New Method for Cyanide Destruction in Gold Mill Effluents and Tailing Slurries

"A new method for oxidative destruction of cyanide in industrial waste waters and slurries, such as gold mill barren liquors, tailing slurries and flotation tailings has been developed at the Inca research laboratories. Rapid decomposition of cyanide and related species is attained by treating the waste waters with a mixture of S02 and air at controlled pH and in the presence of a small amount of copper which acts as a catalyst. The approach selectively oxidizes cyanide and metal cyanide complexes, and also removes iron cyano complexes which are not removed by alkaline chlorination.The new method is shown to be less reagent intensive and therefore more economical than alkaline chlorination for treating gold mill and flotation waste waters. INTRODUCTIONOver 90% of the gold mined in Canada is extracted from the ore by ""cyanidation"". Wastes from the process consist of tailings which contain free cyanide, cyanide combined with heavy metals, thiosalts and thiocyanates. Because of the concern over the effect of toxic cyanides on the environment, all cyanide containing effluents will have to be treated in the future to meet certain government set concentration limits."