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By Bianca Proença

Fotocatalisadores de nióbio foram obtidos por anodização a 15 V, utilizando uma solução de K2HPO4 10% p/p em glicerol anidro como eletrólito por 15 minutos. As amostras foram caracterizadas por difração de raios-X para avaliação da estrutura cristalina obtida. A fotodegradação do glicerol (utilizado como agente de sacrifício) foi avaliada pela técnica de cromatografia líquida de alta eficiência.

Aug 16, 2017

By Jorge Madias

Pin holes as a surface defect, and blow holes as an inner defect, occur in billet / bloom / beam blank casting, particularly for Si-Mn killed steel cast with metering nozzle and oil lubrication. If they are present in abundance or have a large size, they may originate defects in the rolled products. Their characteristics, factors behind their formation, as well as usual processing conditions that promote their occurrence are discussed. Finally, the evolution of these defects during reheating and rolling is analyzed, with industrial examples.

Aug 16, 2017

By José Francisco Cabello Russo, Késsius Bortolan Menezes, Henrique Dias Gatti Turrer, Denílson Rodrigues de Araújo

With the start-up of the Minas-Rio system, Anglo American, in Conceição do Mato Dentro, MG, in 2014, a methodology was also implemented and certified to perform the tests to obtain the results of TML (Transportable Moisture Limit). Such a parameter provides the maximum moisture content contained in the material that could be transported without the risk of the cargo liquefaction process, which could lead to incidents such as the tipping of ships carrying iron ore concentrate in bulk on the deep water. This means that when loading a ship, the moisture content of the material to be transported should not be higher than the TML reference value, obtained in a physical test and intrinsic to the material. Should this occur the charging may be rejected. From 2014 a downward trend was observed for this reference parameter in the Minas-Rio system, with results approaching the moisture of the filtered product, bringing risks to the operation of the project. In this way, an investigation of the possible causes for understanding this downward trend was required.

Oct 3, 2019

By Luiz Henrique Accorsi Gans

First, this works carries an experimental evaluation for austempered ductile iron (ADI) as a gear material. And second, in order to provide a better understanding of the microstructural effect on the stress state of subsurface regions, a finite element method approach was considered using the submodeling tool in ANSYS 11.0. For this, ADI gears were produced from continuous cast iron bars, heat and thermochemical treated and tested in FZG test rig. The results were compared to those of carburized steel AISI 8620 and induction hardened steel AISI 4140 gears. The wear experiments were performed at the temperature of 90ºC with two torque stages: 135 N.m (running-in) and 302 N.m (steady-state). The time for pitting and spalling on the gears surfaces were measured using image analysis. The results showed a very good potential of using ADI for manufacturing gears, replacing induction hardened steels. Also, the ADI gear with smaller nodules showed higher life for pitting. In contact fatigue tests with severe load, the carburized AISI 8620 steel proved more adequate than the austempered ductile iron, showing that the mechanical properties are critical in the resistance to damage in gear contact. The austempered ductile iron with smaller nodule size showed to be very competitive with wear resistance similar to AISI 4140 steel induction hardened. With ANSYS, it was verified that the nodule size affects the gears life independently of the mechanical properties of the matrix. The results showed that the nodules indicate the presence of a concentration stress, but their size doesn’t affect the contact fatigue life as much as the total amount of nodules, regardless of the ductile iron microstructure. The size and number of nodules affects both the nucleation and the propagation stage of cracks. ADIs with higher amount of nodules have a greater wear resistance. Also, compared to the Hertz contact theory (isotropic material), the presence of graphite nodules indicates a non-isotropic material and made the maximum shear stress point moves toward the surface.

Jul 31, 2018

By Alessandra Vieira Guimarães

A liga de Níquel 718 é bastante requisitada para aplicações na indústria aeroespacial devido as suas excelentes propriedades. Endurecida por precipitação, a liga apresenta alta resistência mecânica sob condições extremas e ambientes severos, representando um avanço tecnológico significativo na produção de motores aeroespaciais. Os reparos realizados nos motores são feitos por diferentes processos, porém muitas vezes são realizados até que as especificações estruturais deixem de ser atendidas. Após os reparos, a liga é solubilizada em temperatura inferior a temperatura solvus da fase d, o que pode levar a precipitação crescente desta fase, podendo impactar nas propriedades da liga. O intuito do presente trabalho é avaliar o efeito de múltiplos ciclos de tratamentos térmicos de solubilização e envelhecimento na microestrutura e propriedades mecânicas da liga. Foi possível observar que os múltiplos ciclos induzem uma crescente formação de fase d, reduzindo a resistência mecânica da liga.

