Thermal Analysis of Zinc Sulphide Concentrates and its Relevance to Zinc-Lead Sintering

Sulphide Corporation Pty. Limited has roasted a number of different zinc sulphide concentrates on its sinter machine which pro- duces zinc-lead sinter for an Imperial Smelting Furnace, and results have varied widely. The differences are considered to be functions of !concentrate particle size and reactivity. Amdel have used differential thermal analysis to examine these concentrates and two major effects have been found. Firstly, in concentrates 1containing small quantities of pyrite and chal- L [copyrite, heat is liberated at 400¦C to 650¦C [by oxidation of these two sulphides. Secondly, as particle size decreases, heat release from the oxidation of zinc sulphide commences at flower temperatures and rate of heat release In a sinter bed, the presence of some rite and chalcopyrite would help to heat the cc sulphide to ignition temperature in a orter time, while a finer concentrate would sult in roasting being completed more ickly. Both of these effects result in a arper flame front and minimise the chance heat and combustion fronts being mismatched. is theory is supported by sintering results tained by Sulphide Corporation. As a result