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By Companhia Siderúrgica Nacional - CSN

Balanço Energético Global 2013

Jul 31, 2018

By Douglas Glenn Stalheim

Production of structural steel with a minimum yield strength of 700 Mpa produced as hot rolled coil has become increasingly popular due to cost considerations when compared to quench and temper equivalent product. This grade when produced as hot rolled coil requires the use of microalloy precipitation strengthening mechanisms. This is typically a combination of niobium and titanium microalloys. While the metallurgical concept of structural steel precipitation strengthening mechanisms has been well researched and published, actual implementation into the production process can be very challenging. In addition to achieving a minimum yield strength of 700 Mpa, in many applications additional mechanical property attributes of formability as measured by hole expansion testing along with low temperature toughness properties are now required. Achieving a balance of all the mechanical properties in a stable and repeatable performance in production using microalloy precipitation strengthening mechanisms further increases the challenges. This paper will discuss the metallurgical/process strategies required to successfully produce 700 Mpa minimum yield strength hot rolled structural steel coil. In addition, the role and goals of both niobium and titanium in this product design will be presented.

Oct 30, 2017

By Carlos Gonzalez-Rivera

An alternative cooling curve analysis method focused on the experimental determination of the latent heat of phase changes and phase transformation kinetics is proposed in this work. The method analyses the cooling process of a metallic sample, initially liquid that is contained into a cylindrical metallic mold, both of known weight, thermally isolated at its top and bottom. The method is based on an energy balance associated with the experimental measurement of the temperature change of the sample and the mold during their cooling process. From the numerical processing of the cooling curves, are obtained approximate values of the acting global heat transfer coefficient as a function of temperature in order to describe quantitatively the energy exchange of the metal/mold system with its surroundings. These relationships and other experimental data are used to process the cooling curve of the sample and the mold during solidification, in order to obtain the latent heat of solidification.The method was applied experimentally to zinc and tin of commercial purity, initially liquids and contained into stainless steel molds in order to determine its ability to measure the latent heat of solidification. The obtained results suggests that this method shows a good potential to characterize the solidification of metals.

Oct 30, 2017

By Mühlböck Marlene

Increasingly stringent global environmental regulations are forcing steel producers to continually improve the efficiency of sinter waste gas treatment. With the Selective Waste Gas Recirculation (SWGR) system from Primetals Technologies, lower production costs can be achieved and the size of downstream waste gas cleaning units can be reduced for investment savings. SWGR features the extraction and reuse of hot sinter off gas from selected wind boxes along the sinter strand, which contributes to improved energy efficiency and off gas treatment in the sintering process. With the next generation of SWGR, Primetals Technologies can provide an energy optimized, emission optimized and environmentally friendly solution that meet customer requirements and country specific regulations. This paper demonstrates the latest developments in selective waste gas recirculation, especially results from pot grate tests and comparison from lab to real plant data. Furthermore theoretical finding and mathematical modelling is presented.

Aug 16, 2017

By Guilherme Guidugli

The hot blast stoves are a regenerative heat exchange system, accounting for 10 to 20% of the total energy requirement in an integrated steel plant, responsible for the supply of about one-third of the blast furnace heat input and responsible for a constant flow of hot air to the blast furnace, according to the required production. Because of their important role in the hot metal production, a stable operation and an appropriate combustion control is necessary. This paper aims to present the results of an investigation and modifications performed as an operating multi-furnace plant, as well as the parameters considered to ensure thermal equilibrium, improving in the stoves heating cycle.

Aug 16, 2017

By Shibu John

The COREX® process is beside the FINEX® technology the only industrially realized alternative to the blast furnace route for the production of hot metal. Changes in the raw material sector in respect of decrease in quality, strictly enforced environmental laws and positive operation results of COREX® reference plants make it worth to carefully re-evaluate the COREX® technology in comparison with the traditional blast furnace technology. Integrated Plant concepts based on COREX® offer solutions for future challenges of the iron- and steelmaking industry, which include: economical hot metal production; efficient and highly economic export gas utilization (power generation, DRI production, syngas production for chemical products); lower raw material cost, higher raw material availability; environmental friendly high grade steel production. The economic evaluation of different COREX® gas based plant concepts in comparison with the traditional blast furnace route shows that the COREX® technology is highly competitive in the challenging iron and steel producing environment.