Oct 30, 2017

By Eduardo Vitral

The present study focuses in the simulation of pattern formation by ion beam sputtering on a material surface. This process is responsible for the appearance of unexpectedly organized patterns, such as ripples, nanodots and hexagonal arrays of nanoholes. A numerical analysis of preexisting patterns is proposed to investigate surface dynamics, based on a model derived from a Kuramoto-Sivashinsky anisotropic equation, in a two dimensional surface with periodic boundary conditions. While deterministic, its highly nonlinear character gives a rich range of results, making it possible to describe accurately different patterns. A finite-difference semi-implicit splitting scheme is employed on the discretization of the governing equation. Simulations were conducted with realistic coefficients related to physical parameters (anisotropies, beam orientation, diffusion). The study dealt with a random and a monomode 1D structure initial condition in order to understand how the shape and wavelength of the initial pattern evolve with time. Ripples and hexagonal patterns were observed in the results, being physically consistent with the phenomenon. Moreover, the Method of Manufactured Solution has been used as verification of the developed numerical scheme.

Aug 16, 2017

By Frenk van den Berg

In the manufacturing of steel strip for the automotive sector, the mechanical properties are largely defined by the process conditions in the hot strip mill. In particular the phase transformation, from austenite to ferrite, which takes place during the forced cooling stages on the run out table (ROT) after the finishing mill, governs the microstructure and hence the mechanical properties.In current practice, metallurgical models are used to predict the phase state at each position in the strip. These model predictions are supported by pyrometer measurements along the ROT. Although reliable in the majority of the situations, both measurements and models sometimes have difficulties in providing robust output. In this paper, we present a new type of inline measurement, which directly measures the amount of phase transformed. The instrument is based on a technique known as impedance spectroscopy. As result of a collaboration of different institutes and companies, the equipment is robustly running during several years exclusively in the Hot Strip Mill of Tata Steel in IJmuiden.

Aug 16, 2017

By José Dimas Arruda

O conhecimento do campo de fluxo dentro do molde pode oferecer uma oportunidade de melhorar a limpidez interna do produto final. A técnica PIV foi empregada para avaliar a distribuição de velocidade longitudinal ao longo de uma ampla seção variando da válvula submersa até a face estreita de um molde de lingotamento de placas, bem como a distribuição de velocidade transversal correspondente. Estas informações podem ser utilizadas para avaliar o grau de turbulência interfacial.

Jul 30, 2018

By Salete Martins Alves

The future lubricants must be more environmentally adapted, with a higher level of performance lower total life cycle, cost than currently used lubricants. Environmental friendly, the biodegradable alternatives are available for a large variety of mineral oil based lubricants. Vegetable oils are the major source of these base fluids, although they have lower thermal and oxidation stability and even worse low-temperature behavior than mineral oil. These physical and chemical properties can be improved by chemical modification. The aim of this study was to evaluate physicochemical properties and film formation from modified vegetable oils. The vegetable oil was chemically modified by epoxidation reaction with acetic and formic acid using sunflower oils. Viscosity, iodine value, density, acidity value and thermal stability were determined for epoxidized oils. The film formation was analyzed using a HFRR tribometer. The results showed that epoxidized vegetable oils had excellent properties to be used as lubricant, and their tribological performance is higher than mineral oil.

Jul 31, 2018

By Cesar Santos, Marcelo Duarte Silva, Ediron Antônio Lage, Fábio Silva dos Santos

Ceramic filtration technology, despite consuming about 90% less energy than conventional vacuum filters and producing clean water ready for reuse, faced a big challenge that put in doubt its technical and economic viability. In 2015, the production of pellet feed in this last stage of the process of the Minas-Rio Complex of Anglo American was impacted by deep fillings in the filter medium. The chemical regeneration process indicated by the filter manufacturers did not have the necessary effect. SUEZ then carried out a research work on the potential causes and indicated specialty chemicals. After an intense work of the Anglo American technical team supported by SUEZ, an efficient regeneration methodology was developed. From this reference, SUEZ received another 03 similar challenges with ceramic filters. Among them, the Herculano Mineração Dry Stacking pioneer project, which until 2017 could not process more than 20% of the tailings generated in the pellet feed concentration process. Following adaptations in the regenerative methodology as a function of the mineral characteristics facilitated by the development of a pilot backwash system, success was achieved, providing a condition for production of 3.0Mtpy without the use of tailings dam and with continued decline in the unit cost of the tailings filtration operation.

