New separation technology for lead and mercury from acid sludge of copper smelting using a total hydrometallurgical process - Mining, Metallurgy & Exploration (2024)

The separation of lead (Pb) and mercury (Hg) from copper (Cu) smelting acid sludge using the carbonization and acidleaching total hydrometallurgical process was investigated. The effects of the excess coefficient of sodium carbonate, excess coefficient of nitric acid, conversion time, conversion temperature, dissolution time, and dissolution temperature on the separation efficiency of Pb and Hg were studied. The test results indicated that when the dosage of sodium carbonate was 2.0 times the stoichiometric ratio, the conversion time was 1.5 h, the conversion temperature was 75 ℃, and the amount of nitric acid was 1.8 times the stoichiometric ratio. Additionally, the dissolution time was 1.0 h, the dissolution temperature was 60 ℃, the ratio of liquid–solid was 5:1, and the separation efficiency of Pb and Hg was 98.72%. This study demonstrated the advantages of a short, simple, and environmentally friendly process for separating Pb and Hg from Cu smelting acid sludge, providing complete separation and introducing a new technology.