Aug 17, 2017

By José Aparecido Pereira

The innovative methodology developed by the author allows the elaboration of an Angle Roll Pass Design based on the practical observations of the rolling process and applies mathematical criteria, using the Ekelund´s formula supported by Advanced Excel tools (Reach Goal, PROCV-PROCH, Macros) and AutoCad. The first step is the definition of the number of stands, roll dimensions, gear boxes reduction, initial stock, average reductions, spread factors, finishing speed and type of grooves. For each pass are calculated: bite angle, spread, section reduction, lost and gain of temperature, separating force, speed, torque and motor power. After these calculations and checking of the parameters, the program calculates the dimensions of the passes transforming the flat passes into shaped ones. With these dimensions it is possible to draw the grooves using AutoCad and check section reductions. This methodology was already used for the development of a new project and also to check the parameters of existing ones, with comparison of the results and has shown to be reliable in real and tested projects. It is an innovative process that is not available in known literature.

Oct 1, 2019

By Dong Maolin

A great amount of high temperature off-gas, whose maximum temperature is up to 2100?, is generated during the smelting process of electric arc furnace (EAF). The dust content, which is mainly iron oxide, of the off-gas is high and worthy of industrial recovery. The heat carried by the high temperature off-gas with dust is about 11% of the total energy input of EAF, and some even is as high as 20%. The high-temperature off-gas not only takes away a lot of heat but also places a huge burden to de-dusting system of EAF. It not only reduces the iron oxide dust recovery ratio, but also causes serious pollution problems. With the development of the iron and steel industry, the proportion of molten iron for EAF gradually increases, and even more than 30% in some cases. The increase of molten iron causes increases in the amount of EAF off-gas and heat waste. As a result the problem of dust removal is worsening [1-2]. How to sufficiently recover the sensible heat of the high temperature off-gas, create conditions for efficient dust removal, thus reduce operating costs of dust removal system and the production costs is a problem which EAF steel making companies must pay attention to.

Oct 30, 2017

By Zou Zhongpping

Under the new normal state, blast furnace outputneeds to be adapted to the market demand, however the limitation in blast furnace output has significant impact on blast furnace operation and is prone to cause inactive furnace hearth and higher fuel ratio. To address such problems, some practices to maintain stable and smooth operation of blast furnace in case of output limitation are proposed based on data analysis philosophy, which allows the blast flow and hence the top pressure to be determined based on the hot metal output, and adequate kinetic energy of blast supply can be assured by adjusting the tuyeres. Matching between the oxygen enrichment and the pulverized coal injection is also proposed based on theoretical flametemperature, and burden distribution cycle calculation method is proposed, whichoffersnew approach for analyzing the change in burden distribution pattern.

Oct 30, 2017

By Marcela Gotelip Barbosa

Pellets are the main iron input to the blast furnace at ArcelorMittal Lazaro Cardenas iron and steel making facility in Mexico. Pellets are made at this facility using the concentrates generated and shipped from their captive mines viz., Las Truchas, Pena Colorada, Volcan Sonora. The concentrating plants, after grinding the ore to the liberation size, use magnetic separation and flotation to reject the silica, sulphur and phosphorous impurities. At Volcan Sonora Mines, the ore is contaminated with phosphorous minerals, and hence, after magnetic separation, the phosphate minerals are floated using anionic carboxylate collector (sodium oleate). Apart from floating the phosphate minerals, the sodium oleate also has some tendency to smear on the iron bearing mineral surfaces leaving a hydrophobic surface, which is expected to reduce the green pellet strength due to absorption of ultrafine sized air bubbles on these surfaces, and further generate higher levels of dust during the induration process. In order to alleviate this industrial problem, comparative studies were carried out on the concentrates from magnetic separation using reagents from synthetic sarcosinate and carboxylate family collectors. Results have indicated that the sarcosinate family members not only were found as replacement to carboxylate collectors, but also reduce the phosphorous content below the values achieved with oleate, thus have considerable benefits in the downstream steel making process. Based on the results, plant runs are being taken up at Volcan Sonora. In this article, the laboratory results obtained on iron grades and recoveries, and phosphorous rejection using both the reagents are presented.