Oct 3, 2019

By Flanelson Maciel Monteiro, Marcondes Mendes de Souza, Mauro Froes Meyer

This research is based on a bibliographical review of a field work that was done in the municipality of Parelhas / RN. The area explored, in turn, is known for its richness of mineral resources that are present in pegmatitic rocks. The general objective of this research is to characterize the main properties of the pegmatites and quartzite, in order to verify the heterogeneity of the elements, to raise a possible viability of extraction for economic purposes. The quartzite also presents a siliceous chemical composition. This rock is a source of bricks and silica refractories used in the steel industry and for the preparation of the blast furnace bed, ornamental rock used in different ways (rustic, carved, polished, among others). However, this research resulted in preliminary data, but it would be interesting to be more detailed in order to evaluate the economic viability of these rocks.

Oct 3, 2019

By Felipe Darabas Rzatki

Polyether ether ketone (PEEK) is a high performance thermoplastic often selected for high temperature tribological applications under chemically aggressive environments. The present work evaluate the tribological behavior of a high performance PEEK composite under ambient and high temperature (30 and 80°C, respectively). The atmosphere was also varied (air or tetrafluorethane). An AMTI tribometer equipped with a hermetic chamber and a heating system was used to carry out sliding tests of PEEK cylinders on 304 stainless steel polished discs (Sq < 10 nm) with reciprocating movement and 175 N normal force. Surfaces roughness analyses were performed with a white light interferometer. As expected, there was a strong influence of temperature on the tribological behavior of the samples tested in ambient atmosphere (25% decrease in friction coefficient associated with a 100% increase in wear rate). On the other hand, samples tested in tetrafluorethane atmosphere showed no significant friction temperature dependence.

Jul 31, 2018

By Pedro Jorge Walburga Keglevich de Buzin

The steel production in mini mills generates several process residues, among them there is the electric arc furnace dust (EAFD). This residue has as main elements Fe, O, and Zn, being classified as hazardous by the presence of Pb and Cd. Thermodynamic studies related to the formation of mineral species containing Fe, O and Zn elements were carried on due to the influence of these compounds in hydrometallurgical EAFD recycling processes. In recent years, a rise in the chlorine content of this residue was observed, mainly motivated by the increased use of scrap with polymeric impurities containing this element. In this work, based on computational thermodynamics tool FactSage, a general overview of gaseous and minerals species (found in EAFD) formed by Fe, Zn, O, Cl, H and C is shown – representing the organic origin of chlorine. For this study, the PVC polymer was used as the chlorine carrier substance which contaminates the EAF load.

Jul 30, 2018

By Paulo Conceição, Carlos Sampaio, Carlos Petter, Ariane Kuerten

The Sensor Based-Sorting technology is an emerging technology applied in mineral separation and concentration. The technique consists in using a method known as Dual Energy X-ray Transmission sorting (DE-XRT). The particle's position over the conveyor belt was evaluated and, despite de variability of results, shows that there is no a position with greater accuracy on the sensor's reading. Results obtained indicated that DE-XRT sorting technology was able to significantly reduce the mass and the ash content of the ore feed, being an interesting option for reduction of costs and improvement of coal quality in beneficiation plants.

Oct 3, 2019

By Agnes Ágata Fróes Martins

Placas ósseas metálicas são componentes utilizados para correção ou cura de fraturas ósseas. Em se tratando de implantes ortopédicos, é fundamental conhecer o comportamento dos materiais quando submetidos a esforços mecânicos. Para isto ensaios são realizados baseados em normas técnicas, que no caso específico de placas ósseas, são utilizadas as normas ASTM F382 e ABNT NBR 15672-2. Na execução do ensaio para determinação da rigidez à flexão, de uma placa óssea, pode existir o efeito da flexibilidade do dispositivo de ensaio. Para verificar a magnitude desse efeito, foram realizados três ensaios de flexão estático e um ensaio de flexibilidade do dispositivo de ensaio, onde o ensaio foi interrompido ao final da fase elástica. As propriedades mecânicas da placa foram avaliadas, aplicando a correção da flexibilidade do dispositivo. Os resultados mostraram que para os níveis de carregamento alcançados, as cargas de prova apresentaram pouca influência na flexibilidade do dispositivo, e consequentemente pouca influência na rigidez após os cálculos de correção.

