gerould

I would like to take a moment to consider our polystyrene-silica replica technique, which was developed at the Dow Chemical Co. and which was mentioned in the paper just given by Mr. Thielsch. He stated that he feared that our replica technique would cause difficulty due to deformation of the metal as a result of the application of pressure during the molding process. We at the Dow have never had any reason to suspect that any deformation of the metal was occurring during the molding process. Our procedure has been to heat the polystyrene to a temperature of 160°C. before applying any pressure, at which temperature the polystyrene is a viscous liquid. By so doing the pressure of the polystyrene against the metal is essentially hydraulic and is therefore applied equally in all directions, which we feel should not cause deformation. Our work using this replica technique has brought forth several indications that deformation of the specimen is negligible. These indications are: I. Direct comparisons have been made between the light and electron microscopes when studying a specific spot on a metal surface. These "same spot" studies were obtained by first taking micrographs at high magnification, with a light microscope, of a specific structure that could be readily recog-

Jan 1, 1947

By Andrew Hyslop

In our never ending search for new and better ways of underground mining, we find that transportation has had its share of new ideas in the past few years. The old and still effective method of track haulage has had some competition from rubber-tired cars and belt conveyors, each of which has its own safety hazards which demand close scrutiny in any safety study. The use of shuttle cars, in particular, has introduced clearance hazards caused by the absence of the more or less positive guides formed by the rails of a track sys- tem; likewise the requirement of greater clearance tends to increase roof hazards which we all know to be great enough with the best of methods. However, the subject of transportation hazards is too broad to be covered entirely in one paper, so I will confine myself to track methods which carry the preponderance of underground tonnage. I am quite sure that to this group it is an evident fact that haulage accidents are of major importance. However, to stress the point, it may be well to look at a few figures. Safety statistics can be quite boring and often are subject to question as to mathematical accuracy because of different

Jan 1, 1949

By Ralph Hayden

PAGE I. IntRoduction........239 II. Definition of Anaconda SLime....240 III. The Source of Slime......240 Remodeled Flow Sheet......240 Old Plow Sheet,.......242 IV. ConStitution of Slimes......243 Chemical........243 Physical.........243 V. The Slime Problem.......247 VI. THe Experimental Slime Plant....248 VII. Slime Thickeners. ETc .......249 Slime Ponds........249 Tanks.........249 Comparative Efficiency of Open and Baffle Tanks .260 Callow Tanks........252 Kuchs-Laist Centrifugal Separator....253 Garred Filter........256 Dorr Continuous Thickener.....256 VIII. Concentrators........257 Round Table........558 Peck Centrifugal Concentrator....259 Competitive Tests.......260 Twenty-Deck Round Table..... 260 Slime Feed Distributor......261 IX. ConcluSion.........262 I. Introduction. In the wet concentration of ores there is always a certain amount of very fine material with which to contend. and which invariably carries such quantities of value that the treatment of it is worth while. commercially. This fine material usually contains that portion of the ore which hinders the separation of the mineral values: namely. the colloidal material resulting from the decomposition of certain constituents of the ore. The object of this paper is to show what efforts have been made to solve the slime problem as it occurs in the concentrator of the Washoe

Jan 1, 1914

By I. Stapf

Systematic investigations on silver-rare earth metal systems have been extended on the Ag-Ce system in order to clarify the discrepancies reported in literature. The phase diagram has been reinvestigated on the base of thermal analyses and of microstructure examination on cast and annealed specimen. All intermetallic phases Ag4Ce, Ag3Ce, Ag2Ce and AgCe show no extended range of homogeneity, they melt congruently fm), or decompose peritectically (d) at 815 °C (d), 1030 °C (m), 855 °C (d) and 855 °C (m), respectively. The system shows eutectics at 793 °C/10 at.%, 780 °C/42 at.%, and about 505 °C/81 at.% Ce. d-Ce dissolves up to 2 at .% Ag and decomposes metatectically at 710 °C. Furthermore, the phase transformation of the intermetallics would be clarified. The phases Ag5Ce and Ag51Ce14 reported in literature could not be verified.

Jan 1, 1984