Aug 1, 2018

By Simon Chiartano

A global reflection on the design of blast furnace main runner was investigated in this paper. TRB Company used its skills and expertise to understand what the best option for this sensitive component is, including some innovative tools: intelligent block design for safety lining, thermal & thermomechanical numerical simulation, immersive measurement by thermocouples, IR thermal camera, 3D laser scanner.

Oct 1, 2019

By Marjorie Benegra

This study aims to compare the wear resistance assessed in rubber wheel abrasion test of nickel aluminide coatings deposited by for Plasma Transferred Arc (PTA) and High Velocity Oxigen Fuel (HVOF) manufacturing, using the same raw material. A nickel aluminide powder was atomized and deposited on 316L steel plate substrate. After deposition, some specimens were submitted to a heat treating (1200 °C for 24 h followed by 760°C for 24 h). The coatings deposited using PTA developed different microstructures due to the incorporation of substrate elements, its performance was better than the HVOF coatings, although their Vickers hardness was similar. After heat treating, a significant variation in hardness and wear resistance was observed. For PTA specimens, there were decrease in hardness of 35%, while for HVOF ones this drop was approximately 20%. Nonetheless, the effect of thermal exposure in wear resistance was quite different: an increase of 21% was observed for HVOF coatings, while a reduction of 20% occurred in PTA ones. Microstructures modifications in PTA coatings were significant for their wear resistance. On the other hand, the reduction of porosity and sintering were responsible for a better performance of heat-treated HVOF coatings.

Jul 31, 2018

By Douglas Glenn Stalheim

The demands for improved mechanical properties in hot rolled long products are increasing as the expectations of global Standards and construction designer’s increase. Cost constraints limit the excessive use of expensive alloys to meet these expectations. In addition, depending on the mill, equipment can limit what can be realized to meet the increasing expectations. The most effective way to meet the increasing expectations for improved mechanical properties of optimum strength and ductility is through producing steel with as fine as possible uniform cross sectional grain size in the “as-rolled” condition. The best solution to the development of this fine and uniform cross sectional grain size is to develop a cost effective alloy design coupled with proper metallurgical process control implemented into an existing mill’s equipment capability and layout. In other words, properly bringing together alloy, metallurgy, process control and existing equipment capabilities to develop an optimum product that can meet the increasing demands of the construction designer. This paper is designed to give a solid understanding of the production and metallurgical requirements to achieve a grain size in “as-rolled” long products that is as fine as possible within the limitations of the process and production parameters of the individual plant.

Jul 30, 2018

By Stanislas Mauuary

Price pressure is a real challenge on the stainless steel market. With market globalization, increase production capacity and exorbitant raw material, the margins are squeezing for stainless strip producers. Primetals Technologies offers a wide range of advanced technological solutions to secure the margins of our customers. Our solutions, implemented with professional project management, allow an optimum coil to market time, securing then the return on investment for the investor. Among the possible lever used to optimize the production route, one drastic step can be made to cut rolling time and cost by replacing the common 20-Hi mill stand reversing process by state of art high capacity X-HI® stands in continuous rolling line. Other source of savings can be implemented by integrated several process steps together (rolling, annealing, pickling, skin passing), achieving then savings on stocks and logistics while coil processing is reduced to fraction of hour. Additional solutions can also be implemented on the new, as well as existing line, like maintenance free solid state laser welder, skin-pass and tension levelers, in-line inspection system coupled with process and quality management system.