Aug 8, 2018

By Giulliane Meireles Casali Gonçalves Torres

Os arrebentamentos que ocorrem durante o processo de trefilação geram impacto na produtividade e rendimento operacional em função do retrabalho gerado na realização de solda cada vez que o material se rompe e consequentemente no tempo perdido para execução desta etapa. A metalografia é a ferramenta mais eficiente para caracterização das causas dos arrebentamentos durante a trefilação. Faz-se necessário a utilização de microscopia e aplicação dos reativos específicos destinados a revelar a origem da anomalia. O presente trabalho objetiva mostrar os principais tipos de fraturas na trefilação e suas respectivas origens, através do estudo de quatro casos distintos, são eles: fratura resultante de quebras internas (rupturas centrais), fratura dútil por tração, fraturas resultantes de quebras na solda e fraturas lascadas causadas por formação de “pé de corvo”. Os resultados das análises mostram de forma objetiva se a anomalia foi gerada a partir da matéria prima (defeitos superficiais no fio máquina) ou problemas de processo/operacionais durante a trefilação.

Aug 17, 2017

By Patrizio Damiano

Competitiveness in Electric Arc Furnace production is pushing steelmakers to increase the throughput at the lowest expenditure. The technological challenge is therefore to operate the existing facilities at their top capabilities and to exploit materials and energy sources at the upmost yield and efficiency. Moreover, seizing the opportunity offered from the price variability of metallic feedstock calls for flexible practices, versatile equipment and tools to rapidly tune the melting profiles without hindering steel quality and equipment lifetime. The innovative Danieli Q-MELT Automatic EAF system addresses these aspects implementing a centralized control system which interacts with multiple technological packages. Each of these cutting-edge technologies focuses on one aspect of the EAF cycle, increasing machine availability and resource efficiency, by means of electrode regulation and foamy slag control, charging optimization, off-gas analysis and closed loop injectors control. Moreover, these modules provide the process supervisor application (Melt Model) with important information regarding the process status, thus allowing the adoption of a unified control strategy. The supervisor implements a robust statistical approach to identify process deviations in real time. The first results and technology perspectives inferred from the field immediately after the start-up are described in this paper.

Oct 30, 2017

By Denise Freire Duarte

Desclassificações de corridas por elementos fora da faixa de especificação do tipo do aço que está sendo produzido impactam negativamente nos indicadores da empresa. É esforço contínuo os projetos de melhoria e ações implantadas para a redução dessas desclassificações. Quando uma corrida é desclassificada, há um custo para refazer a corrida perdida, ocorre um processo de reclassificação que fica em estoque aguardando aplicação, perde-se tempo e pontualidade na produção entre outros impactos. Portanto identificar a causa raiz do problema e atuar em ações efetivas e bem implantadas são as chaves para a resolução do problema e melhoramento do processo. O fósforo é um elemento que deve ser controlado pois é item de norma para atendimento às especificações pois impactam na fragilização do material. Este trabalho mostra a análise realizada na busca da causa raiz das ocorrências das desclassificações de fósforo.

Oct 30, 2017

By Elen Mancini Santi Paulettor, Vinicius Calheiros, Eduardo de Oliveira Cabral

At this paper, Eirich will present its new tool for sinter analysis integrated to the sintering control system. For stabilization and optimal, continuous control of the sintering process, QualiMaster MT1, a device was developed which guarantees fully automatic representative sampling and material analysis and thus a high and stable sintering quality. Mining tailings often has a considerable proportion of valuable substances. In addition to this work, we will also present our mixing technology that allows the economic recovery of these mining tailings.

Oct 1, 2019

By LEANDRO RODRIGUES RAMOS

Este trabalho tem por objetivo discutir a abordagem e os resultados referentes à versão do modelo de vazamento direto atualmente instalado na Aciaria da ArcelorMittal Tubarão. Para este trabalho fez-se uso de uma massa de dados histórica de corridas, propondo um novo modelo para predição de composição química (Fósforo e Manganês) ao fim de sopro dos convertedores, baseado em Redes Neurais Artificiais. Em seguida foram avaliados os resultados alcançados e respectivos potenciais de ganho. Desta forma pode-se avaliar e concluir que o uso de técnicas de Machine Learning pode trazer um aumento de produtividade na fabricação de aço minimizando-se os tempos de espera por análises químicas.

Oct 30, 2017