Formation and Particle Size of Jarosite

The rate of precipitation of ferric iron as ammonium jarosite, NH4.Fe3(SO4)2(0H)6 from acidic solutions near 100¦C, was found to increase with weight of jarosite seed crystals, and with concentration of ammonium ion, but to decrease with increasing acidity. The particle size of the product crystals was larger at low sulphate concentrations and at high ammonium concentrations. Particles appeared to be agglomerates, with diameters ranging from 0.5 up to 25 um, and composed of individual crystals of diameters ranging from 2 um apparently down to 0.1 um or Lass