Aug 17, 2017

By Humberto Tronconi Coelho

The use of friction dampers are wide proposed for a variety of mechanical systems for which it is not possible to apply viscoelastic materials, fluid based dampers or others viscous dampers. An important example is the application of friction dampers in aircraft engines to reduce the blades vibration amplitudes. In most cases, friction dampers have been studied in a passive way, however, a significant improvement can be achieved by controlling the normal force in the contact region. The aim of this paper is to study four control strategies for friction dampers based on three different hysteresis cycles. The first control strategy maximizes the energy removal in each harmonic oscillation cycle, by calculating the optimum normal force based on the last displacement peak. The second control strategy combines the first one with the maximum energy removal strategy used in the smart spring devices. Finally, is presented the strategy which homogenously modulates the friction force. Numerical studies were performed with these four strategies defining the performance metrics. The best control strategy was applied experimentally. The experimental test rig was fully identified and its parameters were used for numerical simulations. The obtained results have shown the good performance for the friction damper and selected strategy, also, the agreement between numerical and experimental results.

Jul 31, 2018

By Anand Kumar Agrawal, Kinzel Klaus Peter, Lorenzo Micheletti, Cristiano Castagnola, Horst Kappes, Andre Oliveira, Björn Rösner, Philippe Bermes

Blast furnaces are widely employed today for iron production all around the world, with a total production of around 1.2 billion tons per year. Its operating principle, which relies on usage of coke to reduce the ore, to ensure the permeability in the reaction vessel, to maintain its flexibility of operation and acceptability for varying qualities of iron ores. The blast furnace route is widely considered as the most economic and efficient route of iron production, however it is based on fossil energy carriers. The blast furnace route has undergone significant developments in terms of energy efficiency in the last decades, which led to a substantial reduction in the use of fossil reduction materials. Being an energy intensive process, competitiveness and cost saving in the blast furnace plant was always strongly related to the saving of energy and hence reduction of CO2 emissions. In addition to this, EU emissions trading system (EU ETS) as a cornerstone of the EU's policy in response to climate change has set new “challenges” for iron production in Europe. Paul Wurth has always been deeply involved in the development of energy saving technologies for blast furnaces. In the following a review of energy saving achievements developed in the last decades will be presented and the potential of available CO2 saving technologies will be summarized. Additionally, an outlook about the potential of future technologies, concepts and their impact on the blast furnace and the steel plant’s energy balance will be discussed. Finally, the replacement of carbon by hydrogen as reduction agent in the steel plant will be reviewed, with special focus on a comparison of costs and incentives.

Oct 1, 2019

By Jean François Stumper

This paper presents the TMT “3D TopScan” profilemeter, which is a Radar-based profilemeter that measures the total burden surface within a few seconds and on a continuous basis. This equipment is based on an electronically steered solid-state radar scanner, such that a very large amount of surface data is collected within short time intervals. These new electronically steered antenna systems are the key to meet the demands for both accuracy and speed. The TMT probe is installed at a fixed location at the top cone, such that it does not interfere with the charging, enabling a continuous measurement and a compact design.Blast furnace charging optimization can be achieved based on its measurement data. The burden surface is continuously measured every few seconds, enabling the blast furnace operator to detect any details including asymmetries or irregularities in the surface pattern. A variety of process analysis tools are available. Due to the continuous and fast measurement, the burden descent speed can be supervised without process interruption on an ongoing basis. More accurate process models (layer models) than ever are obtained which fully consider the unsymmetries.This technology, developed by TMT Tapping Measuring Technology, is successfully in operation at Salzgitter Flachstahl GmbH at their blast furnace B. The probe and the data evaluation tools combine today’s technological capabilities in measurement technology with the practical requirements of blast furnace operation.

