Modelling of Two-Phase Flow in a Solvent Extraction Pulsed Column

CFD (Computational Fluid Dynamic) models have been developed and validated for a pulsed column with disk-doughnut internals, as used for solvent extraction. First a single phase model was developed to simulate the turbulent oscillating flow around the internals of the column. This model was successfully validated using detailed PIV measurements of velocity taken at eight different phases through the pulse cycle. Second, the CFD model was extended to allow for a continuous aqueous phase and a dispersed organic phase (kerosene) flowing counter-currently. The model was a two-fluid model that accounts for droplet breakup and coalescence, and solves for droplet size distribution using a population balance model incorporated into the CFX4 package. PDIA (Particle Droplet Image Analysis) measurements were taken on a pilot scale solvent extraction pulsed column to determine droplet size distribution for calibration and validation of the CFD model. The measurements were made under pulsing intensities ranging from 10 mm/s to 32.5 mm/s.