Aug 16, 2017

By Sander Mul, Michael Brandner, Armin Paar

Graphitic HSS roll grades such as ESW’s brand VANIMO can be considered as the latest developments for the last finishing stands in hot strip mills. These roll grades are developed on the basis of the alloying concept of (Carbide Enhanced) Indefinite Chill work roll materials. During the development of VANIMO, the amounts and types of carbide forming elements were increased and adjusted into the direction of cast HSS roll grades. The microstructure of graphitic HSS roll grades therefore consists of tempered martensite, cementite and several different carbide types as well as a well-defined amount of free graphite. The main purpose of graphitic HSS roll grades is to combine the high surface quality of Indefinite Chill alloys as well as the high wear resistance of HSS roll grades. Several systematic steps were taken to increase the wear performance from Carbide-Enhanced Indefinite Chill grades to the more advanced VANIC grade and further on to the highest alloyed roll grade VANIMO. In every development step, the surface quality of the roll grades was carefully monitored. The decision to invest in new testing equipment at ESW’s plant was driven by the wish to see microstructural effects of different alloys in a macroscopic dimension. Usually samples are taken from cast rolls and investigation is done in comparably small areas compared to the total surface of a roll. Rolling of strip is done with the entire barrel, so effects of alloy and microstructure can appear anywhere on the barrel surface. To ensure better understanding and deeper knowledge about influences of alloying trials we decided to install the last version of LRI (Lismar Roll Inspection). LRI includes the latest technology of Eddy Current with an enormous resolution. Depending on the formation of carbide precipitations, carbide network as well as matrix and free graphite, the EC test can detect smallest differences. The possibility to analyze the different results of EC and UT surface wave inspection will be discussed. A few examples of surface effects in the mill application will be discussed and improvement strategies explained.

Oct 1, 2019

By Hongshuang Di, Tianyu Zhang, Huiqiang Huang

A CMnSiAl transformation induced plasticity (TRIP) steel was used to study the effect of retained austenite on room-temperature mechanical properties. The steel plates with retained austenite were obtained by hot rolling, cold rolling and subsequent continuous annealing. The starting and finishing temperature of hot rolling are between Ac1 and Ac3. Reduction ratio of cold rolling is 75%. The continuous annealing is carried out at different intercritical temperatures. The relationship between work hardening exponent and retained austenite was discussed. The results show that, the Ac1 and Ac3 were much high because of the alloy elements, and the temperature range between them was wide. Due to the high hot rolling temperature, the grains was hereditarily refined as a result of dynamic recrystallization. Annealing at intercritical temperature of 930 ºC, retained austenite with relatively high stability reached a maximum volume fraction of 25%, a maximum total elongation of 30.2% and a best ultimate tensile strength × total elongation of 20.1 GPa·%. Instantaneous work hardening exponent reflects strengthening mechanisms at different strain stages. The TRIP effect of retained austenite is the main mechanism during deformation. With retained austenite of sufficient amount and high stability, continuous work hardening was observed in the tensile specimen of 930 ºC.

Oct 1, 2019

By Mathias Woydt

The tribological and mechanical properties of binderless and metal-bonded niobium carbides (8 or 12 vol.-% of Cobalt, 12 vol.-% of Fe3Al) are presented. Rotating disks made of niobium carbide bearing hard metals were mated against alumina (99.7%) under unlubricated (dry) unidirectional sliding tests (0,1 m/s to 12,0 m/s; 22°C and 400°C) as well as in oscillation tests (f= 20 Hz, ?x= 0,2 mm, 2/50/98% rel. humidity, n= 105/106 cycles). Microstructure and phase compositions were determined as well. The tribological data obtained were benchmarked with different ceramics, cermets, hard metals and thermally sprayed coatings, where NbC bonded with 8% and 12% Co presented above 8 m/s the lowest wear rates so far in such a benchmark. Binderless NbC (HP-NbC1) and the metal bonded NbCs exhibited low wear rates under dry sliding associated with high P?V load carrying capacities. NbC-based hard metal bonded with 12 vol.-% of Fe3Al resulted in a higher hardness level than for 12 vol.-% cobalt. The tribological profile established revealed a strong position of NbC bearing materials under tribological considerations and for closed tribosystems against established reference tribo-couples.

Jul 31, 2018